JPS61116511A - Molding machine for foaming material - Google Patents

Molding machine for foaming material

Info

Publication number
JPS61116511A
JPS61116511A JP59239636A JP23963684A JPS61116511A JP S61116511 A JPS61116511 A JP S61116511A JP 59239636 A JP59239636 A JP 59239636A JP 23963684 A JP23963684 A JP 23963684A JP S61116511 A JPS61116511 A JP S61116511A
Authority
JP
Japan
Prior art keywords
foaming material
endless belt
foaming
belt mechanism
foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP59239636A
Other languages
Japanese (ja)
Other versions
JPH0578403B2 (en
Inventor
Kiyoshi Inoue
潔 井上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Technical Research Inc
Original Assignee
IG Technical Research Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Technical Research Inc filed Critical IG Technical Research Inc
Priority to JP59239636A priority Critical patent/JPS61116511A/en
Publication of JPS61116511A publication Critical patent/JPS61116511A/en
Publication of JPH0578403B2 publication Critical patent/JPH0578403B2/ja
Granted legal-status Critical Current

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  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To reduce the price of a machine and to make the machine compact by a method wherein the zone of the start section to the section where foaming material is reacted, expanded and shows the largest blowing pressure are provided by an endless belt mechanism and the zone where carriage and curing are performed is provided with a roll mold. CONSTITUTION:Foaming material 2 (expandable synthetic resin material etc.) is spread, discharged, etc. by a foaming material supply machine 1 on a medium 3 and expanded in a curing oven 4. The curing oven is composed of an endless belt mechanism 5, a roll mold 15, heaters 20-23 and a cover 24. The foaming material 2 is molded in a specified shape and supplied at such a hardness that the original shape is not deformed by cutting, carriage.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は発泡材、例えば発泡性の合成樹脂原料を基材上
に吐出し、これを反応発泡させて所定時間内に任意形状
の複合板、サンドイツチ板等を連続して成形する装置に
関するものである。
Detailed Description of the Invention (Industrial Field of Application) The present invention involves dispensing a foaming material, such as a foamable synthetic resin raw material, onto a base material and reacting and foaming it to form a composite plate of any shape within a predetermined time. , relates to an apparatus for continuously forming sanderch boards, etc.

(従来の技術) 複合板、断熱板を製造する装置としては実公昭53−2
3744号公報、実公昭59−17620号公報等があ
る。
(Prior art) As a device for manufacturing composite boards and heat insulating boards,
3744, Japanese Utility Model Publication No. 59-17620, etc.

(発明が解決しようとする問題点) 上記したような装置で発泡材を成形する場合には次のよ
うな不利があった。すなわち、前者の装置はキャタピラ
式の型部材を回転して製造するため、装置全体を頑丈に
製作する必要があり、それに伴ってモータは高馬力を要
し、しかも重量がスチールベルト等に比して数倍も重く
、それに反して回転速度が最大10〜15a+/win
と遅く、エネルギーの消費が膨大となり、かつ、生産性
が悪くコストアップになるばかりでなく装置の価格が高
額となる欠点があった。また、後者の装置はスチールベ
ルト機構であり、成形速度は前者より速い30〜40m
/winで回転するが複雑な形状の複合板などは型部材
自体が平板であるため製造不可能となる欠点があった。
(Problems to be Solved by the Invention) When molding a foamed material using the above-mentioned apparatus, there are the following disadvantages. In other words, since the former device is manufactured by rotating a caterpillar-type mold member, the entire device must be made sturdy, and the motor therefore requires high horsepower, and is heavier than steel belts etc. It is several times heavier, but the rotation speed is up to 10~15a+/win.
The process is slow, consumes a huge amount of energy, has poor productivity, increases costs, and has the drawbacks of making the equipment expensive. In addition, the latter device has a steel belt mechanism, and the forming speed is 30 to 40 m faster than the former.
/win rotates, but there is a drawback that it is impossible to manufacture complex-shaped composite plates because the mold member itself is a flat plate.

さらに、後者の装置ではスチールベルトが回転するため
プーリの直径がある程度大きくないとスチールベルトが
屈曲しにくくなるため、大口径のプーリを約1メートル
に形成する必要があり、その結果としては装置全体が大
型となり、消費エネルギーが大となる不利があった。
Furthermore, in the latter device, since the steel belt rotates, the steel belt will be difficult to bend unless the diameter of the pulley is large to a certain extent, so it is necessary to form the large diameter pulley to about 1 meter, and as a result, the entire device The disadvantage was that it was large and consumed a lot of energy.

また、従来の装置はいずれも大型であるため、型材の温
度を所定温度まで上昇させるのに約1〜1.5時間を要
する欠点があった。
Further, since all conventional devices are large-sized, they have the disadvantage that it takes about 1 to 1.5 hours to raise the temperature of the mold material to a predetermined temperature.

(問題点を解決するための手段) 本発明はこのような欠点を除去するため、発泡材が反応
、発泡すると共に、その発泡圧が最大となる時間までを
エンドレスベルト機構で形成し、その後に搬送とキュア
を行なう領域をローラ群からなる転子型で形成した発泡
材の成形装置である。
(Means for Solving the Problems) In order to eliminate such drawbacks, the present invention uses an endless belt mechanism to form the reaction and foaming of the foaming material until the time when the foaming pressure reaches its maximum, and then This is a foam molding device in which the area for conveying and curing is formed by a trochanter type consisting of a group of rollers.

(作用) エンドレスベルト機構は発泡材原料が反応、発泡して所
定形状に成形するものであり、転子型は上記機構から送
出される発泡材をそのままの状態で搬送すると共にキュ
アし、見掛上はほぼ硬化したような状態で工場内に送出
し、次工程の所定長さに切断する走行カッタへ送給する
ためのものである。
(Function) The endless belt mechanism reacts and foams the foam material raw material to form it into a predetermined shape, and the trochanter type conveys the foam material sent out from the mechanism as it is, cures it, and forms it into a predetermined shape. The upper part is sent into the factory in a nearly cured state, and is then fed to a traveling cutter that cuts it into a predetermined length in the next process.

(実施例) 以下に、図面を用いて本発明に係る発泡材の成形装置の
一実施例について詳細に説明する。第1図は上記装置の
概略を示す説明図であり、■は発泡材供給機で上下、左
右に移動可能な状態に支持したものであり、具体的な一
例としては例えば、スプレーガン、回転羽根、その他の
吐出機等からなり、発泡材2、例えば発泡性合成樹脂原
料を基材3上に散布、吐出等するものである。土はキュ
アオーブンでエンドレスベルト機構上と転子型■とヒー
タ20〜23とカバー24とから構成したものであり゛
、発泡材2を所定形状に成形すると共に、切断、搬送に
よっても原形を変形しないような硬度にして送出するた
めのものである。さらに説明すると、エンドレスベルト
機構iは発泡材を押圧、成形しながら同一方向に進行す
る上下のエンドレスベルト6.7 (以下、単にベルト
と称す−)と、このベルトを掛合する駆動輪8.9と従
動輪1o、1)と、この駆従動輸間にある領域のベルト
が所定間隙、所謂型12を形成するように支持する補助
輪13.14とから構成したものである。特に、エンド
レスベルト機構iは発泡材2が反応、発泡して型12内
を充填し、はぼ発泡′圧が最大となり、低下し始める領
域までに形成したものである。これは基材3に吐出され
た発泡材2の形状がほぼ定まり、かつ、基材3と後記す
る裏面材との接着もほぼ完了する状態となるからである
。換言すれば、エンドレスベルト機構上に対する圧力は
この領域A位までであり、かつ、基材3等と発泡材2の
接着の良否もこの領域で完了するからである。しかも、
この領域Aは反応、発泡途中の発泡材2と基材3、裏面
材との接着を好条件下で行なうために、平坦なベルト6
.7間で発泡材2が軟らかい状態でボードを揉むように
せず、安定した状態で搬送する必要があることに起因す
るものである。また、補助ローラ13.14はベルト6
.7が発泡圧によって変形するのを防止するものであり
、ベルト6.7の移動をスムーズに、かつ、型12の空
隙を一定に維持するためのものである。さらに、転子型
側は上ローラ群16と下口−°う群17とからなり、そ
のローラ18.19間の上下方向の間隔Tは型12の上
下型部材、所謂ベルト6.7間の間隔と同じように、か
つ、型12の延長線上に配列するものである。また、ロ
ーラ18.19の進行方向に対する配列はエンドレスベ
ルト機構上の出口から遠ざかるに従って粗ピツチとなる
ように配列したものである。さらに説明すると、転子型
用はエンドレスベルト機構上から送出される複合板、特
に発泡材2は既に所定形状に成形され、発泡圧が低下し
始めているが、まだ発泡組織が柔い硬化途中の発泡材2
を見掛上、硬化した状態にしてその出口からキュアオー
ブン3外に送出し、基材3、裏面材間に芯材として発泡
材2が剥離せずに一体に固着した状態で送出されるため
のものである。しかも、転子型■は発泡材2を搬送中に
揉むこともなく、型として厚さを規制しながら搬送しう
るちのである。なお、ローラ18.19はフリーローラ
構造、あるいは上、下ローラ群16.17を駆動したり
、もしくはローラ群16.17のうちの下ローラ群17
を駆動し、上ローラ群16をフリーローラとするもので
あり、かつ、ローラ群16.17の両方、または一方を
駆動するときはエンドレスベルト機構上と同一速度にす
るものである。前記したヒータ20〜23はエンドレス
ベルト機構i、転子型用を約30〜1)0℃程度まで加
温し、発泡材2の反応、発泡を促進させると共に、必要
なキュアを行ない、かつ、温度に敏感な化学反応物であ
る発泡材2の反応系、発泡組織を均質化するものである
。なお、ヒータ20〜23は全部装着する必要がないと
きにはヒータ2L 23を装着し、熱効率を有効に活用
することもできる。さらにカバー24はキュアオーブン
生の熱を外気に放出せず、効果的に活用すると共に、燃
焼ガスを工場外へ排気するように機能するものである。
(Example) Hereinafter, an example of the foam material molding apparatus according to the present invention will be described in detail with reference to the drawings. Fig. 1 is an explanatory diagram showing the outline of the above-mentioned device, and () is supported by a foam material feeder so as to be movable up and down and left and right. , and other discharge machines, etc., and sprays and discharges the foaming material 2, for example, a foamable synthetic resin raw material, onto the base material 3. The soil is made up of an endless belt mechanism, a trochanter type ■, heaters 20 to 23, and a cover 24 in a curing oven.The foamed material 2 is formed into a predetermined shape, and the original shape is also deformed by cutting and conveying. It is intended to be sent out with a hardness that will not cause it. To explain further, the endless belt mechanism i consists of upper and lower endless belts 6.7 (hereinafter simply referred to as belts) that move in the same direction while pressing and molding the foam material, and a drive wheel 8.9 that engages these belts. It is composed of a driven wheel 1o, 1), and an auxiliary wheel 13, 14 that supports the belt in the area between the driven and driven wheels so as to form a predetermined gap, a so-called shape 12. In particular, the endless belt mechanism i is formed until the foaming material 2 reacts and foams to fill the inside of the mold 12 until the foaming pressure reaches its maximum and begins to decrease. This is because the shape of the foamed material 2 discharged onto the base material 3 is almost fixed, and the adhesion between the base material 3 and the backing material to be described later is almost completed. In other words, the pressure on the endless belt mechanism is limited to this area A, and the adhesion between the base material 3 and the like and the foamed material 2 is determined in this area. Moreover,
In this area A, a flat belt 6 is used to bond the foam material 2, base material 3, and back surface material during reaction and foaming under favorable conditions.
.. This is due to the fact that it is necessary to transport the board in a stable state without rubbing the board while the foam material 2 is still soft. In addition, the auxiliary rollers 13 and 14 are connected to the belt 6.
.. This is to prevent belts 6 and 7 from deforming due to foaming pressure, and to ensure smooth movement of belts 6 and 7 and to maintain a constant gap in mold 12. Further, the trochanter mold side consists of an upper roller group 16 and a lower roller group 17, and the vertical distance T between the rollers 18 and 19 is equal to the distance between the upper and lower mold members of the mold 12, so-called belts 6 and 7. They are arranged at the same intervals and on an extension line of the mold 12. Further, the rollers 18 and 19 are arranged in a direction in which the rollers 18 and 19 are arranged in such a manner that the pitch becomes coarser as the distance from the outlet on the endless belt mechanism increases. To explain further, for the trochanter type, the composite plate sent out from the endless belt mechanism, especially the foam material 2, has already been formed into a predetermined shape and the foaming pressure has begun to decrease, but the foam structure is still soft and in the process of curing. Foam material 2
This is because the foamed material 2 is sent out from the exit of the cure oven 3 in an apparently cured state, and the foamed material 2 is fixed as a core material between the base material 3 and the back material without peeling off. belongs to. Moreover, the trochanter mold (2) does not rub the foamed material 2 during transportation, and can be used as a mold to transport the foam while regulating its thickness. Note that the rollers 18.19 have a free roller structure, or drive the upper and lower roller groups 16.17, or drive the lower roller group 17 of the roller groups 16.17.
The upper roller group 16 is used as a free roller, and when driving both or one of the roller groups 16 and 17, the speed is the same as that on the endless belt mechanism. The heaters 20 to 23 described above heat the endless belt mechanism i and the trochanter type to about 30 to 1) 0°C to promote the reaction and foaming of the foaming material 2 and perform necessary curing, and This homogenizes the reaction system and foam structure of the foam material 2, which is a temperature-sensitive chemical reactant. Note that when it is not necessary to install all of the heaters 20 to 23, the heater 2L 23 can be installed to effectively utilize thermal efficiency. Furthermore, the cover 24 functions to effectively utilize raw heat from the cure oven without releasing it to the outside air, and to exhaust combustion gas to the outside of the factory.

なお、キュアオーブン土の出、入口には複合板等の通過
する開口部が設けられている。25は裏面材で、例えば
紙、金属薄、金属板等の1種、または2種を積層したも
のからなり、ガイドローラ26を介して基材3上に案内
し、キュアオープン玉の人口に送給されるものである。
Note that an opening through which a composite plate or the like passes is provided at the outlet and inlet of the cure oven soil. Reference numeral 25 denotes a backing material, which is made of one or two layers of paper, thin metal, metal plate, etc., and is guided onto the base material 3 via a guide roller 26 and sent to the cured open ball. It is something that is provided.

27は搬送機で基材3をキュアオーブン↓に送給するた
めのものである。28は走行力フタでキュアオーブン生
の出口から送出される複合帯を定尺に切断するものであ
り、29は送出機で定尺に切断したボードを次工程に送
出するためのものである。
27 is a conveyor for feeding the base material 3 to the cure oven ↓. Reference numeral 28 is a running power lid for cutting the composite strip sent out from the raw outlet of the cure oven into regular lengths, and 29 is for sending the boards cut into regular lengths by a delivery machine to the next process.

次に本発明に係る発泡材の成形装置の動作について説明
する。いま、第2図に示すようなボードを第1図に示す
装置を用いて連続して製造すると仮定する。まず、発泡
材2としてはポリウレタンフォーム用原料、基材3とし
ては樋状に成形した金属板、裏面材25としてはアルミ
アスベスト紙、キュアオーブン生の雰囲気温を90℃、
エンドレスベルト機構1)転子型長p回転速度を30+
w/sinとし、厚さ15mのサンドインチ構造のボー
ドSを形した基材3を搬送機27によって連続して矢印
イ方向に搬送する。そして基材3が発泡材供給機lの真
下に到着すると、発泡材2、所謂未発泡のポリウレタン
フォーム用原料がコンベンショナル法によって混合され
、基材3上に吐出される。吐出された原料は第4図にお
いてBの領域の挙動を示す。すなわち、第4図は基材3
の中心線上の計測であり、上記原料は大部分が充填範囲
に分散されて吐出され、しかも発泡圧は裏面材25上で
の発泡圧を測定するためにこの領域では零である0次に
基材3がガイドローラ26の位置に到達すると、裏面材
25が基材3上に案内され、発泡途中の原料上に積層さ
れ、型12に送出される。そして、発泡材2は両部材間
で第5図に示すように急激に発泡し、それに伴って発泡
圧も上昇し、発泡圧が上、下ベルト6.7に付加される
と共に、基材3、裏面材25間の空隙が発泡材2によっ
て第6図に示すように充填され、はぼ発泡が終り、発泡
圧も最大となり、発泡圧が降下し始めた時点で転子型用
に送給する。なお、発泡材2は基材3と裏面材25によ
って形成される空隙に対して35kg/rdのフオーム
のときに使用する量の100%として充填し、その際の
最大発泡圧は180g/c+Jであった。この状態を第
4図Aの領域に示す、また、この領域Aでは発泡材2の
接着性、発泡高さ、充填状態がほぼ決まるため反応、発
泡途中の発泡材2を揉むことなく搬送し、より強力に接
着し、かつ、基材3、裏面材25との剥離がなく、発泡
組織に亀裂の発生もなくスムーズに搬送することができ
るものである。次に、エンドレスベルト機構工の型12
の出口から送出されたボードは高さと搬送方向のみを規
制した転子型用によって矢印口方向に搬送される。そし
て、この転子型用では発泡材2をキュアし、キュアオー
ブン生の出口から外気に送出した際に、搬送、運搬に耐
える程度に発泡組織を硬化させるものである。勿論、高
さ規制のローラは予備的なものであるが、それよりも主
にボードSを変位せずに型内をスムーズに移動させるの
に有効に働くものである。なお、転子型用を移動中の発
泡材2の挙動は第4図Cの領域に示す。次に転子型用を
出た連続帯状のボードSは走行カッタ28によって定尺
に切断され、送出機29を介して2次成形機(図示せず
)に送給5し、ダブル幅の中心を切断すると共に、端部
に舌片を形成して第2図に示すようなボードとするもの
である。
Next, the operation of the foam material molding apparatus according to the present invention will be explained. Assume now that boards as shown in FIG. 2 are manufactured continuously using the apparatus shown in FIG. First, the foam material 2 is a raw material for polyurethane foam, the base material 3 is a metal plate shaped like a gutter, the back material 25 is aluminum asbestos paper, and the ambient temperature in the cure oven is 90°C.
Endless belt mechanism 1) Trochanter type long p rotation speed 30+
A base material 3 shaped like a board S having a sand inch structure and having a thickness of 15 m is continuously transported in the direction of arrow A by a transporting machine 27. When the base material 3 arrives directly below the foam material feeder 1, the foam material 2, a so-called unfoamed raw material for polyurethane foam, is mixed by a conventional method and discharged onto the base material 3. The discharged raw material exhibits the behavior in region B in FIG. That is, FIG. 4 shows the base material 3
This is a measurement on the center line of When the material 3 reaches the position of the guide roller 26, the backing material 25 is guided onto the base material 3, laminated on the raw material that is being foamed, and sent to the mold 12. Then, the foam material 2 rapidly foams between the two members as shown in FIG. 5, and the foaming pressure increases accordingly. The gap between the backing materials 25 is filled with the foam material 2 as shown in FIG. do. In addition, the foaming material 2 was filled into the void formed by the base material 3 and the backing material 25 at 100% of the amount used for the 35 kg/rd foam, and the maximum foaming pressure at that time was 180 g/c+J. there were. This state is shown in the area A in FIG. 4. In addition, in this area A, the adhesiveness, foaming height, and filling state of the foamed material 2 are almost determined, so the foamed material 2 in the middle of reaction and foaming is transported without being rubbed. It has stronger adhesion, does not peel off from the base material 3 and back material 25, and can be transported smoothly without cracking in the foamed structure. Next, type 12 of the endless belt mechanism worker
The board sent out from the outlet is conveyed in the direction of the arrow by a trochanter-type board whose height and conveyance direction are only regulated. In this case for the trochanter type, when the foam material 2 is cured and sent out to the outside air from the outlet of the cure oven, the foam structure is hardened to the extent that it can withstand transportation and transportation. Of course, the height regulating roller is a preliminary one, but it is more effective mainly in moving the board S smoothly within the mold without displacing it. The behavior of the foamed material 2 during movement in the trochanteric mold is shown in the region C of FIG. Next, the continuous band-shaped board S that has come out of the trochanter mold is cut into regular lengths by a traveling cutter 28, fed to a secondary forming machine (not shown) via a feeder 29, and then placed at the center of the double width. The board is then cut and tongues are formed at the ends to form a board as shown in FIG.

(発明の効果) 上述したように本発明に係る発泡材の成形装置によれば
、発泡材の反応、発泡特性に応じた成形装置としたため
、従前の堅牢で大型のキュアオーブンに比して装置の価
格が約〃になり、しかもコンパクトに形成でき、その上
、消費エネルギーも従前に比して約10〜30%減とし
た特徴がある。また、本発明に係る装置によって製造し
たボードは発泡材と基材、裏面材との剥離もなく、かつ
、発泡組織も従前のように型全部をエンドレスベルト機
構で製造したときと同じように製造できる特徴がある。
(Effects of the Invention) As described above, according to the foamed material molding device of the present invention, the molding device is adapted to the reaction and foaming characteristics of the foamed material. It has the characteristics that the price is about 〃, it can be formed compactly, and the energy consumption is reduced by about 10 to 30% compared to the conventional one. In addition, the board manufactured by the apparatus according to the present invention has no peeling between the foam material, the base material, and the back material, and the foam structure is the same as in the past when the entire mold was manufactured using an endless belt mechanism. There are features that allow it.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に係る発泡材の成形装置の一例を示す説
明図、第2図は上記装置により製造されるボードの一例
を示す斜視図、第3図は基材の一例を示す斜視図、第4
図はキュアオーブン内での発泡材の挙動を示す特性図、
第5図、第6図は第1図α−α線、β−β線における切
断面図である。 1・・・発泡材供給機、3・・・基材、↓・・・キュア
オーブン、5・−−エンドレスベルト機構1、匝・・・
転子型。
FIG. 1 is an explanatory diagram showing an example of a foam material molding device according to the present invention, FIG. 2 is a perspective view showing an example of a board manufactured by the above device, and FIG. 3 is a perspective view showing an example of a base material. , 4th
The figure shows the behavior of the foam material in the curing oven.
5 and 6 are cross-sectional views taken along the α-α line and the β-β line in FIG. 1. 1... Foaming material feeder, 3... Base material, ↓... Cure oven, 5... Endless belt mechanism 1, Trowel...
Trochanteric type.

Claims (1)

【特許請求の範囲】[Claims] (1)合成樹脂発泡体原料を所定形状に連続して成形す
る装置において、上記原料が吐出された後に反応発泡し
、発泡圧が最大になる領域に対してある平行間隙を有し
て同一水平方向に移動するエンドレスベルト機構を配設
し、該機構の後に上記平行間隙を延長するように上下に
配列した多数個のローラからなる転子型を設けたことを
特徴とする発泡材の成形装置。
(1) In a device that continuously molds a synthetic resin foam raw material into a predetermined shape, the raw material is discharged and then reacted and foamed, with a certain parallel gap between the areas where the foaming pressure is maximum, and the same horizontal An apparatus for molding a foamed material, characterized in that an endless belt mechanism that moves in the direction is provided, and a trochanter type consisting of a large number of rollers arranged vertically so as to extend the parallel gap is provided behind the mechanism. .
JP59239636A 1984-11-13 1984-11-13 Molding machine for foaming material Granted JPS61116511A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59239636A JPS61116511A (en) 1984-11-13 1984-11-13 Molding machine for foaming material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59239636A JPS61116511A (en) 1984-11-13 1984-11-13 Molding machine for foaming material

Publications (2)

Publication Number Publication Date
JPS61116511A true JPS61116511A (en) 1986-06-04
JPH0578403B2 JPH0578403B2 (en) 1993-10-28

Family

ID=17047656

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59239636A Granted JPS61116511A (en) 1984-11-13 1984-11-13 Molding machine for foaming material

Country Status (1)

Country Link
JP (1) JPS61116511A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5496575A (en) * 1978-01-17 1979-07-31 Takashi Ishikawa Method of making composite having expansion layer of synthetic resin

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5496575A (en) * 1978-01-17 1979-07-31 Takashi Ishikawa Method of making composite having expansion layer of synthetic resin

Also Published As

Publication number Publication date
JPH0578403B2 (en) 1993-10-28

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