JPS6140207A - Cosmetic - Google Patents

Abstract

PURPOSE:Cosmetic capable of showing positively effects of active ingredients in cosmetic, obtained by adding a gas selected from carbon dioxide, hydrogen sulfide, and radon to an oily base, blending cosmetic with the base. CONSTITUTION:A gas selected from carbon dioxide, hydrogen sulfide, and radon is introduced into an oily base such as a vegetable oil, animal oil, synthetic oil, fatty acid, natural or synthetic fatty acid triglyceride, etc. at low temperature - temperature under heating, and 50-3,000ppm gas is dissolved and contained in it. The only base containing the gas is emulsified directly or by the use of a surface active agent, to give a water-in-oil type emulsion or an oil-in-water type emulsion, which is blended with cosmetic. An oily cosmetic having >=40wt% of the oily base, especially an oily cosmetic, free from water phase part is preferable.

Description

[Detailed Description of the Invention] [Field of Industrial Application] The present invention is effective in skin or hair cosmetics by blending a specific gas into an oily base, as long as the cosmetics are suitable. This invention relates to cosmetics that can more actively express the effects of ingredients.

[Prior art]

Conventional cosmetics include creams, lotions, milky lotions,
Lotions, hair tonics, and hair liquids using aqueous ethanol solutions are mainly used, but these cosmetics are designed mainly based on the feeling of use, and the effects of the active ingredients contained in the cosmetics are mainly used. The current situation is that the design is not designed to actively express this.

[Problem that the invention seeks to solve]

In cosmetics, it is desired that the effects of active ingredients such as physiologically active substances and pharmacologically active substances contained in the cosmetics can be fully expressed, as well as the feeling of use.

[Means for solving problems]

In view of the current situation, the present inventor conducted extensive research in order to obtain a cosmetic that can fully exhibit the effects of the active ingredients contained in the cosmetic without changing the feel of the cosmetic. The present invention has been completed based on the discovery that a cosmetic that meets the above objectives can be obtained by using an oily base containing one or more gases selected from carbon, aqueous sulfide, and radon.

That is, the present invention provides a cosmetic containing an oily base containing lam or two or more gases selected from carbon dioxide, hydrogen sulfide, and 1o-radon.

The oily base used for non-exploited BAK can be any oily base used in cosmetics, such as vegetable oils, animal oils, synthetic oils, silicone oils, fatty acids, and natural or synthetic fatty acid triglycerides. .

Vegetable oils include olive oil, almond oil, jojoba oil, peanut oil, evening primrose oil, macadamia nut oil, castor oil, coconut oil, cacao butter, gnome oil, gnome kernel oil, safflower oil, and sunflower oil. oil, safflower oil, hydrogenated coconut oil, hydrogenated lumber oil, agocado oil, glaze oil, do oil, sesame oil,
Examples include tzanka oil, soybean oil, camellia oil, corn oil, rapeseed oil, persic oil, cottonseed oil, Japanese wax, and carnauba wax. Examples of animal oils include lanolin and dinolin fermentation conductors, turdle oil, guinea pig oil, mink oil, beeswax, stanlan, squalene, noristane, beef tallow,
Examples include hydrogenated oil, lard, egg yolk oil, shellac, and honey. As a synthetic oil, daughter, fluid IQ rough-in, α-olefin oligomer, fluid? Liisoptylene, silistan,
Vaseline, No-Q Laugh-in, etc. are being discontinued. Examples of fatty acids include linear saturated fatty acids such as hexanoic acid, hezotanoic acid, octanoic acid, and nonanoic acid: 2-ethylhexanoic acid, incasilonic acid, 2-methylundecanoic acid, 3-methyltocosanoic acid, 2,2-methyldodecanoic acid, methyltetradecanoic acid,
2-ethyltetradecanoic acid, 2-propyltridecanoic acid, 2-butyldodecanoic acid, 2-pentylundecanoic acid,
Branched saturated fatty acids such as 2-he-ff-runonanoic acid, 2,3-zomethylteto-2decanoic acid, 2-ethylhexadecanoic acid, 2-hebutylundecanoic acid, 2-butyltetradecanoic acid, isostearic acid, and emery-type instearic acid; 3
-hexenoic acid, 4-hexenoic acid, 6-hezothenic acid, 3-
Octenoic acid, 2-decenoic acid, 4-decenoic acid, 9-undecenoic acid, 10-undecenoic acid, 3-dodecenic acid, cis-
9-tridecenoic acid, 4-nato-2decenoic acid, cis-9-hexadenoic acid, cis-7-hebuta-7'cenoic acid, cis-8
-hesitadecenoic acid, cis-9-hetudecenoic acid, cis-
Straight chain monoenoic fatty acids such as 7-octadecenoic acid, cis-8-octadecenoic acid, cis-9-nonadecenoic acid, cis-11-eicosenoic acid; trans-2-methyl-2-pentenoic acid, cis-2-methyl-2 -hexenoic acid, 2-methylenehexanoic acid, methacrylic acid, 2-ethylhexanoic acid,
Branched monoene fatty acids such as 3-methyl-2-nonenoic acid, 3-methyl-3-nonenoic acid b L8-)-ze<-dimethyl-2-dodecenoic acid &; linoleic acid, trans-10,
cis-12-octadecasier, n#, cis-9. cis-
i i -yi-p Sea, tri or tetraene & fatty acids such as tadecacienic acid, lylunic acid, aquidonic acid, cur79nodonic acid; z-hexic acid, 2-hebutic acid, 2-octynic acid, 7- Octenoic acid, 2-nonynoic acid, 2-decynoic acid, 6-unzosic acid.

6-dobsic acid, 7-dobsic acid, 6-trypsin powder,
Acetylene fatty acids such as 8-trypsin powder can be removed. We also use natural and synthetic fats.
As the glyceride, for example, tributyrin (4-4t
4),) Ricazoμin (6,6,6),) Ricasilyrin (8°8.8in, l-casilloyl-2,3-diolein (6,18', 18'), l-en2ide- 2,3-cycanoliline (8,8,18'), l-lyluo2.3-cycanoliline (8,8°18''), 1-cabusoliru2.
3-zoolein (8-18'=18')%) linnanin (9t9-9),) lycazoline (10,10゜1
0), l-9 uro-2,3-cycaprin (101l O
-12), l-myrist-2゜3-cicazoline (10
, 10, 14), l-oleo-2,3-cicazoline (1
0,10゜18')% l-elide 2,3-cicazoline (10-10#1g'), l-lyluo-2゜3-cicazoline (10,10,18''), 2-oleide i, a-
Cicaprine (io, is'.

10), l-capryl-2,3-zoolein (10,1
8', 1B'), l-casolyl-2゜3-thiethiison (10,18', 18'), l-oleo-2#3-zo2
Urine (12°12.18'), l-ethizono2,
3-Zolaurin (12,12,18')% l-Ryluo2.3-Zolaurin (12,12,18'') 2-oleo-1,3-Silaurin (12°18', 12), l
-Silalow 2,3-zoolein (12#l 8'#
l 8'L l-2uro-2,3-zolyluin (12
, 18', 18'), l-oleo-2,3-simiristin (14°14.18'), l-oleo-2,3-simiristin (14114,18''), l-, myrist-
2,3-diolein (14,18'.

18'), l-myristo-2,3-zolyluin (14,
18", 18"), l-no-Q-lumito-=2.3-diolein (16,18', 18'), 1-no-Q-lumi)-2
, 3-zolyluin (16, l 8", 18"), l-
Steer"-2t 3-diolein (18a 18',
18')% I-stearo-2,3-zolylin (18
゜18"l 8 // ), triolein (18'.

is’, is’), triolein (18“.

18'', l8'), 2-stearo-1,3-diolein (18', 18.18'), and the like.

Furthermore, as silicone oils, methyl siloxane, methyl phenyl siloxane, and zomethyl? Risiloxane? Liethylene glycol copolymer, zomethyl? Examples include phosphorusoxane borizolobylene glycol copolymer, cyclic zomethylsiloxane, dimethyltrimethylpolysiloxane, amine silicone, methylhydrozoene polysiloxane, and the like. These oils, fatty acids and fatty acid triglycerides can be used alone or in combination with 2. It can be used as a mixture of m or more.

In order to incorporate carbon dioxide, hydrogen sulfide or radon into these oil-based bases, it is sufficient to blow the gas into the oil-based base at a low to slightly elevated temperature and dissolve it under normal pressure or increased pressure. .

The amount of the gas contained in the oily base is 50 to 300%
0 ppm is preferable □ The oil base containing carbon dioxide, hydrogen sulfide or radon in this way can be used as it is or by emulsifying it with a surfactant to form a water-in-oil emulsion, an oil-in-water emulsion, etc. It can be incorporated into cosmetics in various forms.

The cosmetic of the present invention contains the oily base in an amount of 15% by weight of the total composition.
Above, preferably 40! : Fit% or more of oil-based cosmetics are preferred, and oil-based cosmetics without an aqueous phase are particularly preferred.

Examples of such oil-based cosmetics include creams such as cleansing creams, foundations, long oils, hair tonics, hair liquids, etc. Examples include mart, cosmetic oil, etc.

Even if the cosmetic of the present invention only contains the oily base,
The oil is well absorbed through the skin and provides good effects, but when an active ingredient such as a physiologically active or pharmacologically active substance is further added, the skin absorption of the active ingredient is extremely good.

Examples of such active ingredients include the following four.

Vitamins niretenol, retinol acetate, retinol lumitate, dehydroretinol, ercocalciferol, a-α-tocopherol, #-α-tocopherol acetate, a-α-tocopherol calcium succinate, ubiquinone, phytonadione, menaquinone, Menazoone, thiamin hydrochloride, thiamin nitrate, thiamin phosphate, riboflavin, funpin mononucleotide, Sumetsubibutyrate, pyridoxine hydrochloride, pyridoxal 5'-phosphate, pyridoxine cazolylate, ZonoQ pyridoxine rumitate, TorinoQ Pyridoxine rumitate, dianocobalamin, hydroxycobalamin, deoxyadenomylcobalamin, methyl; basimin, nicotinic acid, nicotinic acid amide, nicotine powder benzyl, No-Q
Calcium Ntothenate, Sodium Ntothenate, 7
9-totenyl alcohol, cycarboethoxylate, ethyl ester, zolopyrene glycol solution, acetyl-9-totenyl ethyl ether, 9-totenyl ethyl ether, piotin, folic acid, choline, inositol,
Ascorbic acid, sodium ascorbate, ascorbyl stearate, noq-lumitin powder ascorbyl, dino-9 ascorbyl rumitate.

Hormone agent 22st 2zool, estrone, ethinyl est 2zool, quethylstilbestol, hexestrol, cortisone, hydrocortisone, zolednisone, zolednisolone, sequestering agent: edetate disodium, sodium citrate, sodium polyphosphate , sodium metaphosphate, gluconic acid, urocanic acid as a UV absorber, 4
-2-ethoxyethyl methoxycinnamate, ethyl noq-aminobenzoate, 2-'(2-hydroxy-5-methylphenyl)benzotriazole, 2-hydroxy-4
- methoxybenzo V-phenone, m-inflammatory agent near 2 toin,
Aloe powder, icta-7-al, guaiazulene, sodium guaiazulene sulfonate, glycyrrhizinic acid, zopotassium glycyrrhizinate, monoammonium glycyrrhizinate, β-glycyrrhetinic acid, glycyrrhetinyl stearate, stearyl glycyrrhetinate, methyl salicylate, hinokitiol.

Astringent: Nianthine dihydroxyaluminum, allantoin dihydroxyaluminum, aluminum hydroxychloride, zinc chloride, aluminum chloride, ferric chloride, cashmine, dry aluminum potassium sulfate, /e zinc roughenol sulfonate.

Bactericidal agents: benzoic acid, sodium chloride, salicylic acid,
Sodium salicylate, Nlupine iron, Nlubin potassium, dehydroacetic acid, sodium dehydroacetate, ethyl benzoate, butyl butyloxybenzoate, I
Norovir Q laoxybenzoate, /9. F methyl oxybenzoate, inzolobyl methylphenol, cresol,
Chlorxylenol, thymol, IQ lachlorphenol, resorcinol, g-element No. 101, photosensitive No. 8201, Ri”y MinT %thianthole, lysozyme chloride%m
Rhexisone acid, chlorhexicine gluconate, trichlorocarbanilide, 3-trifluoromethyl-4,
4'-Zochlorocarpanilito, hexachloro7ene, boric acid.

Antiperspirant, deodorant: aluminum chloride, aluminum sulfate, aluminum acetate, aluminum 7-mer sulfonate, sodium perborate.

Hair preparations selenium disulfide, alkylisoquinolinium bromide, cinpyrithione, biaenamine, thianthol,
Cantharis tincture, ginger tincture, capsicum tincture, bromine FIR potassium, sodium bromate.

Moisturizer: glycerin, sodium chondroitin sulfate,
l, 3-butylene glycol, sodium lactate, maltitol, xylitol, amino acids.

Herbal medicines (powders, solvent extracts, extracted extracts),
Byakujutsu, Kakatsuku, Keigai, Kouboku, Senkyu, Spruce, Touki, Shokyoku, Peony,
Aukaku - Scutellariae, Sanshin, Keihi, Nijinzon, Pukryoku, Dokugaku, Calamus, Gaiyou, Matsubusa,
Byakushi, Juyaku, Wikyo, Chimpi, Kambi,
Chamomile.

Sebum secretion promoter: ■ General formula (wherein R is a saturated aliphatic hydrocarbon having a total of 11 to 23 carbon atoms and having at least one alkyl substituent from the carboxyl group bonding position to the center of the main chain) Branched fatty acid cholesteryl ester O represented by (representing a group) r-Oryza, Nor.

■ Yokuinin or Yokuinin extract with a molecular weight of 15
00 or less.

These active ingredients are usually blended in an amount of 0.01 to 20% by weight, preferably 0.05 to 10% by weight.

[Effect]

The cosmetic of the present invention is a base and a composition thereof that can more actively express the effects of the active ingredients contained therein. The mechanism of action is not clear, but it is presumed that the carbon dioxide, hydrogen sulfide, or radon contained in the oily base promotes skin blood flow and skin absorption of the active ingredient.

〔Example〕

Next, the present invention will be explained with reference to Examples.

Example 1 Cleansing cream: ■ Norifin 4.
0 parts by weight ■ Setanol
1.0■ Vaseline 20.
0 ■ Linoleic acid 30.0
■Glyceryl monostearate 2,5■
Zorobilene glycol 3.0■ Glycerin 2.0■ a-α-tocopherol 3.0L Purified water
Mix a total of 100 ■■ and heat it to about 45°C, put it in a pressure-resistant container, and keep it at 3 atm while blowing in carbon dioxide for 30 minutes. After blowing in carbon dioxide, add ■■■■■, mix well, and keep at 60°C. Add the mixture of ■■ [phase] that was separately kept at 60'C, stir, and homogenize using a homogenizer. , cool to room temperature and form a product.

Example 2 Using the Kuri Renzon Cream prepared in Example 1 and a control cleansing cream, the make-up makeup was wiped off.
Furthermore, after washing with water, evaluation was conducted with 10 female subjects.
I had a friend use it on both her left and right cheeks.

In addition, the cleansing cream of the control product was manufactured using the manufacturing method of Example 1 without performing the process of blowing carbon dioxide into ■■. The results are shown in Table 1.

-1st surface hair oil: ■ Camellia oil 75.0 parts by weight ■ Methyl? Resiloxane (leg) 20.0 ■ a-
α-tocopherol 5.0 ■ and ■ are mixed, placed in a sealed container, radon is blown into the container at normal pressure for 1 minute, then ■ is added, and the mixture is thoroughly mixed to form a product.

When five women used the uninvented hair oil for one week, the frequency of itching was significantly reduced compared to a commercially available hair oil containing camellia oil divided by camellia oil.

Example 4 Hair liquid: ■Stawa 2-in 8.01 parts ■Instearin@io.

■ Cyclic dimethylsiloxane 3.0 ■ ?
Lyoxyethylene ethyl 0.8 alcohol ether■ Inocetyl isostearate 8.0■
Guaiazulene 0. O1■ Ethanol 45.0■ Sodium lactate 0.l■ Purified water
Balance meter 100 ■■■ was mixed, placed in a counter-pressure container, and carbon dioxide was blown in at 3 atm for 30 minutes, then ■ - ■ were added and heated to about 45℃, and ■ previously heated to about 45℃ ■Mix to make a product.

When 10 men used this hair liquid for a week, most of the 7 men who had occasionally felt itching stopped feeling itchy.

Example 5 Yarimard: ■ Liquid Norifin 35 parts by weight ■
White petrolatum 50 ■ Isopropyl lanolin 5 ■ Rava / 5 total 100 After heating and dissolving ■ ~ ■ at 60℃, keep at 3 atm for 15 minutes while blowing carbon dioxide, cool to 45℃, and then fill in a container. and make it into a product.

Example 6 Sulfur-containing cosmetics: ■ Precipitated sulfur 0.53 iU part ■
Purified 2 Norin 4.5 ■ NoQ Nuffin 6 ■ Cetostearyl alcohol
4. White Vaseline 85 After heating and dissolving 1 to 2 at 55 DEG C., hydrogen sulfide is blown into the solution at normal pressure for 10 minutes, and the product is prepared after cooling to room temperature.

LOL Example 7 Cosmetic oil: ■ Stawann 27.0 parts by weight ■ Linoleic acid 53.0 ■
, (2) are mixed, heated to about 45°C, placed in a pressure-resistant container, kept at 3 atm for 30 minutes while blowing in carbon dioxide, then (2) is added thereto, and stirred well to obtain a product.

When people used this product, they found that it made their skin feel softer and moisturized than previous products.

that's all

Claims (1)

[Claims] 1. A cosmetic containing an oily base containing a gas selected from the group of carbon dioxide, hydrogen sulfide and radon.