JPS6088431A - Heating method by photo irradiation - Google Patents

Heating method by photo irradiation

Info

Publication number
JPS6088431A
JPS6088431A JP19528883A JP19528883A JPS6088431A JP S6088431 A JPS6088431 A JP S6088431A JP 19528883 A JP19528883 A JP 19528883A JP 19528883 A JP19528883 A JP 19528883A JP S6088431 A JPS6088431 A JP S6088431A
Authority
JP
Japan
Prior art keywords
wafer
temperature
outer periphery
heating
auxiliary heater
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19528883A
Other languages
Japanese (ja)
Inventor
Tetsuji Arai
荒井 徹次
Hiroshi Shimizu
洋 清水
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ushio Denki KK
Ushio Inc
Original Assignee
Ushio Denki KK
Ushio Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ushio Denki KK, Ushio Inc filed Critical Ushio Denki KK
Priority to JP19528883A priority Critical patent/JPS6088431A/en
Publication of JPS6088431A publication Critical patent/JPS6088431A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/268Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
    • H01L21/2686Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation using incoherent radiation

Abstract

PURPOSE:To enable the even heating of wafers by a method wherein the heat amount by auxiliary heating is determined in the optimum range according to the temperature of heat treatment of wafers. CONSTITUTION:The surface of a wafer 5 is heated by photo irradiation with main heaters 3, and the neighborhood of the outer periphery of the wafer is heated in an auxiliary manner by means of a ring-form auxiliary heater 6 provided in proximity to the neighborhood of the outer periphery of the wafer. When the temperature of heat treatment of the wafer is T deg.C and the power applied per unit length of the circumference of the wafer by means of the auxiliary heater is W watt/cm, it is contrived that a relation of 0.20T-212>=W>=0.14T- 152 is satisfied at T>=1,100 deg.C. In this case, for example, the main heaters 3 are arranged in the upper and lower parts in a device casing 1 via reflection member 2, and the density of irradiation energy on the wafer is made uniform within + or -2%. A transparent container 4 made of quartz glass is arranged at the center of the casing, and the wafer the object to be processed is placed and supported on the auxiliary heater used also as a supporter therein.

Description

【発明の詳細な説明】 本発明は半導体ウェハーを光照射により加熱する方法に
関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of heating a semiconductor wafer by irradiating it with light.

最近、半導体ウェハー(以下単に「ウェハー」という。Recently, semiconductor wafers (hereinafter simply referred to as ``wafers'') have become popular.

)への不純物の導入方法として、不純物濃度1.接合の
深さt−精密に制御し得ることから、不純物をイオン状
態にして加速してウェハーに打ち込むイオン注入法が使
用されてきている。このイオン注入法においては、イオ
ンが注入された後のウェハーの表面における結晶状態が
変化して荒れたものとなるため、この荒れを消失せしめ
て良好な表面状態とするために、イオン注入後約100
0℃またはそれ以上の温度にウェハーを加熱処理する必
要があり、この加熱処理は、注入された不純物の深さ方
向の濃度分布が熱拡散により変化しないようく短時間で
行なわなければならない。
), the impurity concentration is 1. Since the junction depth t can be precisely controlled, ion implantation has been used in which impurities are ionized and accelerated and implanted into the wafer. In this ion implantation method, the crystal state of the wafer surface changes after the ions are implanted and becomes rough, so in order to eliminate this roughness and create a good surface condition, approximately 100
It is necessary to heat the wafer to a temperature of 0° C. or higher, and this heat treatment must be performed in a short time so that the concentration distribution of the implanted impurity in the depth direction does not change due to thermal diffusion.

また、生産性を向上させるためにもウェハーの急速加熱
、急速冷却が要請されている。
Furthermore, rapid heating and cooling of wafers is required to improve productivity.

このような加熱処理の他にも、半導体の製造において加
熱が必要とされる工程があり、例えば不純物拡散工程、
化学的気相IjM長工程、電気的活性化のための熱JI
I:瑠工程、更には7リコンウエノ・−の表層全窒化若
しくは酸化せしめるための熱処理工程等があり、これら
の工程を遂行する場合にも上述と同様にウェハーの急速
加熱、急速冷却が要請される。
In addition to such heat treatment, there are other processes that require heating in semiconductor manufacturing, such as impurity diffusion processes,
Chemical vapor phase IjM long process, thermal JI for electrical activation
I: There is a heat treatment process for fully nitriding or oxidizing the surface layer of the 7 recon wafer, and when performing these processes, rapid heating and cooling of the wafer is required as described above. .

このようなをMWにより、最近、ウェハーを光照射で加
熱する光照射炉が開発され、この光照射炉によれば、わ
ずか数秒間という短時間で1000℃〜1400℃まで
昇温か川[1ヒである。
Using MW, a light irradiation furnace has recently been developed that heats the wafer with light irradiation.This light irradiation furnace can heat the wafer from 1000℃ to 1400℃ in just a few seconds. It is.

ところで、ウェハー、例えば単結晶シリコンを単に光照
射することにより、数秒間以内の短時間において、温度
1150℃前後の処理温度に昇温せしめ史にこの処理温
度に保つという加熱処理を施す場合には、外温時及び処
理温度時においてウェハーにおける外周部若しくは外周
近傍部と中央部との間に比較的大きな温1川差が生じ、
この温度差が原因となってウェハーに後の処理工程で支
障をきたすような大きな「反り」が発生し、更には「ス
リップライン」と呼ばれる損傷が発生することが分った
。そしてウェハーの7−ト抵抗値もこの温度差のために
バラツキが生じ、その性能に態形/pを及はしていた。
By the way, when performing heat treatment on a wafer, for example, single crystal silicon, by simply irradiating it with light, the temperature is raised to a processing temperature of around 1150°C within a short period of several seconds, and then maintained at this processing temperature throughout the process. , a relatively large difference in temperature occurs between the outer periphery or the vicinity of the outer periphery and the center of the wafer at external temperature and processing temperature,
It has been found that this temperature difference causes large ``warps'' in the wafers that can interfere with subsequent processing steps, as well as damage called ``slip lines.'' This temperature difference also caused variations in the wafer's 7-t resistance value, which affected its performance.

これは、ウェハーの厚さは普通0.5門前後程度と非常
に薄く、厚さ方向における温度分布は、時間的には10
−5秒の桁の程度で緩第11されるので実質的には」ζ
影qtを及はすことはないが、ウェハーの面に沿った方
向における温度分布は、たとえウェハーの表面を均一な
照射エネルギー密度で光照射しても、ウェハー外周部若
しくは外周近傍部からの熱放散がウェハーの中央部から
の熱放散よりも大きいので、昇温時においてはウエノ・
−の外周部若しくは外周近傍部の温度がウェハーの中央
部の温度に追従できず、処理温度時においてもウェハー
の外周部若しくは外周近傍部の温度がウェハーの中央部
の温度にまで達することがなく、結局ウェハーの外周部
若[7くは外周近傍部の温度はウェハーの中央部の温度
より和尚に低くなってしまうからである。
This is because the thickness of the wafer is usually very thin, around 0.5 mm, and the temperature distribution in the thickness direction is approximately 10 mm thick over time.
- Since it is slowed down to the order of 5 seconds, it is essentially "ζ
However, the temperature distribution in the direction along the wafer surface is such that even if the wafer surface is irradiated with light at a uniform irradiation energy density, heat from the wafer periphery or near the wafer periphery Since the heat dissipation is larger than that from the center of the wafer, the wafer
- The temperature at or near the outer periphery of the wafer cannot follow the temperature at the center of the wafer, and even at processing temperatures, the temperature at or near the outer periphery of the wafer does not reach the temperature at the center of the wafer. This is because the temperature at or near the outer periphery of the wafer ends up being much lower than the temperature at the center of the wafer.

このよりな4(情から、ウエノ・−の外周部若しくは外
周近傍部を更に補助的に加熱する方法が提案されている
。この方法は、ウェハーの表mk〕・ロゲンランプなど
の主加熱器よシの光照射により主加熱する一方、ウエノ
・−の外周部若しくは外周近傍部をランプ或いはヒータ
などのリンク状の補助加熱器により補助的に加熱しなが
らウェハーを加熱するものである。
For this reason, a method has been proposed in which the outer periphery of the wafer or the vicinity of the outer periphery is additionally heated. The wafer is primarily heated by light irradiation, and the wafer is heated while the outer periphery or the vicinity of the wafer is auxiliary heated by a link-shaped auxiliary heater such as a lamp or heater.

しかし、この補助加熱を行なっても、これにより加えら
れる熱量が過小であったり過大であったりすればウェハ
ーの温l1jLl”、I均一とならずに前述の不具合が
発生する。ま1ζ、過圧iM h=1もウェハーの熱処
理温匿により異なる。
However, even if this auxiliary heating is performed, if the amount of heat applied is too small or too large, the wafer temperature will not be uniform and the above-mentioned problem will occur. iM h=1 also varies depending on the heat treatment temperature of the wafer.

そこで本発明は、上記の事+?+に鑑みてなされたもの
であり、その目的とするところは、補助加熱による熱量
をウェハーの熱処理温度に応じてその最適範囲を定めて
、ウェハーの均一加熱を可能とするウェハーの光照射加
熱方法を従供することにあり、鋭意詳細な研究を行った
結果、本発明を完成したものである。そして本発明の構
成は、主加熱器にてウェハーの表面を光照射して加熱す
るとともに、ウェハーの外周近傍に近接して配設された
リング状の補助加熱器にてウェハーの外周近傍全補助的
に加熱する方法であって、ウエノ・−〇熱処理温度をT
(℃)、補助加熱器によりウエノ・−の円周の単位長さ
当りに加えられるパワーをW(”ツ1/rrn)とした
とき、T≧1100℃において、0.20T−212≧
W≧0.14T−152なる関係を満すことを特徴とす
る。
Therefore, the present invention addresses the above-mentioned problems +? The purpose of this method is to provide a wafer light irradiation heating method that enables uniform heating of the wafer by determining the optimal range of the amount of heat from auxiliary heating depending on the wafer heat treatment temperature. The present invention was completed as a result of intensive and detailed research. The structure of the present invention is such that a main heater heats the surface of the wafer by irradiating light, and a ring-shaped auxiliary heater disposed close to the wafer's outer periphery assists the entire wafer's outer periphery. It is a method of heating Ueno--〇 heat treatment temperature to T
(°C), and when the power applied per unit length of the circumference of Ueno- by the auxiliary heater is W ("tsu1/rrn), when T≧1100°C, 0.20T-212≧
It is characterized by satisfying the relationship W≧0.14T-152.

以下に図面に糸いて本発明の実施しll’r具体的に説
明する。
The implementation of the present invention will be specifically explained below with reference to the drawings.

第1図は本発明の実施例に使用される光照射加熱炉の概
略を示す断面図であるが、装置箱1内の上方と下方には
反射部材2f:介して主加熱器6が配設されていZゴこ
の主加熱器6は消費電力が2150Wの棒状のハロゲン
電球が平面状に近接して並べてなる面状光分であって、
ウェハー上での照射エネルギー密度の均一度が±2%以
内の均一を 性であシ、被処理物1400℃まで昇温させることがで
きる。装置箱1内の中央には石英ガラスからなる透明容
器4が配置され、その内部には被処理物であるウェハー
5が支持器を兼ねる補助加熱器6上に載置されて支持さ
れている。ウェハー5は直径6インチ(周長約24cr
n)、厚さが0.4mの円板状であって、40KeVの
エネルギーにてリンイオンが5 X 10 ” 5”/
cr4の割合で注入された単結晶シリコンより成る。補
助加熱器6は、第2図に示すようにリンク状の封体61
内にフィラメント62が封入されたハロゲン′醒球であ
って、最大消費電力は1300 Wである。そして封体
61上には4個の支持具7が掛止されており、この支持
具7の突起上にウェハー5が載置される。従ってウニ/
・−5の外周近傍5aは補助加熱器6の直上に位Iff
、 L、その距離りは10Inllとなっている。もっ
とも、補助加熱器6は外周近傍5aの直下である必要i
−fなく、外周縁の側方でも上方でもよく、またその距
離りは外周縁から5〜15mの範囲で選ばれる。
FIG. 1 is a cross-sectional view schematically showing a light irradiation heating furnace used in an embodiment of the present invention, and a main heater 6 is disposed above and below inside the device box 1 via a reflecting member 2f. The main heater 6 is a planar light bulb made of bar-shaped halogen bulbs with a power consumption of 2150 W arranged closely in a plane.
The uniformity of the irradiation energy density on the wafer is within ±2%, and the temperature of the object to be processed can be raised to 1400°C. A transparent container 4 made of quartz glass is placed in the center of the apparatus box 1, and a wafer 5, which is an object to be processed, is placed and supported on an auxiliary heater 6 which also serves as a supporter. Wafer 5 has a diameter of 6 inches (circumference approximately 24 cr)
n), is a disk shape with a thickness of 0.4 m, and phosphorus ions are 5 x 10"5"/
It consists of monocrystalline silicon implanted with a proportion of cr4. The auxiliary heater 6 includes a link-shaped enclosure 61 as shown in FIG.
It is a halogen bulb with a filament 62 sealed inside, and its maximum power consumption is 1300W. Four supports 7 are hung on the seal 61, and the wafer 5 is placed on the protrusions of the supports 7. Therefore, sea urchin/
・The vicinity of the outer periphery 5a of -5 is located directly above the auxiliary heater 6.
, L, the distance is 10Inll. However, the auxiliary heater 6 needs to be located directly under the outer circumference 5a.
-f, it may be on the side or above the outer periphery, and the distance is selected within the range of 5 to 15 m from the outer periphery.

しかして、主加熱器6によりウェハー5の表面が光照射
されて加熱されるとともに外周近傍5aが補助加熱器6
により加熱されて、外周近傍からの大きな熱放散が補償
されて全体が均一に加熱される訳であるが、前述のよう
に補助加熱器乙による加熱が過大であったり過小で6っ
たりすれは全体が均一にならず、あいかわらず「反り」
やスリップラインが発生するし、7−ト抵抗値のバラツ
キも小さくならない。
Thus, the surface of the wafer 5 is irradiated with light and heated by the main heater 6, and the vicinity of the outer periphery 5a is heated by the auxiliary heater 6.
This compensates for the large heat dissipation from the vicinity of the outer periphery and heats the entire area evenly, but as mentioned above, if the heating by the auxiliary heater B is too much or too little, The whole is not uniform, and there is still "warp"
Otherwise, slip lines will occur, and the variation in the resistance value will not be reduced.

そこで本発明では、ウェハー5の熱処理温度Tを110
0〜1300℃の範囲で、壕だ、ウエノ・−5の単位円
長当りに対する補助加熱器6の消費電力を最高5077
−F7crnまでの範囲で加熱し、スリップラインの発
生の有無を調べると同時にシー)−Ut抗値ρのバラツ
キを測定して、このバラツキを許容範囲内とすることが
できる加熱条件をめた。なお、ウェハー5のシート抵抗
値ρのバラツキの許容範囲は、平均値を吃、標準偏差分
σとしたとき、3 a /7.が5チ以内である。その
測定結果を第4図に示すが、図中の0印は3a/−が5
%以内の点を、ρ ×印は5%以上の点をそれぞれプロットしたものである
。ここで0印はは1.”W=0.20T−212とW=
0.14T−152の2本のlI]、翅の範囲内にあり
、従って、内直線間の斜線で示す領域Aであればシート
抵抗値のバラツキを許容範囲内とすることができ、実際
に0印では「反り」やスリップラインが発生しなかった
。これにχ・1してW>0.20T−Q 1 ’J−7
S! L IA自ITJ) 丁t 11 rr+ k畳
i lN+ 1lll lik 9’L A f ? 
ン−ハn1rtJcが過大であって、外周近傍5aの方
が中央部より温度が高くなり過ぎ、逆にW<0.’14
T−152である領域Cでは加熱が過小であって外周近
傍5aが低く、いずれにしても均一加熱の目的を達成す
ることができない。
Therefore, in the present invention, the heat treatment temperature T of the wafer 5 is set to 110
In the range of 0 to 1300℃, the power consumption of the auxiliary heater 6 per unit circular length of Moda Ueno-5 is up to 5077
-F7crn was heated to check for the occurrence of slip lines, and at the same time, the variation in the C)-Ut resistance value ρ was measured to find heating conditions that could keep this variation within the allowable range. Note that the allowable range of variation in the sheet resistance value ρ of the wafer 5 is 3 a /7. is within 5 inches. The measurement results are shown in Figure 4. The 0 mark in the figure indicates that 3a/- is 5.
The points within ρ are plotted, and the × marks are plotted for points with ρ of 5% or more. Here, the 0 mark is 1. ”W=0.20T-212 and W=
0.14T-152 two lI], is within the range of the wings, and therefore, in the area A indicated by the diagonal lines between the inner straight lines, the variation in sheet resistance value can be kept within the permissible range, and in practice At the 0 mark, no "warpage" or slip lines occurred. Add χ・1 to this and get W>0.20T-Q 1 'J-7
S! L IA own ITJ) Ding t 11 rr+ ktatami i lN+ 1llll lik 9'L A f?
n1rtJc is too large, and the temperature near the outer periphery 5a becomes too high than that at the center, and conversely, W<0. '14
In region C, which is T-152, the heating is too low and the temperature near the outer periphery 5a is low, and in any case, the purpose of uniform heating cannot be achieved.

以上説明したように本発明は、ウェハーの熱処理温度T
(℃)と補助加熱器によりウェハーの円周の単位長さ当
シに加えられるパワーW (′7ツト/cm )ヲ変化
させて調査し、T≧1100℃において、0.20T−
212≧W≧0.14T−152なる関係を満すときに
均一加熱の目的を達成できることを見い出したので、本
発明に従えば、各熱処理温度における補助加熱器による
補助加熱の適旧範囲を容易にめることができ、「反り」
やスリップラインが発生せず、シート抵抗値のバラツキ
も小さなウェハーをイ0ることのできる光照射加熱方法
を提供することができる。
As explained above, in the present invention, the wafer heat treatment temperature T
(°C) and the power W ('7t/cm) applied by the auxiliary heater per unit length of the wafer's circumference.
It has been found that the purpose of uniform heating can be achieved when the relationship 212≧W≧0.14T-152 is satisfied. According to the present invention, the appropriate range of auxiliary heating by the auxiliary heater at each heat treatment temperature can be easily determined. Can be bent and "warped"
It is possible to provide a light irradiation heating method that can heat wafers without generating slip lines or slip lines and with small variations in sheet resistance.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例に使用される加熱炉の断面図、
第2図は補助加熱器の平面図、第5図は同じく断面図、
第4図はデータの説明図をそれぞれ示す。 1・・・装置箱 2・・・反射部材 5・・・主加熱器 4・・・透明容器 5・・・ウェハー 6・・・補助加熱器出願人 ウシオ
電機株式会社 代理人 弁理士 田原寅之助 3
FIG. 1 is a sectional view of a heating furnace used in an embodiment of the present invention;
Figure 2 is a plan view of the auxiliary heater, Figure 5 is a cross-sectional view,
FIG. 4 shows explanatory diagrams of the data. 1... Equipment box 2... Reflective member 5... Main heater 4... Transparent container 5... Wafer 6... Auxiliary heater applicant Ushio Inc. agent Patent attorney Toranosuke Tahara 3

Claims (1)

【特許請求の範囲】 主加熱器にて半導体ウェハーの表面を光照射して加熱す
るとともに、半導体ウェハーの外周近傍に近接して配設
されたリング状の補助加熱器にて半導体ウェハーの外周
近傍を補助的に加熱する方法であって、 半導体ウェハーの熱処理温度tT(℃)、補助加熱器に
よシ半導体ウェハーの円周の単位長さ当りに加えられる
バク−eW(7ツト、名)、としたとき、T≧1100
℃において、α20T−212kW、Po、14T−1
52なる関係を満すことを特徴とする半導体ウェハーの
光照射加熱方法。
[Claims] A main heater irradiates the surface of the semiconductor wafer with light to heat it, and a ring-shaped auxiliary heater disposed close to the outer periphery of the semiconductor wafer heats the surface of the semiconductor wafer. A method of auxiliary heating of a semiconductor wafer, comprising: a heat treatment temperature tT (°C) of a semiconductor wafer, a heat treatment temperature tT (°C) of a semiconductor wafer; When, T≧1100
At °C, α20T-212kW, Po, 14T-1
A method for heating a semiconductor wafer by light irradiation, characterized in that the following relationship is satisfied:
JP19528883A 1983-10-20 1983-10-20 Heating method by photo irradiation Pending JPS6088431A (en)

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JP19528883A JPS6088431A (en) 1983-10-20 1983-10-20 Heating method by photo irradiation

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Application Number Priority Date Filing Date Title
JP19528883A JPS6088431A (en) 1983-10-20 1983-10-20 Heating method by photo irradiation

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JPS6088431A true JPS6088431A (en) 1985-05-18

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62188239A (en) * 1985-09-27 1987-08-17 エイ・ティ・アンド・ティ・コーポレーション Manufacture of electrically isolated device
EP0345443A2 (en) * 1988-05-09 1989-12-13 Siemens Aktiengesellschaft Process for the rapid thermal annealing of a semiconductor wafer using irradiation

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58175826A (en) * 1981-12-04 1983-10-15 Ushio Inc Heating method for semiconductor through light irradiation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58175826A (en) * 1981-12-04 1983-10-15 Ushio Inc Heating method for semiconductor through light irradiation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62188239A (en) * 1985-09-27 1987-08-17 エイ・ティ・アンド・ティ・コーポレーション Manufacture of electrically isolated device
EP0345443A2 (en) * 1988-05-09 1989-12-13 Siemens Aktiengesellschaft Process for the rapid thermal annealing of a semiconductor wafer using irradiation

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