JPS6127440B2 - - Google Patents
Info
- Publication number
- JPS6127440B2 JPS6127440B2 JP54025944A JP2594479A JPS6127440B2 JP S6127440 B2 JPS6127440 B2 JP S6127440B2 JP 54025944 A JP54025944 A JP 54025944A JP 2594479 A JP2594479 A JP 2594479A JP S6127440 B2 JPS6127440 B2 JP S6127440B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- alkyl
- leather
- fur
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 239000010985 leather Substances 0.000 claims description 13
- 239000003945 anionic surfactant Substances 0.000 claims description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 6
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000003093 cationic surfactant Substances 0.000 description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 5
- 241000289581 Macropus sp. Species 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000005238 degreasing Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
本発明は皮革乃至毛皮の製造工程で使用して、
あるいは皮革乃至毛皮製品の洗浄時に使用して、
これらに柔軟性を付与できる処理剤組成物に関す
る。
皮革乃至は毛皮の処理剤には古くから石鹸、ア
ルキルアリールスルホン酸塩、高度硫酸化油、ア
ルキル硫酸エステル塩で例示されるアニオン界面
活性剤やポリオキシエチレンアルキルフエニルエ
ーテル、ポリオキシエチレンアルキルエーテル、
ポリオキシエチレン脂肪酸エステル、ポリオキシ
エチレンアミノエーテルなどで例示されるノニオ
ン界面活性剤が汎用されている。
しかし、アニオン界面活性剤には動物質蛋白質
を変化させる性質があるため、これを単独で使用
すると皮革乃至毛皮の柔軟性が失われてしまう欠
点があり、またノニオン界面活性剤にも皮革乃至
毛皮の風合を損うという欠点がある。そこで従来
技術は前記の如き欠点の解決手段として、加脂剤
を併用する方法の外、特公昭44−24509号公報に
見られるようにアニオン界面活性剤と脂肪族アミ
ンオキシドあるいは両性界面活性剤との併用法な
どを提案している。しかしながら、皮革乃至毛皮
の柔軟性に限つて言えば、上記した従来技術は何
れも充分に満足できる程の柔軟性を皮革乃至は毛
皮に付与することができず、この点で従来技術は
改良の余地を残している。
本発明者らはこれらの事情を鑑みて、皮革乃至
毛皮に柔軟性を付与できる処理剤組成物を開発す
べく鋭意研究を重ねた結果、特定なカチオン界面
活性剤とアニオン界面活性剤とのコンプレツクス
が目的とする柔軟性付与に極めて効果的であるこ
とを見い出した。
而して本発明に係る皮革・毛皮用処理剤組成物
は、第四級アンモニウム塩カチオン界面活性剤と
アニオン界面活性剤とのコンプレツクスを含有す
ることを特徴とする。本発明に於て、第四級アン
モニウム塩型カチオン界面活性剤は式：
（但し、R1，R2は炭素数１〜22のアルキル基
又はヒドロキシアルキル基で、少なくとも一方は
炭素数６〜22のアルキル基又はヒドロキシアルキ
ル基であり、R3，R4は炭素数１〜４のアルキル
基、ベンジル基、（−CH2CH2O）−nH，ｎ＝１〜
３，Ｘは一価のアニオンで四級化剤の残基であ
る）で示されるカチオン界面活性剤であることを
可とし、特にモノ長鎖アルキル型第四級アンモニ
ウム塩であることが好ましい。またアニオン界面
活性剤は石鹸、アルキルベンゼンスルホン酸塩、
アルキル硫酸エステル塩、ポリオキシエチレンア
ルキルエーテル硫酸エステル塩、ポリオキシエチ
レンアルキルフエニルエーテル硫酸エステル塩、
オレフインスルホン酸塩及びパラフインスルホン
酸塩からなる群から選ばれる１種もしくは２種以
上であることを可とする。
本発明の処理剤組成物は水中で第四級アンモニ
ウム塩型カチオン界面活性剤とアニオン界面活性
剤を反応せしめてコンプレツクスを生成させるこ
とにより通常調製されるが、両界面活性剤は第四
級アンモニウム塩型カチオン界面活性剤１モル当
りアニオン界面活性剤0.7〜1.3モルの、好ましく
は0.8〜1.2モルの割合で使用される。アニオン界
面活性剤の使用量が0.7モルより少ない場合並び
に1.3モルより多い場合は、生成するコンプレツ
クスのカチオン電荷とアニオン電荷のバランスが
かなり崩れるため、コンプレツクスの皮革乃至毛
皮に対する親和力が低下して好ましくない。
本発明のコンプレツクスは水への溶解性が悪
い。このため処理剤組成物の調製に当つては、分
散媒たる水を撹拌しながら所定量の第四級アンモ
ニウム塩型カチオン界面活性剤とアニオン界面活
性剤を添加するか、あるいは予め水に適当な分散
剤、例えばポリオキシエチレン系ノニオン界面活
性剤を添加し、分散剤の存在下にコンプレツクス
を生成させる方法が推奨される。
本発明の処理剤組成物は皮革乃至毛皮の製造工
程、例えば脱脂及び／又は染色工程で使用できる
外、皮革乃至毛皮製品の洗浄時にも使用できる
が、何れの場合も処理剤、組成物中のコンプレツ
クス濃度は少なくとも0.05重量％、好ましくは
0.2〜2.0重量％にある。そしてこの濃度範囲でコ
ンプレツクスを含有する限り本発明の処理剤組成
物は皮革乃至毛皮に対して所望通りの柔軟性を付
与することができ、加えて当該処理剤組成物には
或る程度の脱脂並びに洗浄効果を期待することも
できる。
実施例
(1) 処理剤組成物の調製
ジエツトアジテイターを具えた容器に100重量
部の水と１重量部の分散剤リポノツクスNC6E
（商品名：ライオン油脂(株)製）を加えて約80℃に
加温し、これをかきまぜながら表−１に示すアニ
オン界面活性剤とカチオン界面活性剤を表−１に
示すモル比で徐々に加えた。しかる後、容器内の
分散液に高剪断力を加えながら冷却して処理剤組
成物Ａ〜Ｈを調製した。
The present invention can be used in the manufacturing process of leather or fur,
Or use it when cleaning leather or fur products,
The present invention relates to a processing agent composition that can impart flexibility to these materials. Leather and fur treatment agents have long been used as soaps, alkylaryl sulfonates, highly sulfated oils, anionic surfactants such as alkyl sulfate salts, polyoxyethylene alkyl phenyl ethers, and polyoxyethylene alkyl ethers. ,
Nonionic surfactants such as polyoxyethylene fatty acid ester and polyoxyethylene amino ether are widely used. However, since anionic surfactants have the property of changing animal proteins, they have the disadvantage of causing loss of flexibility in leather or fur when used alone; The disadvantage is that it spoils the texture of the product. Therefore, as a means to solve the above-mentioned drawbacks, conventional techniques have not only used fatliquoring agents in combination, but also used anionic surfactants and aliphatic amine oxides or amphoteric surfactants, as seen in Japanese Patent Publication No. 44-24509. We are proposing ways to use them in combination. However, when it comes to the flexibility of leather or fur, none of the above-mentioned conventional techniques can give leather or fur enough flexibility, and in this respect, the conventional techniques cannot be improved. leaving room. In view of these circumstances, the inventors of the present invention have conducted extensive research to develop a treatment composition that can impart flexibility to leather or fur. It has been found that Tuxus is extremely effective in imparting the desired flexibility. The leather/fur treatment composition according to the present invention is characterized by containing a complex of a quaternary ammonium salt cationic surfactant and an anionic surfactant. In the present invention, the quaternary ammonium salt type cationic surfactant has the formula: (However, R 1 and R 2 are an alkyl group or a hydroxyalkyl group having 1 to 22 carbon atoms, at least one is an alkyl group or a hydroxyalkyl group having 6 to 22 carbon atoms, and R 3 and R 4 are an alkyl group or a hydroxyalkyl group having 1 to 22 carbon atoms. ~4 alkyl group , benzyl group, ( -CH2CH2O )-nH, n=1~
3, X is a monovalent anion and is the residue of a quaternizing agent), and mono-long chain alkyl type quaternary ammonium salts are particularly preferred. Anionic surfactants include soaps, alkylbenzenesulfonates,
Alkyl sulfate salt, polyoxyethylene alkyl ether sulfate salt, polyoxyethylene alkyl phenyl ether sulfate salt,
It is allowed to be one or more selected from the group consisting of olefin sulfonate and paraffin sulfonate. The treatment composition of the present invention is usually prepared by reacting a quaternary ammonium salt type cationic surfactant and an anionic surfactant in water to form a complex. The anionic surfactant is used in a proportion of 0.7 to 1.3 moles, preferably 0.8 to 1.2 moles, per mole of the ammonium salt type cationic surfactant. If the amount of anionic surfactant used is less than 0.7 mol or more than 1.3 mol, the balance between the cationic charge and the anionic charge of the generated complex will be considerably disrupted, resulting in a decrease in the affinity of the complex for leather or fur. Undesirable. The complexes of the invention have poor solubility in water. Therefore, when preparing a treatment composition, a predetermined amount of a quaternary ammonium salt type cationic surfactant and an anionic surfactant are added to water as a dispersion medium while stirring, or a suitable amount is added to water in advance. A method is recommended in which a dispersant, such as a polyoxyethylene nonionic surfactant, is added and a complex is generated in the presence of the dispersant. The treatment composition of the present invention can be used in the manufacturing process of leather or fur, such as degreasing and/or dyeing, and can also be used when cleaning leather or fur products; The complex concentration is at least 0.05% by weight, preferably
It is in the range of 0.2-2.0% by weight. As long as the complex is contained within this concentration range, the treatment composition of the present invention can impart desired flexibility to leather or fur. It can also be expected to have degreasing and cleaning effects. Example (1) Preparation of treatment composition In a container equipped with a jet agitator, 100 parts by weight of water and 1 part by weight of the dispersant Liponox NC6E were added.
(Product name: manufactured by Lion Yushi Co., Ltd.) and heated to approximately 80℃, and while stirring, gradually added the anionic surfactant and cationic surfactant shown in Table 1 in the molar ratio shown in Table 1. added to. Thereafter, the dispersion in the container was cooled while applying a high shearing force to prepare processing agent compositions A to H.
【表】【table】
【表】
(2) 柔軟性評価〔その１〕
表−１に示した処理剤組成物Ａ〜Ｈをそれぞれ
水で稀釈してコンプレツクス濃度（組成物Ｈにつ
いては界面活性剤濃度）が0.5重量％及び1.5重量
％の処理液を調製する。この処理液１中にカン
ガルー皮（厚さ1.2mm、サイズ2.5cm×15cm）を室
温で６時間浸漬した後、軽く揉み洗いする。しか
る後カンガルー皮を１の水中で１回軽く浸漬す
すぎし、そのまま引き上げて一昼夜風乾させる。
次に45度カンチレバー法〔染色加工講座３、
205ページ（昭和33年、共立出版(株)発行）参照〕
により、水平面に試験片（カンガルー皮）を置い
て45度の斜面に突き出し、試験片の先端が斜面に
接するまでの長さ（突き出た長さ）を計測する。
この長さが短い程揉柔軟性に富む。結果を表−２
に示す。[Table] (2) Flexibility evaluation [Part 1] Treating agent compositions A to H shown in Table 1 were each diluted with water to give a complex concentration (surfactant concentration for composition H) of 0.5 weight. % and 1.5% by weight treatment solutions are prepared. A kangaroo skin (thickness 1.2 mm, size 2.5 cm x 15 cm) is immersed in this treatment solution 1 for 6 hours at room temperature, and then gently rubbed and washed. After that, the kangaroo skin is lightly immersed once in 1 water and rinsed, then taken out and air-dried overnight. Next, the 45 degree cantilever method [Dyeing Processing Course 3,
See page 205 (1955, published by Kyoritsu Shuppan Co., Ltd.)]
A test piece (kangaroo skin) is placed on a horizontal surface, protruded onto a 45-degree slope, and the length until the tip of the test piece touches the slope (length of protrusion) is measured.
The shorter the length, the more flexible it is during rolling. Table 2 of the results
Shown below.
【表】
(3) 柔軟性評価〔その２〕
表−１に示した処理剤組成物Ａ〜Ｈをそれぞれ
水で稀釈してコンプレツクス濃度（組成物Ｈにつ
いては界面活性剤濃度が1.0重量％）の処理液を
調製する。この処理液５中にムートン（市販品
を15cm×15cmに裁断したもの）を室温で６時間浸
漬してから軽く揉み洗いする。しかる後ムートン
を５の水中で１回軽く浸漬すすぎし、そのまま
引き上げて一昼夜風乾させる。
次に男子７名、女子８名計15名の判定人に処理
液Ａ〜Ｇで処理した各ムートンの感触を処理液Ｈ
で処理したムートンの感触との対比から、「非常
に柔軟性に富んでいる」、「柔軟性がある」、「解ら
ない」及び「柔軟性が悪い」の４段階で評価させ
た。結果を表−３に示す。[Table] (3) Flexibility evaluation [Part 2] Treatment agent compositions A to H shown in Table 1 were each diluted with water to determine the complex concentration (for composition H, the surfactant concentration was 1.0% by weight). ) Prepare the treatment solution. Mouton (a commercially available product cut into 15 cm x 15 cm) is immersed in this treatment solution 5 for 6 hours at room temperature, and then gently rubbed and washed. After that, the shearling was lightly immersed once in water from step 5 and rinsed, then taken out and air-dried for a day and night. Next, a total of 15 judges, 7 men and 8 women, evaluated the feel of each shearling coat treated with treatment liquids A to G.
Based on the comparison with the feel of shearling treated with , the texture was evaluated on a four-point scale: ``Very flexible,''``Flexible,'' ``I don't understand,'' and ``Poor flexibility.'' The results are shown in Table-3.
【表】【table】
【表】【table】
Claims (1)
又はヒドロキシアルキル基で、少なくとも一方は
炭素数６〜22のアルキル基又はヒドロキシアルキ
ル基であり、R3，R4は炭素数１〜４のアルキル
基、ベンジル基、（−CH2CH2O）−nH，ｎ＝１〜
８，Ｘは一価のアニオンで四級化剤の残基であ
る） で示される第四級アンモニウム塩型カチオン界面
活性剤１モルとアニオン界面活性剤0.7〜1.8モル
との反応生成物であるコンプレツクスを含有する
ことを特徴とする皮革・毛皮用処理剤組成物。 ２ 前記のアニオン界面活性剤が石鹸、アルキル
ベンゼンスルホン酸塩、アルキル硫酸エステル
塩、ポリオキシエチレンアルキルエーテル硫酸エ
ステル塩、ポリオキシエチレンアルキルフエニル
エーテル硫酸エステル塩、オレフインスルホン酸
塩及びパラフインスルホン酸塩からなる群から選
ばれる１種もしくは２種以上である特許請求の範
囲第１項記載の組成物。[Claims] 1 Formula: (However, R 1 and R 2 are an alkyl group or a hydroxyalkyl group having 1 to 22 carbon atoms, at least one is an alkyl group or a hydroxyalkyl group having 6 to 22 carbon atoms, and R 3 and R 4 are an alkyl group or a hydroxyalkyl group having 1 to 22 carbon atoms. ~4 alkyl group , benzyl group, ( -CH2CH2O )-nH, n=1~
8. A leather/fur treatment composition characterized by containing complexes. 2. The anionic surfactant is selected from soap, alkylbenzene sulfonate, alkyl sulfate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, olefin sulfonate, and paraffin sulfonate. The composition according to claim 1, which is one or more selected from the group consisting of:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2594479A JPS55119000A (en) | 1979-03-06 | 1979-03-06 | Leather and feather treating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2594479A JPS55119000A (en) | 1979-03-06 | 1979-03-06 | Leather and feather treating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55119000A JPS55119000A (en) | 1980-09-12 |
| JPS6127440B2 true JPS6127440B2 (en) | 1986-06-25 |
Family
ID=12179857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2594479A Granted JPS55119000A (en) | 1979-03-06 | 1979-03-06 | Leather and feather treating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55119000A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4416111A1 (en) * | 1994-05-06 | 1995-11-09 | Henkel Kgaa | Cationic agents for greasing leather and fur |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3920563A (en) * | 1972-10-31 | 1975-11-18 | Colgate Palmolive Co | Soap-cationic combinations as rinse cycle softeners |
| US3920565A (en) * | 1973-02-23 | 1975-11-18 | Procter & Gamble | Fabric softener composition and method |
| JPS5352799A (en) * | 1976-10-19 | 1978-05-13 | Kao Corp | Fabric softening agent composition |
-
1979
- 1979-03-06 JP JP2594479A patent/JPS55119000A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3920563A (en) * | 1972-10-31 | 1975-11-18 | Colgate Palmolive Co | Soap-cationic combinations as rinse cycle softeners |
| US3920565A (en) * | 1973-02-23 | 1975-11-18 | Procter & Gamble | Fabric softener composition and method |
| JPS5352799A (en) * | 1976-10-19 | 1978-05-13 | Kao Corp | Fabric softening agent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55119000A (en) | 1980-09-12 |
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