JPS6063537A - Photoworking negative - Google Patents

Photoworking negative

Info

Publication number
JPS6063537A
JPS6063537A JP58171103A JP17110383A JPS6063537A JP S6063537 A JPS6063537 A JP S6063537A JP 58171103 A JP58171103 A JP 58171103A JP 17110383 A JP17110383 A JP 17110383A JP S6063537 A JPS6063537 A JP S6063537A
Authority
JP
Japan
Prior art keywords
light
negative
photoworking
glass
worked
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58171103A
Other languages
Japanese (ja)
Inventor
Saburo Nobutoki
信時 三郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP58171103A priority Critical patent/JPS6063537A/en
Publication of JPS6063537A publication Critical patent/JPS6063537A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F1/00Originals for photomechanical production of textured or patterned surfaces, e.g., masks, photo-masks, reticles; Mask blanks or pellicles therefor; Containers specially adapted therefor; Preparation thereof

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Preparing Plates And Mask In Photomechanical Process (AREA)

Abstract

PURPOSE:To prevent a working negative from being damaged by a foreign matter existing between a surface to be worked and a photoworking negative, by constituting so that a worked face side surface of a light non-transmitting part graphic is projected higher than a worked face side surfade of a figure of a light transmitting part. CONSTITUTION:A worked face side surface (chrome surface) of a graphic of a light non-transmitting part 4 of a photoworking negative 3 is projected desirably about 2mum higher than a worked face side surface (glass surface) of a figue of a light transmitting part. In this way, the glass part except the chrome graphic part 4 is etched to a depth of >= several mum, and a distance between the glass surface and the surface of a photosensitive film 2 of the object to be worked 1 is made large, by which even if a foreign matter 7 of about several mum exists, the negative is not damaged, or a degree of the damage is made slight by reducing a contact pressure. In this way, even if photoworking is executed by adopting a contact exposing method or a proximity exposing method which is nearly close to a tight contact, the probability by which the photoworking negative is damaged by a foreign matter is reduced remarkably.

Description

【発明の詳細な説明】 〔発明の利用分野〕 本発明は異物による損傷を受け難くした精密ホト加工用
原版に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Application of the Invention] The present invention relates to an original plate for precision photoprocessing that is less susceptible to damage by foreign objects.

〔発明の背景〕[Background of the invention]

いわゆるホト加工を行う工程で、感光性被膜を施した被
加工物表面を、所望図形を形成させたホト加工用原版を
介して露光する方法として、原版を感光性被膜にtri
着させて露光する方法(%HI’露光法露光値かな間隔
をおいて員光する方法(近接露光法)、及び投写レンズ
により図形原版像を投写する方法(投影露光法)がある
In the so-called photo-processing process, the surface of the workpiece coated with a photosensitive film is exposed to light through a photo-processing original plate on which a desired pattern has been formed.
There are two methods: a method in which the image of the original pattern is projected using a projection lens (proximity exposure method), and a method in which the original pattern image is projected using a projection lens (projection exposure method).

上記3種類の露光法の長短を略述すれば、(a)密着露
光法は原版図形の形状を最も忠実に再現できる反面、僅
かな異物の介在にょリボト加工用原版や被加工物の表面
が損傷を受け易く、歩留りが低くなり昂い、(b)近接
露光法では原版と被加工感光■臭の間隔を、もちろん図
形の精細度によって異なるが、lないし数μmに保持し
て露光するので、異物の介在は、その異物が影を生ずる
という一過性の事故原因となるが、原版を損傷するには
至らないのが特長で、その反面、露光された図形はその
周辺に半影部分があるため図形形状の誤差があったり、
露光、現像後の残留被膜の周辺部所面が急峻ではない欠
点を持つ、(C)投影露光法は、縮小露光等全く別の目
的に用いられる場合があるが、一般に近接露光法の長短
が一層甚だしく現れる。
To summarize the advantages and disadvantages of the three types of exposure methods mentioned above, (a) the contact exposure method can most faithfully reproduce the shape of the original image, but on the other hand, the surface of the original plate for ribbing or the workpiece is (b) In the close exposure method, the distance between the original plate and the workpiece is maintained at 1 to several μm, depending on the fineness of the figure, and then exposed. The presence of a foreign object causes a temporary accident in which the foreign object creates a shadow, but the feature is that it does not damage the original plate.On the other hand, the exposed figure may have a penumbra area around it. Because of this, there may be errors in the figure shape,
(C) Projection exposure method, which has the disadvantage that the peripheral part of the residual film after exposure and development is not steep, may be used for completely different purposes such as reduction exposure, but in general, the advantages and disadvantages of close-up exposure method are It becomes even more serious.

従って、目的に合致した感光剤の性質、図形精度に対す
る要求などに沿って、上記いずれかの方法が選択されて
いる。
Therefore, one of the above methods is selected depending on the properties of the photosensitizer that meet the purpose, the requirements for graphic accuracy, and so on.

かかるホト加工に使用される原版には、通常、ガラス基
板にクローム被膜を形成し、この被膜をホト加工により
蝕刻したものや、ガラス基板に銀写真乳剤を塗布した乾
板を、露光、現像して図形形状に銀粒子を析出させた写
真像が使用される。
The original plates used for such photoprocessing are usually those in which a chrome film is formed on a glass substrate and this film is etched by photoprocessing, or a dry plate in which a silver photographic emulsion is coated on a glass substrate, which is exposed and developed. A photographic image in which silver particles are deposited in a graphic shape is used.

後者は表面がゼラチンを主とする有機被膜なので極めて
傷付き5いため、主に前者が使用されている。しかし、
前者の方が後者より丈夫と云っても、単に比較上のこと
であり、ホト加工用原版が異物によって損傷を受け易い
ことはクローム原版と頚も免れ龍い。
The former is mainly used because the surface of the latter is an organic coating mainly made of gelatin and is therefore extremely susceptible to scratches. but,
Although it may be said that the former is more durable than the latter, it is merely a matter of comparison; the original plate for photo processing is easily damaged by foreign objects, and the same is true for the original plate for chrome.

現在使用されているクローム原版においては、ガラス面
上に厚さ200〜700nm程度にスパッタリング法又
は真空蒸着法により形成したクローム膜を写真蝕刻して
図形が形成されている。クローム膜は、光反射率を低く
してフレア現象を少しでも減少させるため、片側の面ま
たは両側の面を帯黒色の亜酸化物で形成することもある
In currently used chrome master plates, figures are formed by photo-etching a chrome film formed on a glass surface to a thickness of about 200 to 700 nm by sputtering or vacuum evaporation. The chrome film is sometimes made of blackish suboxide on one or both sides in order to lower the light reflectance and reduce the flare phenomenon.

かかる構造であるから、厳密には、密着露光法では、ホ
ト加工用原版の突出したクローム部が、主に、被加工物
の感光性被膜に密着していると表現すべきであるが、ク
ローム部とガラス部の段差は、一般に工程中に存在する
異物の厚さに比べて小さいため、万一かかる異物が存在
すると、原版のクローム部のみならずガラス部に於いて
も接着ないし損傷を与えてしまうことになる。
Because of this structure, strictly speaking, in the contact exposure method, the protruding chrome parts of the photoprocessing master should be expressed as being in close contact with the photosensitive coating of the workpiece. The height difference between the chrome part and the glass part is generally smaller than the thickness of foreign matter that exists during the process, so if such foreign matter were to exist, it could cause adhesion or damage not only to the chrome part of the original plate but also to the glass part. This will result in

被加工図形の精細度や感光剤の分光感度特性に応じクロ
ーム以外の光遮断性被膜が使用されることもあるが、基
本的には事情は同等である。
Depending on the fineness of the figure to be processed and the spectral sensitivity characteristics of the photosensitizer, a light-shielding coating other than chrome may be used, but the circumstances are basically the same.

〔発明の目的〕[Purpose of the invention]

本発明の目的は、損傷を受ける確率が大幅に減少するよ
うにしたホト加工用原版を提供することにある。
An object of the present invention is to provide an original plate for photoprocessing in which the probability of damage is significantly reduced.

〔発明の概要〕[Summary of the invention]

上記目的を達成するために本発明においては、ホト加工
用原版の、光不透過部図形の被加工面側表面(クローム
面)を光透退部図形の被加工面側表面(ガラス面)より
少なくとも1μm程度、好ましくは2μm程度以上高く
突出させることとした。実際には、クローム図形部以外
のガラス部を深さ数μm以上蝕刻し、ガラス表面と被加
工物の感光性被膜表面との距離を大きくし、数μm程度
の異物が万一存在した場合にも、原版に損傷を与えない
か、接触圧を小さくして損傷を軽度に止めようとするの
である。このようにして、ホト加工用原版のガラス部す
なわち光透過部と被加工物の感光性被膜表面との間に異
物が存在しても原版は殆ど損傷を受けなくなり、損傷を
受ける確率が大幅に低下することになる。
In order to achieve the above object, in the present invention, the surface of the photoprocessing original plate on the processing surface side (chrome surface) of the light-opaque part figure is made closer to the processing side surface (glass surface) of the light-transmitting part figure. The protrusion is made to protrude at least about 1 μm, preferably about 2 μm or more. In reality, the glass parts other than the chrome graphic parts are etched to a depth of several micrometers or more, and the distance between the glass surface and the photosensitive coating surface of the workpiece is increased, so that in the unlikely event that foreign matter of several micrometers is present, In this case, attempts are made to minimize damage to the original plate by reducing the contact pressure. In this way, even if a foreign object exists between the glass part, that is, the light-transmitting part, of the photoprocessing original plate and the photosensitive coating surface of the workpiece, the original plate will hardly be damaged, and the probability of damage will be greatly reduced. This will result in a decline.

〔発明の実施例〕[Embodiments of the invention]

第1図は本発明に係るホト加工用原版を被加工物に密着
させた状態を示し、1は被加工物基体、2は被加工物基
体上の感光性被膜、3は本発明に係るホト加工用原版の
ガラス基板、4は本発明に係る突出して形成された光不
透過部、5は(光不透過部以外の)光透過部の蝕刻除去
された部分、6は上記蝕刻に於ける残存部、7は異物で
ある。
FIG. 1 shows a state in which the original plate for photoprocessing according to the present invention is brought into close contact with a workpiece, where 1 is the base of the workpiece, 2 is the photosensitive coating on the base of the workpiece, and 3 is the photosensitive film according to the present invention. The glass substrate of the original plate for processing, 4 is the light-opaque portion formed in a protruding manner according to the present invention, 5 is the portion of the light-transmissive portion (other than the light-opaque portion) that has been etched away, and 6 is the portion of the light-transmissive portion (other than the light-opaque portion) that has been removed by etching. The remaining portion 7 is a foreign substance.

この図から、原版の光透過部と被加工物との間に異物が
存在していても、原版に損傷を与えないことが良く判る
From this figure, it is clearly seen that even if foreign matter exists between the light-transmitting part of the original and the workpiece, the original will not be damaged.

露光すべき図形形状にもよるが、クローム図形の間隔が
大きい時は、ガラス原版を密着させる圧力の為にガラス
原版が湾曲して、蝕刻した原版のガラス面が被加工物に
接触してしまい、本発明の効果が減殺されてしまう事が
あるので、かかる場合は、原版図形設計に際し事情の許
す限り、面積は小であっても蝕刻しないガラス部を支持
柱として所々に残存させておくことが有効である。
It depends on the shape of the figure to be exposed, but when the distance between the chrome figures is large, the pressure that brings the glass master into close contact causes the glass master to curve, causing the etched glass surface of the master to come into contact with the workpiece. However, the effect of the present invention may be diminished, so in such a case, as far as circumstances permit when designing the original graphic, unetched glass parts should be left in places as supporting pillars, even if the area is small. is valid.

このようなりローム原版を作成する方法としては、クロ
ーム蝕刻に次いで、そのままガラス蝕刻を行えば良いわ
けで、弗化水素系薬物による蝕刻、フレオンを混ぜた雰
囲気によるプラズマ蝕刻等が使用できる。また、更に容
易にガラス基板の蝕刻を行うには感光性ガラス板にクロ
ームパターンを形成し、次いでガラス蝕刻を行うことも
急峻な蝕刻断面を得るために極めて有効である。
As a method for producing such a roam master plate, glass etching can be performed directly after chrome etching, and etching with a hydrogen fluoride drug, plasma etching in an atmosphere containing Freon, etc. can be used. Furthermore, in order to more easily etch the glass substrate, it is very effective to form a chrome pattern on a photosensitive glass plate and then perform glass etching to obtain a steeply etched cross section.

上述の基板ガラス蝕刻に代えて、基板上に、基板ガラス
およびクロムを蝕刻しない薬品により蝕刻される物質の
被膜を形成した上で、クロムを被着、蝕刻を行い、次い
で蝕刻により形成されたクロムを陰閉材として下地膜の
蝕刻を行うことも可能で、この場合、ガラス基板の弗化
水素系薬物による蝕刻に起こりがちな蝕刻面の荒れを防
止できる利点がある。
Instead of the substrate glass etching described above, a film of a substance that is etched by a chemical that does not etch the substrate glass and chromium is formed on the substrate, and then chromium is deposited and etched, and then the chromium formed by etching is performed. It is also possible to perform etching of the base film using a negative occlusion agent. In this case, there is an advantage that the etched surface can be prevented from becoming rough, which tends to occur when etching a glass substrate with a hydrogen fluoride-based drug.

[41uの方法としてクローム図形の厚さを大とする事
も考えられるが、この場合、不透光体である部分の厚さ
が大きいため感光膜上のクローム膜に対向しない部分に
半影部があるため現像後の残存膜断面が急峻となりにく
い欠点がある。しかし、この方法でも、感光膜のガンマ
特性の如何によっては、本発明の目的とする効果を達成
することも可能である。
[As a method for 41u, it is possible to increase the thickness of the chrome figure, but in this case, since the thickness of the opaque part is large, a penumbra is formed on the part of the photoresist that does not face the chrome film. Therefore, there is a drawback that the cross section of the remaining film after development is difficult to become steep. However, even with this method, depending on the gamma characteristics of the photoresist film, it is possible to achieve the effects aimed at by the present invention.

これに対しガラス基板のクローム非存在部を蝕刻した原
版に於いても、原版を通過する光線の蝕刻部に於ける散
乱が若干あるため、従来の原版に於けると全く同等の光
量分布は得られないが、その変化は無視し得る程度のも
のである。
On the other hand, even with an original plate in which the chromium-free areas of the glass substrate are etched, there is some scattering of the light beam passing through the original plate in the etched areas, so it is not possible to obtain exactly the same light intensity distribution as with a conventional original plate. However, the change is negligible.

ガラス表面の蝕刻量が大きい程効果は大であるが、かか
る工程に多く存在する異物の厚さや、通常の原版におけ
る光不透過部クローム膜の厚さより考えて、少なくとも
lIJm以上、望ましくは3μm以上とすることが好ま
しい。
The greater the amount of etching on the glass surface, the greater the effect, but considering the thickness of foreign substances that are often present in this process and the thickness of the chrome film in the light-opaque area of a normal original plate, it should be at least lIJm or more, preferably 3 μm or more. It is preferable that

又、光不透過部としては、通常、前述の如<Crまたは
Cr亜酸化物が使用されているが、ガラス基板を弗化水
素酸系薬物により蝕刻する場合においては、やや安定性
を欠くので、pt被被膜使用することも好適である。
Furthermore, as described above, Cr or Cr suboxide is usually used as the light-opaque part, but it is somewhat unstable when etching a glass substrate with a hydrofluoric acid drug. , it is also suitable to use a PT coating.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明によれば、密着露光法、或い
は殆ど密着に近い近接露光法を採用してホト加工を行う
為のホト加工用原版が、被加工物とホト加工用原版の間
に存在する恐れのある異物によって損傷される確率が大
幅に低減する。
As explained above, according to the present invention, a photoprocessing original plate for photoprocessing using a contact exposure method or a near-contact exposure method is placed between a workpiece and a photoprocessing original plate. The probability of being damaged by foreign objects that may be present is significantly reduced.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に係るホト加工用原版を被加工物に密着
させた状態を示す図である。 1−被加工物基体、2・−・被加工物基体上の感光性被
膜、3一本発明に係るホト加工用原版のガラス基板、4
一本発明により突出して形成された光不透過部(クロー
ム部)、5・−(光不透過部以外の)光透過部の蝕刻除
去された部分、6−前記蝕刻に於ける残存部、7−異物
。 第 1 図
FIG. 1 is a diagram showing a state in which the original plate for photoprocessing according to the present invention is brought into close contact with a workpiece. 1-Workpiece substrate, 2.--Photosensitive coating on workpiece substrate, 3-Glass substrate of photoprocessing original plate according to the present invention, 4
1. A light-opaque part (chrome part) formed protrudingly according to the present invention, 5. - A portion of the light-transmissive part (other than the light-opaque part) that has been etched away, 6. A remaining part of the etching, 7. -Foreign objects. Figure 1

Claims (1)

【特許請求の範囲】 1、被加工感光面に密着または極めて微少な間隔を以て
対峙させて感光、加工するのに用いるホト加工用原版に
おいて、光不透過部図形の被加工面側表面を光透退部図
形の被加工面側表面よりも高く突出させたことを特徴と
するホト加工用原版2、光不透過部図形の被加工面側表
面を光透退部図形の被加工面側表面より少なくとも2μ
m以上高く突出させた特許請求の範囲第1項記載のホト
加工用原版。 3、光透過部は、光不透過部支持体表面を蝕刻すること
により形成した特許請求の範囲第1項記載のホト加工用
原版。
[Scope of Claims] 1. In a photoprocessing original plate used for exposure and processing in close contact with the photosensitive surface to be processed or facing it with an extremely small distance, the surface of the pattern of the light-opaque part on the side of the processed surface is transparent. An original plate for photoprocessing 2 characterized by protruding higher than the surface of the processed side of the recessed part figure, the surface of the processed side of the light-opaque part figure is higher than the surface of the processed side of the light-transparent part figure. at least 2μ
The original plate for photoprocessing according to claim 1, which is projected higher than m or more. 3. The original plate for photoprocessing according to claim 1, wherein the light-transmitting portion is formed by etching the surface of the support for the non-light-transmitting portion.
JP58171103A 1983-09-19 1983-09-19 Photoworking negative Pending JPS6063537A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58171103A JPS6063537A (en) 1983-09-19 1983-09-19 Photoworking negative

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58171103A JPS6063537A (en) 1983-09-19 1983-09-19 Photoworking negative

Publications (1)

Publication Number Publication Date
JPS6063537A true JPS6063537A (en) 1985-04-11

Family

ID=15917029

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58171103A Pending JPS6063537A (en) 1983-09-19 1983-09-19 Photoworking negative

Country Status (1)

Country Link
JP (1) JPS6063537A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0310412A2 (en) * 1987-09-30 1989-04-05 Sharp Kabushiki Kaisha Improvements in photo-masks
US5079113A (en) * 1988-09-29 1992-01-07 Sharp Kabushiki Kaisha Photo-mask
US5260150A (en) * 1987-09-30 1993-11-09 Sharp Kabushiki Kaisha Photo-mask with light shielding film buried in substrate
JP2008284914A (en) * 2007-05-15 2008-11-27 Honda Motor Co Ltd Window glass with shade for vehicle

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0310412A2 (en) * 1987-09-30 1989-04-05 Sharp Kabushiki Kaisha Improvements in photo-masks
US5260150A (en) * 1987-09-30 1993-11-09 Sharp Kabushiki Kaisha Photo-mask with light shielding film buried in substrate
US5079113A (en) * 1988-09-29 1992-01-07 Sharp Kabushiki Kaisha Photo-mask
JP2008284914A (en) * 2007-05-15 2008-11-27 Honda Motor Co Ltd Window glass with shade for vehicle

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