JPS61147833A - Spectacle frame - Google Patents

Spectacle frame

Info

Publication number
JPS61147833A
JPS61147833A JP26531584A JP26531584A JPS61147833A JP S61147833 A JPS61147833 A JP S61147833A JP 26531584 A JP26531584 A JP 26531584A JP 26531584 A JP26531584 A JP 26531584A JP S61147833 A JPS61147833 A JP S61147833A
Authority
JP
Japan
Prior art keywords
corrosion resistance
weight
alloy
machinability
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP26531584A
Other languages
Japanese (ja)
Other versions
JPH0663050B2 (en
Inventor
Takashi Kuze
久世 孝
Mitsuhiro Matsunaga
充弘 松永
Hirozo Sugai
菅井 普三
Takashi Ishigami
隆 石上
Noriaki Yagi
典章 八木
Kounosuke Yamauchi
山内 鴻之祐
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YAMAUCHI SHOTEN KK
Toshiba Corp
Original Assignee
YAMAUCHI SHOTEN KK
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YAMAUCHI SHOTEN KK, Toshiba Corp filed Critical YAMAUCHI SHOTEN KK
Priority to JP26531584A priority Critical patent/JPH0663050B2/en
Publication of JPS61147833A publication Critical patent/JPS61147833A/en
Publication of JPH0663050B2 publication Critical patent/JPH0663050B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Eyeglasses (AREA)

Abstract

PURPOSE:To obtain spectacle frames having satisfactory machinability and corrosion resistance by incorporating a specified percentage of one or more among Pb, Te, S, Se, Bi, Ca and Ag into an Ni-Cu alloy. CONSTITUTION:An alloy having superior machinability and corrosion resistance and suitable for use as a material for spectacle frames is obtd. by incorporating 0.05-5wt% one or more among Pb, Te, S, Se, Bi, Ca and Ag into an Ni-Cu alloy. The hot workability can be improved by further incorporating at least one among 0.01-4wt% Ti, 0.001-0.5wt% C and 0.001-0.5wt% Mg.

Description

【発明の詳細な説明】 (発明の技術分野) 本発明は、快削性及び耐食性が良好な眼鏡枠に関する。[Detailed description of the invention] (Technical field of invention) The present invention relates to an eyeglass frame with good free-cutting properties and corrosion resistance.

(発明の技術的背景及びその問題点) 眼鏡枠は図面に示されるごとく、テンプル■。(Technical background of the invention and its problems) As shown in the drawing, the glasses frame is a temple ■.

アイリム■、やま■、はこ■、あし■、リムロック■、
ヒンジ■、わたり■、かざり■、ねじ■などの各種部品
からなっている。
Eye rim■, mountain■, box■, foot■, rimrock■,
It consists of various parts such as a hinge ■, a crossing ■, a decoration ■, and a screw ■.

これら眼鏡部品に使用される材料はプラスチック、金属
等様々なものが使用されている。特に金属性眼鏡はデザ
インのスマートさ、機能的優秀性の点から重用されてい
る。
Various materials such as plastics and metals are used for these eyeglass parts. In particular, metal glasses are valued for their smart design and excellent functionality.

眼鏡部品を構成する金属材料には洋白、ステンレス鋼、
アルミニウム、黄銅、りん青銅、ニッケルクロム合金な
どが使用されている。これらのうちニッケル銅合金は色
情、耐食性及び加工性に優れている点で極めて好ましい
材料である。
The metal materials that make up eyeglass parts include nickel silver, stainless steel,
Aluminum, brass, phosphor bronze, nickel-chromium alloys, etc. are used. Among these, nickel-copper alloy is an extremely preferable material because it has excellent luster, corrosion resistance, and workability.

しかし、ニッケル銅合金は眼鏡用としては快削性が必ず
しも十分満足されるものではない。
However, nickel-copper alloys do not necessarily have sufficient machinability for eyeglasses.

そこで耐食性及び快削性を兼ね備えたニッケルー銅合金
が求められているわけであるが、快削性を改善しようと
すると耐食性が低下し、一方耐食性を改善しようとする
と快削性が低下し、双方の特性を満足する眼鏡用ニッケ
ル銅合金が得られず、したがってそのような眼鏡枠も得
られなかった。
Therefore, there is a need for a nickel-copper alloy that has both corrosion resistance and free machinability. However, if you try to improve the free machinability, the corrosion resistance will decrease, and on the other hand, if you try to improve the corrosion resistance, the free machinability will decrease. It has not been possible to obtain a nickel-copper alloy for eyeglasses that satisfies the characteristics described above, and therefore, it has also not been possible to obtain such an eyeglass frame.

(発明の目的) 本発明の第一の目的は、快削性が良好で、かつ耐食性が
良好なニッケル銅合金でなる眼鏡枠を提供することにあ
り、本発明の第二の目的は、快削性、熱間加工性及び耐
食性が良好なニッケル銅合金でなる眼鏡枠を提供するこ
とにある。
(Object of the Invention) The first object of the present invention is to provide an eyeglass frame made of a nickel-copper alloy that has good free machinability and good corrosion resistance. An object of the present invention is to provide an eyeglass frame made of a nickel-copper alloy having good machinability, hot workability, and corrosion resistance.

(発明の概要) 本発明は、第一の目的を達成する為にPb。(Summary of the invention) In order to achieve the first object, the present invention uses Pb.

re、s、se、st、ca及びAgから選択された1
種又は2種以上の元素を重量%で0.005〜5%含有
させたニッケル銅合金でなる@鏡枠を提供する。即ち、
Pb、Te、S。
1 selected from re, s, se, st, ca and Ag
To provide a lens frame made of a nickel-copper alloy containing a species or two or more elements in an amount of 0.005 to 5% by weight. That is,
Pb, Te, S.

3e 、 Bi 、 Ca及びAIJの元素は、Cu 
−Ni合金中に低融点の金属性介在物あるいは非金属性
介在物として存在し、耐食性をあまり低下させず潤滑効
果を向上させ、かつ切削工具の刃先に生じるきりこを落
す効果を向上させる。
3e, Bi, Ca and AIJ elements are Cu
- Exists in the Ni alloy as a low-melting-point metallic inclusion or non-metallic inclusion, improves the lubrication effect without significantly reducing corrosion resistance, and improves the effect of removing burrs formed on the cutting edge of a cutting tool.

しかし、この種の元素が多すぎると熱間加工性及び快削
性が低下し、一方少なずぎると効果が少ない。したがっ
て、その含有層としては0.001〜5重量%、更には
0.01〜2重同%、更には0.1〜1重量%が好まし
い。
However, if there is too much of this type of element, hot workability and free machinability will be reduced, while if there is too little, the effect will be small. Therefore, the content of the layer is preferably 0.001 to 5% by weight, more preferably 0.01 to 2% by weight, and even more preferably 0.1 to 1% by weight.

この本発明により耐食性と快削性が共に良好な合金が得
られるが、更に熱間加工性を改善しようとすると、快削
性及び耐食性が低下しやすく、耐食性、快削性、加工性
の特性を共に満足する合金が得られにくかった。そこで
本発明は、第二の目的を達成する為にPb 、Te 、
S。
According to the present invention, an alloy with good corrosion resistance and free machinability can be obtained. However, if an attempt is made to further improve the hot workability, the free machinability and corrosion resistance tend to deteriorate, and the properties of corrosion resistance, free machinability, and workability deteriorate. It has been difficult to obtain an alloy that satisfies both. Therefore, in order to achieve the second objective, the present invention provides Pb, Te,
S.

Se、3i 、 Ca及び八〇から選択された少なくと
も1種の元素を金山%で0.005〜5%含有させ、か
つTi  :  0.01〜4重量%、C:0.005
〜0.5重量%及びMg:  0.002〜0.1重量
%から選択された少なくとも1種の元素を含有させたこ
とを特徴とするニッケル銅でなる眼鏡枠を提供する。
At least one element selected from Se, 3i, Ca, and 80 is contained in an amount of 0.005 to 5% in Kanayama%, Ti: 0.01 to 4% by weight, and C: 0.005%.
Provided is an eyeglass frame made of nickel copper, characterized in that it contains at least one element selected from 0.5% by weight and Mg: 0.002 to 0.1% by weight.

ここでTi、C及びMgの添加は前記添加元素(Pb、
Te、S、86.Bi、Ca及びAa )の添加効果の
切削性を低下させることなく熱間加工性を向上させる。
Here, the addition of Ti, C and Mg is the addition of the above-mentioned additive elements (Pb,
Te, S, 86. Addition of Bi, Ca, and Aa) improves hot workability without reducing machinability.

即ち、Tiは窒素を固定しブローホールの発生を防止し
、C及びMQは結晶粒の粒大化を防ぐのに役立つ。しか
し、これらの添加元素が多すぎると熱間加工性を低下さ
せ、一方少なすぎても良好な熱間加工性が得にくい。し
たがって、Ti成分の範囲としては0.01〜4重母%
、更にはO,OS〜2重量%、更には0.1〜1重量%
が好ましく、C及びfvlの成分範囲としてはともに0
.001〜0.5重量%、更には0.01〜0.1重量
%が好ましい。
That is, Ti fixes nitrogen and prevents blowholes from occurring, and C and MQ help prevent crystal grains from increasing in size. However, if there are too many of these additive elements, hot workability will be reduced, while if there are too little, it will be difficult to obtain good hot workability. Therefore, the range of Ti component is 0.01 to 4%
, further O,OS ~2% by weight, furthermore 0.1-1% by weight
is preferable, and the component ranges of C and fvl are both 0.
.. 0.001 to 0.5% by weight, more preferably 0.01 to 0.1% by weight.

一方、本発明合金の含有量としては装飾性及び耐食性の
点から10〜90重量%が好ましい。これらの特性のほ
かに更に変形加工性及び高耐食性に着目するとCu成分
は10〜30%が好ましく、一方耐海水性及び高温強度
に着目すると60〜75%が好ましい。このようにそれ
ぞれの要求特性により一層好ましい成分範囲がある。以
上述べた本発明の合金は切削性が特に要求される眼鏡部
品に有効であり、例えばヒンジに適する。このヒンジと
しての快削性は、直径3IIIlのストレートドリルを
使用し荷@ 13kg、時間30秒で穿孔できる深さが
2.5mm以上、更には3mm以上あるのが望ましく、
本発明の合金はこの要求特性を満す。
On the other hand, the content of the alloy of the present invention is preferably 10 to 90% by weight from the viewpoint of decorativeness and corrosion resistance. In addition to these properties, when considering deformation workability and high corrosion resistance, the Cu content is preferably 10 to 30%, while when considering seawater resistance and high temperature strength, it is preferably 60 to 75%. As described above, there are more preferable component ranges depending on the required characteristics. The alloy of the present invention described above is effective for eyeglass parts that particularly require machinability, and is suitable for, for example, hinges. In terms of free-cutting properties for this hinge, it is desirable that the depth is 2.5 mm or more, more preferably 3 mm or more, which can be drilled in 30 seconds using a 3III diameter straight drill with a load of 13 kg.
The alloy of the present invention satisfies this required property.

(発明の実施例) 本発明の実施例について説明する。第1表に示す合金で
眼鏡枠を製造する際の熱間加工性。
(Embodiments of the invention) Examples of the invention will be described. Hot workability when manufacturing eyeglass frames using the alloys shown in Table 1.

快削性について更に製品の耐食性について測定した。そ
の測定方法として切削性は直径3mn+のストレートド
リルを使用し荷重13kgで時間30秒間の条件下で穿
孔し、その深さを測定し、耐食性は食塩1.0%、尿素
0.2%、硫化ナトリウム0.03%、砂糖0.02%
、アンモニア水0.02%、乳@ 0.1%、残り水の
組成よりなる人工汗に10分間浸漬後10分間乾燥のく
り返しにより腐食発生を測定し、熱間加工性は温度70
0〜1100℃、圧下率50%の条件で目視により測定
した。
In addition to the free machinability, the corrosion resistance of the product was also measured. As a measurement method, machinability is measured by drilling a hole using a straight drill with a diameter of 3 mm+ under a load of 13 kg for 30 seconds, and measuring the depth. Sodium 0.03%, sugar 0.02%
, ammonia water 0.02%, milk @ 0.1%, and remaining water were immersed in artificial sweat for 10 minutes and dried repeatedly for 10 minutes to measure the occurrence of corrosion. Hot workability was determined at a temperature of 70
It was measured visually under the conditions of 0 to 1100°C and a rolling reduction of 50%.

ここでの評価は以下の如くした。The evaluation here was as follows.

X・・・・・・完全にくだけた Δ・・・・・・クラックが入った O・・・・・・実用としての歩留りを確保できる程度で
あった ◎・・・・・・加工性は良好であった 0・・・・・・加工性は極めて良好であった以  下 
 余  白 第1表から明らかな如く、本発明実施例の眼鏡枠は比較
例に比べて、耐食性及び切削性が双方とも良好である。
X...Completely broken Δ...Cracked O...The yield was sufficient for practical use◎...The workability was Good: 0: Workability was extremely good:
As is clear from Table 1, the eyeglass frames of the examples of the present invention have better corrosion resistance and machinability than the comparative examples.

又、本発明の眼鏡枠はT′i等を添加することによりろ
う付性及び加工性が良好であり、特に眼鏡部品のヒンジ
、リムロック、アイリム、テンプル、ハコ、ブリッヂの
順に適していた。
Furthermore, the spectacle frame of the present invention has good brazing properties and workability due to the addition of T'i and the like, and is particularly suitable for the hinges, rim locks, eye rims, temples, frames, and bridges of spectacle parts, in that order.

(発明の効果) 以上説明したように、本発明はニッケル鋼合金にPb、
Te、S、Se、Bi 、Ca及びIJから選択された
1種又は2種以上の元素を重量%で0.005〜5%含
有させた合金を用いることにより、快削性が良好で、か
つ耐食性が良好な眼鏡枠を提供でき、更にTi  : 
 0.01〜4重量%、 C:  0.001〜0.5
重量%及びMg:0.001〜0.5重量%から選択さ
れた少なくとも1種の元素を含有させた合金をもちいる
ことにより耐食性、快削性及び熱間加工性が良好な眼鏡
枠を提供できる。
(Effects of the Invention) As explained above, the present invention provides a nickel steel alloy with Pb and
By using an alloy containing 0.005 to 5% by weight of one or more elements selected from Te, S, Se, Bi, Ca, and IJ, it has good free machinability and It is possible to provide an eyeglass frame with good corrosion resistance, and furthermore, it contains Ti:
0.01-4% by weight, C: 0.001-0.5
By using an alloy containing at least one element selected from weight% and Mg: 0.001 to 0.5% by weight, an eyeglass frame with good corrosion resistance, free machinability, and hot workability is provided. can.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明眼鏡の一例を示す斜視図である。 1・・・テンプル    2・・・アイリム3・・・や
ま      4・・・はこ5・・・あし      
6・・・リムロック7・・・ヒンジ     8・・・
わたり9・・・かざり    10・・・ねじ(731
7)代理人 弁理士  則 近 憲 佑(ほか1名)
The drawing is a perspective view showing an example of the eyeglasses of the present invention. 1... Temple 2... Eye rim 3... Yama 4... Box 5... Legs
6...Rim lock 7...Hinge 8...
Watari 9... Decoration 10... Screw (731
7) Agent: Patent attorney Kensuke Chika (and 1 other person)

Claims (2)

【特許請求の範囲】[Claims] (1)Pb、Te、S、Se、Bi、Ca及びAgから
選択された1種又は2種以上の元素を重量%で0.00
5〜5%含有させたニッケル銅合金でなる眼鏡枠。
(1) 0.00% by weight of one or more elements selected from Pb, Te, S, Se, Bi, Ca, and Ag
An eyeglass frame made of a nickel-copper alloy containing 5 to 5%.
(2)Pb、Te、S、Bi、Ca及びAgから選択さ
れた1種又は2種以上の元素を重量%で0.005〜5
%含有させ、かつTi:0.01〜4重量%、C:0.
001〜0.5重量%及びMg:0.001〜0.5重
量%から選択された少なくとも1種を含有させたニッケ
ル銅合金でなる眼鏡枠。
(2) 0.005 to 5% by weight of one or more elements selected from Pb, Te, S, Bi, Ca, and Ag;
%, Ti: 0.01 to 4% by weight, C: 0.
An eyeglass frame made of a nickel-copper alloy containing at least one selected from 0.001 to 0.5% by weight and Mg: 0.001 to 0.5% by weight.
JP26531584A 1984-12-18 1984-12-18 Eyeglass frame Expired - Lifetime JPH0663050B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP26531584A JPH0663050B2 (en) 1984-12-18 1984-12-18 Eyeglass frame

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP26531584A JPH0663050B2 (en) 1984-12-18 1984-12-18 Eyeglass frame

Publications (2)

Publication Number Publication Date
JPS61147833A true JPS61147833A (en) 1986-07-05
JPH0663050B2 JPH0663050B2 (en) 1994-08-17

Family

ID=17415486

Family Applications (1)

Application Number Title Priority Date Filing Date
JP26531584A Expired - Lifetime JPH0663050B2 (en) 1984-12-18 1984-12-18 Eyeglass frame

Country Status (1)

Country Link
JP (1) JPH0663050B2 (en)

Also Published As

Publication number Publication date
JPH0663050B2 (en) 1994-08-17

Similar Documents

Publication Publication Date Title
US5167726A (en) Machinable lead-free wrought copper-containing alloys
JPS6213055Y2 (en)
US5037708A (en) Silver palladium alloy
CN101787461A (en) Environment-friendly manganese brass alloy and manufacturing method thereof
US4446102A (en) Yellow gold jewelry alloy
RU2767960C2 (en) Clockwork component
JP2000504431A (en) Metal frames for glasses
US7311876B2 (en) Discoloration-resistant timepiece or jewelry part
JPH01136943A (en) Alloy
JPH09184033A (en) White gold alloy
US5270001A (en) Alloy, in particular for use in the manufacture of jewelry, frames for glass, and the like
JPS61147833A (en) Spectacle frame
DE3465635D1 (en) Use of nickel alloys for spectacle frames
Vilaplana et al. New trends in the use of metals in jewellery
JPS61143545A (en) Ornamental alloy
US2076577A (en) Free cutting alloys
US7128792B2 (en) Sterling silver manganese alloy compositions
JP2886818B2 (en) Method of manufacturing copper alloy for decoration
JP4006939B2 (en) High strength titanium alloy
US4264360A (en) Chromium modified silicon-tin containing copper base alloys
JPS6148133B2 (en)
JPS5835588B2 (en) decorative alloy
US20200308673A1 (en) Low gold jewelry alloy
JPH06264166A (en) Copper-base alloy excellent in corrosion resistance, machinability and workability
WO2015151720A1 (en) Low-lead brass alloy for plumbing member