JPS6042606B2 - Manufacturing method for ultra-thin ceramic capacitors - Google Patents

Manufacturing method for ultra-thin ceramic capacitors

Info

Publication number
JPS6042606B2
JPS6042606B2 JP6920976A JP6920976A JPS6042606B2 JP S6042606 B2 JPS6042606 B2 JP S6042606B2 JP 6920976 A JP6920976 A JP 6920976A JP 6920976 A JP6920976 A JP 6920976A JP S6042606 B2 JPS6042606 B2 JP S6042606B2
Authority
JP
Japan
Prior art keywords
ultra
manufacturing
ceramic capacitors
thin ceramic
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP6920976A
Other languages
Japanese (ja)
Other versions
JPS52151858A (en
Inventor
博 大島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Noritake Co Ltd
Original Assignee
Noritake Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Noritake Co Ltd filed Critical Noritake Co Ltd
Priority to JP6920976A priority Critical patent/JPS6042606B2/en
Publication of JPS52151858A publication Critical patent/JPS52151858A/en
Publication of JPS6042606B2 publication Critical patent/JPS6042606B2/en
Expired legal-status Critical Current

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  • Producing Shaped Articles From Materials (AREA)
  • Ceramic Capacitors (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)

Description

【発明の詳細な説明】 (発明の目的) 本発明は電子腕時計、無線通信器、カメラ、電卓等に使
用される超薄型のセラミックコンデンサーの製法に関す
る。
DETAILED DESCRIPTION OF THE INVENTION (Object of the Invention) The present invention relates to a method for manufacturing ultra-thin ceramic capacitors used in electronic wristwatches, wireless communication devices, cameras, calculators, and the like.

この発明の目的は超薄型のセラミックコンデンサーを能
率よく製造することにある。
The purpose of this invention is to efficiently manufacture ultra-thin ceramic capacitors.

更に他の目的は製造を容易に且つ任意の形状のものを得
ることにある。(従来技術) 従来のこの種の薄型セラミックコンデンサーは素材をロ
ール成形法により薄く延展し、これを所望の形状にパン
チングマシン等で打抜き後、乾燥、焼成する方法が行わ
れていたが、極めて薄く延展することが困難であり、こ
の極薄の成形品の乾燥、焼成作業における手作業となる
取扱いが極めて困難であるばかりか、成形品が変形し易
く、製品の不良率が高く、従つて歩止りも低く、安価な
製品は到底望めなかつた。
A further object is to facilitate manufacturing and to obtain any shape. (Prior art) Conventionally, this type of thin ceramic capacitor was made by rolling the material thinly using a roll forming method, punching it into the desired shape using a punching machine, etc., and then drying and firing it. Not only is it difficult to spread, and the manual handling during drying and firing of this ultra-thin molded product is extremely difficult, but the molded product is easily deformed, resulting in a high product defect rate, and It had a low stopping speed, and I couldn't hope for a cheap product.

まして超薄型の製品等は考えられもしなかつた。(発明
の構成) 本発明は上述の不具合に鑑み、従来と全く異なる技術に
基づいて製造するもので素材をスクリーン印刷技術によ
り転写用紙等の基体に所望形状に印刷し、その上を樹脂
により被膜層を施したものを乾燥、焼成して超薄型のコ
ンデンサーを得ようとしたものである。
Moreover, ultra-thin products were unthinkable. (Structure of the Invention) In view of the above-mentioned problems, the present invention is manufactured based on a technology completely different from the conventional one, in which a material is printed in a desired shape on a substrate such as transfer paper using screen printing technology, and then a resin is coated on the material. This was an attempt to obtain an ultra-thin capacitor by drying and firing the layered product.

なおコンデンサーを構成する誘電材料としてはBaO・
4T1O、、TIO。など又は両者を組み合わせるこ
とは公知である。温度補償系てはTiO2や各種チタン
酸塩を主成分とし、高誘電率系ではBaT1O3を主成
分とし、スズ酸塩やジルコン酸塩を副成分として構成さ
れていることも知られている。本発明を更に実施例に基
づいて詳述すればチタン酸バリウムの粒度8μm以下の
もの80%以上の粉体180%以下の粉体ては粒度して
はらつきを生ずるため印刷後にパターンして’゛むら’
’を生ずる。
The dielectric material constituting the capacitor is BaO.
4T1O,,TIO. etc. or a combination of both is known. It is also known that temperature compensation systems are composed of TiO2 and various titanates as main components, and high dielectric constant systems are composed of BaT1O3 as a main component and stannate and zirconate as subcomponents. To further explain the present invention in detail based on examples, barium titanate particles with a particle size of 8 μm or less cause powders with a particle size of 80% or more, and powders with a particle size of 180% or less to cause fluctuations in particle size, so they are not patterned after printing.゛mura'
' is produced.

からなる誘電材料8腫量部と公知のベヒクル゜(例えば
エチルセルローズの15%有機溶液)20重量部を混合
機、3本ローラーミル等により攪拌混練してペースト状
のインキを調製した。そして図示のようにこのインキを
用いプラスチックフィルム又は転写紙などの基体1にス
クリーン印刷法に、より厚さ10〜301LmN好まし
くは20〜24μmの円形パターン2を印刷した。なお
印刷は厚さによりシルクスクリーン、ナイロンスクリー
ン又はメッシュメタルスクリーンを使用し所望形状に印
刷できる。誘電材料の印刷を完了した後、前記パターン
の全面を覆うようにアクリル樹脂を主成分とする合成樹
脂によりスクリーン印刷法によつて被膜層3を設ける。
スクリーン印刷法は公知の通りであり、プラスチックフ
ィルム又は転写紙などの基体上に予め印刷されたコンデ
ンサー模様の全面又は模様よりやや大きめの製版したス
クリーン枠を印刷機に取り付け、合成樹脂液を網枠の上
に入れ、スクイジー(ゴムへら)で擦ることにより、網
枠の下の基体は合成樹脂によつて被覆される。これを乾
燥すると所望の被覆層が得られる。完全に乾燥せしめ、
約1230゜Cまで昇温し1230℃で6紛間保持し徐
冷すれば極薄型のセラミックコンデンサー用の素体を得
られる。この素体を用いて常法辷より電極を設けてセラ
ミックコンデンサーを製作できる。(発明の作用・効果
) 従来は誘電材料からなる配合原料をスプレードライヤー
などを用い顆粒化原料とし、これをブレス成形して成型
品とする。
A paste-like ink was prepared by stirring and kneading 8 parts of the dielectric material consisting of the above and 20 parts by weight of a known vehicle (for example, a 15% organic solution of ethyl cellulose) using a mixer, a three-roller mill, or the like. Then, as shown in the figure, using this ink, a circular pattern 2 having a thickness of 10 to 301 LmN, preferably 20 to 24 μm, was printed on a substrate 1 such as a plastic film or transfer paper by screen printing. Depending on the thickness, a silk screen, nylon screen, or mesh metal screen can be used to print in the desired shape. After printing of the dielectric material is completed, a coating layer 3 is provided by a screen printing method using a synthetic resin mainly composed of acrylic resin so as to cover the entire surface of the pattern.
The screen printing method is a well-known method, in which a screen frame made from a screen frame that is slightly larger than the entire surface of the capacitor pattern previously printed on a substrate such as a plastic film or transfer paper, or a screen frame slightly larger than the pattern is attached to the printing machine, and the synthetic resin liquid is applied to the screen frame. The substrate under the mesh frame is coated with the synthetic resin by placing it on top and rubbing it with a squeegee (rubber spatula). When this is dried, the desired coating layer is obtained. Let it dry completely,
By raising the temperature to about 1230°C, holding the powder at 1230°C, and slowly cooling it, an element body for an ultra-thin ceramic capacitor can be obtained. Using this element, a ceramic capacitor can be manufactured by attaching electrodes in a conventional manner. (Operations and Effects of the Invention) Conventionally, a compounded raw material made of a dielectric material is made into a granulated raw material using a spray dryer or the like, and this is press-molded to form a molded product.

或は配合原料に有機バインダーを添加し、押出し機によ
りグリーン・シートを作り、打抜機で成型品とし、これ
らの成型品を焼結が起るまで約1200しC〜1400
℃の高温で焼成し、電極焼付、リード線加工を施してセ
ラミックコンデンサーとしていた。本発明はセラミック
コンデンサー用物質の誘電体微粉をセルローズ系樹脂、
アクリロ系樹脂等の公知のベヒクル又は、及び溶剤で混
練したペースト状のインクをプラスチックフィルム又は
転写紙等の基体に所望形状にスクリーン印刷し、合成樹
脂て被膜層を施し、乾燥後焼成することを特徴とする超
薄型のセラミックコンデンサーの製法であるから、厚さ
1轍μm以下のものが得られるからコンデンサーの容量
を高めることができる。
Alternatively, an organic binder is added to the blended raw materials, a green sheet is made using an extruder, and a molded product is formed using a punching machine.
The ceramic capacitor was made by firing at a high temperature of °C, baking the electrodes, and processing the lead wires. The present invention uses dielectric fine powder of a material for ceramic capacitors, cellulose resin,
A paste-like ink kneaded with a known vehicle or solvent such as acrylic resin is screen printed onto a substrate such as a plastic film or transfer paper in the desired shape, a synthetic resin coating layer is applied, and the film is dried and fired. Since this is a unique manufacturing method for ultra-thin ceramic capacitors, it is possible to obtain capacitors with a thickness of 1 μm or less, thereby increasing the capacitance of the capacitor.

従来の機械的方法では素体の厚さを100pm以下にす
ることは不可能であつた。更に従来の製造法ては成形性
の良否、焼成条件など複雑な要因が介在するが、本発明
によればスクリーン印刷法の利用、印刷基体としてプラ
スチックフィルム或は転写紙を用いるため成形が容易で
且つ形状も各種任意のものが得られる利点が大である。
With conventional mechanical methods, it has been impossible to reduce the thickness of the element body to 100 pm or less. Furthermore, conventional manufacturing methods involve complicated factors such as moldability, firing conditions, etc., but according to the present invention, molding is easy due to the use of screen printing and the use of plastic film or transfer paper as the printing substrate. Moreover, it has the great advantage that various arbitrary shapes can be obtained.

更に極薄のセラミックコンデンサーの成形が可能となり
、成形後のハンドリングが容易となり、且つ製品に変形
を生ずることが殆んどない。また従来より低温で焼成可
能となつた。かくして電子腕時計、無線通信器、カメラ
、電卓等に使用される超薄型のセラミックコンデンサー
が容易且つ安価に歩留り良く製造できるようになつた効
果は絶大である。
Furthermore, it becomes possible to mold extremely thin ceramic capacitors, and handling after molding becomes easy, and there is almost no deformation of the product. Additionally, it has become possible to fire at a lower temperature than before. In this way, ultra-thin ceramic capacitors used in electronic wristwatches, wireless communication devices, cameras, calculators, etc. can now be manufactured easily, inexpensively, and with high yield, which has a tremendous effect.

【図面の簡単な説明】[Brief explanation of the drawing]

図面はこの発明の実施に係る一部を破断して示す製品の
平面図である。 主要部分の符号の説明、1・・・・・基体、2・・・・
・・円形パターン、3・・・・・・被膜層。
The drawing is a partially cutaway plan view of a product according to the present invention. Explanation of symbols of main parts, 1...Base, 2...
...Circular pattern, 3...Coating layer.

Claims (1)

【特許請求の範囲】[Claims] 1 セラミックコンデンサー用物質の誘電体微粉をセル
ローズ系樹脂、アクリロ系樹脂等の公知のベヒクル又は
、及び溶剤で混練したペースト状のインクをプラスチッ
クフィルム又は転写紙等の基体に所望形状にスクリーン
印刷し、アクリル樹脂を主成分とする合成樹脂で被膜層
を施し、乾燥後焼成することを特徴とする超薄型のセラ
ミックコンデンサーの製法。
1 Screen print a paste ink prepared by kneading dielectric fine powder of a ceramic capacitor material with a known vehicle or solvent such as cellulose resin or acrylic resin on a substrate such as a plastic film or transfer paper into the desired shape, A manufacturing method for ultra-thin ceramic capacitors, which is characterized by applying a coating layer using synthetic resin, the main component of which is acrylic resin, and then firing it after drying.
JP6920976A 1976-06-11 1976-06-11 Manufacturing method for ultra-thin ceramic capacitors Expired JPS6042606B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6920976A JPS6042606B2 (en) 1976-06-11 1976-06-11 Manufacturing method for ultra-thin ceramic capacitors

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6920976A JPS6042606B2 (en) 1976-06-11 1976-06-11 Manufacturing method for ultra-thin ceramic capacitors

Publications (2)

Publication Number Publication Date
JPS52151858A JPS52151858A (en) 1977-12-16
JPS6042606B2 true JPS6042606B2 (en) 1985-09-24

Family

ID=13396092

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6920976A Expired JPS6042606B2 (en) 1976-06-11 1976-06-11 Manufacturing method for ultra-thin ceramic capacitors

Country Status (1)

Country Link
JP (1) JPS6042606B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62202705A (en) * 1985-11-05 1987-09-07 株式会社 麗光 Ceramic film
US20090078458A1 (en) * 2007-09-21 2009-03-26 Ricoh Company, Ltd. Paste composition, insulating film, multilayer interconnection structure, printed-circuit board, image display device, and manufacturing method of paste composition

Also Published As

Publication number Publication date
JPS52151858A (en) 1977-12-16

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