JPS6115891Y2 - - Google Patents
Info
- Publication number
- JPS6115891Y2 JPS6115891Y2 JP9663881U JP9663881U JPS6115891Y2 JP S6115891 Y2 JPS6115891 Y2 JP S6115891Y2 JP 9663881 U JP9663881 U JP 9663881U JP 9663881 U JP9663881 U JP 9663881U JP S6115891 Y2 JPS6115891 Y2 JP S6115891Y2
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- fragrances
- impregnated
- vapor pressure
- impregnated body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003205 fragrance Substances 0.000 claims description 49
- 239000002131 composite material Substances 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 230000000052 comparative effect Effects 0.000 description 7
- 239000011148 porous material Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 235000019645 odor Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002386 air freshener Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Description
本考案は複合香料からなる芳香体において経時
的に香調が変化せず、常に一定の芳香を発する芳
香体に関する。
一般家庭、自動車等に使用する芳香体は家庭内
の居間、台所、トイレや自動車内等異なる匂いの
場所に普遍的に使用し得るように、個人的好みだ
けで使用する香水とは異なり、数多くの単品香料
を混ぜて多数の人が好むような香調を発するよう
に工夫されている。しかし香料はそれぞれ個有の
蒸気圧があり、例えば2種の複合香料の場合、そ
れが室温で蒸気圧の大なるものと小なるものの2
種であるときは、従来のように2種の香料を混合
して溶剤に溶かした液状や、適当な担体に同時に
浸み込ませた固型のもの等にあつては、蒸気圧の
大なるものが先に揮散し、ある時間経過した後で
は蒸気圧の大なるものは殆んど残存せず、蒸気圧
の小なるもののみが残つて、始めと終りでは香調
も香量も異なる。
また香料の保留剤としてグリコール類等を使用
することがあるが、これは蒸気圧の大なる香料を
保留剤に溶解することによつて急激な揮散を抑え
て放香時間を延長させようとするもので、単味の
香料については常時ほぼ一定の香量にコントロー
ルするという意味では効果はあるが、数種の複合
香料については本考案の目的とする経時的に香調
を変化させないで一定の芳香を発する面では充分
でない。
本考案者らは蒸気圧の異なる数種の香料からな
る複合香料をいかにして経時的に香調を変化させ
ないで一定に保つことができるかについて種々検
討した結果、香料を浸み込ませる担体を蒸気圧に
応じて別々にし、蒸気圧の大→小に従つて揮散し
難くするようにすることによつて目的を達し本考
案を完成した。
本考案を図によつて説明する。第1図は本考案
の複合香料芳香体の一実施例で3種類の蒸気圧の
異なる香料を使用するとすれば、蒸気圧の大→小
の順序に従いそれぞれ別個に香料を浸み込ませた
担体、すなわち含浸体を1,2,3の如く下から
上に適宜間隔を置いて設ける。すなわち蒸気圧の
大なる程揮散し難くする。6は各段の含浸体を支
える支柱である。そして最下段含浸体1の直ぐ上
段の含浸体2にいくつかの孔4を穿設して最下段
含浸体1より揮散した香料の通路とする。さらに
最上段含浸体3にも孔5を穿設するが、中段含浸
体2の香料は最下段含浸体1の香料より蒸気圧が
小さいためと、最下段含浸体1からの香料との共
通通路とするために中段の孔4より最上段の孔5
は孔径を大きくするか、孔数を多くする必要があ
る。この孔径及び孔数は使用する各香料の蒸気圧
の相対関係によつて異なり、一概には決められな
いが、最下段の直ぐ上段〜最上段において大凡2
〜15mmφ(含浸体の面積によつても異なる)の範
囲である。
3段の含浸体を例えば図の如き頂上に放香口8
をもつた容器7に収納すれば複合香料芳香体とな
る。
例として3段の場合で本考案を説明したが、香
料の種類がさらに多ければ含浸体の段数をそれだ
け増せばよく、何段設けても差支えない。また香
料の種類が異なつても蒸気圧に殆んど差がなけれ
ば同じ担体に何種類の香料を含浸させても何ら差
支えない。
ここで含浸体は香料を浸み込ませる担体である
から、香料の浸み込みやすい多孔質プラスチツ
ク、紙、素焼陶器等、香料と反応したり、香料
を変質させないものであれば何でもよく特に制限
はない。さらに担体としてプラスチツク成形品を
使用し、成形時に予め香料を配合して適当形状に
成形して含浸体とすることもできる。この場合成
形時の温度で殆んど揮散したり熱分解する香料は
使用できない。また形状も第1図の如き円形のほ
か、惰円、多角形等任意に選び得る。さらに含浸
体の大きさを下段に行くに従い大きくして行き上
記の孔の代りにすることもできる。
次に実施例を挙げて本考案をさらに具体的に説
明する。
実施例、比較例1
3種の香料を揮散しやすい順にトツプノート
(例えば沸点200℃以下)、ミドルノート(例えば
沸点200〜240℃)及びエンドノート(例えば沸点
240℃以上)とし、これらを第1図の如く下の段
から担体に香料別に含浸させた後容器に収納して
揮散させた。この場合香料量はすべて約10gで担
体は50mmφであり、孔は上段が5mmφを数個、中
段には3mmφを数個あけた。
一方実施例と同一寸法の3段の担体に実施例と
同じ3種の香料を混合して含浸させ揮散させた。
実施例及び比較例1の揮散量の経時変化を第1
表に示す。
比較例 2
比較例1に使用したトツプノート、ミドルノー
ト及びエンドノートの3種の香料を混合して製品
化されている市販のゲル芳香剤を実施例1と同じ
容器に収納して揮散させた揮散量の経時変化を第
1表に示す。
なお第1表は各経時(揮散率)で標準状態(各
例における密封状態)の香調と比較して(1)「同
じ」、(2)「やや違う」及び(3)「明らかに違う」の
3ランクに別けて20名の人の嗅覚による判定結果
を示したものである。
The present invention relates to an aromatic body made of a composite fragrance that does not change its scent tone over time and always emits a constant aroma. Unlike perfumes, which are used only based on personal preference, aromatic substances used in general homes and automobiles can be used universally in places with different odors such as the living room, kitchen, toilet, and inside of automobiles. It is designed to mix individual fragrances to produce a scent that is liked by many people. However, each fragrance has its own unique vapor pressure. For example, in the case of two types of compound fragrance, one with a high vapor pressure and one with a small vapor pressure at room temperature.
When the seeds are in the form of a liquid, which is a conventional mixture of two types of fragrances dissolved in a solvent, or solids, which are impregnated into a suitable carrier at the same time, they have a large vapor pressure. The substances volatilize first, and after a certain period of time, there is almost no residue left of those with high vapor pressure, only those with low vapor pressure, and the fragrance tone and amount are different at the beginning and end. In addition, glycols and the like are sometimes used as fragrance retention agents, but by dissolving fragrances with a high vapor pressure into the retention agent, it is possible to suppress rapid volatilization and extend the fragrance release time. Although it is effective in the sense of controlling the fragrance amount to a constant level at all times for single fragrances, it is effective in controlling the fragrance amount to a constant level over time, which is the purpose of this invention, for several types of compound fragrances. It is not sufficient in terms of emitting aroma. The inventors of the present invention conducted various studies on how to maintain a constant fragrance tone over time without changing the fragrance tone of a composite fragrance consisting of several types of fragrances with different vapor pressures. The objective was achieved and the present invention was completed by dividing the vapor pressure into different amounts depending on the vapor pressure, and making it more difficult to volatilize as the vapor pressure increases. The present invention will be explained using figures. Figure 1 shows an example of the composite fragrance aromatic product of the present invention. If three types of fragrances with different vapor pressures are used, the carriers are impregnated with the fragrances separately according to the order of the vapor pressure from high to low. That is, the impregnated bodies are provided at appropriate intervals such as 1, 2, and 3 from bottom to top. In other words, the higher the vapor pressure, the more difficult it is to volatilize. 6 is a support supporting the impregnated body at each stage. Then, several holes 4 are bored in the impregnated body 2 immediately above the lowermost impregnated body 1 to serve as a passage for the fragrance volatilized from the lowermost impregnated body 1. Furthermore, a hole 5 is also bored in the uppermost impregnated body 3, but this is because the fragrance in the middle impregnated body 2 has a lower vapor pressure than the fragrance in the lowermost impregnated body 1, and because it is a common passage with the fragrance from the lowermost impregnated body 1. In order to
It is necessary to increase the pore diameter or the number of pores. The pore diameter and number of pores vary depending on the relative relationship of vapor pressure of each fragrance used, and cannot be determined unconditionally, but approximately 2
~15mmφ (varies depending on the area of the impregnated body). For example, a three-tiered impregnated body with an incense outlet 8 at the top as shown in the figure.
If it is stored in a container 7 with a shape, it becomes a composite fragrance aromatic body. As an example, the present invention has been described in the case of three stages, but if there are more types of fragrances, the number of stages of the impregnated body may be increased accordingly, and there is no problem in providing any number of stages. Further, even if the types of fragrances are different, there is no problem even if the same carrier is impregnated with any number of fragrances as long as there is almost no difference in vapor pressure. Here, the impregnated body is a carrier into which the fragrance is impregnated, so any material that does not react with the fragrance or change the quality of the fragrance, such as porous plastic, paper, and unglazed pottery into which the fragrance permeates, may be used, and there are no particular restrictions. There isn't. Furthermore, it is also possible to use a plastic molded article as a carrier, mix a fragrance in advance at the time of molding, and mold it into a suitable shape to obtain an impregnated body. In this case, fragrances that mostly volatilize or thermally decompose at the temperature during molding cannot be used. In addition to the circular shape shown in FIG. 1, the shape can be arbitrarily selected such as a circular shape or a polygonal shape. Furthermore, the size of the impregnated body can be increased toward the bottom, and can be used instead of the holes described above. Next, the present invention will be explained in more detail with reference to Examples. Examples, Comparative Example 1 Three types of fragrances are ranked in order of ease of volatilization: top notes (e.g. boiling point below 200°C), middle notes (e.g. boiling point 200-240°C) and end notes (e.g. boiling point
240° C. or above), and the carrier was impregnated with each fragrance from the lower stage as shown in Fig. 1, and then stored in a container and volatilized. In this case, the amount of fragrance was about 10 g in all cases, the carrier was 50 mm in diameter, and several 5 mm in diameter holes were made in the upper stage and several 3 mm in diameter in the middle stage. On the other hand, a three-stage carrier having the same dimensions as in the example was impregnated with a mixture of the same three fragrances as in the example, and then volatilized. The changes over time in the amount of volatilization in Example and Comparative Example 1 were
Shown in the table. Comparative Example 2 A commercially available gel fragrance produced by mixing the top note, middle note, and end note fragrances used in Comparative Example 1 was stored in the same container as in Example 1 and volatilized. Table 1 shows the change in volatilization amount over time. Table 1 shows the fragrance tone compared to the standard state (sealed state in each example) at each time (volatilization rate): (1) "same", (2) "slightly different" and (3) "obviously different". The results are based on the olfactory judgments of 20 people, divided into three ranks.
【表】
なお実施例、比較例1及び2における香料の重
量の時間の経過と共に変化する状況を第2図に示
した。
比較例 3
現在市販されているカードボード型芳香剤(1
枚の紙に複合香料を含浸させたもの)を揮散さ
せ匂いの強さを実施例と比較した(20人の嗅覚に
て判定した)。この結果を図示すれば第3図の如
くであつた。[Table] FIG. 2 shows how the weight of the perfume in Examples and Comparative Examples 1 and 2 changes over time. Comparative Example 3 Cardboard type air freshener currently on the market (1
A sheet of paper impregnated with a composite fragrance) was volatilized and the strength of the odor was compared with that of the example (judged by the sense of smell of 20 people). The results are shown in FIG. 3.
第1図は本考案の一実施態様の斜視図である。
第2図は各例における香料の重量の経時変化を示
すグラフである。第3図は比較例3を実施例と比
較して匂いの強さを示すグラフである。
1,2,3……含浸体、4,5……孔、6……
支柱、7……容器、8……放香口。
FIG. 1 is a perspective view of one embodiment of the present invention.
FIG. 2 is a graph showing the change over time in the weight of the fragrance in each example. FIG. 3 is a graph showing the strength of odor comparing Comparative Example 3 with Example. 1, 2, 3... Impregnated body, 4, 5... Hole, 6...
Post, 7... Container, 8... Incense vent.
Claims (1)
香体において、蒸気圧の大から小の順序に従つて
該複数種の香料別の含浸体を下から上に複数段設
け、最下段の含浸体の直ぐ上段以上の含浸体には
各香料の蒸気圧に応じ適宜密度で孔を穿設するこ
とを特徴とする複合香料芳香体の構造。 In a composite fragrance aromatic body consisting of multiple types of fragrances with different vapor pressures, impregnated bodies for each of the multiple types of fragrances are provided in multiple stages from bottom to top in order of vapor pressure from high to low, and the impregnated bodies in the lowest stage are A structure of a composite fragrance aromatic body, characterized in that the impregnated body immediately above the upper stage is provided with holes at an appropriate density depending on the vapor pressure of each fragrance.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9663881U JPS585441U (en) | 1981-07-01 | 1981-07-01 | Composite fragrance aromatic body |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP9663881U JPS585441U (en) | 1981-07-01 | 1981-07-01 | Composite fragrance aromatic body |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS585441U JPS585441U (en) | 1983-01-13 |
JPS6115891Y2 true JPS6115891Y2 (en) | 1986-05-16 |
Family
ID=29891481
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP9663881U Granted JPS585441U (en) | 1981-07-01 | 1981-07-01 | Composite fragrance aromatic body |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS585441U (en) |
-
1981
- 1981-07-01 JP JP9663881U patent/JPS585441U/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS585441U (en) | 1983-01-13 |
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