JPS611637A - Stabilization of organic acid - Google Patents
Stabilization of organic acidInfo
- Publication number
- JPS611637A JPS611637A JP59123380A JP12338084A JPS611637A JP S611637 A JPS611637 A JP S611637A JP 59123380 A JP59123380 A JP 59123380A JP 12338084 A JP12338084 A JP 12338084A JP S611637 A JPS611637 A JP S611637A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- organic
- powder
- water
- organic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Furan Compounds (AREA)
- Pyridine Compounds (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発Ｆ！Ａは有機酸のコーティングによる安定、化方法
に関する。特にアルカリ性物質或は漂白−等と共に配合
して安定な組成物をつくるのに適した安定化された有機
酸粉末を得る方法に関する。[Detailed description of the invention] [Industrial application field] The original F! A relates to a method for stabilization and stabilization by coating with an organic acid. In particular, it relates to a method for obtaining a stabilized organic acid powder suitable for combination with alkaline substances, bleaching agents, etc. to form stable compositions.
一般に、有機酸を発泡を目的と（７て重曹などのアルカ
リ性塩等と共存させると、接触部分の中和反応によシ有
機酸の安定性が劣化する。又、塩素系や酸素系の酸化剤
などと共存させると、有機酸が酸化剤の分解を促進させ
、酸化剤の安定性が劣化する。例えば従来一般に、浴剤
、風呂水清浄剤、風呂釜清浄剤等に、有機酸と重曹を組
み合せた発泡剤組成物が利用される。しかし１、有機酸
と重曹をそのまま配合したものは原料中の水分、吸湿等
により反応が起こりＣＯ２ガスが発生し、包装がツクし
たり使用時の発泡性が低下する等の欠点があった。Generally, when an organic acid is coexisting with an alkaline salt such as baking soda for the purpose of foaming (7), the stability of the organic acid deteriorates due to the neutralization reaction of the contact area. If the organic acid coexists with the oxidizing agent, the decomposition of the oxidizing agent will be accelerated and the stability of the oxidizing agent will deteriorate.For example, in the past, organic acids and baking soda were commonly used in bath additives, bath water cleaners, bath kettle cleaners, etc. However, if organic acid and baking soda are combined as is, a reaction occurs due to moisture in the raw materials, moisture absorption, etc., and CO2 gas is generated, which may cause the packaging to become stiff or cause problems during use. There were drawbacks such as a decrease in foamability.
これらの現象を防ぐために、有機酸粉末をコーティング
することが考えられるが、水溶性でないものでコーティ
ングした場合には、水中で実際に使用することができな
いし、又有機物だけでコーティングした場合には、・こ
の有機物とその他の同時に共存せしめられる成分との反
応を考えなければならないので広く応用の利くものとは
言えない。To prevent these phenomena, it is possible to coat with organic acid powder, but if it is coated with something that is not water-soluble, it cannot actually be used in water, and if it is coated with only organic matter, it will not work. ,・Since the reaction between this organic substance and other components coexisting at the same time must be considered, it cannot be said to be widely applicable.
本発明者等は、有機酸の粉末と融点４０℃以上の水溶性
有機物を混合し、一旦水溶性有機物の融点以上に加熱す
ることによシコーティングすると、容易に更にその外側
に有機又は無機物質の粉体をコーティングすることがで
きることを見い出し、本発明を完成するに至った。即ち
本発明は常温で固体の有機酸の粉末を、４０℃以上の融
点を有する水溶性有機物により、該水溶性有機物の融点
以上の温度でコーティングし、次で化学的に不活性な有
機又は無機物質の粉体を更にその上にコーティングする
ことを特徴とする有機酸の安定化方法を提供するもので
ある。The present inventors have discovered that when an organic acid powder and a water-soluble organic substance with a melting point of 40°C or higher are mixed and once coated by heating the mixture to a temperature above the melting point of the water-soluble organic substance, organic or inorganic substances can be easily coated on the outside. The present inventors discovered that it is possible to coat the powder of That is, in the present invention, an organic acid powder that is solid at room temperature is coated with a water-soluble organic substance having a melting point of 40°C or higher at a temperature higher than the melting point of the water-soluble organic substance, and then coated with a chemically inert organic or inorganic substance. The present invention provides a method for stabilizing an organic acid, which comprises further coating a powder of the substance thereon.
本発明の方法によれば、一番外側に反応性の低い無機又
は有機粉体があるため、他の共存成分との反応が防止さ
れ、更に二重のコーティングによシ完全な皮膜が形成さ
れるため、単一のコーティングの場合の欠点をすべて克
服することができ、利用価値の高い安定化された有機酸
が容易に得られる。According to the method of the present invention, since the inorganic or organic powder with low reactivity is on the outermost layer, reaction with other coexisting components is prevented, and a complete film is formed by double coating. As a result, all the drawbacks of a single coating can be overcome and a highly useful stabilized organic acid can be easily obtained.
本発明で使用される有機酸は、酒石酸、蓚酸、クエン酸
、コハク酸、グルタル酸、アジピン酸、リンゴ酸、フマ
ール酸、アスコルビン酸、安息香酸、ニコチン酸、アス
パラギン酸、などの有機カルボン酸やｐ−トルエンスル
ホン酸などのスルホン酸やスルファミン酸など常温で固
体のものであり、融点が５０℃以上のものが適当である
。コーティングのし易さから見て有機酸粉末の粒径は４
４μ以上が好ましく、より好ましくは、２５０μ以上で
ある。The organic acids used in the present invention include organic carboxylic acids such as tartaric acid, oxalic acid, citric acid, succinic acid, glutaric acid, adipic acid, malic acid, fumaric acid, ascorbic acid, benzoic acid, nicotinic acid, and aspartic acid. Suitable examples include sulfonic acids such as p-toluenesulfonic acid and sulfamic acid, which are solid at room temperature and have a melting point of 50°C or higher. From the viewpoint of ease of coating, the particle size of organic acid powder is 4.
It is preferably 4μ or more, more preferably 250μ or more.
次に４０℃以上の融点を有し、バインダーの働きをする
水溶性有機物としては分子量２００〜２０．０００のポ
リエチレングリコール、エチレンオキサイド・プロピレ
ンオキサイドブロック共重合物、ポリエチレングリコー
ルアルキルエーテル（エチレンオキサイド付加モル数１
５以上。Next, examples of water-soluble organic substances that have a melting point of 40°C or higher and act as a binder include polyethylene glycol with a molecular weight of 200 to 20,000, ethylene oxide/propylene oxide block copolymers, and polyethylene glycol alkyl ether (ethylene oxide added mole). Number 1
5 or more.
アルキル基の炭素数８〜２２）等が使用できるが、特に
、分子量４ 、０００〜１３，０００のポリエチレング
リコールがコーティングの作業性から見て好ましい。Although alkyl groups having 8 to 22 carbon atoms can be used, polyethylene glycol having a molecular weight of 4,000 to 13,000 is particularly preferred from the viewpoint of coating workability.
有機酸粉末に例えばポリエチレングリコールをコーティ
ングするに当っては、有機酸の融点以下でポリエチレン
グリコールの融点以上の温度に加熱して行なう。其の後
冷却するか、又はその１まの状態で、これに無機又は有
機物質の粉末をまぶしてコーティングすればよい。When coating an organic acid powder with, for example, polyethylene glycol, it is heated to a temperature below the melting point of the organic acid and above the melting point of polyethylene glycol. After that, it may be cooled, or it may be coated with an inorganic or organic powder.
無機又は有機物質の粉体としては、硫酸ナトリウム、塩
化ナトリウム、珪酸カルシウムの様な硫酸、塩酸、珪酸
のアルカリ金属又はアルカリ土類金属塩、ゼオライト、
二酸化ケイ素、無水クエン酸ナトリウム等アルカリ、漂
白剤等に対し化学的に不活性なものであればどの様なも
のも使用できるが、特に無水硫酸マグネシウム、珪酸カ
ルシウム、無水クエン酸ナトリウム及びゼオライトが好
ましい。粒径は４４μ以下が好ましく、より好ましくは
２０μ以下である。ゼオライトとしては次式で表わされ
るものが適尚である。 （Ｍ２／ｒｌＯ）Ｘ−Ａ！２０
．・（Ｓ１０□）ｙ（Ｍはナトリウム、カリクム、カル
シウム又はマグネシウム、ｎはＭの原子価に等しい数、
Ｘは０，７〜１．５、ｙは０．８〜１．０）。Powders of inorganic or organic substances include sulfuric acid, hydrochloric acid, alkali metal or alkaline earth metal salts of silicic acid such as sodium sulfate, sodium chloride, and calcium silicate, zeolites,
Any material can be used as long as it is chemically inert to alkalis such as silicon dioxide, anhydrous sodium citrate, bleaching agents, etc., but particularly preferred are anhydrous magnesium sulfate, calcium silicate, anhydrous sodium citrate, and zeolite. . The particle size is preferably 44μ or less, more preferably 20μ or less. Suitable zeolites are those represented by the following formula. (M2/rlO)X-A! 20
．．・(S10□)y (M is sodium, calicum, calcium or magnesium, n is a number equal to the valence of M,
X is 0.7-1.5, y is 0.8-1.0).
次に本発明の実施に当っての有機酸粉末と、４０℃以上
の融点を有する水溶性有機物と、化学的に不活性な有機
又は無機物質の粉体との使用割合であるが、有機′ｗ１
１００重量部に対して水溶性有機物は１〜４０重量部、
好ましくは３〜２５重量部、有機又は無機物質の粉体は
１−４０重量部、好ましくは３〜２５重量部で、何れも
有機酸粉末のまわりをコーティングし得る量あればよい
。Next, in carrying out the present invention, the proportions of organic acid powder, water-soluble organic substance having a melting point of 40°C or higher, and chemically inert organic or inorganic substance powder are as follows. w1
1 to 40 parts by weight of water-soluble organic matter per 100 parts by weight,
The amount is preferably 3 to 25 parts by weight, and the amount of organic or inorganic powder is 1 to 40 parts by weight, preferably 3 to 25 parts by weight, as long as the amount is enough to coat the organic acid powder.
本発明によれば常温で固体の有機酸粉末はポリエチレン
グリコールの様な水溶性有機物と、化学的に不活性な有
機又は無機粉体とによシ二重にコーティングされるので
、この様にコーティングされた有機酸は例えば重曹の様
なアルカリ物質と配合して発泡剤組成物とした場合、重
曹と有機酸との間に不活性な粉体が存在することにより
接触が防止され、ＣＯ２ガスの発生や発泡性の低下が起
らない。しかも本発明では水溶性有機物がバインダーと
して用いられているので、使用時水中で簡単に溶解し、
その上にコーティングした粉体を分散させ得る０
〔実施例〕
以下に本発明を実施例によシ更に詳述するが、本発明は
これらの実施例に限定されるものではない。According to the present invention, the organic acid powder, which is solid at room temperature, is double coated with a water-soluble organic substance such as polyethylene glycol and a chemically inert organic or inorganic powder. For example, when the organic acid produced is mixed with an alkaline substance such as baking soda to form a blowing agent composition, the presence of inert powder between the baking soda and the organic acid prevents contact and prevents CO2 gas from coming into contact with the organic acid. No generation or deterioration of foaming properties occurs. Moreover, since water-soluble organic substances are used as binders in the present invention, they easily dissolve in water during use.
The powder coated thereon can be dispersed. [Examples] The present invention will be described in more detail below with reference to Examples, but the present invention is not limited to these Examples.
実施例１
第１表に示す組成の配合を調整し、よく混合した後５０
℃２０日間保存して炭酸ガス発生量を調べることによシ
有機酸の残存率を測定した。Example 1 After adjusting the composition shown in Table 1 and mixing well,
The residual rate of the organic acid was measured by storing it at ℃ for 20 days and checking the amount of carbon dioxide gas generated.
結果を第１表に示す。The results are shown in Table 1.
実施例２
第２表に示す組成の配合を調整し、３ｆの錠剤とした後
、５０℃２０日間保存し有効塩素の残存率を測定した。Example 2 The composition shown in Table 2 was adjusted and the tablets were made into 3f tablets, which were stored at 50°C for 20 days and the residual rate of available chlorine was measured.
本発明品５
ジクロルイソシアヌル酸ソーダ ５０本発明品４
ジクロルインシアヌル酸ソーダ ５０比較品４
ジクロルインシアヌル酸ソーダ ５０の比でコーテ
ィングし冷却した
もの ５゜比較品５
ジクロルイソシアヌル酸ソーダ ５０クエン酸（粒
径７１０μ）４５
ポリエチレングリコール（分子
量６０００ ） ５第 ２
表
〔発明の効果〕
本発明によればアルカリ及び塩素系、酸素系漂白剤に対
して安定な有機酵粉末が容易に得られる。即ち本発明の
方法では冷却下でも不活性粉体の均一なコーティングが
可能であり、比較的低温でコーティングが行なえるだめ
、作業性が良好で、工程の短縮も可能である。本発明に
よシ安定化された有機酸は、実施例にも示す如く、重曹
の様なアルカリ性物質と配合して安定な発泡剤組成物を
与えることが出来るし、又漂白剤と配合して安定な漂白
剤組成物を与えることが出来る。Inventive product 5 Sodium dichloroisocyanurate 50 Inventive product 4 Sodium dichloroisocyanurate 50 Comparative product 4 Sodium dichloroisocyanurate Coated at a ratio of 50 and cooled 5° Comparative product 5 Sodium dichloroisocyanurate 50 Citric acid (particle size 710 μ) 45 Polyethylene glycol (molecular weight 6000) 5 2nd
Table [Effects of the Invention] According to the present invention, an organic yeast powder that is stable against alkali, chlorine, and oxygen bleaches can be easily obtained. That is, in the method of the present invention, it is possible to uniformly coat the inert powder even under cooling, and since the coating can be performed at a relatively low temperature, the workability is good and the process can be shortened. The organic acid stabilized according to the present invention can be blended with an alkaline substance such as baking soda to provide a stable blowing agent composition, as shown in the Examples, and can be blended with a bleaching agent to provide a stable blowing agent composition. A stable bleach composition can be provided.
出願人代理人 古 谷 馨１ＣApplicant's agent Kaoru Furutani 1C
Claims (1)
有する水溶性有機物により、該水溶性有機物の融点以上
の温度でコーティングし、次で化学的に不活性な有機又
は無機物質の粉体を更にその上にコーティングすること
を特徴とする有機酸の安定化方法。 ２ 有機酸が、酒石酸、リンゴ酸、クエン酸、コハク酸
、グルタル酸又はアジピン酸である特許請求の範囲第１
項記載の安定化方法。 ３ 水溶性有機物が分子量２０００〜２００００のポリ
エチレングリコール、エチレンオキサイド・プロピレン
オキサイドブロック共重合物又はポリエチレングリコー
ルアルキルエーテル（エチレンオキサイド付加モル数１
５以上、アルキル基の炭素数８〜２２）である特許請求
の範囲第１項記載の安定化方法。 ４ 有機又は無機物質の粉体が無水硫酸マグネシウム、
珪酸カルシウム、無水クエン酸ナトリウム又は次式 （Ｍ＿２＿／＿ｎＯ）＿ｘ・Ａｌ＿２Ｏ＿３・（ＳｉＯ
＿２）＿ｙ（Ｍはナトリウム、カリウム、カルシウム又
はマグネシウム、ｎはＭの原子価に等しい数、ｘは０．
７〜１．５、ｙは０．８〜１．０）で表わされるゼオラ
イトである特許請求の範囲第１項記載の安定化方法。 ５ 有機酸１００重量部に対する割合が、水溶性有機物
１〜４０重量部、有機又は無機物質の粉体１〜４０重量
部である特許請求の範囲第１項〜第４項の何れか１項に
記載の安定化方法。[Claims] 1. An organic acid powder that is solid at room temperature is coated with a water-soluble organic substance having a melting point of 40°C or higher at a temperature higher than the melting point of the water-soluble organic substance, and then coated with a chemically inert powder. A method for stabilizing an organic acid, which comprises further coating a powder of an organic or inorganic substance thereon. 2 Claim 1 in which the organic acid is tartaric acid, malic acid, citric acid, succinic acid, glutaric acid or adipic acid
Stabilization method described in section. 3 The water-soluble organic substance is polyethylene glycol with a molecular weight of 2000 to 20000, an ethylene oxide/propylene oxide block copolymer, or a polyethylene glycol alkyl ether (the number of moles of ethylene oxide added is 1
5 or more, and the number of carbon atoms in the alkyl group is 8 to 22). 4 Organic or inorganic substance powder is anhydrous magnesium sulfate,
Calcium silicate, anhydrous sodium citrate or the following formula (M_2_/_nO)_x・Al_2O_3・(SiO
_2)_y (M is sodium, potassium, calcium, or magnesium, n is a number equal to the valence of M, x is 0.
7 to 1.5, and y is 0.8 to 1.0). 5. According to any one of claims 1 to 4, the proportion of water-soluble organic substance to 100 parts by weight of organic acid is 1 to 40 parts by weight, and 1 to 40 parts by weight of powder of organic or inorganic substance. Stabilization method described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59123380A JPS611637A (en) | 1984-06-15 | 1984-06-15 | Stabilization of organic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59123380A JPS611637A (en) | 1984-06-15 | 1984-06-15 | Stabilization of organic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS611637A true JPS611637A (en) | 1986-01-07 |
| JPH0430937B2 JPH0430937B2 (en) | 1992-05-25 |
Family
ID=14859145
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59123380A Granted JPS611637A (en) | 1984-06-15 | 1984-06-15 | Stabilization of organic acid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS611637A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0276868A (en) * | 1987-10-19 | 1990-03-16 | Takeda Chem Ind Ltd | Production of stable sodium ascorbate composition and powder |
| EP0396287A2 (en) * | 1989-05-04 | 1990-11-07 | The Clorox Company | Method and product for enhanced bleaching with in situ peracid formation |
| JPH04506677A (en) * | 1989-05-16 | 1992-11-19 | ジェイ エム ヒューバー コーポレーション | Endothermic blowing agent composition and application |
| JP2001276597A (en) * | 2000-03-31 | 2001-10-09 | Kobayashi Pharmaceut Co Ltd | Granulated powder, its production method, and solid compression molded item |
| US20120190608A1 (en) * | 2009-05-20 | 2012-07-26 | Reckitt Benckiser N.V. | Coated crystalline polycarboxylate particles |
| JP2018115296A (en) * | 2017-01-20 | 2018-07-26 | 株式会社Adeka | Cleaning agent composition and cleaning method thereof |
| JPWO2017183726A1 (en) * | 2016-04-22 | 2019-02-28 | 四国化成工業株式会社 | Solid bleaching agent-containing and cleaning composition |
| JP2019183162A (en) * | 2019-06-19 | 2019-10-24 | 株式会社Adeka | Detergent composition and cleaning method therefor |
-
1984
- 1984-06-15 JP JP59123380A patent/JPS611637A/en active Granted
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0276868A (en) * | 1987-10-19 | 1990-03-16 | Takeda Chem Ind Ltd | Production of stable sodium ascorbate composition and powder |
| EP0396287A2 (en) * | 1989-05-04 | 1990-11-07 | The Clorox Company | Method and product for enhanced bleaching with in situ peracid formation |
| EP0396287A3 (en) * | 1989-05-04 | 1991-10-02 | The Clorox Company | Method and product for enhanced bleaching with in situ peracid formation |
| US5505740A (en) * | 1989-05-04 | 1996-04-09 | The Clorox Company | Method and product for enhanced bleaching with in situ peracid formation |
| JPH04506677A (en) * | 1989-05-16 | 1992-11-19 | ジェイ エム ヒューバー コーポレーション | Endothermic blowing agent composition and application |
| JP2001276597A (en) * | 2000-03-31 | 2001-10-09 | Kobayashi Pharmaceut Co Ltd | Granulated powder, its production method, and solid compression molded item |
| US20120190608A1 (en) * | 2009-05-20 | 2012-07-26 | Reckitt Benckiser N.V. | Coated crystalline polycarboxylate particles |
| JPWO2017183726A1 (en) * | 2016-04-22 | 2019-02-28 | 四国化成工業株式会社 | Solid bleaching agent-containing and cleaning composition |
| JP2018115296A (en) * | 2017-01-20 | 2018-07-26 | 株式会社Adeka | Cleaning agent composition and cleaning method thereof |
| JP2019183162A (en) * | 2019-06-19 | 2019-10-24 | 株式会社Adeka | Detergent composition and cleaning method therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0430937B2 (en) | 1992-05-25 |
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