JPS6114228B2 - - Google Patents

Info

Publication number
JPS6114228B2
JPS6114228B2 JP1668682A JP1668682A JPS6114228B2 JP S6114228 B2 JPS6114228 B2 JP S6114228B2 JP 1668682 A JP1668682 A JP 1668682A JP 1668682 A JP1668682 A JP 1668682A JP S6114228 B2 JPS6114228 B2 JP S6114228B2
Authority
JP
Japan
Prior art keywords
film
gold
transparent
pear
light source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP1668682A
Other languages
Japanese (ja)
Other versions
JPS58133371A (en
Inventor
Sakae Morikawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP1668682A priority Critical patent/JPS58133371A/en
Publication of JPS58133371A publication Critical patent/JPS58133371A/en
Publication of JPS6114228B2 publication Critical patent/JPS6114228B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/02Pretreatment of the material to be coated
    • C23C14/024Deposition of sublayers, e.g. to promote adhesion of the coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Surface Treatment Of Glass (AREA)
  • Physical Vapour Deposition (AREA)

Description

【発明の詳細な説明】 本発明は、金色と透光色との二色性梨子地状装
飾材の製造法に係り、ガラス板及びプラスチツク
板等の透明板、又はプラスチツクフイルム等に、
その乾燥皮膜が透明で、且つ、表面が微粒面、ち
りめん状及び粗面になる塗料を塗布し、その乾燥
皮膜に透光性を高くすべく金を真空蒸着させるこ
とで、通常の場合には金色、そして光源からの光
を透光させた場合には金色と異なる透光色となる
梨子地状に仕上げた金色と透光色との二色性梨子
地状装飾材の製造法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing a dichroic pear-shaped decorative material of gold and translucent colors, which can be applied to transparent plates such as glass plates and plastic plates, or plastic films, etc.
In normal cases, the dry film is transparent and the surface is fine grained, crepe-like, or rough by applying a paint and vacuum-depositing gold on the dry film to increase translucency. This article relates to a method for producing a dichroic pear-shaped decorative material with a golden color and a translucent color, which is finished in a pear-like finish that is golden and has a translucent color different from gold when light from a light source is transmitted through it. be.

従来から壁板、照明器具、その他室内装飾品等
を金色の梨子地状仕上げにした製品は、柔らかい
素材感を醸し出し、安堵感や、やすらぎを与える
と共に豪華さをも醸し出すものとして需要が非常
に多かつた。
Traditionally, wallboards, lighting fixtures, and other interior decoration items finished with a golden pear-like texture have been in high demand as they create a soft texture that gives a sense of security and peace, as well as a sense of luxury. It was a lot.

しかし、金属皮膜によつて金色の梨子地状仕上
げを行なうには、該皮膜を厚くしなければでき難
く、特に貴金属等の高価なものを使用するとなる
と、材料費だけでも高価になり、製品として市場
で販売される段になると非常に高価な製品となつ
てしまうのが現状であつた。しかも、金属皮膜が
厚いので透光性が低く照明器具等には不向きであ
り、安価なもので透光性を有する製品の出現が望
まれていた。
However, it is difficult to achieve a golden pear-like finish using a metal film unless the film is thick, and especially if expensive materials such as precious metals are used, the material cost alone will be expensive, and the product will not be suitable. The current situation is that the products are extremely expensive when sold on the market. Moreover, since the metal film is thick, it has low light transmittance and is unsuitable for lighting equipment, etc., and there has been a desire for an inexpensive product with light transmittance.

又、薄い金属皮膜による模様仕上げとして、特
公昭56―14745号公報にて金属蒸着模様シートの
製造方法が提案されたが、この方法では、連続模
様が打ち抜かれたシートと通常のシートとを重畳
して、抜ち抜かれたシート側に金属蒸着を行ない
前記重畳したシートを同時に蒸着したものなの
で、大きな模様等には有効であるが、ガラス板、
プラスチツク板等の表面に梨子地の様な素材地を
表現する場合にこの方法では不可能であつた。
In addition, as a pattern finish using a thin metal film, a method for manufacturing a metal-deposited pattern sheet was proposed in Japanese Patent Publication No. 14745/1983, but in this method, a sheet with a continuous pattern punched out and a regular sheet are superimposed. Then, metal vapor deposition is performed on the side of the punched sheet, and the superimposed sheets are vapor-deposited at the same time, so it is effective for large patterns, etc.
This method was not possible when expressing a material such as pear-like texture on the surface of a plastic board or the like.

本発明は、上述の欠点を解消すべく開発された
もので、その要旨とする処は、ガラス板、プラス
チツク板、プラスチツクフイルム等の透明な材料
で且つ内側に光源を有する装飾物に使用する材料
の表面に、乾燥皮膜が透明で、しかも、該皮膜の
表面が微粒面、ちりめん状、あるいは粗面になる
塗料を塗布し、該塗料の塗布面の乾燥皮膜に真空
蒸着法により、金を、透光性が高くなる程度の薄
い皮膜とすべく蒸着することに存するものであ
る。
The present invention was developed in order to solve the above-mentioned drawbacks, and its gist is that it is a transparent material such as a glass plate, a plastic plate, a plastic film, etc., and is used for decorative objects that have a light source inside. A paint is applied to the surface of the dry film that is transparent and has a fine-grained, crepe-like, or rough surface, and then gold is applied to the dry film on the coated surface by a vacuum evaporation method. The purpose is to vapor-deposit a thin film with high translucency.

以下、図面と共に本発明に係る金色と透光色と
の二色性梨子地状装飾材の製造法について説明す
ると、先ず、ガラス板、アクリル板等のプラスチ
ツク板、塩化ビニール樹脂及びポリエステル樹脂
等のプラスチツクフイルム等の透明で且つ内側に
光源4を有する装飾物に使用する材料1の表面、
図示にあつては内側面に、乾燥した皮膜2が透明
で、しかも、該皮膜2の表面が微粒面、ちりめん
状、あるいは粗面の様な素材感を醸し出すアクリ
ル樹脂、エポキシ樹脂等の樹脂系の塗料を塗布す
る。
Below, we will explain the manufacturing method of the dichroic pear-shaped decorative material of gold and transparent color according to the present invention with reference to the drawings. The surface of a material 1 used for decorations, such as plastic film, which is transparent and has a light source 4 inside;
In the illustration, the dried film 2 is transparent on the inner surface, and the surface of the film 2 is made of resin such as acrylic resin or epoxy resin that creates a texture like a fine grained surface, a crepe-like surface, or a rough surface. Apply the paint.

次に、この塗料を塗布して皮膜2を形成した前
記透明な材料1は、塗料を乾燥させた後、真空蒸
着装置(図示せず)の中で、塗料の表面に、厚さ
が1ミクロン以下、実際には、透光性が高くなる
0.1ミクロン以下の薄皮膜3として金を蒸着形成
し、金色と透光色との二色性梨子地状装飾材を製
造するものである。
Next, the transparent material 1 coated with this paint to form a film 2 is coated on the surface of the paint to a thickness of 1 micron in a vacuum evaporator (not shown) after the paint is dried. Below, the translucency actually increases.
Gold is vapor-deposited as a thin film 3 of 0.1 micron or less to produce a dichroic pear-shaped decorative material of gold and translucent colors.

その結果、この装飾材は、光源4を点灯しない
時には装飾物の内部は暗くなつているから金色の
梨子他状を呈し、光源4を点灯した時には光源4
からの光によつて透光色となる。
As a result, when the light source 4 is not turned on, the interior of the decoration is dark, so the decorative material takes on a golden pear shape, and when the light source 4 is turned on, the light source 4
It becomes a translucent color when exposed to light.

そして、この装飾材は、塗料を塗布して、乾燥
後に金を真空蒸着するだけの簡単な方法で透明な
材料1の表面を二色性の金色梨子地状に仕上げる
ことができると共に、金の薄皮膜3を真空蒸着で
は、0.1ミクロン以下の厚さに蒸着させるので、
高価な金を使用しても安価にて製造することがで
きる。
With this decorative material, the surface of the transparent material 1 can be finished in a dichroic golden pear-like texture by simply applying paint and vacuum-depositing gold after drying. In vacuum deposition, the thin film 3 is deposited to a thickness of 0.1 micron or less, so
Even if expensive gold is used, it can be manufactured at low cost.

しかも、透明な材料1に梨子地状薄皮膜3を蒸
着させるので、蒸着面と反対の面から見ても梨子
地状に仕上がり、そのうえ、第2図に示す照明器
具等に利用すれば、前述したように光源4を点灯
しない時には照明器具を表面から見ると金色の梨
子地状を呈していて、光源4を点灯した際には、
例えば膜厚が0.0045ミクロンの場合には淡い藤色
となつて透光し部屋中を柔らかい光で満たすと共
に、豪華さをも醸し出すものである。尚、図中5
は透明性保護皮膜である。
Moreover, since the pear-like thin film 3 is deposited on the transparent material 1, it has a pear-like finish even when viewed from the side opposite to the vapor-deposited surface.Furthermore, when used in the lighting equipment shown in FIG. 2, the above-mentioned As shown above, when the light source 4 is not turned on, the lighting fixture has a golden pear-like appearance when viewed from the surface, and when the light source 4 is turned on,
For example, when the film thickness is 0.0045 microns, it becomes a pale mauve color and transmits light, filling the room with soft light and creating a sense of luxury. In addition, 5 in the figure
is a transparent protective film.

更に、前記装飾材を、例えば自動車の計器盤等
に利用する場合、昼間、計器盤内部灯を点灯しな
い時には、会社名、マークあるいは車名等を金色
で表現し、夜間、内部灯を点灯した時に、裏側に
適当な色、例えば赤色あるいは緑色とかにイルミ
ネートしておけば金色の部分が前記各色に変化し
て非常に美しく効果的である。
Furthermore, when the above-mentioned decorative material is used, for example, in the instrument panel of a car, when the interior lights of the instrument panel are not turned on during the day, the company name, mark, or car name, etc. are expressed in gold, and the interior lights are turned on at night. Sometimes, if the back side is illuminated with an appropriate color, such as red or green, the gold part changes to each of the colors mentioned above, making it very beautiful and effective.

以下に、本発明に係る金色と透光色との二色性
梨子地状装飾材の製造法の実施例を記す。
Examples of the method for manufacturing a dichroic pear-shaped decorative material of gold and transparent color according to the present invention will be described below.

実施例 1 エポキシエステルを主原料として製造されたち
りめん仕上げ透明塗料である日本コーテイング株
式会社製No.5001リンクルクリヤーワニスをガラス
板に塗布し、得られた乾燥皮膜の表面に金を皮膜
厚0.0045ミクロンで真空蒸着させた。
Example 1 No. 5001 wrinkle clear varnish manufactured by Nippon Coating Co., Ltd., which is a crepe finish transparent paint manufactured using epoxy ester as the main raw material, was applied to a glass plate, and gold was applied to the surface of the resulting dry film to a thickness of 0.0045 microns. vacuum evaporated.

その結果、従来のガラス板が有する冷たいイメ
ージが全く無くなり、柔らかいちりめん状の感じ
で、且つ、豪華な金色のガラス板に仕上がり、透
光色は藤色であつた。
As a result, the cold image that conventional glass plates had was completely eliminated, and the glass plate had a soft, crepe-like feel and a luxurious golden color, and the transparent color was mauve.

実施例 2 エポキシ樹脂を主原料として製造されたビーズ
仕上塗料である日本コーテイング株式会社製No.
5008ビーズクリヤーワニスをアクリル板に塗布
し、得られた乾燥皮膜の表面に皮膜厚0.005ミク
ロンの金を真空蒸着により蒸着させた。
Example 2 No. 2 manufactured by Nippon Coating Co., Ltd., which is a bead finishing paint manufactured using epoxy resin as the main raw material.
5008 bead clear varnish was applied to an acrylic plate, and gold with a thickness of 0.005 microns was deposited on the surface of the resulting dry film by vacuum evaporation.

その結果、従来のアクリル板の持つ軽くてちや
ちなイメージが無くなり、表面は金色の微粒面を
呈し、豪華で重量感を醸し出しているので室内装
飾用の化粧板として有効であり、その透光色は藤
色であつた。
As a result, the light and small image of conventional acrylic boards is eliminated, and the surface exhibits a golden fine grain surface, creating a luxurious and weighty feel, making it effective as a decorative board for interior decoration. It was mauve in color.

実施例 3 米国ローム・アンド・ハス社製塗料用アクリル
樹脂アクノロイドB―72を50%、キシロール49
%、オクチル酸アルミニウム1%を混合して得ら
れた透明塗料を使用し、シルクスクリーン法によ
つてプラスチツクフイルムの表面に印刷し、得ら
れた乾燥皮膜の表面に金を皮膜厚0.005ミクロン
で真空蒸着により蒸着させた。
Example 3 50% of acrylic resin Acnoroid B-72 for paint manufactured by Rohm & Hass Co., Ltd. in the United States, xylol 49
%, aluminum octylate 1% was used to print on the surface of a plastic film by the silk screen method, and then gold was applied to the surface of the resulting dried film at a thickness of 0.005 microns under vacuum. It was deposited by vapor deposition.

その結果、プラスチツクフイルムは、金色の粗
面で、且つ、藤色の透光色となる美しいシートに
なり、照明器具の外装品等に使用すると室内を柔
らかい光で満たすと共に、照明器具も豪華な雰囲
気にするものである。
As a result, the plastic film becomes a beautiful sheet with a golden rough surface and a mauve translucent color.When used as exterior parts for lighting equipment, it fills a room with soft light, and also makes lighting equipment look luxurious. It sets the mood.

実施例 4 記アクリロイドB72を40%、米国ダウケミカル
社製エトセル10CP(エチルセルローズ)を10
%、キシロール35%Nブタノール15%を混合して
得られた透明塗料を使用し、シルクスクリーン法
によつてガラス板の表面に印刷し、得られた乾燥
皮膜の表面に金を皮膜厚0.01ミクロンで真空蒸着
により蒸着させた。
Example 4 40% of the above acryloid B72, 10% of Ethocel 10CP (ethyl cellulose) manufactured by Dow Chemical Company, USA
%, 35% xylol and 15% N-butanol were used to print on the surface of a glass plate using the silk screen method, and gold was applied to the surface of the dried film to a thickness of 0.01 micron. It was deposited by vacuum evaporation.

その結果、ガラス板は片面が金色の粗面にな
り、反対面はガラスそのままの面なので、戸棚、
人形ケース等の壁板として使用することにより人
形等をより豪華に見せるものであり、しかも、内
部から光をあてて透光されれば緑がかつた藤色の
透光色が得られる。また、オーデイオ製品のパネ
ル板として使用し、文字表示の部分のみに金を蒸
着させれば内部の光源4を点灯させることで文字
のみを藤色にして表現させることもできる。
As a result, one side of the glass plate has a golden rough surface, and the other side is just glass, so it can be used as a cupboard.
By using it as a wall panel for doll cases, etc., it makes the dolls look more luxurious, and if the light is shined from inside, a transparent color of mauve with a hint of green can be obtained. Furthermore, if it is used as a panel board for an audio product and gold is vapor-deposited only on the part where the text is displayed, only the text can be expressed in mauve by lighting up the internal light source 4.

又、金の透光色は、皮膜厚によつて若干異なる
ものであり、皮膜厚0.1ミクロンに近くなるにつ
れその透光色は藤色から緑色に変化する。
Furthermore, the transparent color of gold varies slightly depending on the film thickness, and as the film thickness approaches 0.1 micron, the transparent color changes from mauve to green.

尚、これら実施例に示した使用例は代表的なも
のを示したに過ぎず、その他、多方面の分野にわ
たつて使用が可能である。
It should be noted that the examples of use shown in these embodiments are merely representative ones, and the present invention can be used in a wide variety of other fields.

叙上の如く示した通り、本発明に係る金色と透
光色との二色性梨子地状装飾材の製造法は、内側
に光源を有する装飾物に使用する透明な材料の表
面に、乾燥皮膜が透明で、且つ、表面が微粒面、
ちりめん状、及び、粗面になる塗料を塗布して乾
燥させ、その後、この乾燥させた皮膜面に真空蒸
着法により薄い金属皮膜にすると透光性の高い金
を蒸着させるだけの簡単な方法で、金色の梨子地
状仕上げを容易に行なえ、且つ、薄皮膜としての
材料である金も少量で済み材料の節約をすること
ができるので安価にて提供できる。そして、前記
光源を有する装飾物に使用する材料であるからこ
そ、例えば照明器具等の場合等には、光源を点灯
しない時は金色を呈し、光源を点灯した時には、
金の皮膜厚の違いによつて藤色から緑色までの透
光色を呈する二色性を有するものであり、透光さ
れた光は柔らかい雰囲気となり、しかも金色の梨
子地状であるから需要者に、柔らかい素材感と豪
華さとを醸し出し安堵感や、やすらぎを与える製
品を提供できるものである。
As shown above, the method for producing the dichroic pear-shaped decorative material of gold and translucent color according to the present invention is to dry the surface of the transparent material used for decorations having a light source inside. The film is transparent, and the surface is fine-grained,
It is a simple method that involves applying a crepe-like or rough paint, letting it dry, and then depositing highly translucent gold on the dried film surface to form a thin metal film using a vacuum deposition method. A golden pear-like finish can be easily achieved, and a small amount of gold, which is a material for the thin film, is required, which saves on materials, so it can be provided at a low cost. And because it is a material used for decorations that have the light source, for example, in the case of lighting equipment, etc., when the light source is not turned on, it takes on a golden color, and when the light source is turned on, it takes on a golden color.
It has dichroism, exhibiting a transparent color ranging from mauve to green depending on the thickness of the gold coating, and the transmitted light creates a soft atmosphere, and it has a golden pear-like texture, making it popular among consumers. It is possible to provide products that have a soft texture and luxurious feel, giving a sense of relief and relaxation.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施により形成された製品の
断面図、第2図はこの製品を照明器具に利用した
際の要部断面図である。 1…透明な材料、2…皮膜、3…薄皮膜、4…
光源。
FIG. 1 is a cross-sectional view of a product formed by implementing the present invention, and FIG. 2 is a cross-sectional view of a main part when this product is used in a lighting fixture. 1...Transparent material, 2...film, 3...thin film, 4...
light source.

Claims (1)

【特許請求の範囲】[Claims] 1 ガラス板、プラスチツク板、プラスチツクフ
イルム等の透明な材料で且つ内側に光源を有する
装飾物に使用する材料の表面に、乾燥皮膜が透明
で、しかも、該皮膜の表面が微粒面、ちりめん
状、あるいは粗面になる塗料を塗布し、該塗料の
塗布面の乾燥皮膜に真空蒸着法により、金を、透
光性が高くなる程度の薄い皮膜とすべく蒸着する
ことを特徴とした金色と透光色との二色性梨子地
状装飾材の製造法。
1. A dry film is transparent on the surface of a transparent material such as a glass plate, a plastic plate, a plastic film, etc., and is used for decorations that have a light source inside, and the surface of the film is fine-grained, crepe-like, Alternatively, a coating that creates a rough surface is applied, and gold is deposited on the dried film of the coating surface using a vacuum evaporation method to form a thin film with high translucency. A method for producing a dichroic pear-shaped decorative material with light colors.
JP1668682A 1982-02-04 1982-02-04 Formation of golden or silvery aventurine thin film Granted JPS58133371A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1668682A JPS58133371A (en) 1982-02-04 1982-02-04 Formation of golden or silvery aventurine thin film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1668682A JPS58133371A (en) 1982-02-04 1982-02-04 Formation of golden or silvery aventurine thin film

Publications (2)

Publication Number Publication Date
JPS58133371A JPS58133371A (en) 1983-08-09
JPS6114228B2 true JPS6114228B2 (en) 1986-04-17

Family

ID=11923193

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1668682A Granted JPS58133371A (en) 1982-02-04 1982-02-04 Formation of golden or silvery aventurine thin film

Country Status (1)

Country Link
JP (1) JPS58133371A (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7658017B1 (en) * 2004-01-12 2010-02-09 Thomas Brian Laviolette Vacuum drying method
CN101652497A (en) * 2007-06-20 2010-02-17 东莞万德电子制品有限公司 Form the method for color plating on a kind of transparent plastic article
JP5461147B2 (en) * 2009-11-02 2014-04-02 藤倉化成株式会社 Composite coating for automobiles
CN102398398A (en) * 2011-02-22 2012-04-04 汪砚秋 Hydrophobic plastic film
FR2995245B1 (en) * 2012-09-10 2015-05-15 Saint Gobain DECORATIVE GLAZING WITH REFLECTIVE LAYER DEPOSITED ON A TEXTURED SUBSTRATE

Also Published As

Publication number Publication date
JPS58133371A (en) 1983-08-09

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