JPS61101083A - Solar battery module - Google Patents

Solar battery module

Info

Publication number
JPS61101083A
JPS61101083A JP59223513A JP22351384A JPS61101083A JP S61101083 A JPS61101083 A JP S61101083A JP 59223513 A JP59223513 A JP 59223513A JP 22351384 A JP22351384 A JP 22351384A JP S61101083 A JPS61101083 A JP S61101083A
Authority
JP
Japan
Prior art keywords
solar cell
film
active hydrogen
solar battery
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP59223513A
Other languages
Japanese (ja)
Other versions
JPH0476229B2 (en
Inventor
Akihiko Nakano
明彦 中野
Hitoshi Matsumoto
仁 松本
Hiroshi Uda
宇田 宏
Yasumasa Komatsu
小松 康允
Kiyoshi Kuribayashi
清 栗林
Seiji Ikegami
池上 清治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP59223513A priority Critical patent/JPS61101083A/en
Publication of JPS61101083A publication Critical patent/JPS61101083A/en
Publication of JPH0476229B2 publication Critical patent/JPH0476229B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/543Solar cells from Group II-VI materials

Abstract

PURPOSE:To realize a solar battery module with its characteristics not deteriorat ed under a high-temperature, high-moisture test by a method wherein the solar battery module is constituted of a thin-film solar battery element formed on a substrate and a protecting film of a dielectric resin containing perfluoroalky lene groups and active hydrogen. CONSTITUTION:A CdS film 2 is formed on the entire surface of a glass substrate 1 and, on top of the CdS film 2, a CdTe film 3, C film 4, Ag electrode 5 are formed, with a space reserved for an Ag-In electrode 6. Covering the entirety, a compound resin film 7 is formed containing perfluoroalkylene groups and active hydrogen. A solar battery module produced to this design is excellent in withstanding high temeratures and moisture and, when exposed to such adverse environmental conditions, suffer from so small a reduction in its photovoltaic capability as 3% which may be said to fall within the error allowance of measurement.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は太陽電池モジュール、特に耐熱性、耐湿性や耐
候性にすぐれた外観のよい太陽電池モジュールに関する
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a solar cell module, and particularly to a solar cell module with excellent heat resistance, moisture resistance and weather resistance, and a good appearance.

従来例の構成とその問題点 最近エネルギー供給の一手段として太陽電池が注目され
ている。その理由は無限ともいえるクリーンな太陽エネ
ルギーから直接電気エネルギーが容易に取り出せるから
である。しかしながら現在では上記電気エネルギー製造
原価が高いため充分に普及する段階にまで至っていない
。しかし上記利点を応用した太陽電池モジュールが出始
め、次第に普及する兆が見えている。
Conventional configurations and their problems Recently, solar cells have been attracting attention as a means of energy supply. The reason for this is that electrical energy can be easily extracted directly from the almost infinite amount of clean solar energy. However, due to the high cost of producing the electrical energy, it has not yet reached a stage where it is fully widespread. However, solar cell modules that take advantage of the above advantages have begun to appear, and there are signs that they will gradually become popular.

太陽電池の実用化を計るに当っては、それによって作ら
れる電力の原価を下げるようにすることは勿論であるが
、作られた太陽電池モジュールの可使寿命をできる限り
長くできるようにしなければならない。即ち製品の長期
にわたる信頼性が高くなければならず、このため従来か
ら太陽電池モジュールの信頼性、長期寿命の向上に関し
て努力が払われているが、未だ充分とはいえない点があ
った。
In planning the practical use of solar cells, it is of course important to reduce the cost of the electricity produced by them, but it is also important to ensure that the usable life of the solar cell modules produced is as long as possible. It won't happen. That is, the product must have high long-term reliability, and for this reason, efforts have been made to improve the reliability and long-term life of solar cell modules, but there are still some points that cannot be said to be sufficient.

太陽電池モジュールの信頼性を上げるためには、各種の
方法があるが、その一つに太陽電池素子に耐熱性、耐湿
性、耐候性のすぐれた塗料を塗布して外部からの影響を
遮断する方法がある。すでに本発明からはCd S /
Cd T e系太陽電池素子にエポキシ樹脂を塗布する
ことにより、該太陽電池素子の耐熱、耐湿性を向上させ
うろことを見い出し、特許出願を行った。しかしエポキ
シ樹脂は耐候性において、素子性能は低下させにくいが
、それ自身が少し黄変し、外観不良の原因となったり、
よりきびしい高温耐湿試験では劣化を捷ぬがれない欠点
をもっていた。
There are various methods to increase the reliability of solar cell modules, one of which is to coat the solar cell elements with a paint that has excellent heat resistance, moisture resistance, and weather resistance to block external influences. There is a way. Already from the present invention, Cd S /
We have discovered that coating a Cd Te solar cell element with an epoxy resin can improve the heat resistance and moisture resistance of the solar cell element, and have filed a patent application. However, although epoxy resin does not easily deteriorate element performance due to its weather resistance, it may yellow itself slightly and cause poor appearance.
It had the disadvantage of being unable to avoid deterioration in more severe high temperature and humidity resistance tests.

発明の目的 本発明は上記のような欠点、つ丑り樹脂自体の着色、た
とえば黄変がなく、よりきびしい高温耐湿試験でも劣化
しない太陽電池モジュールを提供しようとするものであ
る。
OBJECTS OF THE INVENTION The present invention aims to provide a solar cell module that does not have the above-mentioned drawbacks, such as coloring of the resin itself, such as yellowing, and does not deteriorate even in a more severe high temperature and humidity test.

ヴ1、明の構成 本発明の太陽電池モジュールは、ガラス、ステンレス等
の基板と、基板上に形成されたCdS/CdTe もL
< はアモルファス−シリコン(以下a−8i と略す
)等の薄膜型太陽電池素子とパーフロロアルキレン基と
活性水素を含む樹脂の誘導体を成分とする保護膜とより
成っている。パー70ロアルキレン基と活性水素を含む
樹脂は、たとえば、旭ガラス株式会社からルミフロンの
商標で市販されている。このルミフロンは分子中にパー
70ロアルギレン基とペンダントな活性水素、より詳し
くはOH基を持っており、通常は数平均分子量2万から
8万の含ふっ素ポリマーで、メラミンやイソシアネート
基を持つ化合物と反応して、架橋ポリマー、ここで拭誘
導体と称するもの、を生じる。本発明の太陽電池モジュ
ールはこの誘導体で保護されたことを特徴とする。
1. Bright Structure The solar cell module of the present invention has a substrate made of glass, stainless steel, etc., and CdS/CdTe formed on the substrate.
< is composed of a thin film type solar cell element such as amorphous silicon (hereinafter abbreviated as a-8i) and a protective film containing a resin derivative containing a perfluoroalkylene group and active hydrogen. Resins containing a per70 alkylene group and active hydrogen are commercially available from Asahi Glass Co., Ltd. under the trademark Lumiflon, for example. Lumiflon has a per70-roargylene group and a pendant active hydrogen, more specifically an OH group, in its molecule, and is a fluorine-containing polymer with a number average molecular weight of 20,000 to 80,000, and is similar to compounds with melamine and isocyanate groups. The reaction produces a crosslinked polymer, referred to herein as a wipe derivative. The solar cell module of the present invention is characterized by being protected by this derivative.

実施例の説明 本発明を実施例を用いて説明する。Description of examples The present invention will be explained using examples.

(実施例1) 図は本発明の詳細な説明するための太陽電池モジュール
の要部断面図である。図において1はガラス基板で、そ
の上全面にCdS 膜2が形成さね1、その土にAg−
In電極6用のスペースをあけてCdTe膜3.C膜4
.Ag電極5が形成されている。上記CdTe膜3.C
膜4.Aq電極6が未形成のCdS  膜2上にはAg
−In  電極6が形成されている。そして、それら全
体を被覆して樹脂7が形成されている。樹脂7はパーフ
ロロアルキレン基と活性水素を含む化合物である。旭ガ
ラス株式会社製の“ルミフロン■“LF302Ct7)
 1007i量部と日本ポリウレタン工業株式会社製の
へキザ6 ゝ メチレンジインシアネートの三量体である“コロ間加熱
硬化させて形成させた。
(Example 1) The figure is a sectional view of a main part of a solar cell module for explaining the present invention in detail. In the figure, 1 is a glass substrate, on which a CdS film 2 is formed on the entire surface, and Ag-
Leave a space for the In electrode 6 and deposit the CdTe film 3. C film 4
.. An Ag electrode 5 is formed. The above CdTe film 3. C
Membrane 4. Ag on the CdS film 2 on which the Aq electrode 6 is not formed.
-In electrode 6 is formed. A resin 7 is formed to cover all of them. Resin 7 is a compound containing a perfluoroalkylene group and active hydrogen. “Lumiflon ■” LF302Ct7) manufactured by Asahi Glass Co., Ltd.
1007i and Hekiza 6, a trimer of methylene diinocyanate manufactured by Nippon Polyurethane Industries Co., Ltd., was formed by heating and curing between rollers.

以上のように形成された太陽電池モジュールを80℃、
相対湿度95%の条件下に1000時間おいて後太陽電
池の特性ならびに外観を調べた。
The solar cell module formed as described above was heated to 80°C.
The solar cells were left under conditions of 95% relative humidity for 1000 hours, and then the characteristics and appearance of the solar cells were examined.

結果を参考データと共に第1表に示す。第1表において
太陽電池モジュール番号1は、本実施例のもので、番号
2〜8は比較のための参考データである。
The results are shown in Table 1 along with reference data. In Table 1, solar cell module number 1 is that of this example, and numbers 2 to 8 are reference data for comparison.

第1表から明らかなように本発明の太陽電池モジュール
は高温耐熱性がよく、光電特性の低下は3係で、測定誤
差内とも言える程の劣化しか示さなかった。
As is clear from Table 1, the solar cell module of the present invention had good high-temperature heat resistance, and the photoelectric properties showed only a factor of 3 deterioration, which could be said to be within the measurement error.

(実施例2) 実施例1と同様に太陽電池モジュールを形成した。ただ
し、樹脂7の形成条件を温度80℃で60分間、温度1
00℃で20分間から80分間、温度120℃で20分
間と変化させた。しかし、得らhた太陽電池モジュール
は、いずれも表示していないが実施例1(モジュール番
号1)とほぼ同様の信頼性を示した。
(Example 2) A solar cell module was formed in the same manner as in Example 1. However, the conditions for forming resin 7 are: temperature 80°C for 60 minutes, temperature 1
The temperature was changed from 20 minutes to 80 minutes at 00°C and 20 minutes at 120°C. However, the obtained solar cell module showed almost the same reliability as Example 1 (module number 1), although none are shown.

(実施例3) ゛ ルミフロン302Cの100重量部と松下電工株式
会社製のレゾール型フェノール樹脂CT1000010
0重量部の混合物を使用するほかは、実施例1と同様に
太陽電池モジュールを形成した。ライフテストの結果を
番号9として第1表に併記しである。
(Example 3) 100 parts by weight of Lumiflon 302C and resol type phenolic resin CT1000010 manufactured by Matsushita Electric Works Co., Ltd.
A solar cell module was formed in the same manner as in Example 1, except that 0 parts by weight of the mixture was used. The results of the life test are listed as number 9 in Table 1.

第1表から明らかなように、本発明の太陽電池モジュー
ルは高温耐熱性がよいことがわかる0コロネートEHの
場合よりや\劣るデータであるが、今迄優秀と言われて
来たエポキシ樹脂等のデータと比較して、本実施例は非
常にすぐわている。
As is clear from Table 1, the data for the solar cell module of the present invention is slightly inferior to that of 0 Coronate EH, which shows good high-temperature heat resistance, but the data is slightly inferior to that of 0 Coronate EH, which shows that the solar cell module of the present invention has good high-temperature heat resistance. Compared to the data of , this example is very superior.

第1表 *1 日本油脂株式会社製のウレタン樹脂*2 ダウ・
コーニング株式会社製のシリコン樹脂*3 信越化学工
業株式会社製のシリコン樹脂*4 泉化成工業株式会社
製のエポキシ樹脂*5 日本ベルノックス株式会社製の
エポキシ樹脂 *6 日東電気工業株式会社製のエポキシ樹脂ノも *7 松下電工株式会社製のレゾール型フェノ−樹脂 発明の効果 すでに実施例の中で述べたように、被覆樹脂として、パ
ー70ロアルキレン基と活性水素を含む樹脂誘導体が使
われている太陽電池モジュールは眩極めて高い信頼性を
持っているすぐれたものである。従来優秀と言われて来
たエポキシ樹脂等に比べても、パーフロロアルキレン基
と活性水素を含む樹脂の誘導体は、格段の耐湿性を示す
−にに光沢があるため、その点でもモジュールの酉品価
値が高い。
Table 1 *1 Urethane resin manufactured by Nippon Oil & Fats Co., Ltd. *2 Dow・
Silicone resin manufactured by Corning Corporation *3 Silicone resin manufactured by Shin-Etsu Chemical Co., Ltd. *4 Epoxy resin manufactured by Izumi Kasei Co., Ltd. *5 Epoxy resin manufactured by Nippon Bellnox Co., Ltd. *6 Epoxy manufactured by Nitto Electric Industry Co., Ltd. Resin also *7 Effects of the resol type pheno resin invention manufactured by Matsushita Electric Works Co., Ltd. As already mentioned in the examples, a resin derivative containing a per-70 alkylene group and active hydrogen is used as the coating resin. The solar cell modules currently available are of excellent quality with extremely high reliability. Compared to epoxy resins, which have traditionally been said to be excellent, resin derivatives containing perfluoroalkylene groups and active hydrogen exhibit outstanding moisture resistance and are glossy, which is why they are the best choice for modules. High product value.

さらにまた、太陽電池モジュールは、素子を作物するた
めにテトラ−・Alはく・テトラ−の三層膜でカバーさ
れることが多いが、パーフロロアルキレン基と活性水素
を含む樹脂誘導体はこのテトラ−三層膜等の含ふっ素ポ
リマーフィルムを伺10 ゝ 着させ易いという特徴をもっている。
Furthermore, solar cell modules are often covered with a three-layer film of tetra-, aluminum foil, and tetra-layer to produce devices, but resin derivatives containing perfluoroalkylene groups and active hydrogen are - It has the characteristic that it is easy to attach fluorine-containing polymer films such as three-layer films.

勿論、この含ふっ素ポリマーフィルムはパーフロロアル
キレン基と活性水素を含む樹脂誘導体を硬化させる前に
接触させておき、その状態のま\硬化させねばならない
。上記テトラ−はふっ素樹脂フィルムなので、この樹脂
誘導体との親和性がよく、よく接着するという効果があ
る。
Of course, this fluorine-containing polymer film must be brought into contact with the resin derivative containing perfluoroalkylene groups and active hydrogen before curing, and must be cured in that state. Since the above-mentioned tetra is a fluororesin film, it has good affinity with this resin derivative and has the effect of good adhesion.

パー70ロアルキレン基と活性水素を含む樹脂は目下の
ところ旭ガラス株式会社よりルミフロンの商標で発表さ
れているが、分子量が異なるなどの様々なグレードのも
のがある。LF302Cの外KLF1ooC,LF20
0C、LF300C。
Resins containing per-70 alkylene groups and active hydrogen are currently being released by Asahi Glass Co., Ltd. under the trademark Lumiflon, but there are various grades of resins with different molecular weights. Outside of LF302C KLF1ooC, LF20
0C, LF300C.

果を得た。I got results.

1だ、薄膜型太陽電池素子としては、a−8t太陽電池
素子があるが、CdS/CdTd  太陽電池素子の時
と同様に、パー70ロアルキレン基ト活性水素を含む樹
脂の誘導体でカバーすると、他の樹脂でカバーされたも
のより高温耐湿性がすぐれていることがわかった。
1. As a thin film type solar cell element, there is an A-8T solar cell element, but as with the CdS/CdTd solar cell element, if it is covered with a resin derivative containing per70 alkylene group active hydrogen, It was found that the high temperature and humidity resistance was superior to those covered with other resins.

【図面の簡単な説明】[Brief explanation of the drawing]

図は本発明の詳細な説明するだめの太陽電池モジュール
の要部断面図である。 1・・・・・・ガラス基板、2・・・・・・CdS 膜
、3・・・・・・CdTe膜、4・・・・・・C膜、5
・・・・・・Aq主電極6・・・・・・Ag−In電極
、7・・・・・・樹脂。
The figure is a sectional view of a main part of a solar cell module for which the present invention will not be explained in detail. DESCRIPTION OF SYMBOLS 1... Glass substrate, 2... CdS film, 3... CdTe film, 4... C film, 5
...Aq main electrode 6...Ag-In electrode, 7...Resin.

Claims (7)

【特許請求の範囲】[Claims] (1)基板と、この基板上に形成された薄膜型太陽電池
素子と、パーフロロアルキレン基と活性水素を含む樹脂
の誘導体を成分とする保護膜とより成る太陽電池モジュ
ール。
(1) A solar cell module comprising a substrate, a thin film solar cell element formed on the substrate, and a protective film containing a resin derivative containing a perfluoroalkylene group and active hydrogen.
(2)基板がガラスであることを特徴とする特許請求の
範囲第1項記載の太陽電池モジュール。
(2) The solar cell module according to claim 1, wherein the substrate is glass.
(3)薄膜型太陽電池素子がCdS/CdTe型太陽電
池であることを特徴とする特許請求の範囲第1項記載の
太陽電池モジュール。
(3) The solar cell module according to claim 1, wherein the thin film solar cell element is a CdS/CdTe type solar cell.
(4)薄膜型太陽電池素子がアモルファス・シリコン太
陽電池素子であることを特徴とする特許請求の範囲第1
項記載の太陽電池モジュール。
(4) Claim 1, characterized in that the thin film solar cell element is an amorphous silicon solar cell element.
The solar cell module described in Section 1.
(5)保護膜が、パーフロロアルキレン基と活性水素を
含む樹脂と、イソシアネート基を含む化合物とからの反
応物を成分とすることを特徴とする特許請求の範囲第1
項記載の太陽電池モジュール。
(5) Claim 1, wherein the protective film contains a reaction product of a resin containing a perfluoroalkylene group and active hydrogen, and a compound containing an isocyanate group.
The solar cell module described in Section 1.
(6)保護膜がパーフロロアルキレン基と活性水素を含
む樹脂と、フェノール樹脂とからの反応物を成分とする
ことを特徴とする特許請求の範囲第1項記載の太陽電池
モジュール。
(6) The solar cell module according to claim 1, wherein the protective film contains a reaction product of a resin containing a perfluoroalkylene group and active hydrogen, and a phenol resin.
(7)基板と、基板上に形成された薄膜型太陽電池素子
と、パーフロロアルキレン基および活性水素を含む樹脂
の誘導体を成分とする接着剤と、Alはくを含む保護膜
とより成る太陽電池モジュール。
(7) A solar cell consisting of a substrate, a thin film solar cell element formed on the substrate, an adhesive containing a resin derivative containing a perfluoroalkylene group and active hydrogen, and a protective film containing an Al foil. battery module.
JP59223513A 1984-10-24 1984-10-24 Solar battery module Granted JPS61101083A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59223513A JPS61101083A (en) 1984-10-24 1984-10-24 Solar battery module

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59223513A JPS61101083A (en) 1984-10-24 1984-10-24 Solar battery module

Publications (2)

Publication Number Publication Date
JPS61101083A true JPS61101083A (en) 1986-05-19
JPH0476229B2 JPH0476229B2 (en) 1992-12-03

Family

ID=16799316

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59223513A Granted JPS61101083A (en) 1984-10-24 1984-10-24 Solar battery module

Country Status (1)

Country Link
JP (1) JPS61101083A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH057532U (en) * 1991-07-15 1993-02-02 トヨタ車体株式会社 Seat track
EP0641030A2 (en) * 1993-08-31 1995-03-01 Canon Kabushiki Kaisha Photoelectric conversion device and photoelectric conversion module each having a protective member comprised of fluorine-containing polymer resin
US5597422A (en) * 1994-04-30 1997-01-28 Canon Kabushiki Kaisha Light-transmissive resin sealed semiconductor and production process thereof
EP1005096A3 (en) * 1998-11-12 2000-12-27 Kaneka Corporation Solar cell module
WO2011125691A1 (en) * 2010-04-01 2011-10-13 住友化学株式会社 Resin composition for use in an organic thin-film transistor insulation layer, overcoat insulation layer, and organic thin-film transistor
WO2011158929A1 (en) * 2010-06-17 2011-12-22 住友化学株式会社 Optical energy-crosslinkable insulating layer material for organic thin film transistor, overcoat insulating layer, and organic thin film transistor
WO2012029700A1 (en) * 2010-08-30 2012-03-08 住友化学株式会社 Composition for insulating layer of organic thin-film transistor, and organic thin-film transistor
WO2012063845A1 (en) * 2010-11-10 2012-05-18 住友化学株式会社 Organic element material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5538071A (en) * 1978-09-11 1980-03-17 Matsushita Electric Ind Co Ltd Solar battery
JPS5961971A (en) * 1982-09-30 1984-04-09 Fuji Electric Co Ltd Solar battery module

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5538071A (en) * 1978-09-11 1980-03-17 Matsushita Electric Ind Co Ltd Solar battery
JPS5961971A (en) * 1982-09-30 1984-04-09 Fuji Electric Co Ltd Solar battery module

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH057532U (en) * 1991-07-15 1993-02-02 トヨタ車体株式会社 Seat track
EP0641030A2 (en) * 1993-08-31 1995-03-01 Canon Kabushiki Kaisha Photoelectric conversion device and photoelectric conversion module each having a protective member comprised of fluorine-containing polymer resin
EP0641030A3 (en) * 1993-08-31 1996-02-28 Canon Kk Photoelectric conversion device and photoelectric conversion module each having a protective member comprised of fluorine-containing polymer resin.
US5530264A (en) * 1993-08-31 1996-06-25 Canon Kabushiki Kaisha Photoelectric conversion device and photoelectric conversion module each having a protective member comprised of fluorine-containing polymer resin
US5597422A (en) * 1994-04-30 1997-01-28 Canon Kabushiki Kaisha Light-transmissive resin sealed semiconductor and production process thereof
EP1005096A3 (en) * 1998-11-12 2000-12-27 Kaneka Corporation Solar cell module
US6300556B1 (en) 1998-11-12 2001-10-09 Kaneka Corporation Solar cell module
US6384315B1 (en) 1998-11-12 2002-05-07 Kaneka Corporation Solar cell module
WO2011125691A1 (en) * 2010-04-01 2011-10-13 住友化学株式会社 Resin composition for use in an organic thin-film transistor insulation layer, overcoat insulation layer, and organic thin-film transistor
JP2011225854A (en) * 2010-04-01 2011-11-10 Sumitomo Chemical Co Ltd Resin composition for organic thin-film transistor insulating layer, overcoat insulating layer, and organic thin-film transistor
WO2011158929A1 (en) * 2010-06-17 2011-12-22 住友化学株式会社 Optical energy-crosslinkable insulating layer material for organic thin film transistor, overcoat insulating layer, and organic thin film transistor
WO2012029700A1 (en) * 2010-08-30 2012-03-08 住友化学株式会社 Composition for insulating layer of organic thin-film transistor, and organic thin-film transistor
WO2012063845A1 (en) * 2010-11-10 2012-05-18 住友化学株式会社 Organic element material

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