JPS61266953A - Gas concentration detector - Google Patents

Gas concentration detector

Info

Publication number
JPS61266953A
JPS61266953A JP60109754A JP10975485A JPS61266953A JP S61266953 A JPS61266953 A JP S61266953A JP 60109754 A JP60109754 A JP 60109754A JP 10975485 A JP10975485 A JP 10975485A JP S61266953 A JPS61266953 A JP S61266953A
Authority
JP
Japan
Prior art keywords
gas
solid electrolyte
measured
electrode
concentration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60109754A
Other languages
Japanese (ja)
Inventor
Shunichi Itabashi
板橋 俊一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP60109754A priority Critical patent/JPS61266953A/en
Publication of JPS61266953A publication Critical patent/JPS61266953A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a small-sized gas concn. detector having simple constitution without using gas having 100% concn. by constituting one of electrodes of a metal having the same kind of ions as a solid electrolyte. CONSTITUTION:The solid electrolyte 5 is inserted into a cylinder 7 and the solid electrolyte 5 is sandwiched by two electrodes 6, 8. Pt is used form the electrode 6 on the side of the gas to be measured and the metal having the same kind of ions as the solid electrolyte 5 calculated in the gas to be measured is used for the other electrode 8. The solid electrolyte 5 is lead chloride and the metal of lead is used for the electrode 8 if the gas to be measured is gaseous chlorine. Pure gas of 100% is supplied on the supply side of the gas to be measure prior to the use in such constitution and a calibration is preliminarily made in an arithmetic circuit 3 by using the electromotive force generated in the solid electrolyte 5 by such supply. The electromotive force generated by the gas to be measured is thereafter subjected to concn. conversion by the calibrated arithmetic circuit 4.

Description

【発明の詳細な説明】 技術分野 本発明はガス濃度検出装置に関し、特に大気中に含まれ
るガスの濃度を検出するガス濃度検出装置に関する。
TECHNICAL FIELD The present invention relates to a gas concentration detection device, and more particularly to a gas concentration detection device for detecting the concentration of gas contained in the atmosphere.

良見亘韮 従来、固体電解質を使用したガスセンサはガス濃淡電池
として使用してい゛るので、この固体電解質を挟持した
一方の電極には100%濃度ガスを常時供給し、他方の
電極には検出すべき被測定ガスを供給してその濃度差に
より生じる固体電解質の起電力からネルンストの方程式
を使用してそのガスの濃度を換算算出している。
Wataru Yoshimi Conventionally, gas sensors using solid electrolytes are used as gas concentration batteries, so 100% concentration gas is constantly supplied to one electrode with the solid electrolyte sandwiched between them, and the detection signal is supplied to the other electrode. The concentration of the gas to be measured is calculated using the Nernst equation from the electromotive force of the solid electrolyte generated due to the concentration difference.

かかる構成のガス濃度検出装置では、一方の電極に常時
100%濃度ガスを供給し続ける必要があるので、装置
自体が複雑かつ大型となる欠点がある。また、ガスの吸
着現象により、固体電解質における正確な起電力が測定
困難となるために、ガスの濃度を直読できないという欠
点もある。
In a gas concentration detection device having such a configuration, it is necessary to constantly supply 100% concentration gas to one electrode, which has the disadvantage that the device itself becomes complicated and large. Furthermore, the gas adsorption phenomenon makes it difficult to accurately measure the electromotive force in the solid electrolyte, so there is also the drawback that the gas concentration cannot be directly read.

11立l潰 本発明は、100%濃度のガスを使用することなく小型
で構成の簡単なガス濃度検出装置を提供することを目的
としている。
SUMMARY OF THE INVENTION An object of the present invention is to provide a gas concentration detection device that is small and has a simple configuration without using 100% concentration gas.

1豆立旦羞 本発明によるガス濃度検出装置は、固体電解質を2個の
電極により挟持して一方の電極に被測定ガスを供給し、
これ等2個の電極間に生じる電位差よって被測定ガスの
濃度を検出するようにしたガス濃度検出装置を対象とし
、その特徴とするところは、当該2個の電極の他方を、
固体電解質と同種のイオンを有する金属により構成した
ことに一1fH&−+麺。
The gas concentration detection device according to the present invention has a solid electrolyte sandwiched between two electrodes, and a gas to be measured is supplied to one of the electrodes.
The target is a gas concentration detection device that detects the concentration of a gas to be measured by the potential difference generated between these two electrodes, and its characteristics are that the other of the two electrodes is
1fH&-+ noodles in that it is made of a metal containing the same type of ions as the solid electrolyte.

1鳳1 以下、図面を用いて本発明の詳細な説明する。1 pho 1 Hereinafter, the present invention will be explained in detail using the drawings.

第1図は本発明の実施例のガス濃度検出装置の構成を示
す、ブロック図であり、ガスセンサ1により被測定ガス
の濃度に対応する起電力が発生され、電圧計2において
その起電力が測定される。そして演算回路2でこの起電
力に対応する濃度をネルンストの方程式より算出して、
この算出した濃度をモニタ4にて可視表示するようにな
っている。
FIG. 1 is a block diagram showing the configuration of a gas concentration detection device according to an embodiment of the present invention, in which a gas sensor 1 generates an electromotive force corresponding to the concentration of a gas to be measured, and a voltmeter 2 measures the electromotive force. be done. Then, the calculation circuit 2 calculates the concentration corresponding to this electromotive force using Nernst's equation,
The calculated concentration is visually displayed on the monitor 4.

第2図は第1図のガスセンサ1の構成例を示す断面図で
ある。図において、筒7の中に固体電解質5を挿入し、
この固体電解質5を2個の電極6゜8により挟持するの
である。被測定ガス側の電極6としては従来と同様にP
t(白金)を使用し、他方の電極8としては、被測定ガ
ス中で焼成きれた固体電解質5と同種のイオンを有する
金属が使用される。被測定ガスが例えば塩素ガスであれ
ば、固体電解質5は塩化鉛であり、電極8は鉛の金属が
用いられる。
FIG. 2 is a sectional view showing an example of the configuration of the gas sensor 1 shown in FIG. 1. In the figure, a solid electrolyte 5 is inserted into a cylinder 7,
This solid electrolyte 5 is sandwiched between two electrodes 6°8. As the electrode 6 on the gas to be measured side, P is used as in the conventional case.
As the other electrode 8, a metal having the same type of ions as the solid electrolyte 5 fired in the gas to be measured is used. If the gas to be measured is, for example, chlorine gas, the solid electrolyte 5 is lead chloride, and the electrode 8 is made of lead metal.

尚、7aは被測定ガス導入用の筒部であり、9゜9aは
リード線である。
Note that 7a is a cylindrical portion for introducing the gas to be measured, and 9.degree. 9a is a lead wire.

かかる構成において、使用前に被測定ガス供給側に10
0%の純正ガスを供給し、これによって固体電解質5に
生じた起電力を用いて演算回路3にて校正を行なってお
く。以後は100%濃度ガスを供給することなく、こう
して校正された演算回路4によって被測定ガスにより生
じた起電力を濃度換算するのである。
In such a configuration, 10
0% pure gas is supplied, and the calculation circuit 3 uses the electromotive force generated in the solid electrolyte 5 to perform calibration. Thereafter, without supplying 100% concentration gas, the electromotive force generated by the gas to be measured is converted into concentration using the thus calibrated arithmetic circuit 4.

1豆立11 叙上の如く、本発明によれば、100%の純正ガスを常
時供給し続ける必要がなくなるので、装置の簡素化小形
化が可能となると共に、100%ガスの吸着現象による
起電力の劣化が防止可能となり、正確な被測定ガスの濃
度検出ができるという効果がある。
1. As mentioned above, according to the present invention, it is no longer necessary to constantly supply 100% pure gas, which makes it possible to simplify and downsize the device, and to prevent the occurrence of 100% gas adsorption. This has the effect of being able to prevent power deterioration and accurately detecting the concentration of the gas to be measured.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の実施例の機能ブロック図、第2図は本
発明に使用するガスセンサ部の構成例の断面図である。 主要部分の符号の説明 5・・・・・・固体電解質 6.8・・・・・・電極
FIG. 1 is a functional block diagram of an embodiment of the present invention, and FIG. 2 is a sectional view of an example of the configuration of a gas sensor section used in the present invention. Explanation of symbols of main parts 5...Solid electrolyte 6.8...Electrode

Claims (1)

【特許請求の範囲】[Claims] 固体電解質を2個の電極により挟持して一方の電極に被
測定ガスを供給し、前記2個の電極間に生じる電位差よ
って前記被測定ガスの濃度を検出するようにしたガス濃
度検出装置であって、前記他方の電極を、前記固体電解
質と同種のイオンを有する金属により構成したことを特
徴とするガス濃度検出装置。
A gas concentration detecting device in which a solid electrolyte is sandwiched between two electrodes, a gas to be measured is supplied to one electrode, and the concentration of the gas to be measured is detected by a potential difference generated between the two electrodes. A gas concentration detection device characterized in that the other electrode is made of a metal containing ions of the same type as the solid electrolyte.
JP60109754A 1985-05-22 1985-05-22 Gas concentration detector Pending JPS61266953A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60109754A JPS61266953A (en) 1985-05-22 1985-05-22 Gas concentration detector

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60109754A JPS61266953A (en) 1985-05-22 1985-05-22 Gas concentration detector

Publications (1)

Publication Number Publication Date
JPS61266953A true JPS61266953A (en) 1986-11-26

Family

ID=14518399

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60109754A Pending JPS61266953A (en) 1985-05-22 1985-05-22 Gas concentration detector

Country Status (1)

Country Link
JP (1) JPS61266953A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005181331A (en) * 2003-12-18 2005-07-07 General Electric Co <Ge> System for monitoring combustible gas

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005181331A (en) * 2003-12-18 2005-07-07 General Electric Co <Ge> System for monitoring combustible gas

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