JPS6047636A - Enrichment of soya milk with calcium - Google Patents

Enrichment of soya milk with calcium

Info

Publication number
JPS6047636A
JPS6047636A JP58154778A JP15477883A JPS6047636A JP S6047636 A JPS6047636 A JP S6047636A JP 58154778 A JP58154778 A JP 58154778A JP 15477883 A JP15477883 A JP 15477883A JP S6047636 A JPS6047636 A JP S6047636A
Authority
JP
Japan
Prior art keywords
calcium
soya milk
compound
milk
propylene glycol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58154778A
Other languages
Japanese (ja)
Inventor
Shuzo Shimoyama
下山 修三
Kazumi Akaike
赤池 和美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kawasaki Kasei Chemicals Ltd
Original Assignee
Kawasaki Kasei Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Kasei Chemicals Ltd filed Critical Kawasaki Kasei Chemicals Ltd
Priority to JP58154778A priority Critical patent/JPS6047636A/en
Publication of JPS6047636A publication Critical patent/JPS6047636A/en
Pending legal-status Critical Current

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  • Dairy Products (AREA)
  • Beans For Foods Or Fodder (AREA)

Abstract

PURPOSE:To obtain a calcium-enriched soya milk, without causing coagulation, by adding a calcium compound to a soya milk in the presence of glycerol or propylene glycol. CONSTITUTION:Soybeans are treated with hot water, etc. to dissolve proteins and other components and remove fibrous material therefrom to obtain a soya milk. The obtained soya milk is added with glycerol or propylene glycol, and then with an water-soluble and edible calcium compound to obtain a calcium- enriched soya milk. The calcium compound is an organic acid calcium salt (e.g. calcium malate, calcium lactate, etc.) or an inorganic acid calcium salt (e.g. calcium chloride). The amount of glycerol or propylene glycol is preferably about equimolar to the calcium in the calcium compound added to the soya milk.

Description

【発明の詳細な説明】 本発明は、豆乳のカルシウム強化方法に関する。[Detailed description of the invention] The present invention relates to a method for fortifying soymilk with calcium.

日本は火山国であるために、土壌にはミネラル分、特に
カルシウムの含有量が外国に比べて低い。従って、野菜
などに含まれるカルシウムの含有量も外国より低い。ま
た最近は、日本の食生活の洋風化が著しく進み、肉食が
普及したために体内のカルシウムがtP4¥1される。
Because Japan is a volcanic country, its soil has a lower mineral content, especially calcium, than in other countries. Therefore, the calcium content in vegetables is also lower than in other countries. Recently, the Japanese diet has become much more Westernized, and meat consumption has become widespread, resulting in the amount of calcium in the body being reduced to 4 yen per tP.

一般の加工食品にもリン酸塩が多く使用され、さらに飴
、菓子類の摂取量も増大しやはり体内のカルシウムを消
費する。このことが最近の骨折の増加にも現れている。
A large amount of phosphate is used in general processed foods, and the intake of candy and sweets also increases, which consumes calcium in the body. This is also reflected in the recent increase in fractures.

このことにより、あらゆる食品からカルシウムを補給す
る必要性が生している。
This has created a need to supplement calcium from all foods.

豆乳には、通常カルシウムとして約14mg/ l0h
Lか含フ↑:れていない(日本食品標準成分表)ので、
豆乳にカル、・・ラムを強化することが永年の課題であ
った。通常、q7L7こカルシウムを添加する場合、最
大で28mB%迄であうことが開示されている(特開昭
57−208966号公till)。これ1.11カル
、ノウムイオンの蛋白凝固作用によって豆乳が凝固ちる
ため、豆乳のカルシウム強化は実質的に豆乳の全カルノ
ウノ・呈として40mg%位しか実施することができな
かった。
Soy milk usually contains about 14 mg/l0h of calcium.
Contains L or F ↑: Not included (Japanese Food Standard Composition Table),
It has been a long-standing challenge to strengthen soymilk, cal, and rum. It is disclosed that when q7L7 calcium is added, the amount is usually up to 28 mB% (Japanese Patent Application Laid-Open No. 57-208966 till). Because the soymilk coagulates due to the protein coagulation effect of the 1.11 calcium ions, soymilk can only be fortified with calcium by approximately 40 mg% of the total calcium content of soymilk.

本発明者らは、これらの欠点を解決するために鋭、α検
ajの結果、豆乳に金属イオン封鎖剤としてグリレリン
又11プロピレングリコールを存在させ、リンゴ酸カル
ンウJ、 、?l乳酸カルシウム等のカルシウム化合物
を添加するとい)筒便な方法によって、豆乳の全カルシ
ウム量を約50m(H% IJ、 −j: ’3ji化
する方法を見出し本発明を完成した。
In order to solve these shortcomings, the present inventors conducted a thorough investigation and found that glycerin or 11-propylene glycol was present in soybean milk as a sequestering agent, and malic acid was added to the soybean milk. The present invention was accomplished by discovering a method for reducing the total calcium content of soy milk to about 50 m (H% IJ, -j: '3ji) by a convenient method (adding a calcium compound such as calcium lactate).

本発明において、グリセリン又はプロピレングリ−1−
ルの使用量はカルシウム化合物に含まれるカルシウムを
JJI 、1にして0.6モル倍以上、好ましくは0.
6〜3.0Tニル1韻通品は約当モル倍から選ばれる。
In the present invention, glycerin or propylene glycerin-1-
The amount of calcium to be used is at least 0.6 times the calcium contained in the calcium compound based on JJI, 1, preferably 0.6 mole or more.
A product containing 6 to 3.0T nil is selected from about twice the equivalent mole.

グリセリン又はプロピレングリコールは過剰すぎても効
果はなく、経路的で1.1)、rい。
Glycerin or propylene glycol has no effect if used in excess;

なお、グリセリン又はプロピレングリコールし、1、シ
ープガーエステル等の通常用いられるポリオールよりり
1児がある。
It should be noted that glycerin or propylene glycol is more useful than commonly used polyols such as 1 and Schiepgar ester.

本発明に使用し得るカルシウム化合物番J、食用がii
J能ζあり、水溶性のものが好ましく、原則として有聞
又GJ無間の化合物であってもよい。特に、塩類が好ま
しい。有機の化合物としては、例えばリンゴ酸、乳酸、
グJl−XIン酸、n1酸等の有機酸のカルシウム塩が
あげられる。無機の化合物としては、例えば塩化カルシ
ウム、硫酸カルシウム等の無機酸のカルシウム塩があげ
られる。
Calcium compound number J that can be used in the present invention, edible is ii
It is preferable to use a water-soluble compound having J-potency ζ, and in principle, it may be a compound having a monotonous or a GJ-mugen. Particularly preferred are salts. Examples of organic compounds include malic acid, lactic acid,
Examples include calcium salts of organic acids such as phosphoric acid and n1 acid. Examples of the inorganic compound include calcium salts of inorganic acids such as calcium chloride and calcium sulfate.

炭酸力ルシウJ、等の不溶性の化合物を使用する場合は
、グリセリンの存在している豆ILに炭酸力ルシウJえ
と上記の塩に対応する有機又は無機の酸を添加し溶解さ
−H,pHを所定の値(例えば6〜8)に調整すること
も可能である。
When using an insoluble compound such as carbonic acid, add an organic or inorganic acid corresponding to the above salt to the bean IL in which glycerin is present and dissolve it at -H, pH. It is also possible to adjust to a predetermined value (for example, 6 to 8).

本発明において豆乳とは、例えば一般に規格化されてい
るような豆乳、即ちΦ大豆から熱水等により、蛋白その
他の成分を溶出させ、繊維物質を除去して得られる乳状
の飲料で、大豆固形分8%以上の大豆豆乳液、■大豆豆
乳であり、大豆固形分が6%以上8%未満:大豆豆乳に
大豆油その他の植物油脂及び糖類、食塩等の調味料を加
えた乳状の飲料のもので、大豆固形分が6%以上;脱脂
大豆から熱水等により、蛋白その他の成分を流出させ、
繊維質を除去してえられるものに、大豆油その他の植物
油、糖類、食塩等の調味料を加えた乳状の飲料で、大豆
固形分が6%以上のいわゆる開整豆乳■豆乳又は調整豆
乳に果実、野菜等の搾汁、穀類、乳等の風味原料を加え
た飲料であって、大豆固形分2シロ以上、かつ、風味原
料の固形分が2%未満のいわゆる豆乳飲料があげられる
In the present invention, soy milk is a milky beverage obtained by eluating proteins and other components from Φ soybeans with hot water and removing fiber substances, for example, generally standardized soy milk. Soybean milk liquid with a content of 8% or more, soybean milk with a soybean solid content of 6% or more and less than 8%: A milky drink made by adding soybean oil, other vegetable oils, and seasonings such as sugar and salt to soybean milk. The solid content of soybeans is 6% or more; proteins and other components are washed out from defatted soybeans using hot water, etc.
It is a milky beverage obtained by removing the fiber and adding seasonings such as soybean oil and other vegetable oils, sugars, and salt, and is a so-called open soymilk with a soybean solid content of 6% or more.Soymilk or modified soymilk Examples include soybean milk drinks, which are beverages containing flavor materials such as squeezed fruit, vegetable juice, cereals, milk, etc., and have a soybean solid content of 2 or more and a flavor material solid content of less than 2%.

本発明において、グリセリン又はプロピレンリコール及
びカルシウム化合物を含有せしめる豆乳としては、上記
の大豆豆乳液、調整豆乳又は豆乳飲料のいずれであって
もよい。又、大豆磨砕抽出液を用いてもよい。
In the present invention, the soybean milk containing glycerin or propylene recall and a calcium compound may be any of the above-mentioned soybean milk liquid, adjusted soymilk, or soymilk beverage. Alternatively, a ground soybean extract may be used.

カルシウム化合物を添加する場合、その方法としこは、
わ)体、スラリー又は要すれば液状での添加のいずれで
あってもよいが、添加に際しては急激な面も局13的な
添加をさけるため、豆乳を攪t↑しながら徐々に添加す
るのが好まし・い。添加後は豆乳の品質を安定化さ−U
乙ためにホむゲノ“・イザー等により均質化する必要が
ある。
When adding calcium compounds, the method and method are as follows:
(b) It may be added in the form of soybean milk, slurry, or if necessary, in liquid form, but in order to avoid sudden or sudden addition, it is best to add it gradually while stirring the soymilk. is preferable. After addition, the quality of soy milk is stabilized-U
For this reason, it is necessary to homogenize by using homogeno, iser, etc.

大豆に砕抽出液を使用する場合には、約1〜4%のi+
I+ JIff類、ンユガーエステル・レンチン等の乳
IE 7III 、砂1乃 果糖等の糖類、食塩、麦芽
エキス、蜂蜜、ビタミン、へ゛オ′1等の副原料を加え
、得られる製品を常法により短時間殺菌処理する等の必
要な手段を予め実施するのが好ましい。
When using crushed extract for soybeans, approximately 1-4% i+
Add auxiliary raw materials such as I + JIff, milk IE 7III such as sugar esters and lentin, sugars such as sand 1 or fructose, salt, malt extract, honey, vitamins, and helio'1, and boil the resulting product in a short time by a conventional method. It is preferable to carry out necessary measures such as sterilization treatment in advance.

カルシウム化合物の添加量は、カルシウム、イオンとし
ζ一般に約50mg%以下、好ましくは約45mg%以
下、さらにbrましくは約45mg%以下であり、通常
は10m1%以ト好ましくは30m8%以上、さらに好
ましくは35mg%以」二である。
The amount of calcium compound added is generally about 50 mg% or less, preferably about 45 mg% or less, more preferably about 45 mg% or less, and usually 10 m1% or more, preferably 30 m8% or more, and Preferably it is 35 mg% or more.

しかして、本発明は極めて節Wな方法にd、っ゛ζ凝隼
を起さずに従来より豆乳のカルシウムを強化することの
幼31!:を奏することができる。
Therefore, the present invention provides an extremely economical way to fortify the calcium content of soy milk without causing curdling. : can be played.

以下、実施例により本発明の詳細な説明する。Hereinafter, the present invention will be explained in detail with reference to Examples.

実施例 1 調整豆乳(三菱化成株式会社rM:マプロン・スル−1
)1001111をビーカーに採り、室温下で、グリセ
リンの所定量及びカルシウム化合物としてリンゴ酸カル
シウム又lJ: 7L mカルシウムの所定量をlit
 11:しながら添加し、均質化したのち、70’cま
で昇温し、同温度の恒温槽で静置し、蛋白の凝固状態を
観察した。その結果を、第1表に示す。
Example 1 Adjusted soymilk (Mitsubishi Kasei Corporation rM: Mapron Sulu-1
) 1001111 in a beaker, and at room temperature add a predetermined amount of glycerin and a predetermined amount of calcium malate or calcium as a calcium compound.
11: After adding while stirring and homogenizing, the temperature was raised to 70'C, left standing in a constant temperature bath at the same temperature, and the coagulation state of the protein was observed. The results are shown in Table 1.

第 1 表 *カルシウムイオンとしての量。Table 1 *Amount as calcium ions.

注、−:凝集が認められない。Note: -: No aggregation observed.

+:凝集気味又は一部1L ++:全面的に凝集が認められる。+: Slightly agglomerated or partially 1L ++: Aggregation is observed throughout.

+1+−ρ集分離している。+1+-ρ collection is separated.

なj5、リンゴ酸カルシウムをカルシウムイオンとして
36mg%添加した上記と同様に調製した均質化液を1
0’(: C2週間保持したが凝集は起らなかった。
j5, 1 homogenized solution prepared in the same manner as above to which 36 mg% of calcium malate was added as calcium ion.
0'(:C) No aggregation occurred even though it was kept for 2 weeks.

特許出願人 川崎化成工業株式会社 代表者 丸 川 博Patent applicant: Kawasaki Chemical Industries, Ltd. Representative Hiroshi Marukawa

Claims (5)

【特許請求の範囲】[Claims] (1)豆乳に、グリセリン又はプロピレングリコールの
存在下カルシウム化合物を含有せしめることを特徴とす
る豆乳のカルシウム強化方法。
(1) A method for enriching soy milk with calcium, which comprises making soy milk contain a calcium compound in the presence of glycerin or propylene glycol.
(2)カルシウム化合物が、水溶性である特許請求の範
囲第1項記載の方法。
(2) The method according to claim 1, wherein the calcium compound is water-soluble.
(3)カルシウム化合物が、食用可能なカルシウム化合
物である特許請求の範囲第1項記載の方法。
(3) The method according to claim 1, wherein the calcium compound is an edible calcium compound.
(4)カルシウム化合物が、有機酸のカルシウム塩であ
る特許請求の範囲第3項記載の方法。
(4) The method according to claim 3, wherein the calcium compound is a calcium salt of an organic acid.
(5)カルシウム化合物が、無機酸のカルシウム塩であ
る特許請求の範囲第3項記載の方法。
(5) The method according to claim 3, wherein the calcium compound is a calcium salt of an inorganic acid.
JP58154778A 1983-08-26 1983-08-26 Enrichment of soya milk with calcium Pending JPS6047636A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58154778A JPS6047636A (en) 1983-08-26 1983-08-26 Enrichment of soya milk with calcium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58154778A JPS6047636A (en) 1983-08-26 1983-08-26 Enrichment of soya milk with calcium

Publications (1)

Publication Number Publication Date
JPS6047636A true JPS6047636A (en) 1985-03-15

Family

ID=15591686

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58154778A Pending JPS6047636A (en) 1983-08-26 1983-08-26 Enrichment of soya milk with calcium

Country Status (1)

Country Link
JP (1) JPS6047636A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6811800B2 (en) 1998-09-29 2004-11-02 The Procter & Gamble Co. Calcium fortified beverages

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6811800B2 (en) 1998-09-29 2004-11-02 The Procter & Gamble Co. Calcium fortified beverages
US6994877B2 (en) 1998-09-29 2006-02-07 The Procter + Gamble Co. Calcium fortified beverages

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