JPS61274938A - Manufacture of vinyl chloride decorative material - Google Patents

Manufacture of vinyl chloride decorative material

Info

Publication number
JPS61274938A
JPS61274938A JP11825785A JP11825785A JPS61274938A JP S61274938 A JPS61274938 A JP S61274938A JP 11825785 A JP11825785 A JP 11825785A JP 11825785 A JP11825785 A JP 11825785A JP S61274938 A JPS61274938 A JP S61274938A
Authority
JP
Japan
Prior art keywords
vinyl chloride
layer
chloride layer
electron beam
decorative material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11825785A
Other languages
Japanese (ja)
Inventor
青山 栄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP11825785A priority Critical patent/JPS61274938A/en
Publication of JPS61274938A publication Critical patent/JPS61274938A/en
Pending legal-status Critical Current

Links

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は塩化ビニル化粧材の製造方法に関するものであ
る。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a method for producing a vinyl chloride decorative material.

(従来の技術) 塩化ビニル化粧材、とくに発泡品は軟かな仕上げのもの
が多く、肌ざわシはよいが、素材感や強度等に不満があ
り、とくに強度は耐久性に影響し、高発泡品のように容
積が犬きく立体感のあるものは傷が付いたり、彼れが生
じたシし易いために長持しないという欠点があった。そ
のために全体を硬く仕上げて強度の向上した化粧材が求
められるようになった。
(Conventional technology) Many vinyl chloride decorative materials, especially foamed products, have a soft finish and feel good on the skin, but are dissatisfied with the feel and strength of the material.In particular, strength affects durability, and high foaming Items that have a large volume and a three-dimensional appearance, such as products, have the disadvantage that they do not last long because they are easily scratched or scratched. For this reason, there has been a demand for decorative materials that have an overall hard finish and improved strength.

(考案の目的及び問題点) 本考案は上述の従来品の欠点を改善すべくなされたもの
で、任意の基材と、その上に形成された塩化ビニル層を
有する化粧板において該塩化ビニル層、とくに嵩高かつ
発泡塩化ビニル層の表面を有するものの表面及びこの層
全体を硬化させることにより、表面の発泡塩化ビニル層
の耐久化をはかろうとするものである。
(Purpose and Problems of the Invention) The present invention was made to improve the drawbacks of the conventional products described above. In particular, by curing the surface and the entire layer of a bulky material having a surface of a foamed vinyl chloride layer, the durability of the foamed vinyl chloride layer on the surface is attempted to be increased.

C問題点を解決するための手段) 上述の問題点を解決するために本発明は任意の基材とそ
の表面に形成された塩化ビニル層からなる化粧シートの
製造において等に表面層が軟質の塩化ビニル発泡体より
なる場合において、該塩化ビニル層中に予め、電子線に
よって硬化反応する成分を混入させておき、加熱加工し
、またはしないで、その上に電子線を照射して該層を硬
化することを要点とするものである。
Means for Solving Problem C) In order to solve the above-mentioned problems, the present invention provides a method for manufacturing a decorative sheet consisting of an arbitrary base material and a vinyl chloride layer formed on the surface thereof, in which the surface layer is soft. In the case of a vinyl chloride foam, a component that is hardened by an electron beam is mixed into the vinyl chloride layer in advance, and the layer is irradiated with an electron beam with or without heat processing. The main point is that it hardens.

(作 用) 本発明は上述の構成となっているので通常の塩化ビニル
の配合では可塑剤の量や種類を変えたり、樹脂や充填剤
を工夫したりしても得られない風合や硬さのものが得ら
れ、特に図柄が石や砂、塗壁の強度があるので傷や破れ
に対しての耐久性が大で従来品よりも耐久性が生ずるも
のである。
(Function) Since the present invention has the above-mentioned structure, it has a texture and hardness that cannot be obtained with ordinary vinyl chloride formulations, even by changing the amount and type of plasticizer or devising resins and fillers. In particular, since the design has the strength of stone, sand, and painted walls, it is highly resistant to scratches and tears, making it more durable than conventional products.

(実施例) 本発明の実施例について第1図の工程説明図によって説
明する。lは基材で原反ロール2に巻かれガイドロール
や送りロール群3を通り、次いで後述の配合よりなる多
官能基を有するアクリレート、発泡剤等を含んだ塩化ビ
ニルに一ストレジンの配合物4を上記紙等の基材1の上
にコーティングし、加熱炉5で発泡させ、エンゴス工程
6でエンがスを行い次いで電子線照射装置7で電子線照
射を行って塩化ビニル層を硬化して硬化塩化ビニル層2
を形成した後、冷却ロール8を経て巻取りロール9に巻
き取られる。
(Example) An example of the present invention will be described with reference to process diagrams shown in FIG. 1 is a base material, which is wound around a raw roll 2 and passed through a guide roll and a feed roll group 3, and then a mixture 4 of vinyl chloride and one strain resin containing an acrylate having a polyfunctional group, a blowing agent, etc., as described below. is coated on a base material 1 such as the above-mentioned paper, foamed in a heating furnace 5, energized in an engosing step 6, and then irradiated with an electron beam in an electron beam irradiation device 7 to harden the vinyl chloride layer. Cured vinyl chloride layer 2
After forming, the film is passed through a cooling roll 8 and wound onto a winding roll 9.

基材1としてはシート状のもの板状のもの等が任意に使
用できる。また多官能基を有し、電子線照射により硬化
する成分としてはアクリレートがよく、ポリオールアク
リレート、ポリエステルアクリレート、ウレタンアクリ
レート、エポキシアクリレート等が使用できる。
As the base material 1, a sheet-like material, a plate-like material, etc. can be arbitrarily used. Further, as a component having a polyfunctional group and curing by electron beam irradiation, acrylate is preferred, and polyol acrylate, polyester acrylate, urethane acrylate, epoxy acrylate, etc. can be used.

電子線照射により硬化する成分と発泡剤を含有する塩化
ビニルペースト4の配合の1例を示せば下表の通りであ
る。
An example of the formulation of vinyl chloride paste 4 containing a component that hardens by electron beam irradiation and a foaming agent is shown in the table below.

可塑剤 D OP      50 多官能アクリレート  トリレンジイソシアネート  
20充填剤 caco350 顔   料  TiO□             2
0発 泡 剤  AZ−8(商品名、大塚化学社)  
7安定 剤  KF−80D−2(商品名、共同薬品社
)基材1として壁紙用裏付紙80AF−10(重陽国策
パルプ社製)に200μの厚さで塗布し、加熱炉5で2
00’でω秒の条件で発泡させ、エンデス工程6でエン
デスを施したあと電子線照射装置7で電子線照射を行い
、軟質の発泡体エンボスした塩化ビニル層を硬化して硬
化したエン?ス発泡塩化ビニル層2を形成することがで
きた。
Plasticizer D OP 50 Polyfunctional acrylate Tolylene diisocyanate
20 Filler caco350 Pigment TiO□ 2
0 Foaming agent AZ-8 (product name, Otsuka Chemical Co., Ltd.)
7 Stabilizer KF-80D-2 (trade name, Kyodo Yakuhin Co., Ltd.) was applied to wallpaper backing paper 80AF-10 (manufactured by Chūyo Kokusaku Pulp Co., Ltd.) as the base material 1 at a thickness of 200μ, and heated in a heating furnace 5 for 2
Foaming was carried out under the conditions of 00' and ω seconds, and after being endowed in an ending step 6, electron beam irradiation was performed in an electron beam irradiation device 7 to harden the soft foam embossed vinyl chloride layer. The foamed vinyl chloride layer 2 could be formed.

(効 果) 本発明は上述の構成となっているので基体上に通常軟質
で嵩のある塩化ビニル発泡体を表面にもつエンゲス加工
したものでは使用中に破損し易く、従って耐久力が乏し
いが、本発明の方法によってエンがス加工して、電子線
照射した硬化塩化ビニル層を有する化粧板は強度が大と
なり硬い仕上りとなり耐久性も大きく、従来の欠点を改
善することができた。
(Effects) Since the present invention has the above-mentioned structure, if the base material is usually engraved and has a soft and bulky vinyl chloride foam on its surface, it will easily break during use and will therefore have poor durability. A decorative board having a hardened vinyl chloride layer that has been engraved by the method of the present invention and irradiated with electron beams has increased strength, a hard finish, and great durability, and has been able to improve the conventional drawbacks.

また上記の配合中、発泡剤を使用しないものにおいても
、電子線照射によって塩化ビニル層を硬化させてこの層
の強度を増し、耐久性を大ならしめることができるもの
である。
Furthermore, even in the above formulation, even when no blowing agent is used, the vinyl chloride layer can be cured by electron beam irradiation to increase the strength of this layer and increase its durability.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に係る塩化ビニル化粧材の製造方法の工
程説明図である。 1・・・・・・基体(紙)   2・・・・・・原反ロ
ール3・・・・・・ロール群 4・・・・・・塩化ビニル配合物(電子線照射による硬
化する組成物) 5・・・・・・加熱炉     6・・・・・・エンゴ
ス工程7・・・・・・電子線照射装置 8・・・・・・
冷却ロール9・・・・・・巻取りロール
FIG. 1 is a process explanatory diagram of a method for producing a vinyl chloride decorative material according to the present invention. 1...Base (paper) 2... Raw roll 3... Roll group 4... Vinyl chloride compound (composition that hardens by electron beam irradiation) ) 5... Heating furnace 6... Engos process 7... Electron beam irradiation device 8...
Cooling roll 9... Winding roll

Claims (2)

【特許請求の範囲】[Claims] (1)任意の基材と、その表面に形成された塩化ビニル
層とからなる化粧シートの製造において、該塩化ビニル
層中に予め電子線によつて硬化反応する成分を混入させ
ておき、電子線をその上から照射して上記塩化ビニル層
を硬化せしめることを特徴とする塩化ビニル化粧材の製
造方法。
(1) In the production of a decorative sheet consisting of an arbitrary base material and a vinyl chloride layer formed on the surface thereof, a component that is cured by electron beams is mixed into the vinyl chloride layer in advance, and A method for producing a vinyl chloride decorative material, comprising curing the vinyl chloride layer by irradiating the vinyl chloride layer from above.
(2)上記配合の塩化ビニル層中に更に発泡剤を含有せ
しめておき加熱加工後にその表面を電子線照射して該層
の硬度を上げることを特徴とする特許請求の範囲第1項
記載の塩化ビニル化粧材の製造方法。
(2) A blowing agent is further contained in the vinyl chloride layer of the above formulation, and after heat processing, the surface thereof is irradiated with an electron beam to increase the hardness of the layer. Method for manufacturing vinyl chloride decorative materials.
JP11825785A 1985-05-31 1985-05-31 Manufacture of vinyl chloride decorative material Pending JPS61274938A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11825785A JPS61274938A (en) 1985-05-31 1985-05-31 Manufacture of vinyl chloride decorative material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11825785A JPS61274938A (en) 1985-05-31 1985-05-31 Manufacture of vinyl chloride decorative material

Publications (1)

Publication Number Publication Date
JPS61274938A true JPS61274938A (en) 1986-12-05

Family

ID=14732141

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11825785A Pending JPS61274938A (en) 1985-05-31 1985-05-31 Manufacture of vinyl chloride decorative material

Country Status (1)

Country Link
JP (1) JPS61274938A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010069729A (en) * 2008-09-18 2010-04-02 Okamoto Ind Inc Heat molding decorative sheet and method for producing the same
JP2013043441A (en) * 2011-08-26 2013-03-04 Dainippon Printing Co Ltd Method for producing foamed laminate sheet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010069729A (en) * 2008-09-18 2010-04-02 Okamoto Ind Inc Heat molding decorative sheet and method for producing the same
JP2013043441A (en) * 2011-08-26 2013-03-04 Dainippon Printing Co Ltd Method for producing foamed laminate sheet

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