JPS6115926B2 - - Google Patents
Info
- Publication number
- JPS6115926B2 JPS6115926B2 JP2631679A JP2631679A JPS6115926B2 JP S6115926 B2 JPS6115926 B2 JP S6115926B2 JP 2631679 A JP2631679 A JP 2631679A JP 2631679 A JP2631679 A JP 2631679A JP S6115926 B2 JPS6115926 B2 JP S6115926B2
- Authority
- JP
- Japan
- Prior art keywords
- wire
- steel
- cooled
- strength
- conveyor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000831 Steel Inorganic materials 0.000 claims description 32
- 239000010959 steel Substances 0.000 claims description 32
- 238000001816 cooling Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000005098 hot rolling Methods 0.000 claims description 4
- 229910000734 martensite Inorganic materials 0.000 claims description 4
- 229910001566 austenite Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 238000005496 tempering Methods 0.000 description 6
- 238000010791 quenching Methods 0.000 description 5
- 230000000171 quenching effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000000137 annealing Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000010622 cold drawing Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/525—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
Description
本発明は、PC鋼棒用等の高張力鋼線材の製造
方法に関するものである。
従来、たとえばJIS―G―3109 SBPD130/145
級(ここに130は降伏点を、145は引張強度を示
す)の高張力PC鋼棒は、圧延素材を得た後、冷
間伸線矯正(異形)加工し、これを焼入し、次い
で焼戻して製造するものである。この従来法は、
焼入れによつて目標の引張強度を得るものであ
り、したがつて焼入れ、焼戻しに要する製造費お
よび製造設備が嵩みかつ大規模となつていた。
本発明は前記問題点を一挙に解決したものであ
り、特定の成分の鋼を用い、かつ圧延条件を特定
化することによつて、焼入を一切省き、圧延のみ
で高張力鋼線材を製造し、さらに従来の焼戻し工
程において温間矯正法を適用し、降伏点、耐リラ
クセーシヨン特性等の機械的性質を改善し、もつ
て大巾な合理化を達成するとともに、PC鋼棒に
要求される種々の機械的性質を十分満足する高張
力鋼線材を得ることを目的とするものである。
すなわち本発明は、C:0.10〜0.40%、Si:
0.05〜1.50%、Mn:0.70〜2.50%、Cr:0.10〜
1.50%、Mo:0.05〜0.50%、残部Fe:および不
可避の不純物からなる成分系の鋼を、熱間圧延
後、直ちに500〜700℃に強制冷却し、過冷オース
テナイトの状態でコンベア上に連続したリング状
をなして展開し、衝風によつて7℃/sec以上の
冷却速度で冷却してコンベア上において線材全体
をマルテンサイト組織となした後、集束装置にお
いてコイル状とし徐冷してセルフテンパーを行な
い、強靭性を有する引張強度110Kg/mm2以上の高
強度の高張力鋼線材を得、続いて100〜450℃の温
度範囲で線材の曲りが4mm/1.5m以内になるよ
うに温間矯正を行ない、高降伏点を有し、かつ耐
リラクセーシヨン特性の優れた高張力鋼線材を得
ることを特徴とするものである。
本発明においては熱間圧延後直ちに500〜700℃
に強制冷却する。この場合の衝風冷却開始時すな
わち過冷オーステナイト材料温度を500〜700℃と
したのは、理論的には700℃以上の材料を冷却し
てもコンベア上においてマルテンサイト組織とす
ることは可能であるが、冷却開始温度が高くなる
と必然的に衝風冷却時間が長時間となり特に7
℃/sec程度の冷却速度では現実的なコンベア長
さの制限があるためマルテンサイト変態が完了し
ないうちに次の集束装置に入るので、部分的にペ
イナイト組織が生じ所期の目的から不適である。
一方、下限を500℃としたのは実際の圧延作業に
おいてこれ以下の温度にきわめて短時間のうちに
圧延直後冷却することは困難でありまた経済的で
もないからである。
さらに本発明の鋼は特定の組成を有している。
Cは鋼に必要な強度と焼入性を与えるために添加
されるが、C量が0.40%以上になるとPC鋼棒に
要求される延性および点溶接性が著しく劣下し好
ましくない。C量が0.10%以下では、PC鋼棒と
しての必要な強度が発現しない。Siは焼入性の向
上、強度および強靭の改善に有効な元素である
が、Si量が1.50%以下ではその効果がなく、Si量
が1.50%以上添加すると延性が劣化し好ましくな
い。Mnは焼入性向上に効果があるが、0.70%以
下では焼入性向上期待できないし、2.50%以上で
は経済的でない。CrはMnと同様に鋼の焼入性を
向上させるが、0.10%以下ではその効果がない
し、1.50%以上を越えると経済的でない。Moも
Crと同様に鋼の焼入性を向上させるが、0.05%以
下ではその効果がなく、0.50%以上では経済的で
ない。
一方、衝風による冷却速度は7℃/sec以上が
望ましい。その以下の速度では、ペイナイト組
織、フエライト組織等が発生し、不完全焼入組織
となり所期の目的を達成できない。
次に、熱間圧延において前述のような方法を採
用することによつて、目標の引張強度を得ること
は可能であるが、PC鋼棒に要求される降伏点、
耐リラクセーシヨン特性を得ることはできない。
そのため、本発明においては、集束装置において
線材を徐冷した後、ひき続いて、従来の焼戻し工
程に相当する温間矯正を行なう。この温間矯正に
よつて、線材の曲りが矯正されるとともに、PC
鋼棒に要求される降伏点、耐リラクセーシヨン特
性を十分に満足しかつ従来の焼戻しによるものよ
り良好な線材が得られる。
この温間矯正は、100〜450℃の温度範囲で線材
の曲りが1.5m当り4mm以下となるように行な
う。ここにおいて矯正温度を100〜450℃としたの
は、100℃以下では優れたリラクセーシヨン値が
得られないため、450℃以上では本成分系におい
て高降伏点が得られないためである。さらに、
PC鋼棒は真直性が大きく要求され、例えば1.5m
当り4mm以上の曲りは製品として使用できないと
いうことから、矯正効果は4mm/1.5m以下とし
た。
次に本発明者が行なつた実験例を示す。すなわ
ち第1表に示す本発明に係る10種の鋼を供試材と
した。
The present invention relates to a method for manufacturing high-tensile steel wire rods for use in PC steel bars and the like. Conventionally, for example, JIS-G-3109 SBPD130/145
High-strength PC steel bars of grade (130 indicates yield point and 145 indicates tensile strength) are obtained by obtaining rolled material, cold drawing straightening (deformation), quenching, and then It is manufactured by tempering. This conventional method is
The target tensile strength is obtained by quenching, and therefore the manufacturing cost and manufacturing equipment required for quenching and tempering are large and large-scale. The present invention solves the above-mentioned problems all at once. By using steel with specific components and specifying rolling conditions, high-strength steel wire rods can be manufactured only by rolling without quenching. Furthermore, by applying a warm straightening method to the conventional tempering process, we have improved mechanical properties such as yield point and relaxation resistance, achieving significant rationalization and improving the properties required for PC steel bars. The purpose of this study is to obtain a high-tensile steel wire rod that satisfactorily satisfies various mechanical properties. That is, in the present invention, C: 0.10 to 0.40%, Si:
0.05~1.50%, Mn: 0.70~2.50%, Cr: 0.10~
After hot rolling, steel with a composition of 1.50%, Mo: 0.05~0.50%, balance Fe: and unavoidable impurities is immediately forcedly cooled to 500~700℃, and then continuously transferred on a conveyor in the state of supercooled austenite. The wire is rolled out into a ring shape, cooled by air blast at a cooling rate of 7°C/sec or more to make the entire wire into a martensitic structure on a conveyor, and then formed into a coil in a converging device and slowly cooled. Self-tempering is performed to obtain a high-strength, high-strength steel wire with a tensile strength of 110 Kg/mm 2 or more, and then the bending of the wire is within 4 mm/1.5 m in a temperature range of 100 to 450°C. It is characterized by performing warm straightening to obtain a high-tensile steel wire having a high yield point and excellent relaxation resistance. In the present invention, the temperature is 500 to 700℃ immediately after hot rolling.
Forced cooling. In this case, the temperature at the start of blast cooling, that is, the temperature of the supercooled austenite material, was set at 500 to 700°C because theoretically it is possible to form a martensitic structure on the conveyor even if the material is cooled to 700°C or higher. However, if the cooling start temperature increases, the blast cooling time will inevitably become longer, especially at 7.
At a cooling rate of about °C/sec, there is a practical limit on the length of the conveyor, so the material enters the next focusing device before martensitic transformation is complete, resulting in a partial paynite structure, which is unsuitable for the intended purpose. .
On the other hand, the lower limit was set at 500° C. because in actual rolling operations, it is difficult and uneconomical to cool down to a temperature lower than this in a very short time immediately after rolling. Furthermore, the steel of the invention has a specific composition.
C is added to give the steel the necessary strength and hardenability, but if the C content exceeds 0.40%, the ductility and spot weldability required for a PC steel bar will significantly deteriorate, which is undesirable. If the C content is less than 0.10%, the required strength as a PC steel bar will not be achieved. Si is an element effective in improving hardenability, strength, and toughness, but if the amount of Si is less than 1.50%, it has no effect, and if the amount of Si is added more than 1.50%, the ductility deteriorates, which is not preferable. Mn is effective in improving hardenability, but if it is less than 0.70%, no improvement in hardenability can be expected, and if it is more than 2.50%, it is not economical. Like Mn, Cr improves the hardenability of steel, but if it is less than 0.10% it has no effect, and if it exceeds 1.50% it is not economical. Mo too
Like Cr, it improves the hardenability of steel, but if it is less than 0.05% it has no effect and if it is more than 0.50% it is not economical. On the other hand, the cooling rate by blast is preferably 7° C./sec or more. At a speed lower than that, a paynite structure, a ferrite structure, etc. are generated, resulting in an incompletely quenched structure and the intended purpose cannot be achieved. Next, although it is possible to obtain the target tensile strength by adopting the method described above in hot rolling, the yield point required for the PC steel bar,
Anti-relaxation properties cannot be obtained.
Therefore, in the present invention, after the wire is slowly cooled in the focusing device, warm straightening corresponding to the conventional tempering process is performed. Through this warm straightening, the bend in the wire is straightened, and the PC
A wire rod that fully satisfies the yield point and relaxation resistance characteristics required of a steel rod and is better than that obtained by conventional tempering can be obtained. This warm straightening is carried out in a temperature range of 100 to 450°C so that the bending of the wire is 4 mm or less per 1.5 m. The reason why the straightening temperature is set at 100 to 450°C is that an excellent relaxation value cannot be obtained below 100°C, and a high yield point cannot be obtained in this component system above 450°C. moreover,
PC steel bars require great straightness, for example 1.5m
Since bends of 4 mm or more cannot be used as products, the straightening effect was set to 4 mm/1.5 m or less. Next, an example of an experiment conducted by the present inventor will be shown. That is, 10 types of steel according to the present invention shown in Table 1 were used as test materials.
【表】【table】
【表】
これらの鋼を熱間圧延によつて7.1mmφに圧延
し、強制水冷設備によつて650℃に直ちに急冷し
た。この場合、650℃および500℃を安定して得る
ために、圧延速度を従来法の45m/Secを35m/
Secに下げて圧延した。続いてレーイングコーン
によりリング状となし、コンベア上に展開し、
0.4m/Secの速度でコンベア上に移動させた。こ
のときコンベアの下部および両サイドから7℃/
sec以上(約10℃/sec)の冷却能力を有する衝風
を吹付け冷却したコンベア長さは40mであり、冷
却時間は100秒である。次いで集束装置にてコイ
ル状となし徐冷した。
こうして得られた線材の引張性質を第2表に示
す。また鋼組成は同じであるが、強制冷却温度を
850℃とし、かつ冷却速度を4℃/secとした比較
例による線材の引張性質も併記した。[Table] These steels were hot rolled to a diameter of 7.1 mm and immediately quenched to 650°C using forced water cooling equipment. In this case, in order to stably obtain 650℃ and 500℃, the rolling speed was changed from the conventional method of 45m/Sec to 35m/Sec.
It was lowered to Sec and rolled. Next, it is formed into a ring shape using a laying cone and rolled out on a conveyor.
It was moved onto the conveyor at a speed of 0.4 m/Sec. At this time, from the bottom and both sides of the conveyor,
The length of the conveyor, which was cooled by blowing air with a cooling capacity of 10° C. or more (approximately 10° C./sec), was 40 m, and the cooling time was 100 seconds. Next, it was formed into a coil shape using a convergence device and slowly cooled. The tensile properties of the wire thus obtained are shown in Table 2. Also, although the steel composition is the same, the forced cooling temperature has been changed.
The tensile properties of a wire rod according to a comparative example where the temperature was 850°C and the cooling rate was 4°C/sec are also shown.
【表】【table】
【表】
上記から明らかなように、本発明法によれば、
PC鋼棒等に用いても十分な高引張強度を有し、
かつばらつきが小さく、また延性も秀れた線材が
得られることが判明する。(さらに、鋼組成は同
じでも、製造条件を変えると、強度が低く、ばら
つきの大きい線材を得ることになる。
しかしながら、このままでは降伏点が極めて低
いため、引続いて集束装置においてコイル状とし
徐冷した線材を温間矯正した。供試材は1表に示
すA,D,F,GおよびJおよびIの5鋼種を使
用し、第2表における強制冷却温度550℃のもの
について温間矯正を実施した。矯正温度は、
200,300および500℃とし、加熱は抵抗加熱法に
よつて行なつた。矯正は前記の加熱を行なつた
後、千鳥状に配列した計9個のアイドル―ロール
群を水平および垂直に配列して行ない線材の曲り
が2mm/1.5m以内となるようにロールの圧下を
調整した。線材の送り速度は、5m/minであ
る。
こうして得られた線材の降伏点、常温リラクセ
ーシヨン値等の機械的性質を第3表に示す。また
比較のために温間矯正を行なわない単なる低温焼
鈍法による比較例も併記した。さらに、リラクセ
ーシヨン値は、降伏荷重の80%の荷重を負荷し、
10時間経過後の値である。[Table] As is clear from the above, according to the method of the present invention,
It has high tensile strength enough to be used in PC steel bars, etc.
It has also been found that a wire rod with small variations and excellent ductility can be obtained. (Furthermore, even if the steel composition is the same, changing the manufacturing conditions will result in a wire with low strength and large variations. However, as the yield point is extremely low, it is subsequently made into a coil in a converging device and gradually reduced. The cooled wire rods were warm-straightened. Five steel types, A, D, F, G, J, and I, shown in Table 1 were used as test materials, and those with a forced cooling temperature of 550°C in Table 2 were warm-straightened. The straightening temperature was
Heating was carried out at 200, 300 and 500°C using a resistance heating method. After the above-mentioned heating, straightening is performed by horizontally and vertically arranging a total of nine idle roll groups arranged in a staggered manner, and rolling down the rolls so that the wire bends within 2 mm/1.5 m. It was adjusted. The feeding speed of the wire rod was 5 m/min. Table 3 shows mechanical properties such as yield point and room temperature relaxation value of the wire thus obtained. For comparison, a comparative example using a simple low-temperature annealing method without warm straightening is also shown. Furthermore, the relaxation value applies a load of 80% of the yield load,
This is the value after 10 hours.
【表】【table】
【表】
第3表から明らかなように、100〜450℃で温間
矯正を行なうことにより、PC鋼棒に要求される
降伏点、リラクセーシヨン値を十分に満足し、真
直性も良好な線材が得られる。
また、上表から明らかなように、本発明法によ
れば、PC鋼棒等に用いても十分な高引張強度を
有し、かつばらつきが小さく、また延性も秀れた
線材が得られることが判明する。さらに鋼組成は
同じでも、製造条件を変えると、強度が低く、ば
らつきの大きい線材を得ることになる。
以上の通り、本発明によれば、特定の組成の鋼
を特定の条件のもとで圧延冷却し、さらに温間矯
正を行なうものであるから、焼入れを行なわなく
とも、高強度の線材を得ることができ、その価値
はきわめて大である。[Table] As is clear from Table 3, by performing warm straightening at 100 to 450℃, the yield point and relaxation value required for PC steel bars are fully satisfied, and the straightness is also good. A wire rod is obtained. Furthermore, as is clear from the above table, according to the method of the present invention, a wire rod with sufficient high tensile strength even when used as a PC steel bar, with small variations, and with excellent ductility can be obtained. becomes clear. Furthermore, even if the steel composition is the same, changing the manufacturing conditions will result in a wire rod with low strength and large variations. As described above, according to the present invention, steel of a specific composition is rolled and cooled under specific conditions, and further warm straightening is performed, so a high-strength wire rod can be obtained without quenching. It is possible to do so, and its value is extremely high.
Claims (1)
0.70〜2.50%、Cr:0.10〜1.50%、Mo:0.05〜
0.50%、残部Feおよび不可避の不純物からなる
成分系の鋼を、熱間圧延後、直ちに500〜700℃に
強制冷却し、過冷オーステナイトの状態でコンベ
ア上に連続したリング状をなして展開し、衝風に
よつて7℃/秒以上の冷却速度で冷却してコンベ
ア上において線材全体をマルテンサイト組織とな
した後、集束装置においてコイル状とし徐冷して
セルフテンパーを行ない、強靭性を有する引張強
度110Kg/mm2以上の高強度の高張力鋼線材を得、
続いて100〜450℃の温度範囲で線材の曲りが4
mm/1.5m以内になるよう温間矯正を行ない、高
降伏点を有し、かつ耐リラクセーシヨン特性の優
れた高張力鋼線材を得ることを特徴とする高張力
線材の製造方法。1 C: 0.10-0.40%, Si: 0.05-1.50%, Mn:
0.70~2.50%, Cr: 0.10~1.50%, Mo: 0.05~
After hot rolling, steel with a composition of 0.50%, the balance being Fe and unavoidable impurities is immediately forcedly cooled to 500 to 700℃ and rolled out in a continuous ring shape on a conveyor in the state of supercooled austenite. The wire is cooled by blast air at a cooling rate of 7°C/sec or more to form a martensitic structure in the entire wire on a conveyor, and then coiled in a converging device and slowly cooled to self-temper, increasing its toughness. Obtain a high-strength high-tensile steel wire rod with a tensile strength of 110 Kg/mm 2 or more,
Next, the wire bends 4 times in the temperature range of 100 to 450℃.
1. A method for producing a high-tensile steel wire, which is characterized by performing warm straightening to within mm/1.5 m to obtain a high-tensile steel wire having a high yield point and excellent relaxation resistance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2631679A JPS55119134A (en) | 1979-03-07 | 1979-03-07 | Manufacture of high tensile steel wire rod |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2631679A JPS55119134A (en) | 1979-03-07 | 1979-03-07 | Manufacture of high tensile steel wire rod |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS55119134A JPS55119134A (en) | 1980-09-12 |
JPS6115926B2 true JPS6115926B2 (en) | 1986-04-26 |
Family
ID=12189970
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2631679A Granted JPS55119134A (en) | 1979-03-07 | 1979-03-07 | Manufacture of high tensile steel wire rod |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS55119134A (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6043892B2 (en) * | 1980-11-08 | 1985-10-01 | 住友金属工業株式会社 | High tensile strength wire manufacturing method |
JPS601931B2 (en) * | 1980-11-08 | 1985-01-18 | 住友金属工業株式会社 | High tensile strength wire manufacturing method |
JPS5782431A (en) * | 1980-11-08 | 1982-05-22 | Sumitomo Metal Ind Ltd | Production of high tension wire rod |
GB2088257B (en) * | 1980-11-08 | 1984-07-18 | Sumitomo Metal Ind | Making rod or wire |
JPS57126913A (en) * | 1981-01-27 | 1982-08-06 | Kobe Steel Ltd | Production of high-toughness high-strength wire or rod steel |
JPS58338A (en) * | 1981-06-26 | 1983-01-05 | High Frequency Heattreat Co Ltd | Manufacturing device for steel rod or steel wire for prestressed concrete with superior delay breaking and superior mechanical characteristics |
CN104451407B (en) * | 2014-11-25 | 2016-08-24 | 东北大学 | A kind of low-carbon hot-rolling ultra-high-strength/tenacity steel and preparation method thereof |
CN106319180A (en) * | 2016-08-31 | 2017-01-11 | 云南德胜钢铁有限公司 | Machining technology of anti-knock reinforcing steel bars |
-
1979
- 1979-03-07 JP JP2631679A patent/JPS55119134A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS55119134A (en) | 1980-09-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4016009A (en) | Producing rolled steel products | |
KR100517674B1 (en) | Hot rolled wire or steel bar for machine structural use capable of dispensing with annealing, and method for producing the same | |
CA2135255C (en) | Cold deformable, high strength, hot rolled bar and method for producing same | |
CN107619993A (en) | Yield strength 750MPa level cold rolling martensite steel plates and its manufacture method | |
EP0190312A1 (en) | Controlled rolling process for dual phase steels and application to rod, wire, sheet and other shapes | |
JPH0112816B2 (en) | ||
US4040872A (en) | Process for strengthening of carbon steels | |
JPS6115926B2 (en) | ||
US4180418A (en) | Method of making a steel wire adapted for cold drawing | |
JPS6358891B2 (en) | ||
CN1067111C (en) | Method of cooling steel sections which are hot from rolling | |
JPS6151007B2 (en) | ||
JPS646249B2 (en) | ||
JP3760640B2 (en) | Steel pipe manufacturing method | |
JPH06346146A (en) | Production of wire rod for cold forming coil spring and device therefor | |
Das et al. | Metallurgical investigation of welding wire rod grade during processing | |
CN103215423B (en) | Production method of hot rolled and phase-change induced plastic steel coil | |
USRE28878E (en) | High-strength low-alloy steels | |
JPH09287029A (en) | Production of high strength seamless steel pipe excellent in toughness | |
JPS5940208B2 (en) | Manufacturing method of high-tensile steel wire rod | |
JPH07150247A (en) | Production of steel tube with high strength and low yield ratio for construction use | |
US3615925A (en) | Heat-treatment of steels | |
JPS6343445B2 (en) | ||
US4284438A (en) | Manufacture of steel products | |
JPS6219488B2 (en) |