JPS6124427A - Adhesion and welding method of porous fluoroplastic film and resin member - Google Patents
Adhesion and welding method of porous fluoroplastic film and resin memberInfo
- Publication number
- JPS6124427A JPS6124427A JP14638084A JP14638084A JPS6124427A JP S6124427 A JPS6124427 A JP S6124427A JP 14638084 A JP14638084 A JP 14638084A JP 14638084 A JP14638084 A JP 14638084A JP S6124427 A JPS6124427 A JP S6124427A
- Authority
- JP
- Japan
- Prior art keywords
- resin member
- fusing
- porous
- bonding
- membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/72—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
- B29C66/727—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined being porous, e.g. foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/08—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/112—Single lapped joints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/114—Single butt joints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/13—Single flanged joints; Fin-type joints; Single hem joints; Edge joints; Interpenetrating fingered joints; Other specific particular designs of joint cross-sections not provided for in groups B29C66/11 - B29C66/12
- B29C66/131—Single flanged joints, i.e. one of the parts to be joined being rigid and flanged in the joint area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/53—Joining single elements to tubular articles, hollow articles or bars
- B29C66/534—Joining single elements to open ends of tubular or hollow articles or to the ends of bars
- B29C66/5346—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/50—General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
- B29C66/51—Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
- B29C66/53—Joining single elements to tubular articles, hollow articles or bars
- B29C66/534—Joining single elements to open ends of tubular or hollow articles or to the ends of bars
- B29C66/5346—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
- B29C66/53461—Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat joining substantially flat covers and/or substantially flat bottoms to open ends of container bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
- B29C66/712—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined the composition of one of the parts to be joined being different from the composition of the other part
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、撥水性材料からなる多孔質膜詳しくは弗素樹
脂多孔質膜と樹脂部材の接着又は融着方法に関するもの
であ゛る。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a porous membrane made of a water-repellent material, and more particularly to a method of bonding or fusing a porous fluororesin membrane and a resin member.
(従来技術)
四弗化エチレン樹脂等弗素樹脂の多孔質膜を樹指部材に
熱融着固定した製品例えばエアベント(水を遮断して気
体を透過させるもの:医療点滴瓶(7) 通−針、中動
車のクラクションのエアベント、電池容器の一エアベン
ト等)、使い捨ての薬液濾過フィルター等に於いて、表
裏で非対称孔を有する(表裏で孔径、孔形状等が異なる
)弗素樹脂例えば四弗化エチレン樹脂の多孔質膜(例え
ばボアフロン(登録商標)住友電工製)を熱可塑性樹脂
(例、(ばABS 、PP 、PE、ポリアミド、ポリ
ウレタン。(Prior art) Products in which a porous film of fluororesin such as tetrafluoroethylene resin is heat-sealed and fixed to a resin member, such as air vents (those that block water and allow gas to pass through: medical drip bottles (7)) , air vents for car horns, air vents for battery containers, etc.), disposable chemical filtration filters, etc. Fluororesins with asymmetric pores on the front and back (pore diameter, pore shape, etc. are different on the front and back) such as tetrafluoroethylene A porous membrane of resin (for example, Boaflon (registered trademark) manufactured by Sumitomo Electric Industries, Ltd.) and a thermoplastic resin (for example, (ABS, PP, PE, polyamide, polyurethane).
PBT、ポリアセタール、ポリエステルエラストマー、
ポリオレフィンエラストマー等)部材に熱融着する必要
を生じる。PBT, polyacetal, polyester elastomer,
(polyolefin elastomer, etc.)
(発明が解決しようとする問題点)
このような際その接着強度(融着部の剥離強度)(接着
強度は具体的には第3図のようにして測定する)にばら
つきがしばしば見られ、極端な場合は弱過ぎて実用に耐
ええなかった。なお第3図中(1)は四弗化エチレン樹
脂等弗素樹脂の多孔質膜、(2)は熱可塑性樹脂部材、
(3)は水、(4)は空気加圧、(5)は融着部である
。(Problems to be Solved by the Invention) In such cases, variations are often observed in the adhesive strength (peel strength of the fused portion) (adhesion strength is specifically measured as shown in Figure 3). In extreme cases, it was too weak to be of practical use. In Fig. 3, (1) is a porous membrane of fluororesin such as tetrafluoroethylene resin, (2) is a thermoplastic resin member,
(3) is water, (4) is air pressurization, and (5) is a fused portion.
上記に鑑み本発明は上記接着強度のばらつきを解消させ
る目的を以て開発されたものであ〜る。In view of the above, the present invention was developed with the aim of eliminating the above-mentioned variations in adhesive strength.
本発明者らはこれを層別して解析したところ、膜の表裏
で接着強度に明らかな差があることがわかった。即ち孔
の大きさが大きい面を熱可塑性樹脂との融着面とする方
がその逆よりも接着強度が大きいことがわかった。The present inventors analyzed this layered layer and found that there was a clear difference in adhesive strength between the front and back sides of the film. That is, it was found that the adhesive strength was greater when the surface with larger pores was used as the surface to be fused with the thermoplastic resin than when the other side was used.
(発明が解決しようとする問題点)
本発明は上記知見に基くものであり、本発明は表と裏で
非対称孔を有する弗素樹脂多孔質膜を熱可塑性樹脂部材
に熱融着する時孔の大きさが大きい面を樹脂部材側とし
て熱融着することを特徴とするものである。(Problems to be Solved by the Invention) The present invention is based on the above-mentioned findings, and the present invention solves the problem of pores when a fluororesin porous membrane having asymmetric pores on the front and back sides is heat-sealed to a thermoplastic resin member. This is characterized in that the larger side is heat-sealed as the resin member side.
なお上記非対称孔とはモデル的に描くと第1図のような
ものである。第1図中(1)は四弗化エチレン樹脂等弗
素樹脂の多孔質膜、(6)は孔であり、(S)は孔の大
きさが小さい面、(L)は孔の大きさが大きい面、(2
)は熱可塑性樹脂部材である。Note that the above-mentioned asymmetric hole is as shown in FIG. 1 when drawn as a model. In Figure 1, (1) is a porous membrane of fluororesin such as tetrafluoroethylene resin, (6) is the pore, (S) is the side with small pore size, and (L) is the side with small pore size. Large side, (2
) is a thermoplastic resin member.
なお又熱融着は例えばヒータによる加熱、高周波誘導加
熱、超音波加熱等で行う。Furthermore, the thermal fusion is performed, for example, by heating with a heater, high-frequency induction heating, ultrasonic heating, or the like.
(作用)
上記により熱融着後の接着強度が向上する。これは熱融
着時に溶融樹脂が孔の中にはいり込みゃすいためと考え
られる。(Function) The adhesive strength after heat fusion is improved by the above. This is thought to be because the molten resin easily enters the holes during thermal fusion.
(実施例) 以下に本発明の理解を助ける・為実施例を述べる。(Example) Examples will be described below to help understand the present invention.
ボアフロンFP−065(孔径0.65 μ)(1)ヲ
ABS樹脂(2)に熱融着した時の接着強度(融着部の
剥離強度)(耐水圧)の実測値(n=soの平均値)を
示せば下記の通りであった。BOREFLON FP-065 (pore diameter 0.65 μ) (1) Actual measured value of adhesive strength (peel strength of fused part) (water pressure resistance) when heat fused to ABS resin (2) (average of n = so The values were shown below.
孔径大の面をシール面とすると・川・・t a 5 K
y/d孔径小の面をシール面とすると・曲・0.92
Kp/c+4上記の試験方法は第2図の通りであり、D
= 7 tm it 。If the surface with the large hole diameter is used as the sealing surface,... ta 5 K
y/d If the surface with small hole diameter is the sealing surface, curved 0.92
Kp/c+4 The above test method is as shown in Figure 2, and D
= 7tmit.
シール幅(W)= 1票であり、(3)は水、(4)は
空気加圧を示している。Seal width (W) = 1 vote, (3) indicates water, and (4) indicates air pressurization.
なお本発明に於いて上記の如く融着は熱融着について説
明したが、熱融着にかえ化学処理(アセトン等の溶剤に
よって部材樹脂を溶融させる、溶融樹脂が多孔質膜の孔
の中に入り込む)、あるいは接着剤処理(接着剤が多孔
質膜の孔の中に入り込む)等融着あるいは接着でもよい
。この際樹脂部材は熱可塑性に限定されない。In the present invention, as described above, thermal fusion has been described as fusion bonding, but instead of thermal fusion, chemical treatment (melting the component resin with a solvent such as acetone, and melting the molten resin into the pores of the porous membrane) It may also be fusion bonding or adhesion, such as adhesive treatment (adhesive enters into the pores of the porous membrane). At this time, the resin member is not limited to thermoplastic material.
なお又本発明に於いて樹脂部材の形状は同等限定される
ものではない。Furthermore, in the present invention, the shape of the resin member is not similarly limited.
(発明の効果)
以上説明したように本発明によると接着又は融着後の接
着強度が著しく向上する弗素樹脂製多孔質膜と樹脂部材
の接、融着方法が得られる。(Effects of the Invention) As explained above, according to the present invention, there is provided a method for bonding and fusing a porous fluororesin membrane and a resin member, in which the adhesive strength after adhesion or fusing is significantly improved.
第1図は本発明の詳細な説明する図、第2図は本発明の
詳細な説明する図、第3図は多孔質膜と・樹脂部材の接
着強度の測定法を説明する図を夫々例示している。
(1)・・・弗素樹脂多孔質膜、(2)・・・樹脂部材
、(3)・・・水、(4)・・・空気加圧、(5)・・
・接、融着部、(6)・・・孔、
(S)・・・孔の大きさが小さい面、
(L)・・・孔の大きさが大きい面
7?1 図
オ 2 図
第3図
〜1Figure 1 is a diagram explaining the present invention in detail, Figure 2 is a diagram explaining the invention in detail, and Figure 3 is a diagram explaining the method for measuring the adhesive strength between a porous membrane and a resin member. are doing. (1)...Fluororesin porous membrane, (2)...Resin member, (3)...Water, (4)...Air pressurization, (5)...
・Connection, fused part, (6)...hole, (S)...surface with small hole size, (L)...face with large hole size 7?1 Figure O 2 Figure Figure 3~1
Claims (8)
脂部材に接着又は融着するに際し、多孔質膜の孔の大き
さが大きい面を部材側にして接着又は融着することを特
徴とする弗素樹脂多孔質膜と樹脂部材の接、融着方法。(1) When adhering or fusing a fluororesin porous membrane that has asymmetric pores on the front and back sides to a resin member, make sure that the side of the porous membrane with larger pores faces the member side. Features: A method for bonding and fusing a porous fluororesin membrane to a resin member.
ーターによる加熱で行う特許請求の範囲第(1)項記載
の弗素樹脂多孔質膜と樹脂部材の接、融着方法。(2) A method for bonding and fusing a porous fluororesin membrane and a resin member according to claim (1), wherein the resin member is a thermoplastic resin member and the fusing is performed by heating with a heater.
周波誘導加熱で行う特許請求の範囲第(1)項記載の弗
素樹脂多孔質膜と樹脂部材の接、融着方法。(3) A method for bonding and fusing a porous fluororesin membrane and a resin member according to claim (1), wherein the resin member is a thermoplastic resin member, and the fusing is performed by high-frequency induction heating.
音波加熱で行う特許請求の範囲第(1)項記載の弗素樹
脂多孔質膜と樹脂部材の接、融着方法。(4) A method for bonding and fusing a porous fluororesin membrane and a resin member according to claim (1), wherein the resin member is a thermoplastic resin member and the fusing is performed by ultrasonic heating.
特許請求の範囲第(2)項、第(3)項又は第(4)項
記載の弗素樹脂多孔質膜と樹脂部材の接、融着方法。(5) A porous fluororesin membrane and a resin member according to claim (2), (3) or (4), which are fused at a fusion temperature equal to or higher than the softening point of the thermoplastic resin. Bonding and fusion methods.
)項記載の弗素樹脂多孔質膜と樹脂部材の接、融着方法
。(6) Claim No. 1 in which fusion is performed by chemical treatment
) A method for bonding and fusing a porous fluororesin membrane and a resin member as described in section 2.
項記載の弗素樹脂多孔質膜と樹脂部材の接、融着方法。(7) Claim No. (1) in which adhesion is performed by adhesive treatment
A method for bonding and fusing a porous fluororesin membrane and a resin member as described in Section 3.
範囲第(1)項記載の弗素樹脂多孔質膜と樹脂部材の接
、融着方法。(8) A method for bonding and fusing a porous fluororesin membrane and a resin member according to claim (1), wherein the fluororesin is a tetrafluoroethylene resin.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14638084A JPS6124427A (en) | 1984-07-13 | 1984-07-13 | Adhesion and welding method of porous fluoroplastic film and resin member |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14638084A JPS6124427A (en) | 1984-07-13 | 1984-07-13 | Adhesion and welding method of porous fluoroplastic film and resin member |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6124427A true JPS6124427A (en) | 1986-02-03 |
Family
ID=15406397
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14638084A Pending JPS6124427A (en) | 1984-07-13 | 1984-07-13 | Adhesion and welding method of porous fluoroplastic film and resin member |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6124427A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015159515A1 (en) * | 2014-04-18 | 2015-10-22 | 日東電工株式会社 | Gas permeation member and production method therefor |
-
1984
- 1984-07-13 JP JP14638084A patent/JPS6124427A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015159515A1 (en) * | 2014-04-18 | 2015-10-22 | 日東電工株式会社 | Gas permeation member and production method therefor |
JP2015205420A (en) * | 2014-04-18 | 2015-11-19 | 日東電工株式会社 | Gas-permeable member and production method thereof |
CN106232325A (en) * | 2014-04-18 | 2016-12-14 | 日东电工株式会社 | Gas permeation component and manufacture method thereof |
US10300665B2 (en) | 2014-04-18 | 2019-05-28 | Nitto Denko Corporation | Gas-permeable member and method for producing the same |
TWI674188B (en) * | 2014-04-18 | 2019-10-11 | 日商日東電工股份有限公司 | Gas permeating member and method of manufacturing same |
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