JPS6111279Y2 - - Google Patents
Info
- Publication number
- JPS6111279Y2 JPS6111279Y2 JP1980098348U JP9834880U JPS6111279Y2 JP S6111279 Y2 JPS6111279 Y2 JP S6111279Y2 JP 1980098348 U JP1980098348 U JP 1980098348U JP 9834880 U JP9834880 U JP 9834880U JP S6111279 Y2 JPS6111279 Y2 JP S6111279Y2
- Authority
- JP
- Japan
- Prior art keywords
- polyester fibers
- modified polyester
- fibers
- cloth
- polyester fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 claims description 73
- 229920000728 polyester Polymers 0.000 claims description 63
- 239000004744 fabric Substances 0.000 claims description 34
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000002585 base Substances 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- -1 alkylene terephthalate Chemical compound 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 239000002759 woven fabric Substances 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011022 opal Substances 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000010018 discharge printing Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- MMINFSMURORWKH-UHFFFAOYSA-N 3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound O=C1OCCOC(=O)C2=CC=C1C=C2 MMINFSMURORWKH-UHFFFAOYSA-N 0.000 description 1
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000009412 basement excavation Methods 0.000 description 1
- QUNWXPCJAGERII-UHFFFAOYSA-N benzene-1,3-dicarboxylic acid;potassium Chemical compound [K].OC(=O)C1=CC=CC(C(O)=O)=C1 QUNWXPCJAGERII-UHFFFAOYSA-N 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- RXQGGECQTVPOOB-UHFFFAOYSA-L disodium 4,6-dimethyl-2-sulfobenzene-1,3-dicarboxylate Chemical compound CC1=CC(=C(C(=C1C(=O)[O-])S(=O)(=O)O)C(=O)[O-])C.[Na+].[Na+] RXQGGECQTVPOOB-UHFFFAOYSA-L 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- IBBQVGDGTMTZRA-UHFFFAOYSA-N sodium;2-sulfobenzene-1,3-dicarboxylic acid Chemical compound [Na].OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O IBBQVGDGTMTZRA-UHFFFAOYSA-N 0.000 description 1
- RTVVXRKGQRRXFJ-UHFFFAOYSA-N sodium;2-sulfobutanedioic acid Chemical compound [Na].OC(=O)CC(C(O)=O)S(O)(=O)=O RTVVXRKGQRRXFJ-UHFFFAOYSA-N 0.000 description 1
- VOCIMMJSIGHGGL-UHFFFAOYSA-N sodium;3-sulfonaphthalene-1,2-dicarboxylic acid Chemical compound [Na].C1=CC=CC2=C(C(O)=O)C(C(=O)O)=C(S(O)(=O)=O)C=C21 VOCIMMJSIGHGGL-UHFFFAOYSA-N 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Woven Fabrics (AREA)
- Decoration Of Textiles (AREA)
Description
【考案の詳細な説明】
本考案は抜蝕布に関するものであり、更に詳し
くは特定の変性ポリエステル繊維を通常ポリエス
テル繊維と混用してなる布帛をアルカリによつて
抜蝕してなる抜蝕布に関する。[Detailed description of the invention] The present invention relates to an etched cloth, and more specifically to an etched cloth made by etching a fabric made by mixing specific modified polyester fibers with ordinary polyester fibers using an alkali. .
従来、ポリエステル繊維を含む抜蝕布の製造法
としてはポリエステル繊維とセルロース繊維との
交編織品に硫酸アルミ、硫酸等の抜蝕剤含有糊液
を印捺して熱処理することによりセルロース繊維
を焼抜する方法、もしくは上記交編織品にフエノ
ール類のアルカリ塩を含有する糊液を印捺し高温
熱処理することによりポリエステル繊維を溶出す
る方法等が知られている。しかしながら、セルロ
ース繊維使いでは鮮明色や堅牢度が得られないこ
と、薄地の商品の表現が難しいこと、高級品イメ
ージが得られないこと等の欠点を有している。 Conventionally, the method for manufacturing a corrosive cloth containing polyester fibers is to print a size solution containing a corrosive agent such as aluminum sulfate or sulfuric acid on a cross-knit woven product of polyester fibers and cellulose fibers, and then heat-treat the resulting product to sinter the cellulose fibers. A method is known in which the polyester fibers are eluted by printing a size solution containing an alkali salt of phenols on the above-mentioned interwoven fabric and subjecting it to high temperature heat treatment. However, the use of cellulose fibers has drawbacks such as not being able to provide vivid colors or fastness, making it difficult to represent products with thin fabrics, and not giving the impression of being a luxury product.
本考案者は上記欠点のない抜蝕布を得るべく鋭
意検討の結果、本考案に到達した。すなわち、本
考案は経糸および／または緯糸の一部または全部
が全酸成分に対し0.1〜10モル％のスルホン酸金
属塩基含有エステル形成性化合物を共重合してな
る変性ポリエステル繊維とスルホン酸金属塩基を
含有しないポリエステル繊維との引揃え混繊糸か
らなる布帛であつて、アルカリによつて変性ポリ
エステル繊維が部分的に溶解または減量加工さ
れ、かつ変性ポリエステル繊維同士および／また
は変性ポリエステル繊維とスルホン酸金属塩基を
含有しないポリエステル繊維とが少くとも部分的
に接着されてなる抜蝕布である。 The inventor of the present invention arrived at the present invention as a result of intensive studies to obtain an erosion cloth that does not have the above-mentioned drawbacks. That is, the present invention is a modified polyester fiber in which a part or all of the warp and/or weft is copolymerized with an ester-forming compound containing a sulfonic acid metal base in an amount of 0.1 to 10 mol% based on the total acid component, and a sulfonic acid metal base. A fabric consisting of drawn mixed yarns with polyester fibers that do not contain sulfonic acid, in which the modified polyester fibers are partially dissolved or reduced in size with alkali, and the modified polyester fibers are mixed with each other and/or the modified polyester fibers with sulfonic acid. This is an abrasive fabric formed by at least partially adhering polyester fibers that do not contain metal bases.
本考案による抜蝕布は、ポリエステル繊維のみ
からの抜蝕が可能であり鮮明性かつ堅牢性に優れ
た抜蝕布を提供することができる。また、フイラ
メントとスパンの自由な組合せにより混繊糸、交
撚糸、被覆糸使いの布帛や交織編等を問わず目的
に応じて使い分けができ、染色技術との組合せで
意匠性の優れた雅趣に富んだ薄地から厚地までの
広範な抜蝕布が提供できる。更に変性ポリエステ
ル繊維は熱変形を受け易いことから熱処理により
変性ポリエステル繊維同士および／または変性ポ
リエステル繊維と通常ポリエステル繊維を少くと
も部分的に接着することができスリツプ防止を容
易に達成することができる特徴も有している。 The corrosion removal cloth according to the present invention is capable of removing corrosion only from polyester fibers, and can provide a corrosion removal cloth with excellent clarity and robustness. In addition, by freely combining filaments and spans, it can be used depending on the purpose, regardless of the purpose, such as mixed yarns, twisted yarns, covered yarn fabrics, mixed weaving, etc., and when combined with dyeing technology, it can create elegant designs with excellent design. We can provide a wide range of anti-corrosion fabrics, from thin fabrics to thick fabrics. Furthermore, since modified polyester fibers are susceptible to thermal deformation, heat treatment can bond modified polyester fibers to each other and/or modified polyester fibers and normal polyester fibers at least partially, making it easy to prevent slipping. It also has
本考案の抜蝕布を構成する変性ポリエステル繊
維としてはポリエステルの製造に際し、金属塩ス
ルホネート基を含有するエステル形成性化合物、
たとえばナトリウムスルホイソフタル酸、カリウ
ムイソフタル酸、ナトリウムスルホイソフタル酸
ジメチル、ナトリウムスルホナフタレンジカルボ
ン酸、ナトリウムスルホコハク酸やスルホン酸金
属塩基含有グリコール等を全酸成分に対し0.1〜
10モル％、好ましくは0.5〜５モル共重合したポ
リエステルを繊維化した繊維が例示される。スル
ホン酸金属塩基含有エステル形成性化合物に加え
てイソフタル酸、脂肪族ジカルボン酸のような共
重合成分を全酸成分に対し15モル％以下、特に５
〜12モル％共重合したアルキレンテレフタレート
系ポリエステル繊維が特に好ましい。 The modified polyester fibers constituting the abrasive fabric of the present invention include ester-forming compounds containing metal salt sulfonate groups,
For example, sodium sulfoisophthalic acid, potassium isophthalic acid, sodium dimethyl sulfoisophthalate, sodium sulfonaphthalene dicarboxylic acid, sodium sulfosuccinic acid, sulfonic acid metal base-containing glycol, etc. are added in amounts of 0.1 to 0.1 to
An example is a fiber made of polyester copolymerized with 10 mol%, preferably 0.5 to 5 mol%. In addition to the sulfonic acid metal base-containing ester-forming compound, the amount of copolymerizable components such as isophthalic acid and aliphatic dicarboxylic acid is 15 mol% or less based on the total acid component, especially 5%.
Particularly preferred are alkylene terephthalate polyester fibers copolymerized with ~12 mol%.
また、本考案の抜蝕布を構成するスルホン酸金
属塩基を含有しないポリエステル繊維（通常ポリ
エステル繊維という）としては、ポリエチレンテ
レフタレート、ポリブチレンテレフタレート、ポ
リエチレン（テレフタレート、イソフタレー
ト）、ポリ（エチレン、ブチレン）テレフタレー
ト、ポリシクロヘキサンジメチレンテレフタレー
ト等の通常の単独重合または共重合ポリエステル
からなる繊維が挙げられ、上記変性ポリエステル
より耐アルカリ性の大きい繊維である。 In addition, polyester fibers (usually referred to as polyester fibers) that do not contain sulfonic acid metal bases and which constitute the excavation fabric of the present invention include polyethylene terephthalate, polybutylene terephthalate, polyethylene (terephthalate, isophthalate), poly(ethylene, butylene), etc. Examples include fibers made of ordinary homopolymerized or copolymerized polyesters such as terephthalate and polycyclohexane dimethylene terephthalate, which have higher alkali resistance than the above-mentioned modified polyesters.
本考案の抜蝕布を図面によつて説明すると、第
１図は本考案による抜蝕布の一例を示した説明図
であり、１は経糸、２は緯糸であり、経糸、緯糸
共に変性ポリエステル繊維と通常ポリエステル繊
維との混用糸で構成されてなる平織布である。３
は変性ポリエステル繊維がアルカリによつて抜蝕
され、通常ポリエステル繊維のみからなる抜蝕部
扮分である。変性ポリエステル繊維と通常ポリエ
ステル繊維の混用形態としては、特に限定はなく
両繊維からなる混繊糸、交撚糸、被覆糸（コアヤ
ーン、カバードヤーン等）等を使用した布帛、変
性ポリエステル繊維糸と通常ポリエステル繊維糸
の交織編布帛等が例示される。また混繊糸は無
撚、有撚いずれであつてもよい。また、上記ポリ
エステル繊維以外の繊維を少量混用して異色性、
異なつた物性を付与することもできる。また、低
融点繊維の少量を混用しスリツプや抜けを防止す
ることもできる。また繊維は捲縮加工されていて
もよく、予め着色されていてもよく、更にフイラ
メント、ステープルいずれであつてもよい。変性
ポリエステル繊維のデニールは通常ポリエステル
繊維のデニールより通常同等以下であることが好
ましいが、変性ポリエステル繊維が異形、中空、
扁平等の表面積の大きい断面形態では変性ポリエ
ステル繊維の方が太デニールであつても好結果が
得られる。 To explain the corroding cloth of the present invention with reference to drawings, Fig. 1 is an explanatory drawing showing an example of the corroding cloth according to the present invention, in which 1 is a warp, and 2 is a weft, and both the warp and the weft are made of modified polyester. It is a plain woven fabric made of a blend of fibers and regular polyester fibers. 3
The modified polyester fibers are etched with alkali, and the etched portion is usually made only of polyester fibers. There are no particular limitations on the mixed form of modified polyester fibers and regular polyester fibers, and fabrics using mixed yarns made of both fibers, intertwisted yarns, covered yarns (core yarns, covered yarns, etc.), modified polyester fiber yarns and regular polyester fibers, etc. Examples include interweaving and knitting fabrics of fiber yarns. Further, the mixed yarn may be untwisted or twisted. In addition, by mixing a small amount of fibers other than the polyester fibers mentioned above, different colors can be created.
It is also possible to impart different physical properties. It is also possible to mix in a small amount of low melting point fibers to prevent slips and shedding. Further, the fibers may be crimped or pre-colored, and may be either filaments or staples. It is preferable that the denier of the modified polyester fiber is usually equal to or less than the denier of the regular polyester fiber, but if the modified polyester fiber is irregularly shaped, hollow,
In a cross-sectional form with a large flat surface area, better results can be obtained with modified polyester fibers even if the fibers have a large denier.
布帛の織編組織も特に限定されるものではな
く、たとえば平織からドビー、ジヤガードを用い
て表面に模様を設けた織物まで広く挙げられる。 The weaving and knitting structure of the fabric is not particularly limited, and includes a wide range of fabrics, from plain weave to dobby and jiyaguard fabrics with patterns on the surface.
本考案の抜蝕布は変性ポリエステル繊維と通常
ポリエステル繊維の混用布帛にナトリウム、カリ
ウムの如きアルカリ金属類の水酸化物、好ましく
は水酸化ナトリウムと所望によりポリエステル溶
解促進剤、助剤等を含む糊液を印捺または任意の
手段により付与した後、乾燥または乾燥すること
なく、通常90℃以上に乾熱または蒸熱して変性ポ
リエステル繊維を部分的に溶解除去または減量す
ることにより得られる。もちろん長時間処理の場
合コールドバツチ方式で抜蝕することも可能であ
る。また、抜蝕前および／または抜蝕後に抗ピル
加工、起毛処理、染色または捺染（防抜染を含
む）等を施し、意匠性に富んだ抜蝕布を得ること
もできる。変性ポリエステル繊維と通常ポリエス
テル繊維は同色に着色してもよく、また変性ポリ
エステル繊維をカチオン染料、通常ポリエステル
繊維を分散染料で異色に染色することもできる。
また抜蝕と同時または抜蝕前もしくは後に布帛全
体の変性ポリエステル繊維を減量加工することも
できる。抜蝕後は通常洗浄後、熱処理たとえば
170℃以上、特に好ましくは190゜〜240℃で短時
間熱処理することにより変性ポリエステル繊維同
士および／または変性ポリエステル繊維と通常ポ
リエステル繊維とを少くとも部分的に接着させる
ことによりスリツプ防止または繊維の抜けを防止
することが必要であるが、抜蝕前熱処理により接
着させてもよい。また、スリツプ防止は樹脂加工
の併用によつて行つてもよい。 The erosion cloth of the present invention is a fabric made of a mixture of modified polyester fibers and regular polyester fibers, and a glue containing hydroxides of alkali metals such as sodium and potassium, preferably sodium hydroxide, and optionally a polyester solubility promoter, auxiliary agent, etc. After applying the liquid by printing or any other means, the modified polyester fibers are obtained by dry heating or steaming, usually at 90° C. or higher, without drying or drying, to partially dissolve and remove the modified polyester fibers or reduce the amount of the modified polyester fibers. Of course, in the case of long-term processing, it is also possible to remove the corrosion using the cold batch method. In addition, anti-pilling treatment, napping treatment, dyeing, printing (including anti-discharge printing), etc. can be applied to the fabric before and/or after the extraction to obtain an etched cloth rich in design. The modified polyester fiber and the normal polyester fiber may be colored the same color, or the modified polyester fiber may be dyed with a cationic dye, and the normal polyester fiber may be dyed with a disperse dye in a different color.
It is also possible to reduce the amount of modified polyester fibers in the entire fabric at the same time as, before or after the removal. After removal, it is usually cleaned and then heat treated, e.g.
Slip prevention or fiber shedding can be prevented by at least partially adhering modified polyester fibers to each other and/or modified polyester fibers and normal polyester fibers by heat treatment for a short time at 170°C or higher, preferably 190° to 240°C. Although it is necessary to prevent this, adhesion may be achieved by heat treatment before removal. Further, slip prevention may be achieved by combined use of resin processing.
以下、実施例により本考案を説明する。 The present invention will be explained below with reference to Examples.
実施例 １
ポリエチレンテレフタレート繊維糸（75d／
86f）と全酸成分に対し５−ナトリウムスルホイ
ソフタレート2.3モル％、イソフレタレート6.5モ
ル％を含むエチレンテレフタレート系変性ポリエ
ステル繊維糸（50d／36f）を引揃えて高圧エアー
ノズル（インターレーサー）に通し乱流空気によ
り混繊して得られた混繊糸にsz2000t／ｍの撚を
施し、ジヨーゼツトにして同色染めした後26％水
酸化ナトリウムと３％第４級アンモニウム系減量
促進剤を含む糊液を印捺し、102℃、30分間スチ
ーミングし水洗、乾燥後、180℃で30秒間熱処理
した。Example 1 Polyethylene terephthalate fiber yarn (75d/
86f) and ethylene terephthalate-based modified polyester fiber yarn (50d/36f) containing 2.3 mol% of 5-sodium sulfoisophthalate and 6.5 mol% of isofretalate based on the total acid component and formed into a high-pressure air nozzle (interlacer). The mixed fiber yarn obtained by mixing it with turbulent air is twisted at sz2000t/m, made into a dioset, dyed in the same color, and then made into a paste containing 26% sodium hydroxide and 3% quaternary ammonium-based weight loss accelerator. The liquid was printed, steamed at 102°C for 30 minutes, washed with water, dried, and then heat treated at 180°C for 30 seconds.
その結果、鮮明かつ堅牢度およびドレープ性の
優れた抜蝕布を得た。 As a result, an etched cloth was obtained which was clear and had excellent fastness and drapability.
実施例 ２
ポリエチレンテレフタレート繊維糸（100d／
36f）と実施例１で用いた変性ポリエステル繊維
糸（50d／36f）からなる紬調加工糸を経糸および
緯糸として織成してなる平織地を異色染め後、実
施例１と同様に抜蝕加工して変性ポリエステル繊
維を部分的に除去し、フアンシー調で鮮明かつ堅
牢なオパールボイルを得た。Example 2 Polyethylene terephthalate fiber yarn (100d/
36f) and the pongee-like textured yarn made of the modified polyester fiber yarn (50d/36f) used in Example 1, was woven as warp and weft, and a plain woven fabric was dyed in a different color, and then subjected to an extraction process in the same manner as in Example 1. The modified polyester fibers were partially removed to obtain a fancy, clear, and robust opal voile.
実施例 ３
経糸としてポリエチレンテレフタレート繊維糸
（75d／36f）緯糸として実施例１で用いた変性ポ
リエステル繊維糸（50d／36f）の2500t／ｍの強
撚糸をｓ、z2本交互に打込んだ平織地のパレス
を異色染めした後、実施例１と同様にして抜蝕加
工し、シヤンブレーオパールパレスを得、更に抜
染プリントを施した。Example 3 A plain woven fabric in which two 2500 t/m strong twisted yarns of polyethylene terephthalate fiber yarn (75d/36f) used as warp yarns and modified polyester fiber yarn (50d/36f) used in Example 1 as weft yarns of s and z were inserted alternately. After dyeing the palace in a different color, it was subjected to a discharge process in the same manner as in Example 1 to obtain a chambray opal palace, which was further subjected to discharge printing.
その結果、鮮明かつ堅牢性に優れた意匠性に富
む抜蝕布を得た。 As a result, an etched cloth was obtained that was clear, robust, and rich in design.
また、変性ポリエステル繊維を完全溶解するこ
となく部分的に約50％減量する程度に抜蝕加工し
たときフアンシーなシヤンプレーオパールパレス
を得た。 In addition, when the modified polyester fiber was subjected to an erosion process to partially reduce the weight by about 50% without completely dissolving it, a fancy symmetrical opal palace was obtained.
実施例 ４
ポリエチレンテレフタレート繊維糸（75d／
36f）と実施例１で用いた変性ポリエステル繊維
糸（50d／36f）の交撚強撚糸をベースに使用し、
実施例２で用いた紬調加工糸を縞柄に交織した平
織地を異色染め後、実施例１と同様にして抜蝕加
工した。その結果、鮮明かつ堅牢でフアンシーな
表面変化に富んだ抜蝕布を得た。Example 4 Polyethylene terephthalate fiber yarn (75d/
36f) and the modified polyester fiber yarn (50d/36f) used in Example 1.
A plain woven fabric in which the pongee-like textured yarn used in Example 2 was mixed and woven in a striped pattern was dyed in a different color, and then subjected to an etching process in the same manner as in Example 1. As a result, we obtained an etched cloth that was clear, robust, and rich in fancy surface changes.
第１図は本考案による抜蝕布の一例を示す説明
図であり、１は経糸、２は緯糸であり、経糸、緯
糸共に変性ポリエステル繊維と通常ポリエステル
繊維との混用糸で織成されてなる平織布である。
３は変性ポリエステル繊維がアルカリによつて抜
蝕されてなる抜蝕部分である。
FIG. 1 is an explanatory diagram showing an example of the cloth to be removed according to the present invention, where 1 is a warp and 2 is a weft, both warp and weft are woven from a mixture of modified polyester fibers and normal polyester fibers. It is a plain woven fabric.
3 is an etched portion formed by etching the modified polyester fiber with an alkali.
Claims (1)
酸成分に対し0.1〜10モル％のスルホン酸金属塩
基含有エステル形成性化合物を共重合してなる変
性ポリエステル繊維とスルホン酸金属塩基を含有
しないポリエステル繊維との引揃え混繊糸からな
る布帛であつて、アルカリによつて変性ポリエス
テル繊維が部分的に溶解または減量加工されてい
ることを特徴とする抜蝕布。 A modified polyester fiber in which part or all of the warp and/or weft is copolymerized with an ester-forming compound containing a sulfonic acid metal base in an amount of 0.1 to 10 mol% based on the total acid component, and a polyester fiber that does not contain a sulfonic acid metal base. What is claimed is: 1. An etched cloth comprising a mixed yarn drawn and mixed with a polyester fiber, wherein modified polyester fibers have been partially dissolved or reduced in weight with an alkali.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1980098348U JPS6111279Y2 (en) | 1980-07-11 | 1980-07-11 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1980098348U JPS6111279Y2 (en) | 1980-07-11 | 1980-07-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5721695U JPS5721695U (en) | 1982-02-04 |
| JPS6111279Y2 true JPS6111279Y2 (en) | 1986-04-09 |
Family
ID=29460072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1980098348U Expired JPS6111279Y2 (en) | 1980-07-11 | 1980-07-11 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6111279Y2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013079464A (en) * | 2011-10-04 | 2013-05-02 | Teijin Frontier Co Ltd | Fabric and clothing material |
| JP2018003193A (en) * | 2016-07-01 | 2018-01-11 | 住江織物株式会社 | Yarn for opal finish fabric and manufacturing method thereof, and fabric for opal finish and manufacturing method of opal finish fabric |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2694712B2 (en) * | 1991-07-04 | 1997-12-24 | 鐘紡株式会社 | Opalized coloring method for polyester fiber and opalized colored fabric |
| JP3067014B2 (en) * | 1995-06-30 | 2000-07-17 | 三菱レイヨン株式会社 | Polyester fiber fabric and method for producing the same |
| JP2011149139A (en) * | 2009-12-25 | 2011-08-04 | Origina Cloth Jacquard Co Ltd | Flame retardant opal processing thread and fabric, clothing and interior ornament using the same |
| JP7383427B2 (en) * | 2019-09-04 | 2023-11-20 | ユニチカトレーディング株式会社 | Partially etched fabric |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4938956A (en) * | 1972-08-17 | 1974-04-11 |
-
1980
- 1980-07-11 JP JP1980098348U patent/JPS6111279Y2/ja not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4938956A (en) * | 1972-08-17 | 1974-04-11 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013079464A (en) * | 2011-10-04 | 2013-05-02 | Teijin Frontier Co Ltd | Fabric and clothing material |
| JP2018003193A (en) * | 2016-07-01 | 2018-01-11 | 住江織物株式会社 | Yarn for opal finish fabric and manufacturing method thereof, and fabric for opal finish and manufacturing method of opal finish fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5721695U (en) | 1982-02-04 |
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