JPS61247772A - Marking ink composition for fluorescent lamp - Google Patents
Marking ink composition for fluorescent lampInfo
- Publication number
- JPS61247772A JPS61247772A JP60088563A JP8856385A JPS61247772A JP S61247772 A JPS61247772 A JP S61247772A JP 60088563 A JP60088563 A JP 60088563A JP 8856385 A JP8856385 A JP 8856385A JP S61247772 A JPS61247772 A JP S61247772A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- oxide
- mark
- pts
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の利用分野〕
本発明は蛍光ランプ用マークインク材料組成物に係り、
そのインク材料の組成特に無機顔料組成により好適な茶
色から金色に至るマーク色調を与えまマークインク組成
物に関する。[Detailed Description of the Invention] [Field of Application of the Invention] The present invention relates to a mark ink material composition for fluorescent lamps,
The present invention relates to a mark ink composition that provides a suitable mark color tone ranging from brown to gold depending on the composition of the ink material, particularly the inorganic pigment composition.
管球用のマークインク材料においてマーク色調を無機顔
料で調節する事例は特開昭５１−１３９１８９号公報あ
るいは公開技報第８０−８５１号で示されているが、い
ずれも酸化銀が用いられており、原価面及び作業性（安
全面）についてとくに配慮されてはいない。Examples of adjusting the mark color tone with inorganic pigments in mark ink materials for tubes are shown in JP-A-51-139189 and JP-A No. 80-851, but in both cases silver oxide is used. Therefore, no particular consideration was given to cost and workability (safety).
したがって、本発明の目的は製造原価が安く、かつ作業
性の良いところの酸化銀なしの蛍光ランプ用マークイン
ク組成物を提供することにある。Therefore, an object of the present invention is to provide a mark ink composition for fluorescent lamps that does not contain silver oxide and is inexpensive to manufacture and has good workability.
前述したように、従来、蛍光ランプ用マークインク材料
は一般に酸化銀とホウ酸鉛との組合せのものが使用され
ていたが、製造原価が高いこと、及び作業性が悪いこと
から改良の余地が残されていた。そこで本発明ではこの
見地から高価な酸化銀なしで実用性のあるインク材料を
検討した結果。As mentioned above, conventional mark ink materials for fluorescent lamps have generally been a combination of silver oxide and lead borate, but there is still room for improvement due to high manufacturing costs and poor workability. It was left behind. Therefore, in the present invention, from this point of view, we investigated a practical ink material without using expensive silver oxide.
いくつかの耐熱性良好な無機顔料を選択し、これとホウ
酸鉛及び充填剤との組合せが最適であることを見出した
ものである。We selected several inorganic pigments with good heat resistance and found that the combination of these with lead borate and fillers was optimal.
以下、本発明を実施例によって詳しく説明する。 Hereinafter, the present invention will be explained in detail with reference to Examples.
実施例１
酸化亜鉛６９部、ホウ酸鉛ガラス（配合比７．７ＰｂＯ
−８２０，）１４部に対し酸化クロム−酸化アンチモン
−酸化チタンの三元系無機顔料（（株）アサヒ化成製商
品名アサヒイエロＮａ５９５０） １０部及び酸化鉛−
酸化アンチモンー酸化チタンの三元系無機顔料（同上ア
サヒイエロＮＱ５１００） ５．５ 部。Example 1 69 parts of zinc oxide, lead borate glass (mixing ratio 7.7PbO
-820,) to 14 parts of chromium oxide-antimony oxide-titanium oxide ternary inorganic pigment (trade name: Asahi Yellow Na5950, manufactured by Asahi Kasei Co., Ltd.) and 10 parts of lead oxide-
Antimony oxide-titanium oxide ternary inorganic pigment (Asahi Yellow NQ5100) 5.5 parts.
酸化コバルト１．５部、グリセリン１８部とをライカイ
機用の磁製乳鉢にとリライカイ機で１時間〜２時間混練
する。このようにして得られたマークインクを環形蛍光
ランプ製造ラインのマーク捺印機で捺印し製球した結果
、金色のマーク色調が得られ、マーク強度も大であり、
またインクのカスレ、ニジミなどの欠点もなかった。1.5 parts of cobalt oxide and 18 parts of glycerin are kneaded in a porcelain mortar for 1 hour to 2 hours using a 2 hour machine. The thus obtained mark ink was stamped on a mark stamping machine on a ring-shaped fluorescent lamp production line and a ball was produced, resulting in a golden mark tone and a high mark strength.
There were also no defects such as ink smearing or bleeding.
実施例２
酸化チタン６９部、ホウ酸鉛ガラス（配合比７．７ Ｐ
ｂ０−Ｂ、Ｏ，）１４部に対して以下実施例と同様な方
法で調合したマークインクを環形蛍光ランプ製造ライン
で捺印、製球した結果、金色のマーク色調が得られ、マ
ーク強度も大であり、インクのカスレ、ニジミなどの欠
点もなかった。Example 2 69 parts of titanium oxide, lead borate glass (mixing ratio 7.7 P
B0-B, O,) 14 parts were mixed with mark ink in the same manner as in the following examples and stamped and made into bulbs on an annular fluorescent lamp production line. As a result, a golden mark tone was obtained and the mark strength was also high. There were no defects such as ink fading or bleeding.
実施例３
酸化チタン３０部、酸化亜鉛３９部、ホウ酸鉛ガラス（
配合比？、７ＰｂＯ−Ｂ、０３）１４部に対して以下実
施例１と同様な方法で調合したマークインクを環形蛍光
ランプ製造ラインで捺印、製球した結果、金色のマーク
色調が得られ、マーク強度も大であり、インクのカスレ
アニシンなどの欠点もなかった。Example 3 30 parts of titanium oxide, 39 parts of zinc oxide, lead borate glass (
Mixing ratio? , 7PbO-B, 03) and 14 parts of the mark ink prepared in the same manner as in Example 1 was stamped and made into bulbs on an annular fluorescent lamp production line. As a result, a golden mark tone was obtained and the mark strength was also high. It was large, and there were no drawbacks such as ink cassoulet herring.
実施例４
酸化亜鉛５８部、ホウ′酸鉛ガラス２８郁、酸化クロム
−酸化アンチモン−酸化チタン三元系無機顔料１０部、
酸化鉛−酸化アンチモンー酸化チタン三元系無機顔料４
部に対しグリセリン１８部とをライカイ機用乳鉢にとリ
ライヵイ機にて１時間混練する。このようにして得られ
たマークイレフを蛍光ランプ製造ラインで捺印、製球し
た結果。Example 4 58 parts of zinc oxide, 28 parts of lead borate glass, 10 parts of chromium oxide-antimony oxide-titanium oxide ternary inorganic pigment,
Lead oxide-antimony oxide-titanium oxide ternary inorganic pigment 4
18 parts of glycerin in a mortar for a Lykai machine and kneaded for 1 hour using a Lykai machine. This is the result of stamping the Mark Iref obtained in this way and making bulbs on a fluorescent lamp manufacturing line.
茶色がかった金色のマーク色調とマーク強度大なるマー
ク印面が得られ、インクのニシン、カスレなどの欠点も
なかった６
実施例５
酸化亜鉛６９部、ホウ酸鉛ガラス（配合比７．７ｐｂ○
−Ｂ、Ｏ，）１４部に対し酸化クロム−酸化アンチモン
−酸化チタンの三元系無機顔料９部。A mark surface with a brownish-gold mark tone and high mark strength was obtained, and there were no defects such as ink redness or fading.6 Example 5 69 parts of zinc oxide, lead borate glass (mixing ratio 7.7 pb○)
-14 parts of B, O, ) and 9 parts of a ternary inorganic pigment of chromium oxide-antimony oxide-titanium oxide.
酸化鉛−酸化アンチモンー酸化チタンの三元系無機顔料
７部、酸化コバルト１部、グリセリン１８部とをライカ
イ機用乳鉢にとリライヵス機で１時間混練する。得られ
たマークインクを環形蛍光ランプ製造ラインで捺印、製
球した結果、鮮やかな黄金色でマーク強度をもつマーク
印面が得られ、インクのカスレアニシンなどの欠点もな
かった。7 parts of a ternary inorganic pigment of lead oxide-antimony oxide-titanium oxide, 1 part of cobalt oxide, and 18 parts of glycerin are kneaded in a mortar for a Lyka machine for 1 hour using a Lyka machine. When the obtained mark ink was stamped and made into balls on a ring-shaped fluorescent lamp production line, a mark surface with a bright golden color and mark strength was obtained, and there were no defects such as cassoulet herring in the ink.
なお、さらに検討した結果、次の組成の範囲内であれば
、上記目的を達成できることが判明した。As a result of further study, it was found that the above object could be achieved within the following composition range.
つまり酸化亜鉛、酸化チタンの一種または二種を５８部
〜７０部とホウ酸鉛ガラス１２〜２８部に対し酸化クロ
ム、酸化アンチモン、酸化チタンからなる三元系無機顔
料６〜１１部と酸化鉛、酸化アンチモン、酸化チタンか
らなる三元系無機顔料３〜８部とさらに要すれば酸化コ
バルト０〜２部とからなる組成物に対して１５〜２０部
のグリセリンを添加したものである。In other words, 58 to 70 parts of one or both of zinc oxide and titanium oxide, 12 to 28 parts of lead borate glass, 6 to 11 parts of a ternary inorganic pigment consisting of chromium oxide, antimony oxide, and titanium oxide, and lead oxide. 15 to 20 parts of glycerin are added to a composition consisting of 3 to 8 parts of a ternary inorganic pigment consisting of antimony oxide, titanium oxide, and, if necessary, 0 to 2 parts of cobalt oxide.
Claims (1)
７０部とホウ酸鉛ガラス１２〜２８部に対し酸化クロム
、酸化アンチモン、酸化チタンからなる三元系無機顔料
６〜１１部と酸化鉛、酸化アンチモン、酸化チタンから
なる三元系無機顔料３〜８部とさらに要すれば酸化コバ
ルト０〜２部からなる組成物に対して１５〜２０部のグ
リセリンを添加してなることを特徴とする蛍光ランプ用
マークインク組成物。 ２、酸化亜鉛、酸化チタンの少くとも一種を６９部、ホ
ウ酸鉛ガラス１４部に対し酸化クロム、酸化アンチモン
、酸化チタンからなる三元系無機顔料９．５部及び酸化
鉛、酸化アンチモン、酸化チタンからなる三元系無機顔
料６部と、酸化コバルト１．５部とからなる組成物に対
して１８部のグリセリンを添加してなることを特徴とす
る第１項の蛍光ランプ用マークインク組成物。[Claims] 1. 58 parts or more of one or both of zinc oxide and titanium oxide
70 parts and 12 to 28 parts of lead borate glass, 6 to 11 parts of a ternary inorganic pigment consisting of chromium oxide, antimony oxide, and titanium oxide, and 3 to 3 parts of a ternary inorganic pigment consisting of lead oxide, antimony oxide, and titanium oxide. 1. A mark ink composition for fluorescent lamps, characterized in that 15 to 20 parts of glycerin is added to a composition consisting of 8 parts and, optionally, 0 to 2 parts of cobalt oxide. 2. 69 parts of at least one of zinc oxide and titanium oxide, 9.5 parts of a ternary inorganic pigment consisting of chromium oxide, antimony oxide, and titanium oxide, and lead oxide, antimony oxide, and titanium oxide to 14 parts of lead borate glass. The mark ink composition for fluorescent lamps according to item 1, characterized in that it is formed by adding 18 parts of glycerin to a composition consisting of 6 parts of a ternary inorganic pigment made of titanium and 1.5 parts of cobalt oxide. thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60088563A JPS61247772A (en) | 1985-04-26 | 1985-04-26 | Marking ink composition for fluorescent lamp |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60088563A JPS61247772A (en) | 1985-04-26 | 1985-04-26 | Marking ink composition for fluorescent lamp |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS61247772A true JPS61247772A (en) | 1986-11-05 |
Family
ID=13946333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60088563A Pending JPS61247772A (en) | 1985-04-26 | 1985-04-26 | Marking ink composition for fluorescent lamp |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61247772A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046120A (en) * | 2014-05-29 | 2014-09-17 | 新沂市德丽照明科技有限公司 | Anti-ageing high-viscosity stamping ink for ceramic metal halide lamps |
-
1985
- 1985-04-26 JP JP60088563A patent/JPS61247772A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046120A (en) * | 2014-05-29 | 2014-09-17 | 新沂市德丽照明科技有限公司 | Anti-ageing high-viscosity stamping ink for ceramic metal halide lamps |
| CN104046120B (en) * | 2014-05-29 | 2016-05-18 | 新沂市德丽照明科技有限公司 | The anti-aging high viscosity pad-ink of a kind of ceramic gold-halogen lamp |
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