JPS6113309Y2 - - Google Patents
Info
- Publication number
- JPS6113309Y2 JPS6113309Y2 JP1980189577U JP18957780U JPS6113309Y2 JP S6113309 Y2 JPS6113309 Y2 JP S6113309Y2 JP 1980189577 U JP1980189577 U JP 1980189577U JP 18957780 U JP18957780 U JP 18957780U JP S6113309 Y2 JPS6113309 Y2 JP S6113309Y2
- Authority
- JP
- Japan
- Prior art keywords
- laminated
- paper
- layer
- metal foil
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011888 foil Substances 0.000 claims description 24
- 239000010410 layer Substances 0.000 claims description 24
- 239000004840 adhesive resin Substances 0.000 claims description 14
- 229920006223 adhesive resin Polymers 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 239000002648 laminated material Substances 0.000 claims description 11
- 229920005992 thermoplastic resin Polymers 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 239000011241 protective layer Substances 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- 238000007639 printing Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 description 14
- -1 bentene Chemical compound 0.000 description 13
- 239000000123 paper Substances 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 238000003475 lamination Methods 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 229920003002 synthetic resin Polymers 0.000 description 6
- 239000000057 synthetic resin Substances 0.000 description 6
- 230000032798 delamination Effects 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000010030 laminating Methods 0.000 description 4
- 229920001684 low density polyethylene Polymers 0.000 description 4
- 239000004702 low-density polyethylene Substances 0.000 description 4
- 239000012790 adhesive layer Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000606 toothpaste Substances 0.000 description 3
- 229940034610 toothpaste Drugs 0.000 description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000007765 extrusion coating Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000005033 polyvinylidene chloride Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- QNRMTGGDHLBXQZ-UHFFFAOYSA-N buta-1,2-diene Chemical compound CC=C=C QNRMTGGDHLBXQZ-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Tubes (AREA)
- Wrappers (AREA)
- Laminated Bodies (AREA)
Description
【考案の詳細な説明】
本考案は練歯磨、化粧品等の押出しチユーブ用
積層材に係り、更に詳しくは揮発性成分により層
間剥離、あるいはストレスクラツクの生ずること
のない押出しチユーブ用積層材に関する。[Detailed Description of the Invention] The present invention relates to a laminate material for extruded tubes for toothpaste, cosmetics, etc., and more particularly to a laminate material for extruded tubes that does not cause delamination or stress cracks due to volatile components.
押出しチユーブ用材料しては、特公昭39−
10847号公報に示されるものが知られている。こ
の公報に記載されるものは、アルミニウム箔の内
側表面に接着剤を介して耐アルカリ性及び耐酸性
を有する合成樹脂膜を積層し、一方前記アルミニ
ウム箔の外側表面には可撓で且つ強靫な合成樹脂
層を被着成層した可撓性積層材であつて、これを
もつて筒状のチユーブ本体を形成せしめるもので
ある。 The material for extruded tubes is
The one shown in Publication No. 10847 is known. In the method described in this publication, a synthetic resin film having alkali resistance and acid resistance is laminated on the inner surface of an aluminum foil via an adhesive, while a flexible and strong film is laminated on the outer surface of the aluminum foil. It is a flexible laminated material on which a synthetic resin layer is deposited, and is used to form a cylindrical tube body.
しかしながら、この公報に記載される積層材で
は、内容物中の芳香油、香料等の揮発性成分が前
記アルミニウム箔とその内側表面に積層されてい
る耐アルカリ性及び耐酸性を有する合成樹脂膜と
を接着している接着剤に達し、その結果アルミニ
ウム箔と耐アルカリ性及び耐酸性を有する合成樹
脂膜とが層間剥離を起こす。 However, in the laminated material described in this publication, volatile components such as aromatic oils and perfumes in the contents are transferred to the aluminum foil and the synthetic resin film having alkali resistance and acid resistance that is laminated on the inner surface of the aluminum foil. The adhesive reaches the bonding agent, and as a result, delamination occurs between the aluminum foil and the alkali-resistant and acid-resistant synthetic resin film.
そのため金属箔と前記耐アルカリ性及び耐酸性
を有する合成樹脂膜との間の接着剤として、金属
箔と直接反応できるアシドポリマーを使用するこ
とが提案されている。実際、エチレン−アクリル
酸共重合体が多用されている。しかし、この樹脂
を用いた積層物は耐ストレススクラツク性が劣る
という欠点を有している。ラミチユーブは使用に
際してくり返し揉まれ、特定の部位にストレスが
かかりやすい。従つて耐ストレスクラツク性はラ
ミチユーブ用積層材の保有すべき重要な性質であ
る。 Therefore, it has been proposed to use an acidic polymer that can directly react with the metal foil as an adhesive between the metal foil and the alkali-resistant and acid-resistant synthetic resin film. In fact, ethylene-acrylic acid copolymers are often used. However, laminates using this resin have the disadvantage of poor stress scratch resistance. Lamitube is rubbed repeatedly during use, which tends to put stress on specific areas. Therefore, stress crack resistance is an important property that laminated materials for lamictic tubes should possess.
エチレン−アクリル酸共重合体は、アクリル酸
含有量が高くなると耐ストレスクラツク性は良好
となるが、耐薬品性が劣下する。一方、ポリエチ
レン系樹脂は溶融指数が低くなるに従つて耐スト
レスクラツク性は向上する。しかし、入手可能な
エチレン−アクリル酸共重合体の溶融指数は2.0
が最低である。 In ethylene-acrylic acid copolymers, as the acrylic acid content increases, stress crack resistance improves, but chemical resistance deteriorates. On the other hand, the stress crack resistance of polyethylene resins improves as the melting index decreases. However, the melt index of the available ethylene-acrylic acid copolymer is 2.0.
is the lowest.
本考案者は、前記のような欠点を改良すべく種
種研究の結果、金属箔の一方の表面に、溶融指数
1.0未満のオレフインとエチレン系不飽和カルボ
ン酸との共重合体を介して熱可塑性樹脂を積層す
ることにより、耐ストレスクラツク性が良好にし
て、層間剥離を生ずることのない積層材を得るこ
とができることを見い出し、かかる知見にもとづ
いて本考案を完成したものである。 In order to improve the above-mentioned drawbacks, the inventor of the present invention, as a result of various researches, decided to add a melting index to one surface of the metal foil.
To obtain a laminated material that has good stress crack resistance and does not cause delamination by laminating a thermoplastic resin through a copolymer of an olefin and an ethylenically unsaturated carboxylic acid having a molecular weight of less than 1.0. The present invention was completed based on this knowledge.
即ち、本考案の要旨は金属箔の一方の表面に溶
融指数1.0未満のオレフインとエチレン系不飽和
カルボン酸とを共重合してなる接着性樹脂を介し
て、熱可塑性樹脂とが積層されており、且つ前記
金属箔の他方の表面に紙が接着積層されており、
この紙表面上に順次下地層、印刷層及び保護層が
設けられていることを特徴とする押出しチユーブ
用積層材である。 That is, the gist of the present invention is that a thermoplastic resin is laminated on one surface of a metal foil via an adhesive resin made by copolymerizing an olefin with a melting index of less than 1.0 and an ethylenically unsaturated carboxylic acid. , and paper is adhesively laminated on the other surface of the metal foil,
This laminated material for extruded tubes is characterized in that a base layer, a printing layer, and a protective layer are sequentially provided on the surface of the paper.
以下、本考案につき図面を参照しながら詳細に
説明する。 Hereinafter, the present invention will be described in detail with reference to the drawings.
第１図は本考案の一実施例を示したものであつ
て、この図面に基づいて本考案を説明すれば、金
属箔１の一表面に接着性樹脂層２を介して熱可塑
性樹脂層３が積層されている。且つ前記金属箔１
の反対面に接着剤層４を介して紙５が積層されて
おり、この紙５表面上に、順次下地層６印刷層７
及び保護層８が設けられている。 FIG. 1 shows an embodiment of the present invention. The present invention will be explained based on this drawing. A thermoplastic resin layer 3 is formed on one surface of a metal foil 1 through an adhesive resin layer 2. are layered. and the metal foil 1
A paper 5 is laminated on the opposite side of the paper 5 with an adhesive layer 4 interposed therebetween.
and a protective layer 8 are provided.
本考案における金属箔１はアルミニウム箔で厚
さ約７〜15μのものが用いられる。 The metal foil 1 in the present invention is an aluminum foil having a thickness of approximately 7 to 15 microns.
また、本考案において接着性樹脂２とは１種も
しくは複数種の溶融指数1.0未満のオレフイン
99.8〜90重量％とエチレン系不飽和カルボン酸
0.2〜10重量％との共重合体である。ここにおい
てオレフインとは、エチレン、プロパン、ブテ
ン、ベンテン、ヘキセン、オクテン、ノネン、デ
セン、４−メチルベンテン−１等であり、これら
の１種あるいは２種以上を適用し得る。また、エ
チレン系不飽和カルボン酸とは、マレイン酸、フ
マル酸、イタコン酸、無水マレイン酸、無水イタ
コン酸などである。共重合の方法としては通常グ
ラフト共重合法による。即ち、事前に重合された
ポリオレフインに対して、エチレン系不飽和カル
ボン酸を有機過酸化物ジアゾ化合物等のラジカル
開始剤、或は電子線、紫外線等のラジカル開始手
段の存在下でグラフト共重合を行う。 In addition, in the present invention, the adhesive resin 2 refers to one or more types of olefins with a melting index of less than 1.0.
Ethylenically unsaturated carboxylic acid with 99.8-90% by weight
It is a copolymer with 0.2 to 10% by weight. Here, olefins include ethylene, propane, butene, bentene, hexene, octene, nonene, decene, 4-methylbentene-1, etc., and one or more of these may be used. Moreover, ethylenically unsaturated carboxylic acids include maleic acid, fumaric acid, itaconic acid, maleic anhydride, itaconic anhydride, and the like. The copolymerization method is usually a graft copolymerization method. That is, graft copolymerization of an ethylenically unsaturated carboxylic acid to a prepolymerized polyolefin is carried out in the presence of a radical initiator such as an organic peroxide diazo compound, or a radical initiator such as an electron beam or an ultraviolet ray. conduct.
本考案において前記接着性樹脂の溶融指数を
1.0未満としたのは、溶融指数1.0未満の前記接着
性樹脂が金属箔に対して充分な接着性を示すのみ
ならず耐ストレスクラツク性に優れるからであ
る。 In the present invention, the melting index of the adhesive resin is
The reason why the adhesive resin has a melting index of less than 1.0 not only exhibits sufficient adhesion to metal foil but also has excellent stress crack resistance.
前記接着性樹脂のアルミニウム箔上へのラミネ
ートは、フイルム化したものをヒートシールによ
り層間接着してラミネートする方法、あるいは押
出しラミネート法等による。 The adhesive resin is laminated onto the aluminum foil by a method of laminating a film by adhering layers by heat sealing, or by an extrusion lamination method.
押出しラミネートは、溶融指数が小さいことよ
り単独では困難であり、共押出しラミネートが好
ましい。前記接着性樹脂層の厚さは３〜50μ好ま
しくは５〜30μである。 Extrusion lamination is difficult to perform alone due to its low melting index, and coextrusion lamination is preferred. The thickness of the adhesive resin layer is 3 to 50 microns, preferably 5 to 30 microns.
３μ以下の厚さを得るのは加工上困難である。
一方、50μ以上のときはコストを上昇させるため
望ましくない。 It is difficult to obtain a thickness of 3 μm or less in terms of processing.
On the other hand, when it is 50μ or more, it is not desirable because it increases the cost.
又、５〜30μのとき特に好ましいのは加工上適
度な厚さであり、充分な接着強度が得られるから
である。 Further, a thickness of 5 to 30 μm is particularly preferable because it is an appropriate thickness for processing and provides sufficient adhesive strength.
前記接着性樹脂層は耐薬品性に優れ、浸透して
きた内容物の各種の揮発性成分によつて影響され
て層間剥離を生ずることはないのみならず、耐ス
トレスクラツク性も優れている。 The adhesive resin layer has excellent chemical resistance, is not affected by various volatile components of the contents that have permeated into it and does not cause delamination, and also has excellent stress crack resistance.
前記接着性樹脂層２上に積層する熱可塑性樹脂
とは、低密度、中密度又は高密度各種ポリエチレ
ン、ポリプロピレン、ポリエチレンテレフタレー
ト、ポリアミド、ポリカーボネート、ポリアセテ
ート、ポリ塩化ビニル、ポリ塩化ビニリデン、ポ
リビニルアルコール、エチレン−ビニルアルコー
ル共重合体、エチレン−酢酸ビニル共重合体、エ
チレン−α−オレフイン共重合体、アイオノマー
樹脂、ポリ−１，２−ブタジエン、ポリブチレ
ン、ポリアクリロニトリル等であり、熱可塑性樹
脂層は２種以上積層して多層としてもかまわな
い。 The thermoplastic resin laminated on the adhesive resin layer 2 includes various types of low density, medium density or high density polyethylene, polypropylene, polyethylene terephthalate, polyamide, polycarbonate, polyacetate, polyvinyl chloride, polyvinylidene chloride, polyvinyl alcohol, Ethylene-vinyl alcohol copolymer, ethylene-vinyl acetate copolymer, ethylene-α-olefin copolymer, ionomer resin, poly-1,2-butadiene, polybutylene, polyacrylonitrile, etc., and the thermoplastic resin layer has two It is also possible to form a multilayer structure by laminating more than one layer.
熱可塑性樹脂層３の積層法は、接着性樹脂層２
と共押出しにより積層するか、あるいは接着性樹
脂層２上への押出しラミネート等による。熱可塑
性樹脂層の厚さは10〜200μ好ましくは30〜100μ
である。 The method of laminating the thermoplastic resin layer 3 is as follows:
or by extrusion lamination onto the adhesive resin layer 2. The thickness of the thermoplastic resin layer is 10-200μ, preferably 30-100μ
It is.
10μ以下のときは十分なヒートシール強度が得
られないため望ましくなく、一方、200μ以上の
ときはコストを上昇させるため望ましくない。 When the thickness is less than 10μ, sufficient heat sealing strength cannot be obtained, which is undesirable.On the other hand, when it is more than 200μ, it is undesirable because it increases cost.
又、30〜100μのとき等に好ましいのは十分な
ヒートシール強度が得られる適度な厚さであるか
らである。 Further, a thickness of 30 to 100 μm is preferable because it is an appropriate thickness that provides sufficient heat sealing strength.
また、接着剤層４はポリオレフイン、ポリ塩化
ビニル、アクリル系樹脂、エポキシ樹脂、ゴム誘
導体、ポリウレタン、その他の合成樹脂を主体と
したもので、金属箔１と紙５とが接着できるもの
であれば何れを使用してもよく、押出コート法、
フイルムラミネート法、溶液塗工法その他、通常
のコーテイング法で形成できる。 The adhesive layer 4 is mainly made of polyolefin, polyvinyl chloride, acrylic resin, epoxy resin, rubber derivative, polyurethane, or other synthetic resin, as long as it can bond the metal foil 1 and paper 5 together. Any method may be used, such as extrusion coating method,
It can be formed by a film lamination method, a solution coating method, or other ordinary coating methods.
紙５はグラシン紙、クラフト紙、模造紙又は合
成紙の何れでもよく、坪量20〜70ｇ／m2程度のも
のが用いられる。 The paper 5 may be glassine paper, kraft paper, imitation paper, or synthetic paper, and has a basis weight of about 20 to 70 g/m 2 .
下地層６は主として樹脂に充填剤、着色剤等を
添加し、溶剤、希釈剤等で充分混練してなる組成
物を通常のコーテイング法で紙５の表面上に形成
する。或は、着色樹脂組成物をフイルム状にし、
各種ラミネート法により形成することもできる。 The base layer 6 is formed by adding a filler, a coloring agent, etc. to a resin, thoroughly kneading the composition with a solvent, a diluent, etc., and forming the composition on the surface of the paper 5 by a conventional coating method. Alternatively, the colored resin composition is made into a film,
It can also be formed by various lamination methods.
印刷層７の印刷模様は、例えば文字、図形等で
あり、印刷層は通常のインキ組成物を使用してオ
フセツト、グラビア、スクリーンフレキソ印刷法
等によつて印刷して形成する。 The printed pattern of the printed layer 7 is, for example, characters, figures, etc., and the printed layer is formed by printing using a conventional ink composition by offset, gravure, screen flexographic printing, or the like.
また、保護層８は、ポリエチレン、ポリプロピ
レン、ポリ塩化ビニル、ポリ塩化ビニリデン、ポ
リスチロール、ポリアミド、ポリエステル等の樹
脂を使用することができ、目的に応じて、１層又
はそれ以上であつてもよい。この保護層８は押出
コート法、フイルムラミネート法溶液塗工法等の
各種方法で積層することができる。 The protective layer 8 can be made of resin such as polyethylene, polypropylene, polyvinyl chloride, polyvinylidene chloride, polystyrene, polyamide, polyester, etc., and may have one or more layers depending on the purpose. . This protective layer 8 can be laminated by various methods such as an extrusion coating method, a film lamination method, and a solution coating method.
以上、詳記した通り、本考案の押出しチユーブ
用積層材は耐薬品性に優れ、内容物の各種成分の
浸透によつても層間剥離を生ずることなく、また
耐ストレスクラツク性も良好であり、練歯磨、化
粧品、香料その他の容器の構成材料として広く使
用することができる利点を有する。 As detailed above, the laminate material for extruded tubes of the present invention has excellent chemical resistance, does not cause delamination even when various components of the contents permeate, and has good stress crack resistance. It has the advantage that it can be widely used as a constituent material for containers for toothpaste, cosmetics, fragrances, and other containers.
次に本考案の実施例をあげて、本考案につき具
体的に説明する。 Next, the present invention will be specifically explained by giving examples of the present invention.
実施例
坪量42ｇ／m2のＡ模造紙と40μの乳白ポリエチ
レンとを20μのポリエチレンを用いて貼合せる。
前記乳白ポリエチレンの反対面にグラビア印刷法
により絵柄を印刷し、さらにこの印刷面上にポリ
エチレンを50μ厚で押出しコーテイングし、保護
膜とする。Example A imitation paper with a basis weight of 42 g/m 2 and milky white polyethylene with a thickness of 40 μ are laminated using polyethylene with a thickness of 20 μ.
A pattern is printed on the opposite side of the milky white polyethylene using a gravure printing method, and polyethylene is extruded and coated on the printed side to a thickness of 50 μm to form a protective film.
次に上述Ａ模造紙の反対面に、厚さ15μのアル
ミニウム箔を20μのポリエチレンを用いて貼合せ
る。 Next, on the opposite side of the above imitation paper A, a 15μ thick aluminum foil is pasted using 20μ thick polyethylene.
該アルミニウム箔面を赤外線ヒーターゾーンを
通過させることにより加熱し、二層共押出しラミ
ネート機により、接着性樹脂（Ｎ−ポリマー
RA1050日本石油化学製M.I.0.5）10μ、低密度ポ
リエチレン（ミラソン16、三井ポリケミカル製）
20μを表面温度約100℃にて、アルミニウム箔に
接して、接着性樹脂を積層する。さらに、低密度
ポリエチレン面に、同一の樹脂を60μ積層する。
得られた積層材で押出しチユーブを形成し、これ
に練歯磨を入れ、40℃にて21ケ月間放置したが、
アルミニウム箔と低密度ポリエチレン間に剥離は
みとめられなかつた。 The aluminum foil surface is heated by passing through an infrared heater zone, and adhesive resin (N-polymer
RA1050 Nippon Petrochemical MI0.5) 10μ, low density polyethylene (Mirason 16, Mitsui Polychemical)
At a surface temperature of approximately 100°C, 20 μm is brought into contact with aluminum foil and adhesive resin is laminated thereon. Furthermore, 60μ of the same resin is laminated on the low-density polyethylene surface.
An extruded tube was formed from the resulting laminated material, toothpaste was added to it, and the tube was left at 40°C for 21 months.
No peeling was observed between the aluminum foil and the low density polyethylene.
第１図は本考案の押出しチユーブ用積層材の実
施例を示す略示断面図である。
１……金属箔、２……接着性樹脂層、３……熱
可塑性樹脂層、４……接着剤層、５……紙、６…
…下地層、７……印刷層、８……保護層。
FIG. 1 is a schematic cross-sectional view showing an embodiment of the laminate material for extruded tubes of the present invention. DESCRIPTION OF SYMBOLS 1... Metal foil, 2... Adhesive resin layer, 3... Thermoplastic resin layer, 4... Adhesive layer, 5... Paper, 6...
... Base layer, 7 ... Printing layer, 8 ... Protective layer.
Claims (1)
融指数1.0未満のオレフインとエチレン系不飽和
カルボン酸とを共重合してなる接着性樹脂を介し
て、熱可塑性樹脂とが積層されており、且つ前記
金属箔の他方の表面に紙が接着積層されており、
この紙表面上に順次下地層、印刷層及び保護層が
設けられていることを特徴とする押出しチユーブ
用積層材。 A thermoplastic resin is laminated on one surface of the metal foil via an adhesive resin made by copolymerizing one or more types of olefin with a melting index of less than 1.0 and an ethylenically unsaturated carboxylic acid, and paper is adhesively laminated on the other surface of the metal foil,
A laminate material for extruded tubes, characterized in that a base layer, a printing layer, and a protective layer are sequentially provided on the surface of the paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1980189577U JPS6113309Y2 (en) | 1980-12-27 | 1980-12-27 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1980189577U JPS6113309Y2 (en) | 1980-12-27 | 1980-12-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57111531U JPS57111531U (en) | 1982-07-09 |
| JPS6113309Y2 true JPS6113309Y2 (en) | 1986-04-24 |
Family
ID=29993714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1980189577U Expired JPS6113309Y2 (en) | 1980-12-27 | 1980-12-27 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6113309Y2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59129524U (en) * | 1983-02-21 | 1984-08-31 | 大日本印刷株式会社 | Laminated material for extruded tubes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5034472A (en) * | 1973-07-30 | 1975-04-02 | ||
| JPS5422769U (en) * | 1977-07-16 | 1979-02-14 | ||
| JPS5422770U (en) * | 1977-07-19 | 1979-02-14 |
-
1980
- 1980-12-27 JP JP1980189577U patent/JPS6113309Y2/ja not_active Expired
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5034472A (en) * | 1973-07-30 | 1975-04-02 | ||
| JPS5422769U (en) * | 1977-07-16 | 1979-02-14 | ||
| JPS5422770U (en) * | 1977-07-19 | 1979-02-14 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57111531U (en) | 1982-07-09 |
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