JPS60501814A - lubricant - Google Patents

lubricant

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Publication number
JPS60501814A
JPS60501814A JP59502611A JP50261184A JPS60501814A JP S60501814 A JPS60501814 A JP S60501814A JP 59502611 A JP59502611 A JP 59502611A JP 50261184 A JP50261184 A JP 50261184A JP S60501814 A JPS60501814 A JP S60501814A
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Prior art keywords
composition
weight
lubricating
substance
substances
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Granted
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JP59502611A
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Japanese (ja)
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JPH0251960B2 (en
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ヘス デイ−セルム
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Individual
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Publication of JPS60501814A publication Critical patent/JPS60501814A/en
Publication of JPH0251960B2 publication Critical patent/JPH0251960B2/ja
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02Petroleum fractions
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/10Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M105/12Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms monohydroxy
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32Esters
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/56Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
    • C10M105/68Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/04Polyethene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34Polyoxyalkylenes
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/50Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/16Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/04Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing propene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M155/00Lubricating compositions characterised by the additive being a macromolecular compound containing atoms of elements not provided for in groups C10M143/00 - C10M153/00
    • C10M155/02Monomer containing silicon
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/02Natural products
    • C10M159/06Waxes, e.g. ozocerite, ceresine, petrolatum, slack-wax
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • C10M2201/102Silicates
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14Synthetic waxes, e.g. polythene waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/283Esters of polyhydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02Unspecified siloxanes; Silicones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/055Particles related characteristics
    • C10N2020/06Particles of special shape or size
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/46Textile oils
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10Semi-solids; greasy

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。 (57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 潤 滑 剤 本発明は、多成分潤滑剤組成物に係るものである。[Detailed description of the invention] lubricant The present invention relates to multicomponent lubricant compositions.

既知の潤滑剤は、一般に異なった等級の鉱油の配合物より成るものである。この 種の材料は水に熔けないが、例えばグリースのついたトレーラ−の連結器や自動 車のドアロック等を扱っている時に、潤滑剤が織物に触れてそれを汚すことがよ くある。全く潤滑されない器具があるのは、多くの場合潤滑剤の汚す効果が原因 であった。なぜなら、例えば衣服に縫い付けたジッパ−は、長時間経つうちには 堅くなりがちであることは経験していることであるからであり、そうならなけれ ばこのような潤滑は望ましいものである。既知の潤滑剤による汚れを落とすには 、通常潤滑剤のついた織物を溶剤その他の組成物で処理しなければならない。こ れは面倒かつ高価であるので、不利と考えられる。Known lubricants generally consist of a blend of different grades of mineral oil. this Although the seed material is not soluble in water, it can be used, for example, in greased trailer hitches or automatic When handling items such as car door locks, the lubricant may come into contact with the fabric and stain it. There are many. The fact that some instruments never get lubricated is often due to the dirtying effects of lubricants. Met. This is because, for example, a zipper sewn onto clothing can become It is our experience that we tend to become stiff, and we must become stiff. A cigarette-like lubrication is desirable. To remove stains from known lubricants , usually requiring treatment of the lubricated fabric with a solvent or other composition. child This is considered a disadvantage as it is cumbersome and expensive.

この点を考慮して、本発明の目的は、水で織物から洗い落とすことのできる潤滑 剤を創り出すことにある。With this in mind, the object of the invention is to provide a lubricant that can be washed off from textiles with water. The goal is to create a drug.

本発明によれば、この目的は、水溶性ビヒクル物質より成り、かつそれに少なく とも一つの潤滑物質を細かく分散した状態で混入した潤滑剤組成物を用いて驚く ほど簡単に達成される。この水溶性ビヒクル物質は、潤滑剤の重量の75〜95 %で、その重量の残部は混入した潤滑物質より成っている。According to the invention, this purpose consists of a water-soluble vehicle substance and at least We are surprised by the use of a lubricant composition containing a finely dispersed lubricant substance. easily achieved. The water-soluble vehicle material contains 75 to 95% of the weight of the lubricant. %, the remainder of its weight being made up of mixed lubricating substances.

潤滑剤の重量割合の大部分を占めるビヒクルが水に可溶であることにより、存在 する割合が少量にすぎない潤滑物質を水を使って織物から洗い落とすことができ る。潤滑物質は、それらの重量割合が少ないので、痕跡やじみを残さないでほぼ 洗い流される。The presence of Water can be used to wash away lubricating substances, which are present in only a small proportion, from textiles. Ru. Lubricating substances, due to their small weight percentage, can be used almost without leaving traces or smearing. Washed away.

このため、織物を溶剤等の清浄用組成物で処理しなくてもよいという利点がある 。試験でわかったように、一般的に通常織物を水で゛洗えば充分である。This has the advantage that the fabric does not need to be treated with cleaning compositions such as solvents. . As tests have shown, it is generally sufficient to wash ordinary fabrics with water.

本発明による潤滑剤組成物の更に有用な効果は、織物及び一般に樹脂製であるジ ッパ−のようなそれに取り付けたファスナーが、概して潤滑剤によって侵されな いことである。それが、更に有用な効果として、衣服に取り付けたジッパ−や他 の器具のファスナーを潤滑するため、それらが長時間の間に堅くならず実際常に 使いやすく、また寿命を長くすることができるようになる理由である。以前はこ れができなかった。本発明の潤滑剤の更に一つの用途は、カーテン用のランナー あるいはそれに用いられるくぼんだレールである。しかし、この潤滑剤は更に、 例えば自動車のロックやトレーラ−の連結器のような織物とよく接触、しがちな 機械部品に用いると有益であり、従来の潤滑剤を用いていた今までの場合よりも 汚れによる不都合がずっと少な(なる。本発明によって得られる有用な効果は、 特に著しい節約がなされる点に見られるであろう。A further advantageous effect of the lubricant composition according to the invention is that it Fasteners attached to it, such as zippers, are generally not attacked by lubricants. That's a good thing. This has an even more useful effect on zippers attached to clothing, etc. Lubricates the fasteners of the appliances so that they do not become stiff over time and in fact always This is why it is easy to use and has a long service life. Previously this I couldn't do it. A further application of the lubricant of the present invention is for curtain runners. Or the recessed rails used for it. However, this lubricant also For example, it often comes into contact with textiles such as car locks and trailer hitches. Beneficial for use on mechanical parts, compared to traditional lubricants. There are far fewer inconveniences due to dirt.The useful effects obtained by the present invention are: Particularly significant savings will be made.

本発明の更に発展の一部として、粒子(particle)または球体の大きさ の異なる一つ以上の潤滑物質をビヒクルに混入したものがある。粒子の大きさが 違うので極めて満足な潤滑性が得られる。As part of a further development of the invention, the particle or sphere size Some lubricants have one or more lubricating substances mixed into the vehicle. particle size Because of this difference, extremely satisfactory lubricity can be obtained.

本発明の中心の考えからなお更に発展した一部として、このビヒクルは、モノヒ ドロキシ・アルコールまたはポリヒドロキシ・アルコールおよび/またはそれに 相応するエーテルおよび/またはそれに相応するエステルとすることができる。As part of a still further development of the central idea of the invention, this vehicle Droxy alcohol or polyhydroxy alcohol and/or It can be the corresponding ether and/or the corresponding ester.

試験によって、ポリエチレン・グリコールがビヒクルとして一層好ましいことが 明らかになった。このようなビヒクルは、広範囲の温度に耐えるとともに潤滑物 質を混入することのできる安定な構造を提供するという、有利な効果があ多。さ らに粘度は、分子量だけが異なる多数の異なった形状の同じビヒクルの一つを選 択することによって、容易に調整することができる。試験の結果、平均分子量5 00のものが物性すなわちコンシステンス(c’onsistence )が軟 膏と似ており、特に便利であることが明らかになった。分子量と融点が異なる多 数の異なった等級の同じ成分を配合することによって、軟化点や溶融点の範囲を 広くすることができる。これは、同時に小さい温度変化によってビヒクルがその 性質を急激に失わないように保証を与えるものであり、従って本発明による潤滑 剤には広い分野の応用が開かれている。Testing has shown that polyethylene glycol is more preferred as a vehicle. It was revealed. Such vehicles can withstand a wide range of temperatures and provide lubricating properties. This has the advantageous effect of providing a stable structure that can be mixed with other materials. difference Furthermore, viscosity is determined by selecting one of many different forms of the same vehicle that differ only in molecular weight. It can be easily adjusted by selecting the As a result of the test, the average molecular weight was 5. 00 has a soft physical property, i.e. consistency (c’consistence). It is similar to a plaster and has proven to be particularly useful. Polymers with different molecular weights and melting points By blending different grades of the same ingredients, the range of softening and melting points can be varied. Can be made wider. This is because at the same time a small temperature change causes the vehicle to This provides a guarantee that the lubrication according to the invention does not suddenly lose its properties. The agent has a wide range of applications.

本発明の更に有用な発展によれば、この潤滑剤はポリエチレン・ワックス、エス テル・ワックスあるいはアミド・ワックスのよこの種の材料は、それらの粒子の 形状と大きさのために、水をさヮとかけることによって容易に織物から洗い落と したり取り去ることができる。同時に、約150℃までの温度で安定という有用 な効果があるため、広い異なった温度範囲にわたって潤滑剤を用いることができ る。潤滑剤を高温で用いる場合にはワックスの若干またはすべてをケイ酸5iO 1nH20に置き換えて、ビヒクルの温度安定性によりいっそう有益な効果が得 られるようにすることができる。According to a further advantageous development of the invention, the lubricant is made of polyethylene wax, Materials of this type, such as tell wax or amide wax, are Because of its shape and size, it can be easily washed off fabrics by splashing water. can be added or removed. At the same time, it is useful because it is stable at temperatures up to about 150℃. The lubricant can be used over a wide range of different temperatures due to its Ru. If the lubricant is used at high temperatures, some or all of the wax may be replaced with 5iO silicate. 1nH20, a more beneficial effect due to the temperature stability of the vehicle. You can make it possible to

本発明の主な考えのなお更に発展の一部として、少なくとも一つの潤滑物質を脂 肪酸および/またはそれのエステルおよび/またはそれのアミドの形とすること ができる。この種の物質は、それらの粒子の形と大きさのために、ワックスと共 に使用する補助剤として非常に有用と考えられている。As part of a still further development of the main idea of the invention, at least one lubricating substance is lubricated. fatty acids and/or their esters and/or their amide forms; Can be done. This type of substance, due to the shape and size of their particles, is similar to wax. It is considered to be very useful as an adjuvant for use in

本発明の更に可能な特徴は、少なくとも一つの潤滑物質がポリシロキサンの形で あることである。このような潤滑物質を用いれば、必要な潤滑物質の総量はほん の少しでよいため、容易に洗い流せるビヒクルの割合が大きくなり、潤滑剤を洗 い流すのがより容易になる。A further possible feature of the invention is that the at least one lubricating substance is in the form of a polysiloxane. It is a certain thing. Using such lubricants, the total amount of lubricants required is only a small amount. Because only a small amount of the lubricant is It becomes easier to wash away.

本発明の更に有用な発展と派生は、請求の範囲と以下に述べる本発明の実施例に ついての説明によって明らかにされる一岬I 長時間の間にジンパーが堅くなるため、使いにくくまた速く摩耗することは、一 般に知られている。これは、適切な潤滑剤で潤滑することによってそうならない ようにすることができる。この目的のための試験に用いた潤滑剤は、ポリエチレ ン・グリコール80重量%、ポリエチレン・ワックス10重量%、エルカミド( erucamid) 10重量%より成るものである。この場合、ポリエチレン ・グリコールはビヒクルを形成し、その中にポリエチレン・ワックスとエルカミ ドが細かく分散した状態で混入されるが、これは標準的な圧力と標準的な温度の 下で撹拌によって行われる。Further useful developments and derivations of the invention can be found in the claims and the embodiments of the invention described below. Ichimisaki I revealed by the explanation of Over time, the jimper becomes stiff, difficult to use, and wears out quickly. Generally known. This can be prevented by lubrication with a suitable lubricant. You can do it like this. The lubricant used in the tests for this purpose was 80% by weight polyethylene glycol, 10% by weight polyethylene wax, erucamide ( erucamide) 10% by weight. In this case, polyethylene ・Glycol forms a vehicle in which polyethylene wax and erucami The particles are mixed in in a finely dispersed state, but this is done under standard pressure and temperature. This is done by stirring below.

ポリエチレン・グリコールの平均分子量は500である。それのコンシスチンシ イ(consistency )すなわち物理的性状は、軟膏に似ているため、 ブラシや小さい刃を使って全く均等に塗ることができる。その平均分子量は、異 なった等級の200〜10,000の範囲の異なった分子量をもつポリエチレン ・グリコールを配合して得たものである。その溶融範囲は高かった。150 ° のオーダーの温度においても、ビヒクルとして用いたポリエチレン・グリコール はその性質を失わなかった。この例では、温度の上限はポリエチレン・ワックス によって可能になった。すなわち、それが熱の影響に最もよく耐えたのである。The average molecular weight of polyethylene glycol is 500. its consistency Consistency, or physical properties, are similar to ointment. It can be applied perfectly evenly using a brush or small blade. Its average molecular weight is polyethylene with different molecular weights ranging from 200 to 10,000 ・It is obtained by blending glycol. Its melting range was high. 150° Even at temperatures on the order of has not lost its character. In this example, the upper temperature limit is the polyethylene wax made possible by. That is, it best withstood the effects of heat.

耐熱性を増すために、そのワ・7クスの全部又は一部をケイ@Sig、nHユ0 に1き換えるとよいかもしれな、い。To increase heat resistance, all or part of the wax It might be a good idea to change it to 1.

長時間にわたって本発明の潤滑剤について試験を行った結果、合成樹脂製のジッ パ−もそれに隣接した人造及び天然繊維製の織物も、どちらもこれによって浸さ れないことがわかった。故意に織物の材料につけた潤滑剤の斑点は、水道栓の水 を使って痕跡を残さず完全に洗い流すことができた。水は約45°Cに加熱する と特に効果的である。As a result of long-term testing of the lubricant of the present invention, synthetic resin zipper Both the par and adjacent fabrics made of man-made and natural fibers are soaked by this. I found out that it doesn't work. Spots of lubricant intentionally placed on textile materials can be removed by water from a tap. I was able to completely wash it off without leaving any traces. Heat the water to approximately 45°C is particularly effective.

この新規な/lI滑剤で潤滑したジノバーは、非常に滑りが自由であった。詰ま ったあるいは堅いジノパーも、この潤滑剤で潤滑ず! れば、極めて短時間に非常に自由に滑るようになった。この効果は、ポリエチレ ン・ワックスとエルカミドの場合は、好適な粒子の大きさと形状に起因する。分 散の状態または粒子の大きさがポリエチレン・ワックスとエルカミドとの中間の 程度であるケイ酸を加えることによって、この点に関してなお更に向」二が見ら れた。形状が適当であるとわかったケイ酸は、エアロシル(Aerosil、登 録商標)(極微小発熱性シリカ)という商品名でデグノサインコーボレーテ・7 ド(Degussa Inc、)が販売しているものであった。Zinovar lubricated with this new /lI lubricant was very free to slide. clog Use this lubricant to lubricate even dry or hard surfaces! In a very short period of time, he was able to skate very freely. This effect is similar to polyethylene In the case of wax and erucamide, this is due to the suitable particle size and shape. minutes The powder state or particle size is between that of polyethylene wax and Erucamide. Still further improvements in this regard can be seen by adding a certain amount of silicic acid. It was. Silicic acid, which was found to have a suitable shape, was manufactured by Aerosil. Degnosign Cobolete 7 is available under the trade name (registered trademark) (ultrafine pyrogenic silica). It was sold by Degussa Inc.

ゲイ酸の添加量は約2〜3重量%であり、同量のポリエチレン・ワックスが置き 換えられた。The amount of gay acid added is approximately 2-3% by weight, and the same amount of polyethylene wax is placed. It was replaced.

例■ ポリエチレン・グリコール90重量%、ポリエチレン・ワックス9.8重量%、 シリコン・オイル0.2重量%より成る潤滑剤の平行した長期試験で、例Iと同 じ有用な機能的効果が見られたが、例Iの場合よりも潤滑剤を洗い落とすのが一 層簡単であった。これは、ビヒクルの割合がより高いことに起因するが、これは シリコン・オイルを使うことによって可能になったのである。例■の配合の場合 にも、ワックスの1部又は全部をケイ酸と置き換えるこさて、図に示すようなジ ッパ−のような帯状またはレール様の構造物の潤滑についての本発明の好ましい 実施例について説明する。Example ■ Polyethylene glycol 90% by weight, polyethylene wax 9.8% by weight, A parallel long-term test of a lubricant consisting of 0.2% by weight silicone oil showed the same results as in Example I. The same useful functional effects were seen, but the lubricant was easier to wash off than in Example I. The layers were easy. This is due to the higher proportion of vehicle, which This was made possible by using silicone oil. Example: For the combination of ■ It is also possible to replace part or all of the wax with silicic acid, as shown in the figure. Preferred embodiments of the present invention for the lubrication of strip-like or rail-like structures such as railcars An example will be explained.

図Gこ見られる潤滑装置は、穴(2)をあけた壁(3)によって塗布ローラ(5 )を収容する作業スペース(4)から分離されており、かつ塗布ローラの回転軸 に垂直に延びる入口スロット(6)を有する潤滑剤用収容スペース(1)を有す るものである。材料(9)の帯片に固定されたジッパ−(スライド・ファスナー )(7)を動かずのは、このスロットを通してである。塗布ローラー(5)は、 ブラシの形で造られれば最良であるが、それが穴(2)をあけた壁をこすりある いはブラシがけをするとともに、穴から出てくる潤滑剤を取り出すような大きさ と位置にし、従ってスロット(6)に置かれたあらゆる物、この場合はジッパ− (7)に潤滑剤を押し付けあるいは拭って、それが潤滑されるようにする。塗布 ローラー(5)は、それに接線方向に触れるジッパ−(7)によって回転される 。The lubricating device seen in Figure G is connected to the applicator roller (5) by means of a wall (3) with holes (2). ) and is separated from the working space (4) containing the a lubricant receiving space (1) with an inlet slot (6) extending perpendicular to the It is something that Zipper (slide fastener) fixed to strip of material (9) )(7) is not moved through this slot. The application roller (5) is It is best if it is made in the form of a brush, which rubs against the wall in which the hole (2) is made. In addition to brushing, it is also large enough to take out the lubricant coming out of the hole. and therefore any object placed in the slot (6), in this case the zipper. (7) Press or wipe lubricant on to ensure it is lubricated. coating The roller (5) is rotated by the zipper (7) touching it tangentially .

塗布ローラー(5)を回転できるようにその中に置きかつ支持した作業スペース (4)は、穴をあけた壁(3)のある頑丈なハウジング(11)中に設けられ、 さらにそこに収容スペース(1)のあるハウジング(14)は、ハウジング(1 1)の上に嵌合あるいは螺合される。ハウジング(14)は、単にゴム様の壁の 屈曲可能な管あるいはガラスびんの形とし、その中の潤滑剤が容易にしぼり出さ れるようにする。しかし、なおバネやネジで作動するピストンを設けることも可 能である。この場合は、望まれる時に潤滑ことのないような横断面とする。a working space in which the applicator roller (5) is rotatably placed and supported; (4) is provided in a sturdy housing (11) with a perforated wall (3); Furthermore, the housing (14) in which the accommodation space (1) is located is 1) is fitted or screwed onto. The housing (14) is simply made of rubber-like walls. Shaped as a bendable tube or glass bottle, from which the lubricant can be easily squeezed out. make it possible to do so. However, it is still possible to provide a piston operated by a spring or screw. It is Noh. In this case, the cross section should be such that it does not lubricate when desired.

国際調査報へGo to international research report

Claims (1)

【特許請求の範囲】[Claims] 1.水溶性ビヒクルと該ビヒクルに含まれた少なくとも一つの潤滑物質より成る 潤滑性の物質の組成物であって、該水溶性ビヒクルが該物質の組成物の75〜9 5重量%を占め、残部は少なくとも一つの潤滑物質であることを特徴とする組成 物。 2、潤滑物質を一つ以上含む請求の範囲第1項に記載の物質の組成物において、 そのような複数の潤滑物質が、該組成物中の一つの潤滑物質の粒子が該組成物中 のもう一つのそのような物質のものと粒子の大きさの点で異なるような粒子の形 で存在している組成物。 3、該ビヒクルが大体、−価アルコール、多価アルコール、そのようなアルコー ルから誘導されたエーテル、そのようなアルコールのエステルより成る群から選 ばれる前記請求の範囲のいずれかに記載の物質の組成物。 4、該ビヒクルがポリエチレン・グリコールである請求の範囲第3項に記載の物 質の組成物。 5、該ビヒクルが分子量500のポリエチレン・グリコールである請求の範囲第 4項に記載の物質の組成物。 6、少なくとも一つの潤滑物質がワックスである前記請求の範囲のいずれかに記 載の物質の組成物。 7、少なくとも一つの潤滑物質がポリエチレン・ワックスの形である請求の範囲 第6項に記載の物質の組成物。 8、大体、脂肪酸、脂肪酸のエステル、脂肪酸のアミドより成る群から選ばれた 少なくとも一つの潤滑物質を含む前記請求の範囲のいずれかに記載の物質の組成 物。 9、少なくとも一つの潤滑物質がエルカミドの形である請求の範囲第8項に記載 の物質の組成物。 10、少なくとも一つの潤滑物質がポリシロキサンの形である前記請求の範囲の いずれかに記載の物質の組成物。 11、少なくとも一つの潤滑物質がシリコン・オイルの形である請求の範囲第1 0項に記載の物質の組成物。 12、大体、分子量500のポリエチレン・グリコール80重量部と、ポリエチ レン・ワックスとエルカミド各々10重量部より成る前記請求の範囲のいずれか に記載の物質の組成物。 13、大体、分子量500のポリエチレン・グリコール90重量部、ポリエチレ ン・ワックス9.8重量部、シリコン・オイル0.2重量部より成る前記請求の 範囲第1項ないし第11項のいずれかに記載の物質の組成物。 14、少なくとも一つの潤滑物質がケイ酸の形である前記請求の範囲のいずれか に記載の物質の組成物。 15、ケイ酸が2〜3重量%で、ワックスの量がそれに相応して減少している請 求の範囲第14項に記載の物質の組成物。 16、織物に接続された取付具、特に、衣服に縫い付けたジッパ−にそれを用い ることを特徴とする請求 の組成物。1. Comprising a water-soluble vehicle and at least one lubricant contained in the vehicle A composition of lubricating material, wherein the water-soluble vehicle comprises 75 to 9 of the composition of the material. 5% by weight, the remainder being at least one lubricating substance thing. 2. The composition of the substance according to claim 1, which contains one or more lubricating substances, Such a plurality of lubricating substances may include particles of one lubricating substance in the composition. a particle shape that differs in particle size from that of another such substance Compositions present in. 3. The vehicle is generally a -hydric alcohol, a polyhydric alcohol, such alcohol. ethers derived from alcohols, esters of such alcohols; A composition of matter according to any of the preceding claims, wherein: 4. The product according to claim 3, wherein the vehicle is polyethylene glycol. quality composition. 5. Claim No. 5, wherein the vehicle is polyethylene glycol with a molecular weight of 500. Composition of substances according to item 4. 6. According to any of the preceding claims, wherein the at least one lubricating substance is wax. Composition of substances listed above. 7. Claims in which at least one lubricating substance is in the form of polyethylene wax A composition of matter according to paragraph 6. 8. Generally selected from the group consisting of fatty acids, fatty acid esters, and fatty acid amides. A composition of matter according to any of the preceding claims comprising at least one lubricating substance. thing. 9. According to claim 8, the at least one lubricating substance is in the form of erucamide. composition of matter. 10. According to the preceding claims, the at least one lubricating substance is in the form of a polysiloxane. A composition of substances according to any of the above. 11. Claim 1, wherein the at least one lubricating substance is in the form of silicone oil. A composition of matter according to item 0. 12. Approximately 80 parts by weight of polyethylene glycol with a molecular weight of 500 and polyethylene Any of the preceding claims comprising 10 parts by weight each of Ren Wax and Erucamide. Composition of the substances described in . 13. Approximately 90 parts by weight of polyethylene glycol with a molecular weight of 500, polyethylene 9.8 parts by weight of wax and 0.2 parts by weight of silicone oil. A composition of substances according to any one of the ranges 1 to 11. 14. Any of the preceding claims, wherein the at least one lubricating substance is in the form of silicic acid. Composition of the substances described in . 15, silicic acid is 2-3% by weight, and the amount of wax is reduced accordingly. A composition of the substance according to claim 14. 16. Its use in attachments connected to textiles, especially zippers sewn into garments. A claim characterized by Composition of.
JP59502611A 1983-07-07 1984-07-03 lubricant Granted JPS60501814A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3324475.8 1983-07-07
DE19833324475 DE3324475A1 (en) 1983-07-07 1983-07-07 LUBRICANT

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Publication Number Publication Date
JPS60501814A true JPS60501814A (en) 1985-10-24
JPH0251960B2 JPH0251960B2 (en) 1990-11-09

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ID=6203368

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JP59502611A Granted JPS60501814A (en) 1983-07-07 1984-07-03 lubricant

Country Status (4)

Country Link
EP (1) EP0148232B1 (en)
JP (1) JPS60501814A (en)
DE (2) DE3324475A1 (en)
WO (1) WO1985000378A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9227058D0 (en) * 1992-12-29 1993-02-24 Castrol Ltd Lubricant
DE19502559C2 (en) * 1995-01-27 1997-01-09 Zeller & Gmelin Gmbh & Co Use of completely washable, biodegradable needle and board oils based on water-soluble polyglycols
US6878677B1 (en) * 1999-03-05 2005-04-12 Idemitsu Kosan Co., Ltd. Refrigerating machine oil compositions
US6855676B2 (en) 2002-02-11 2005-02-15 Ecolab., Inc. Lubricant for conveyor system

Citations (2)

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Publication number Priority date Publication date Assignee Title
GB1406491A (en) * 1971-06-29 1975-09-17 Rotta G Chem Fab Theodor Rotta Medium and process for the treatment of threads and yarn
JPS5523147A (en) * 1978-08-09 1980-02-19 Hitachi Ltd Lubricant for plastic working

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3491854A (en) * 1967-03-27 1970-01-27 Benjamin D Baxter Slide fastener lubricator

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1406491A (en) * 1971-06-29 1975-09-17 Rotta G Chem Fab Theodor Rotta Medium and process for the treatment of threads and yarn
JPS5523147A (en) * 1978-08-09 1980-02-19 Hitachi Ltd Lubricant for plastic working

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EP0148232B1 (en) 1988-10-26
JPH0251960B2 (en) 1990-11-09
WO1985000378A1 (en) 1985-01-31
DE3324475A1 (en) 1985-01-17
DE3474836D1 (en) 1988-12-01

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