JPS61154713A - Descaling method of strip steel - Google Patents

Descaling method of strip steel

Info

Publication number
JPS61154713A
JPS61154713A JP27468084A JP27468084A JPS61154713A JP S61154713 A JPS61154713 A JP S61154713A JP 27468084 A JP27468084 A JP 27468084A JP 27468084 A JP27468084 A JP 27468084A JP S61154713 A JPS61154713 A JP S61154713A
Authority
JP
Japan
Prior art keywords
roll
steel
steel strip
strip
bending
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP27468084A
Other languages
Japanese (ja)
Inventor
Satoru Matoba
哲 的場
Matsuo Adaka
阿高 松男
Yaichiro Mizuyama
水山 弥一郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP27468084A priority Critical patent/JPS61154713A/en
Publication of JPS61154713A publication Critical patent/JPS61154713A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/04Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing
    • B21B45/06Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing of strip material

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)

Abstract

PURPOSE:To remove an oxidized film with good efficiency by subjecting the strip steel with oxidized film to rolling reduction by the roller with the roll which covers its surface with the elastic body having lower elastic coefficients than a steel on one part and with steel made roll on the other part. CONSTITUTION:A roller is composed of the roll which covers its surface by the elastic body having lower elastic coefficients than those of steel of one part, for instance by rubber roll 2 and by steel made roll 1 of the other part. And when the strip steel 3 which is before acid cleaning is passed between rolls 1, 2 with pressurizing state, strip steel 3 is bent to the steel made roll 1 side and cracks are caused on the oxidized film and removed. The acid cleaning is further performed in succession if necessary.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は鋼帯のスケール除去方法に関するものである。[Detailed description of the invention] (Industrial application field) The present invention relates to a method for removing scale from steel strip.

(従来の技術) 鋼帯の酸化膜、いわゆるスケールは巻き取り温度の上昇
と共に、厚くなるため酸による脱スケールが困難となり
、酸洗時間の増加、すなわち、生産性の低下を招いてい
る。この対策として、スケールに亀裂を入れて酸洗性を
向上させることが、一般的で、従来から、鋼帯に繰り返
し曲げをあたえるレベラー型のスケールブレーカ−や、
圧延で亀裂をいれるスキンパス圧延などが実用化されて
いる。しかし、従来の方法には以下に述べる欠点を有し
ている・ すなわち、スキンバス圧延の方法は、スケールに歪を入
れるためには、鋼帯自体もスケールの歪と同じ量圧延で
伸ばす必要があり、余計な変形エネルギーを必要とする
だけでなく、大きい圧延荷重に耐えるための強力なスタ
ンドが必要で高い設備となる欠点を持つ。
(Prior Art) The oxide film, so-called scale, on a steel strip becomes thicker as the winding temperature increases, making it difficult to descale with acid, resulting in an increase in pickling time, ie, a decrease in productivity. As a countermeasure against this problem, it is common practice to create cracks in the scale to improve pickling properties. Conventionally, leveler type scale breakers, which repeatedly bend the steel strip, and
Skin pass rolling, which creates cracks during rolling, has been put into practical use. However, the conventional method has the following drawbacks: In the skin bath rolling method, in order to introduce strain into the scale, the steel strip itself must be rolled by the same amount as the strain on the scale. However, it not only requires extra deformation energy, but also requires a strong stand to withstand the large rolling load, which has the disadvantage of requiring expensive equipment.

レベラー型のスケールブレーカ−は、ロールで鋼帯を曲
げ、スケールに必要な歪を与える方法で、鋼帯自体が全
面的に変形する必要がないので、エネルギー的には有利
であるが、無張力、もしくは、通板に必要な程度の低張
力では鋼帯がロールになかなか馴染まず、ロール半径(
R)よりも大きい半径に曲がるにすぎない、すなわち、
鋼帯の曲率は、ロール曲率より遥かに小さく、曲げ歪ε
は、鋼帯の厚み(1)とロール直径(D = 2R)の
計算式 %式%(1) まで、大きくならないという欠点を持つ。
The leveler type scale breaker is a method that bends the steel strip with rolls to give the necessary strain to the scale, and there is no need for the steel strip itself to fully deform, so it is advantageous in terms of energy, but it is also non-tensionless. Or, if the tension is as low as that required for threading, the steel strip will not easily fit into the roll, and the roll radius (
R), i.e.,
The curvature of the steel strip is much smaller than the roll curvature, and the bending strain ε
has the disadvantage that it cannot increase up to the calculation formula % formula % (1) of the steel strip thickness (1) and the roll diameter (D = 2R).

また、低張力で小径ロールを用いて強く曲げようとする
と、しばしば曲げ歪が不連続にはいる腰折れ現象が発生
し、酸洗性向上につながらないだけでなく、鋼帯の材質
の劣化も引き起こす欠点を有するものである。
Additionally, if you try to bend the steel strip strongly using a small-diameter roll under low tension, a bending phenomenon often occurs in which the bending strain becomes discontinuous, which not only does not improve pickling properties, but also causes deterioration of the material quality of the steel strip. It has the following.

この従来のスケールブレーカ−の欠点を補うものとして
、特開昭58−209415号公報の如くレベラ一部の
人出側に張力を付加するためのプライドルロールをそな
えたテンションレベラー型のスケールブレーカ−も開発
されているが、このテンションレベラーで、大きい張力
を与えるには、多数の張力付加用のプライドルロールが
必要となり、設備費の増大をまねくだけでなく、設備の
占有面積が大きいため、既設の酸洗膜q11の改造のJ
j、i合の制約条件としてきいてくる欠点も有する。
To compensate for the drawbacks of the conventional scale breaker, there is also a tension leveler type scale breaker equipped with a prydle roll for applying tension to the exit side of a part of the leveler, as disclosed in Japanese Patent Application Laid-Open No. 58-209415. However, in order to apply a large tension with this tension leveler, a large number of pre-drill rolls for applying tension are required, which not only increases equipment costs but also requires a large area of equipment, making it difficult to use existing equipment. J of modification of pickling membrane q11
It also has the disadvantage of being a constraint on the j, i combination.

(発明の目的) これらの欠点を解消するものとして、本発明者らは、一
方にゴムで表面を覆ったロール、他方には鋼製ロールで
構成されるロール機を一対とし、このロール機単独、も
しくは、ゴムと鋼の組み合わせを互い違いにした複数の
ロール機にて、鋼帯を圧下することで、スケールに歪を
有効にいれる方法を見出し、その後、必要に応じて酸洗
するようにしたものである。
(Purpose of the Invention) In order to eliminate these drawbacks, the present inventors have developed a pair of roll machines consisting of a roll whose surface is covered with rubber on one side and a steel roll on the other, and this roll machine alone. Alternatively, they found a way to effectively apply strain to the scale by rolling down the steel strip using multiple roll machines with alternating combinations of rubber and steel, and then pickling as necessary. It is something.

(発明の構成・作用) 以下にその発明を図にて説明する。(Structure and operation of the invention) The invention will be explained below using figures.

第1図において、鋼製ロール1と鋼より弾性係数の低い
弾性体、たとえばゴムロール2の間に圧力をかけた状態
で、酸洗前の鋼帯3を通すと、9V5帯が鋼製ロール側
に曲がり、スケールに亀裂がはいるものである。
In FIG. 1, when the steel strip 3 before pickling is passed under pressure between the steel roll 1 and an elastic body with a lower elastic modulus than steel, such as the rubber roll 2, the 9V5 strip is on the side of the steel roll. It bends and cracks appear in the scale.

この方法によってスケールに曲げ歪を与える方法は、テ
ンションレベラーの様な高い張力を必要とせず、無張力
でも、小さいロールに鋼帯を馴染ませて、脱スケールに
必要な歪が簡単に入れられるうえに、場所的にも曲げが
ロール直下近傍で引き起こされるため、スタンドがはい
る幅だけの余地があれば、設置可能となる利点をもつ、
また、曲げがロールと鋼帯の接触部の極めて狭い範囲に
限定されて生じるため、通常のレベラーでみられる腰折
れ現象が現れない。
This method of applying bending strain to the scale does not require high tension like a tension leveler, and even without tension, it is possible to easily apply the strain necessary for descaling by adapting the steel strip to a small roll. In addition, the bending occurs near the bottom of the roll, so it has the advantage that it can be installed as long as there is enough room for the stand to fit.
In addition, since the bending occurs only in an extremely narrow area of the contact area between the roll and the steel strip, the bending phenomenon that occurs with ordinary levelers does not occur.

鋼帯に曲げ変形を与えるに必要なエネルギーは、このロ
ール機を駆動するか、ロール機を無駆動にして、通板の
張力から補給すればよい。後者の通板張力で曲げエネル
ギーを補給する方法では、前者より高目の張力が必要と
なるが、本発明では、帯板曲げエネルギーの補給だけで
よいため、テンションレベラーにくらべるとはるかに小
さい張力でよい、また、スキンパス圧延のように、鋼帯
全体を伸ばしているわけでなく、鋼帯に曲げを与えてい
るだけであるので、強大な圧延荷重を必要としないので
簡単なスタンドでもよく、設備費の大幅な減少がはかれ
るという特徴がある。
The energy required to bend the steel strip can be supplied from the tension of threading by driving the roll machine or by not driving the roll machine. The latter method of replenishing bending energy using strip tension requires a higher tension than the former, but in the present invention, only the strip bending energy needs to be supplied, so the tension is much lower than that of a tension leveler. In addition, unlike skin pass rolling, the entire steel strip is not stretched, but only the steel strip is bent, so a strong rolling load is not required, so a simple stand is sufficient. It is characterized by a significant reduction in equipment costs.

このロール機で鋼帯が曲げられる原理は、双方のロール
の弾性係数が異なるため、圧延圧力をかけると、弾性係
数の小さいロールが大さ?変形し、鋼帯との接触幅が鋼
帯の表裏面で大きく異なり、曲げモーメントを発生させ
、鋼帯は1弾性係数の高いロール、この場合は鋼製ロー
ルの方に、曲がることにある。
The principle behind how steel strips are bent with this roll machine is that both rolls have different elastic modulus, so when rolling pressure is applied, the roll with the smaller elastic modulus becomes larger. The steel strip deforms, and the width of contact with the steel strip differs greatly between the front and back surfaces of the steel strip, generating a bending moment, causing the steel strip to bend toward the roll with a higher elastic modulus, in this case the steel roll.

ここまでゴムロール、鋼製ロールと言う言葉で発明の詳
細な説明していたが、原理的には、双方のロールの弾性
係数に大きい差があればよい。実用的には、鋼製ロール
の□代わりに、耐酸型をもった適当な任意の金属、もし
くはセラミ゛ツクの様な固い物質でロール表面を構成し
たロールを用いてもよい、他方のロール、即ち鋼より弾
性係数の低い弾性体のロールはゴム、合成樹脂、たとえ
ば、ウレタンゴム、ポリプロピレン等のような有機材料
で表面を構成するロールを使ってもよい。耐酸性材料で
ロールな構成すれば、このロール機は酸洗漕中にでも設
置でき、鋼帯のスケールに酸の中でf[1裂をいれるた
め、ざらに酸洗効率の向上が見込める。
Up to this point, the invention has been described in detail using the terms rubber roll and steel roll, but in principle, it is sufficient if there is a large difference in the elastic modulus of both rolls. Practically, instead of the steel roll, a roll whose surface is made of any suitable acid-resistant metal or a hard material such as ceramic may be used. That is, the roll made of an elastic material having a lower elastic modulus than steel may be a roll whose surface is made of rubber, synthetic resin, or an organic material such as urethane rubber or polypropylene. If the roll is made of acid-resistant material, this roll machine can be installed even in a pickling tank, and since f[1 cracks are added to the scale of the steel strip in acid, pickling efficiency can be expected to improve considerably.

次に本発明のロール機の圧下刃、もしくは、ロールギャ
ップをどのように設定するかのべる。
Next, how to set the rolling blade or roll gap of the roll machine of the present invention will be described.

ロール機のロールキャップを閉めながら、目的の鋼帯か
ら切り出した切り板4aを通板すると、第2図に示すよ
うに通板後の切り板4bは鋼製ロール1側に凹に曲がっ
て行く、その曲率は第3図に示すように圧下刃の増大と
ともに大きくなり、やがて鋼製ロールの直径できまる一
定の曲率で飽和する。したがって、このロール機の操業
では、通板後の曲率が飽和する圧下力以上で操業すると
、鋼製側ロール径できまる曲率がいつも鋼帯に与えられ
る。この場合、ロールギャップを目的の鋼帯の最大厚み
のものが十分に曲がるよう一定に設定しておけば、鋼帯
の厚みが薄い側にかわっても、ゴムの弾性性質で、ロー
ル荷重が急減することもなく、かつ、十分な曲げ歪がス
ケールにはいり、操業としてはきわめて簡単に行える。
When the cut plate 4a cut from the target steel strip is passed through it while closing the roll cap of the roll machine, the cut plate 4b after passing through the plate bends concavely toward the steel roll 1 side, as shown in Fig. 2. As shown in FIG. 3, the curvature increases as the number of rolling blades increases, and eventually saturates at a constant curvature determined by the diameter of the steel roll. Therefore, when this roll machine is operated at a rolling force equal to or higher than the rolling force at which the curvature after threading is saturated, the steel strip is always given a curvature determined by the diameter of the steel side roll. In this case, if the roll gap is set at a constant value so that the maximum thickness of the target steel strip can be bent sufficiently, even if the thickness of the steel strip changes to the thinner side, the roll load will rapidly decrease due to the elastic properties of rubber. There is no bending, sufficient bending strain is applied to the scale, and the operation is extremely simple.

鋼帯の曲率と圧下刃の関係は、鋼帯か連続的に繋がって
いるのでロール機で曲げられた部分が途中のパスで曲げ
もどされて、切り板はど顕著に曲げは観測されないが、
ロール機での曲げ原理が同じであるので。
The relationship between the curvature of the steel strip and the rolling blade is that since the steel strip is connected continuously, the part bent by the roll machine is unbent in the middle of the pass, and no noticeable bending is observed in the cut plate.
Because the bending principle in the roll machine is the same.

同じ圧力なら同じ曲げが入っているとしてよい。If the pressure is the same, it can be assumed that the bending is the same.

歪と酸洗時間の関係は第4図に示すように、歪が大きい
ほど、酸洗時間が短くなる。酸洗時間短縮に顕著な効果
の出てくる歪5%以上を板厚3■■の熱間圧延鋼帯板に
与えようとすると、(1)式から、D <Go m+s
φとすればよい、このような小径ロールでは、たわみの
問題が生ずるので、適当にたわみ防止のための大径のバ
ックアップロールをつけて小径化をはかる必要がある。
As shown in FIG. 4, the relationship between strain and pickling time is such that the larger the strain, the shorter the pickling time. When attempting to impart a strain of 5% or more, which has a remarkable effect on shortening the pickling time, to a hot rolled steel strip with a thickness of 3■■, from equation (1), D < Go m+s
Such a small diameter roll, which may be set to φ, causes a problem of deflection, so it is necessary to appropriately install a backup roll of a large diameter to prevent deflection in order to reduce the diameter.

また、曲げ歪5%という程大きい歪を狙わない場合でも
、本発明では、鋼製ロール径そのものと、実際に鋼帯が
ロールで曲げられる曲率が等しいため、従来型のスケー
ルブレーカ−よりも大径としても酸洗性の向上効果が大
きい。
Furthermore, even if the bending strain is not as large as 5%, the present invention has a larger bending strain than conventional scale breakers because the steel roll diameter itself is equal to the curvature at which the steel strip is actually bent by the roll. The diameter also has a large effect on improving pickling properties.

ゴムロールの径は、鋼製ロールと同径である必要はない
、鋼製ロール径よりも大径側の方が望ましい、これは、
ゴムの変形で鋼帯を鋼製ロールに押しつけているので、
おなしロールギャップなら、ゴムロールと鋼帯の接触長
さが、大径側の方が大きく、曲げモーメントが大きくな
ることと、大径側では、ロールのたわみが少ないためで
ある。しかし、小径の場合でも、少しロールの押し込み
力を増して、ゴムの変形量を大きくしてやればよく、ロ
ールのたわみも、クラウンを付けるなりの考慮をすれば
よいので、とくに指定する程のことはない。
The diameter of the rubber roll does not have to be the same as the steel roll; it is preferable that the rubber roll has a larger diameter than the steel roll.
Since the steel strip is pressed against the steel roll by the deformation of the rubber,
In the case of a straight roll gap, the contact length between the rubber roll and the steel strip is larger on the larger diameter side, resulting in a larger bending moment, and the roll deflection is smaller on the larger diameter side. However, even in the case of a small diameter, it is sufficient to increase the pushing force of the roll a little to increase the amount of deformation of the rubber, and the deflection of the roll can also be taken into consideration when attaching a crown, so there is no need to specify anything in particular. do not have.

次に、酸洗時間の減少のための、通板回数であるが、1
回の通板でもその効果を発揮するが、曲げによる脱スケ
ール効果は圧縮側のより、引っ張り側が悪いので、ロー
ルの組み合わせを互い違いにした2回の通板が望ましい
、第5図にその適用例を示す、2回以上は、ロール径と
板厚で歪が決まるので、その効果は飽和してくるが、小
径ロールでパス回数を多く(たとえば、6回以上)すれ
ば、後工程で酸洗しなくてもスケールは殆ど除去される
Next, in order to reduce the pickling time, the number of passes is 1.
This effect can be achieved by passing the sheet through the sheet once, but the descaling effect due to bending is worse on the tension side than on the compression side, so it is desirable to run the sheet twice with alternating combinations of rolls. An example of its application is shown in Figure 5. If the strain is passed more than 2 times, the effect reaches saturation because the strain is determined by the roll diameter and plate thickness, but if the number of passes is large (for example, 6 or more passes) with small diameter rolls, the pickling process will be easier in the later process. Even if you don't do this, most of the scale will be removed.

(次に実施例を示す、) 表1 実施例 供試材二低炭素普通鋼 熱延巻き取り温度ニア30℃ 板厚; 3.2 am 、  板幅: 1000 am
ゴム被覆ロール径: 250 armφウレタンゴム厚
:20+sm 各方法での酸洗時間の評価は熱延のままの鋼帯の酸洗時
間をtootとして、相対比率で評価した。
(Examples are shown next.) Table 1 Example sample material Two-low carbon ordinary steel hot rolled winding temperature near 30°C Plate thickness: 3.2 am, Plate width: 1000 am
Rubber-coated roll diameter: 250 armφ Urethane rubber thickness: 20+sm The pickling time in each method was evaluated based on relative ratios, with the pickling time of the hot-rolled steel strip as tooot.

表  1 (発明の効果) 冷延鋼帯の製造法として、連続焼鈍法が普及して来たが
、一般にJ!!続焼鈍用の8延鋼帯の熱延巻き取り温度
は、箱型焼鈍法の熱延巻き取り温度によりはるかに高い
ため、連続焼鈍鋼帯の増加とともに、酸洗時間の増大を
まねき、生産性の阻害要因となっている。
Table 1 (Effects of the invention) Continuous annealing has become popular as a method for producing cold rolled steel strips, but in general J! ! The hot rolling winding temperature of 8 rolled steel strips for continuous annealing is much higher than the hot rolling winding temperature of the box annealing method, so as the number of continuously annealed steel strips increases, the pickling time increases and productivity decreases. This is a hindering factor.

ここで、本発明を従来の酸洗ラインに適用すれば、簡単
な設備で大きい酸洗時間の減少効果があり、連続焼鈍鋼
帯の多いときには、生産性の低下防止がはかれ、箱型焼
鈍鋼帯の多いときには、増産効果がもたらされる。
If the present invention is applied to the conventional pickling line, it will be possible to greatly reduce the pickling time with simple equipment, and when there are many continuously annealed steel strips, productivity will be prevented from decreasing, and box-type annealing When there is a lot of steel strip, the effect of increasing production is brought about.

また、小径のスチールロールとした本発明のロール機を
多数配置すれば、殆ど、後工程で酸洗を必要としない、
脱スケールラインが構成でき、廃酸などの廃液処理の煩
わしさから逃れる効果も得られる。
In addition, if a large number of roll machines of the present invention with small diameter steel rolls are arranged, pickling is hardly required in the post-process.
A descaling line can be constructed, and the effect of escaping the troublesome treatment of waste liquids such as waste acids can also be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に用いるロール機の構成図、第2図は圧
下刃を変えてのロール通板後の板反りを示す図、第3図
は圧下刃と通板後の板曲率の関係を示す図、第4図は板
の表面歪と酸洗時間の関係を示す図、第5図は本発明を
複数ロール機を用いた例を示す図である。 1・・・鋼製tff−ル、2・・・ゴムロール、3・・
・鋼帯、4a4b・・・切り板。
Figure 1 is a configuration diagram of the roll machine used in the present invention, Figure 2 is a diagram showing the warping of the plate after the roll passes with different rolling blades, and Figure 3 is the relationship between the rolling blade and the plate curvature after passing. FIG. 4 is a diagram showing the relationship between surface strain of a plate and pickling time, and FIG. 5 is a diagram showing an example of the present invention using a multi-roll machine. 1...Steel tff-ru, 2...Rubber roll, 3...
・Steel strip, 4a4b...cut plate.

Claims (2)

【特許請求の範囲】[Claims] (1)一方に鋼より弾性係数の低い弾性体で表面を覆っ
たロール、他方を鋼製ロールとしたロール機にて、酸化
膜のついた鋼帯を圧下することにより、酸化膜を除去す
ることを特徴とする鋼帯のスケール除去方法。
(1) The oxide film is removed by rolling down the steel strip with the oxide film using a roll machine with one roll covered with an elastic material with a lower elastic modulus than steel and the other steel roll. A method for removing scale from a steel strip, characterized by:
(2)一方に鋼より弾性係数の低い弾性体で表面を覆っ
たロール、他方に鋼製ロールで構成されるロール機にて
、酸化膜のついた鋼帯を圧下し、その後、酸洗すること
を特徴とする鋼帯のスケール除去方法。
(2) A steel strip with an oxide film is rolled down using a roll machine consisting of a roll whose surface is covered with an elastic material with a lower elastic modulus than steel on one side and a steel roll on the other, and then pickled. A method for removing scale from a steel strip, characterized by:
JP27468084A 1984-12-28 1984-12-28 Descaling method of strip steel Pending JPS61154713A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27468084A JPS61154713A (en) 1984-12-28 1984-12-28 Descaling method of strip steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27468084A JPS61154713A (en) 1984-12-28 1984-12-28 Descaling method of strip steel

Publications (1)

Publication Number Publication Date
JPS61154713A true JPS61154713A (en) 1986-07-14

Family

ID=17545063

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27468084A Pending JPS61154713A (en) 1984-12-28 1984-12-28 Descaling method of strip steel

Country Status (1)

Country Link
JP (1) JPS61154713A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101231065B1 (en) * 2011-06-02 2013-02-07 (주)금강 Descaling device for pipe manufacturing apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101231065B1 (en) * 2011-06-02 2013-02-07 (주)금강 Descaling device for pipe manufacturing apparatus

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