JPS604223B2 - hair dye - Google Patents
hair dyeInfo
- Publication number
- JPS604223B2 JPS604223B2 JP51008771A JP877176A JPS604223B2 JP S604223 B2 JPS604223 B2 JP S604223B2 JP 51008771 A JP51008771 A JP 51008771A JP 877176 A JP877176 A JP 877176A JP S604223 B2 JPS604223 B2 JP S604223B2
- Authority
- JP
- Japan
- Prior art keywords
- urea
- dyes
- hair
- concentration
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000118 hair dye Substances 0.000 title description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 30
- 239000004202 carbamide Substances 0.000 claims description 30
- 239000000975 dye Substances 0.000 claims description 28
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000000985 reactive dye Substances 0.000 claims description 10
- 239000000986 disperse dye Substances 0.000 claims description 8
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 7
- 239000000980 acid dye Substances 0.000 claims description 7
- 239000000981 basic dye Substances 0.000 claims description 7
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 23
- 238000004043 dyeing Methods 0.000 description 19
- 210000004209 hair Anatomy 0.000 description 18
- 238000011156 evaluation Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- AOMZHDJXSYHPKS-DROYEMJCSA-L Amido Black 10B Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC2=CC(S([O-])(=O)=O)=C(\N=N\C=3C=CC=CC=3)C(O)=C2C(N)=C1\N=N\C1=CC=C(N(=O)=O)C=C1 AOMZHDJXSYHPKS-DROYEMJCSA-L 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- -1 Polyoxyethylene nonyl phenyl ether Polymers 0.000 description 2
- 241000282335 Procyon Species 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000003700 hair damage Effects 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 229940094506 lauryl betaine Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 2
- 235000012756 tartrazine Nutrition 0.000 description 2
- 229960000943 tartrazine Drugs 0.000 description 2
- 239000004149 tartrazine Substances 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- XKTMIJODWOEBKO-UHFFFAOYSA-M Guinee green B Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC=CC=2)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 XKTMIJODWOEBKO-UHFFFAOYSA-M 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- DGOBMKYRQHEFGQ-UHFFFAOYSA-L acid green 5 Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 DGOBMKYRQHEFGQ-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- BMAUDWDYKLUBPY-UHFFFAOYSA-L disodium;3-[[4-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].C=1C=C(N=NC=2C=C3C(=CC=CC3=C(C=2)S([O-])(=O)=O)S([O-])(=O)=O)C(C)=CC=1NC1=NC(Cl)=NC(Cl)=N1 BMAUDWDYKLUBPY-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- GVKCHTBDSMQENH-UHFFFAOYSA-L phloxine B Chemical compound [Na+].[Na+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GVKCHTBDSMQENH-UHFFFAOYSA-L 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- AZLXCBPKSXFMET-UHFFFAOYSA-M sodium 4-[(4-sulfophenyl)diazenyl]naphthalen-1-olate Chemical compound [Na+].C12=CC=CC=C2C(O)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 AZLXCBPKSXFMET-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940071127 thioglycolate Drugs 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
- YQEHHPFEQLDFCN-UHFFFAOYSA-K trisodium 5-[(4,6-dichloro-1,3,5-triazin-2-yl)amino]-4-hydroxy-3-[(2-sulfonatophenyl)diazenyl]naphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].[Na+].Oc1c(N=Nc2ccccc2S([O-])(=O)=O)c(cc2cc(cc(Nc3nc(Cl)nc(Cl)n3)c12)S([O-])(=O)=O)S([O-])(=O)=O YQEHHPFEQLDFCN-UHFFFAOYSA-K 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
- D06P1/6491—(Thio)urea or (cyclic) derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Coloring (AREA)
Description
【発明の詳細な説明】
本発明は酸性染料、塩基性染料、反応性染料および分散
染料からなる群から選ばれた人体に無害な染料の１種も
しくは２種以上を染料として含有する梁毛剤に係るもの
である。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a hair dye containing one or more dyes selected from the group consisting of acid dyes, basic dyes, reactive dyes, and disperse dyes that are harmless to the human body. It is something.
従来もっとも普通に使用されている梁毛剤はフヱニレン
ジアミン系の酸化染料からなるものであるが、この酸化
染料はアレルギー性症をおこす可能性があるばかりでな
く、染毛に当っては皮膚刺戟や毛髪損傷などを生じるア
ルカリおよび過酸化水素水を不可欠とするので、安全性
からも、使用上の便利さの上からも好ましいものではな
く、フェニレンジアミン系の酸化染料を使用しない他の
梁毛剤が要望されており、近年比較的安全性の高夕 し
、反応性染料あるいは分散染料などを使用することが提
案されている。The most commonly used dyestuffs in the past are made of phenylenediamine-based oxidative dyes, but these oxidative dyes not only have the potential to cause allergic symptoms, but also cause skin irritation when dyeing hair. Since it requires alkaline and hydrogen peroxide solutions that can cause hair damage and hair damage, it is not desirable from the standpoint of safety or convenience of use. In recent years, it has been proposed to use reactive dyes or disperse dyes, which are relatively safe.
しかしながらこれらの反応性染料および分散染料は室温
ではケラチン系繊維に対する染着性が悪く、チオグリコ
ール酸塩などのメルカプタン系の還元剤などで繊維を前
処理し０なければならない難点があり、人体に対して使
用可能な温度範囲ならびにｐＨ範囲で満足できる染色濃
度に染毛できる染毛剤を得ることは不可能であつた。他
方羊毛を１００午０以下の温度で染色する低温梁タ色法
として、染浴にペンジルアルコールなどの溶剤を添加し
たり、尿素のような膨潤剤を添加して使用することが知
られているが、ベンジルアルコールの場合その水への溶
解度はせし、ぜし、３．０％（ｗ／ｖ）に過ぎず従って
添加量は通常０．１〜３．蟹容量％であり、尿素の場合
５〜４０重量％（ｗ／ｖ）であり、しかも何れの場合も
格温は７０ｏｏ以上を必要とし、常温に近い低温での染
色を必要とする人毛の染色では十分な染色効果は達成で
きず、また耐洗練性、耐摩擬性も低く、洗剤を用いた洗
糠で容易に脱色する欠点があった。However, these reactive dyes and disperse dyes have poor dyeability on keratin fibers at room temperature, and have the disadvantage that the fibers must be pretreated with a mercaptan-based reducing agent such as thioglycolate. However, it has been impossible to obtain a hair dye that can dye hair to a satisfactory dyeing density within the usable temperature and pH ranges. On the other hand, it is known that the low-temperature dyeing method, in which wool is dyed at temperatures below 100°C, involves adding a solvent such as pendyl alcohol or a swelling agent such as urea to the dye bath. However, in the case of benzyl alcohol, its solubility in water is usually only 3.0% (w/v), so the amount added is usually 0.1 to 3.0% (w/v). % by volume, and in the case of urea it is 5 to 40% by weight (w/v), and in any case, the temperature needs to be 70 oo or higher, and it is used for human hair that requires dyeing at a low temperature close to room temperature. A sufficient dyeing effect could not be achieved by dyeing, and the polishing resistance and abrasion resistance were also low, and the color was easily decolored by washing with detergent.
本発明者は酸性染料、塩基性染料、反応性染料および分
散染料から選ばれた染料を含む水性梁格に添加してその
常温での染着力を向上させ、また染着耐久性を改善し、
しかも人体に無害である添加物質について種々研究を重
ねた結果、上記の梁俗に尿素とペンジルアルコールとの
両者を特定量で添加するときは、尿素あるいはペンジル
アルコールの単独添加では見られない顕著な染色効果が
達成され、その耐久性も極めて良好であることを発見し
、本発明を完成したものである。The present inventor added dyes selected from acid dyes, basic dyes, reactive dyes and disperse dyes to water-based dyes to improve the dyeing power at room temperature and also improve the dyeing durability.
Moreover, as a result of various studies on additive substances that are harmless to the human body, we found that when both urea and pendyl alcohol are added in specific amounts to the above-mentioned Liangsu, this is not the case when urea or pendyl alcohol is added alone. The present invention was completed based on the discovery that a remarkable dyeing effect was achieved and the durability was also extremely good.
本発明で使用する染料は人体に対して有害な作用を有し
ない酸性染料、塩基性染料、反応性染料、分散染料から
任意に選ぶことができ、これには医薬、医薬部外品およ
び化粧品の着色に使用することが許されている。The dye used in the present invention can be arbitrarily selected from acid dyes, basic dyes, reactive dyes, and disperse dyes that have no harmful effect on the human body. Permitted to be used for coloring.
「医薬品等に使用することができるタール色素を定める
省令」に掲示されている法定色素も包含これ、例えば各
実施例に示すもの以外に次のものも使用できる。法定色
素名 一 般 名 分額
赤色１０４号 フロキシンＢ 酸染〃１０５号ロ
−ズベンガル
〃１０６号アンッドレッド
″２０６号リソールレッド 顔
〃 ２１３号 。Legal dyes listed in the "Ministerial Ordinance Specifying Tar Colors That Can Be Used in Pharmaceuticals, etc." are also included. For example, in addition to those shown in each example, the following can also be used. Legal dye name General name Bulk Red No. 104 Phloxine B Acid dye No. 105 Rose Bengal No. 106 And Red'' No. 206 Lysole Red Face No. 213.
−ダミンＢ 塩染〃 ４０１号 ビオラミンＲ
酸染〃５０３号ポンソ−Ｒ
燈色４０２号オレンジ１
黄色４号 タートラヂン
″ ５号 サンセットェロ−ＦＯＦ
〃２０３号キノリンェロ−ＷＳ
″ ４０２号ポーラェロ−５０
″ ４０５号 ェロ−ＯＢ 油梁緑色３号
フアズトグリ−ンＦＯＦ 酸梁〃２０５号 ライトグ
リ−ンＳＦ黄〃 ４０２号 ギネアグリ−ンＢ
青色１号 ブリリアントブルーＦＯＦ〃２号 イ
ンチゴヵルミン
〃 ２０３号 パテントブル−ＮＡ
〃 ２０５号 アルファズリンＦＧ
紫色４０１号 ァＩＪズロールパープル
褐色２０１号 しゾルンンブラゥン
黒色４０１号 ナフトールブループラック前述の通り本
発明は酸性染料、塩基性染料、反応性染料及び分散染料
からなる群から選ばれた染料を１種あるいは２種以上含
む水性染浴に尿素とペンジルアルコールとをともに特定
量添加することを特徴とし、これによって前述した顕著
な効果をあげることに成功したものであるが、この効果
を達成できた理由はおそらく尿素とペンジルアルコール
との共存によって後者の溶解度を著しく上昇し、従って
染料の染着力を増大したものと考えられる。-Damin B Salt Dye No. 401 Violamine R
Acid-dyed No. 503 Ponsor-R Light color No. 402 Orange 1 Yellow No. 4 Tartradine'' No. 5 Sunsetello-FOF No. 203 Kinoline-ERO-WS '' No. 402 Polarello-50'' 405 Ero-OB Yuliang Green No. 3
Fuazto Green FOF Sour Liang No. 205 Light Green SF Yellow No. 402 Guinea Green B Blue No. 1 Brilliant Blue FOF No. 2 Inchigo Carmine No. 203 Patent Blue NA No. 205 Alphazurin FG Purple No. 401 A IJ Zuror Purple Brown No. 201 Shizorun Brown Black No. 401 Naphthol Blue Plaque As mentioned above, the present invention is an aqueous dye containing one or more dyes selected from the group consisting of acid dyes, basic dyes, reactive dyes, and disperse dyes. It is characterized by adding a specific amount of both urea and penzyl alcohol to the dye bath, and by this, it succeeded in achieving the remarkable effect mentioned above. It is thought that the coexistence with dial alcohol significantly increases the solubility of the latter, thereby increasing the dyeing power of the dye.
本発明者らは水にペンジルアルコールを添加して溶解度
を測定し、更にこれに尿素を添加し、尿素量を次第に増
加してペンジルアルコールの溶解度と尿素添加量との関
係及び同様にして尿素の溶解度とペンジルアルコールの
添加量との関係を調査して、第１図に示す結果を得た。The present inventors added penzyl alcohol to water to measure its solubility, then added urea to this, and gradually increased the amount of urea to determine the relationship between the solubility of penzyl alcohol and the amount of urea added. The relationship between the solubility of urea and the amount of pendyl alcohol added was investigated, and the results shown in FIG. 1 were obtained.
なおその試験は２０ｑｏで行ったものである。図から明
らかなように、ベンジルアルコールの水への溶解度は常
温ではゞ３．１％（地／１００肌）に過ぎないが、溶解
度は尿素添加量の増加に伴って次第に上昇し、尿素量５
３％（夕／１００の‘）ではほゞ９．８％にも上昇する
。Note that the test was conducted at 20qo. As is clear from the figure, the solubility of benzyl alcohol in water is only 3.1% (ground/100 skin) at room temperature, but the solubility gradually increases as the amount of urea added increases.
At 3% (evening/100's), it rises to almost 9.8%.
以上の実験結果に鑑み、発明者は更にタートラジンを染
料とする梁格を基準にし、これに尿素およびペンジルア
ルコールを単独で種々の量添加したもの及び両者を共に
種々量を変化して添加したものを用い、染毛して尿素と
ペンジルアルコールとを併用する場合の相乗り効果を調
べた。In view of the above experimental results, the inventor further developed Liangge using tartrazine as a dye, and added urea and pendyl alcohol alone in various amounts, and added both of them in various amounts. We investigated the synergistic effect of using urea and pendyl alcohol together on dyed hair.
染色条件
使用染料 タートラジン
染料濃度 ０．２％
染色温度 ４０００
染色時間 ３０分
染格のｐＨ ３．０〜３．２
染色結果
肉眼で見て、尿素およびペンジルアルコールを共に含ま
ない場合を１とし、最高の濃度に染色されたものを１０
として染色濃度を示した。Dyeing conditions Dye used Tartrazine dye concentration 0.2% Dyeing temperature 4000 Dyeing time 30 minutes Dyeing pH 3.0 to 3.2 Dyeing results When seen with the naked eye, 1 indicates that neither urea nor pendyl alcohol is included. The one dyed to the highest density is 10
The staining density is shown as .
その結果は次表の通りであった。The results are shown in the table below.
備考×は梁浴中にペンジルアルコールまたは尿素が完全
に溶解しないため不適当な場合を示す。Note: × indicates that pendyl alcohol or urea is not completely dissolved in the beam bath and is therefore inappropriate.
上記の表中に示した評価１０を○印、９を△印、Ｚ８を
×印として図に示すと第２図の通りである。The evaluation shown in the table above is shown in FIG. 2, with evaluation 10 marked as ○, 9 marked as △, and Z8 marked as x.
第２図は第１図に示した溶解度曲線評価１０と評価９と
の中間に引いた線、評価９と評価８との中間に引いた線
、及び評価８と評価７（図示せず）との中間に引いた線
をも含んでいる。第２図から明２らかなように、等評価
値線は同じ円状になっており、従ってペンジルアルコー
ル濃度及び尿素濃度と染色濃度との間には特殊な関係が
あることは明らかである。最良の染色性が得られるペン
ジルアルコール濃度及び尿素濃度の相関組成範囲は第２
図に示すように、尿素一ペンジルアルコール−水系にお
けるペンジルアルコールの溶解度曲線Ａ、尿素の溶解度
曲線Ｂ、尿素濃度２５９／１００の‘でのペンジルアル
コールの溶解度点×と尿素濃度３０夕／１００の‘でペ
ンジルアルコール濃度４．５泌／１００Ｍである点Ｙと
を通る直線Ｃ、及び点Ｙと尿素濃度５０夕／１００の上
でペンジルアルコール濃度６．５の【／１００の【であ
る点Ｚとを通る直線Ｄで囲まれた範囲である。Figure 2 shows a line drawn between solubility curve evaluation 10 and evaluation 9 shown in Figure 1, a line drawn between evaluation 9 and evaluation 8, and a line drawn between evaluation 8 and evaluation 7 (not shown). It also includes a line drawn in the middle. As is clear from Figure 2, the equal evaluation value lines have the same circular shape, so it is clear that there is a special relationship between pendyl alcohol concentration, urea concentration, and staining concentration. . The correlation composition range of pendyl alcohol concentration and urea concentration that provides the best stainability is the second
As shown in the figure, the solubility curve A of penzyl alcohol in the urea-penzyl alcohol-water system, the solubility curve B of urea, the solubility point of penzyl alcohol at urea concentration of 259/100 x and the urea concentration of 30/ A straight line C passing through point Y where the concentration of pendyl alcohol is 4.5/100M at 100', and a straight line C passing through point Y where the concentration of pendyl alcohol is 6.5/100 at point Y and the urea concentration of 50/100. This is the range surrounded by a straight line D passing through point Z.
発明者らは更に他の酸性染料、塩基性染料、反応染料お
よび分散染料を単独で含む梁格及び２種以上の染料を含
む染格についても染色実験を行い尿素およびペンジルァ
ルコールを上記の範囲内で共に添加する時は常温で、ま
た人体に悪影響のない州範囲（約ｐＨ２〜１１）で毛髪
を極めて容易にかつ希望の色調、濃度に永久染色できし
かもこの梁俗は悪臭もなく、人体に対しても何等有害な
作用のないことを確認した。更に本発明染毛剤によって
染色した毛髪に対し洗剤を含む温水洗糠試験耐光試験お
よび摩擦試験を行ってその染色堅牢度を調べたが、ほと
んど脱色、変色は見られず、ほゞ永久的な染毛が達成で
きることも認められた。The inventors also carried out dyeing experiments on other acid dyes, basic dyes, reactive dyes, and dyes containing two or more dyes, including a single dye containing acidic dyes, basic dyes, reactive dyes, and disperse dyes. When added together within a certain range, it is possible to permanently dye hair to the desired color tone and concentration at room temperature and within a range that does not have any negative effects on the human body (approximately pH 2 to 11). It was confirmed that there is no harmful effect on the human body. Furthermore, the hair dyed with the hair dye of the present invention was subjected to a light fastness test using a detergent-containing bran wash, a light fastness test, and a friction test to examine the color fastness. It was also recognized that hair dyeing can be achieved.
本発明の染色剤においては染料の種類に応じて梁格を希
望のｐＨ値に調整するための酸、アルカリ特にアンモニ
ア水の如きｐＨ調整剤、浸透、分散を増進するための浸
透剤、分散剤、特に梁毛剤として使用する場合に染格の
毛髪への附着をよくするための増粘剤および香料など従
来この種の梁毛剤の添加剤として通常使用されている添
加剤を適宜添加できることは勿論である。In the dyeing agent of the present invention, a pH adjusting agent such as an acid or alkali, especially ammonia water, is used to adjust the pH value to a desired value depending on the type of dye, and a penetrating agent and a dispersing agent are used to promote penetration and dispersion. In particular, when used as a hair agent, it is of course possible to add additives that have been conventionally used as additives for this type of hair agent, such as thickeners and fragrances to improve the adhesion of the dye to the hair. .
以下本発明を実施例によって更に詳しく説明する。The present invention will be explained in more detail below with reference to Examples.
実施例 １
黒色梁毛剤
ナフトールブルーブラック（酸梁）０．５％（Ｗ）オレ
ンジロ（酸梁） ０．２％（Ｗ）クエン酸
０．５％（Ｗ）ペンジルアル
コール ６．０％（Ｖ）尿 素
３０．０％（Ｗ）ポリオキシェチレ
ンノニルフェニルェーテル（浸透剤用界面活性剤）
０．１％（Ｗ）精製水
残 部なお（Ｗ）は夕／１００瓜【、（Ｖ）
は肌／１００の【で示したパーセントである。Example 1 Black hair agent naphthol blue black (acid beam) 0.5% (W) Orangero (acid beam) 0.2% (W) citric acid
0.5% (W) Penzyl alcohol 6.0% (V) Urea
30.0% (W) Polyoxyethylene nonyl phenyl ether (surfactant for penetrant)
0.1% (W) purified water
The remainder (W) is evening/100 melon [, (V)
is the percentage of skin/100.
まづ水に尿素をとかし、これにペンジルアルコ三ールを
添加して溶解させる。First, dissolve urea in water, add penzylalcotriyl and dissolve it.
この溶液にナフトールブルーブラツクおよびオレンジロ
をとかし、さらにポリオキシエチレンノニルフエニルエ
ーテルを加え、最後にクエン酸で−３．０〜３．５に調
整した。この染格を梁毛に使用するには、毛髪を清浄に
し、これに上記の梁毛剤を常法に従って塗布し、室温に
２０〜３０分放置し、最後に洗髪、乾燥すればよい。Naphthol Blue Black and Orange Yellow were dissolved in this solution, polyoxyethylene nonylphenyl ether was further added, and finally the solution was adjusted to -3.0 to -3.5 with citric acid. To use this dye on hair, the hair is cleaned, the above-mentioned hair care agent is applied to it in a conventional manner, the hair is left at room temperature for 20 to 30 minutes, and finally the hair is washed and dried.
かくして永久的な黒色染毛が達成された。実施例 ２澄
色梁毛剤
プロシオンブリリアントレツド２ＢＳ※
０．２％（Ｗ）
プロシオンイエローＲＳ※ ０．２％（Ｗ）乳
酸 ０．５％（Ｗ）ペン
ジルアルコール ９．０％（Ｖ）尿 素
５０．０％（Ｗ）ラゥリ
ルベタィン（界面活性剤） ０．２％（Ｗ）ヒドロキシ
エチルセルローズ １．８％（Ｗ）精製水
残 部二なお※はＩＣＩ製造の
反応性染料である。Permanent black hair dyeing was thus achieved. Example 2 Procion Brilliant Red 2BS* 0.2% (W) Procion Yellow RS* 0.2% (W) Lactic acid 0.5% (W) Penzyl alcohol 9.0% (V) Urine Basic
50.0% (W) Lauryl betaine (surfactant) 0.2% (W) Hydroxyethyl cellulose 1.8% (W) Purified water
The remaining two ※ are reactive dyes manufactured by ICI.
精製水に尿素、ついでペンジルアルコールをとかし、こ
の溶液にヒドロキシェチルセルローズをとかして粘穂な
液状とし、更にラゥリルベタィンおよびプロシオンプリ
リァントレッドがＳならびにプロシオンィヱローＲＳを
とかし、最後に乳酸でＰＨを３．０〜３．５に調整した
。Dissolve urea in purified water, then dissolve pendyl alcohol, dissolve hydroxyethyl cellulose in this solution to make a viscous liquid, then dissolve Lauryl Betaine and Procyon Prilliant Red S and Procyon Yellow RS, and finally dissolve with lactic acid. The pH was adjusted to 3.0-3.5.
この梁俗は実施例１に述べる方法で染毛用として特に好
適に使用できた。This Liangzoku could be particularly suitably used for hair dyeing by the method described in Example 1.
第１図は尿素−ペンジルアルコール−水系におけるペン
ジルアルコールの溶解度曲線及び尿素の溶解度曲線を示
すグラフ、第２図はペンジルアルコール濃度及び尿素濃
度と染色濃度との関係を示す説明図である。
第「図
第２図Figure 1 is a graph showing the solubility curve of pendyl alcohol and the solubility curve of urea in a urea-pendyl alcohol-water system, and Figure 2 is an explanatory diagram showing the relationship between pendyl alcohol concentration, urea concentration, and staining density. . Figure 2
Claims (1)
からなる群から選ばれた人体に無害な染料の１種もしく
は２種以上を溶解含有し、尿素およびベンジルアルコー
ルを第２図に示すように、２０℃において、尿素−ベン
ジルアルコール−水系におけるベンジルアルコールの溶
解度曲線Ａ、尿素の溶解度曲線Ｂ、尿素濃度２５ｇ／１
００ｍｌでのベンジルアルコールの溶解度点Ｘと尿素濃
度３０ｇ／１００ｍｌでベンジルアルコール濃度４．５
ｍｌ／１００ｍｌである点Ｙとを通る直線Ｃ、及び点Ｙ
と尿素濃度５０ｇ／１００ｍｌでベンジルアルコール濃
度６．５ｍｌ／１００ｍｌである点Ｚとを通る直線Ｄで
囲まれた範囲内の組成で溶解含有していることを特徴と
する染毛剤。1 Contains dissolved one or more kinds of dyes harmless to the human body selected from the group consisting of acid dyes, basic dyes, reactive dyes and disperse dyes, and contains urea and benzyl alcohol as shown in Figure 2. , at 20°C, solubility curve A of benzyl alcohol in urea-benzyl alcohol-water system, solubility curve B of urea, urea concentration 25 g/1
Solubility point X of benzyl alcohol at 00ml and benzyl alcohol concentration 4.5 at urea concentration 30g/100ml
Straight line C passing through point Y, which is ml/100ml, and point Y
and a point Z having a urea concentration of 50 g/100 ml and a benzyl alcohol concentration of 6.5 ml/100 ml.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51008771A JPS604223B2 (en) | 1976-01-28 | 1976-01-28 | hair dye |
| BE166262A BE840879A (en) | 1976-01-28 | 1976-04-16 | DYE COMPOSITION FOR KERATINIC FIBERS, IN PARTICULAR FOR HAIR |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP51008771A JPS604223B2 (en) | 1976-01-28 | 1976-01-28 | hair dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5291028A JPS5291028A (en) | 1977-08-01 |
| JPS604223B2 true JPS604223B2 (en) | 1985-02-02 |
Family
ID=11702147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51008771A Expired JPS604223B2 (en) | 1976-01-28 | 1976-01-28 | hair dye |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS604223B2 (en) |
| BE (1) | BE840879A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6122007A (en) * | 1984-07-06 | 1986-01-30 | Kanebo Ltd | Hair dye |
| JPS6153211A (en) * | 1984-08-21 | 1986-03-17 | Kanebo Ltd | Hair dye |
| US5015263A (en) * | 1985-05-28 | 1991-05-14 | Clairol Incorporated | Composition for coloring skin and method |
| JP3406342B2 (en) * | 1993-03-17 | 2003-05-12 | ライオン株式会社 | Shampoo composition |
| JP2003246715A (en) * | 2002-02-22 | 2003-09-02 | Nikko Chemical Co Ltd | Hair dye composition |
-
1976
- 1976-01-28 JP JP51008771A patent/JPS604223B2/en not_active Expired
- 1976-04-16 BE BE166262A patent/BE840879A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5291028A (en) | 1977-08-01 |
| BE840879A (en) | 1976-08-16 |
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