JPS6122007A - Hair dye - Google Patents
Hair dyeInfo
- Publication number
- JPS6122007A JPS6122007A JP14112184A JP14112184A JPS6122007A JP S6122007 A JPS6122007 A JP S6122007A JP 14112184 A JP14112184 A JP 14112184A JP 14112184 A JP14112184 A JP 14112184A JP S6122007 A JPS6122007 A JP S6122007A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- dye
- acid
- dyeing
- hair dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
Abstract
Description
【発明の詳細な説明】
（技術分野）
本発明は、染色堅牢性に浸れ、短時間にかつ均一に染毛
し得る染毛剤に関する。DETAILED DESCRIPTION OF THE INVENTION (Technical Field) The present invention relates to a hair dye that has excellent color fastness and can dye hair uniformly in a short time.
（従来技術）
従来、汎用されている酸化染毛剤は、施術時、アルカリ
性下に過酸化水素を作用させるために、扱い方によって
は毛髪損傷や一次皮膚刺激を示す危険性がある。このた
め酸性染料を用いた頭皮。(Prior Art) Conventional oxidative hair dyes cause hydrogen peroxide to act under alkaline conditions during treatment, so depending on how they are handled, there is a risk of hair damage or primary skin irritation. For this reason, the scalp is treated with acid dyes.
頭髪に対して影響の少ない染毛剤が開発されてきた。し
かしながら現在、市販されている酸性染料を使用した染
毛剤は、染着性や洗髪時の染色堅牢性などが低い欠点が
あった。Hair dyes that have less effect on hair have been developed. However, currently commercially available hair dyes using acidic dyes have drawbacks such as poor dyeability and dye fastness during hair washing.
従来、毛髪を酸性染料で染色する場合は、染毛が売子す
るまで約３０〜５０分の長時間を必要としていた。この
間、被施術者は、染液が周囲へ飛び散らないようにでき
るだけ不動静座の状態を保持しなければならず、その精
神的、肉体的負担は、はかり知れないものがある。“従
って、頭髪染色の所要時間を少しでも短縮できれは、被
施術者にとって安楽これ以上のものはなく、その改良が
需要者等をして広く要望されている。Conventionally, when hair is dyed with an acid dye, a long time of about 30 to 50 minutes is required for the dyed hair to wear out. During this time, the person receiving the treatment must remain as still as possible to prevent the dye from scattering around them, and the mental and physical burden placed on them is immeasurable. ``Therefore, if the time required for hair dyeing could be shortened even a little, it would be more convenient and convenient for the person receiving the treatment, and improvements in this area are widely desired by consumers and the like.
尚、染毛所要時間を短縮する方法として、染毛処理温度
と高くする方法（染毛する間、頭髪部をキャップ等によ
り菌い、所要の染毛温度を永く保持すること。）や染毛
促進剤（例えば、スチレングリコール）の添加併用が知
られているが、前者の方法では非常に手間がかかり、し
かも効果が少ない等で実用性に乏しく、又後者の方法で
は、未だ充分な効果が得られていない。In addition, as a method to shorten the time required for hair dyeing, there is a method of increasing the hair dyeing temperature (during the hair dyeing, the hair is covered with a cap etc. to prevent germs and the required hair dyeing temperature is maintained for a long time) and hair dyeing. It is known to use an accelerator (for example, styrene glycol) in combination, but the former method is very time-consuming and has little effect, making it impractical, and the latter method is still not sufficiently effective. Not obtained.
（発明の目的）
本発明の目的は、染色堅牢性に優れ、短時間に、かつ均
一に染毛し得る染毛剤を提供することである。(Object of the Invention) An object of the present invention is to provide a hair dye that has excellent color fastness and can dye hair uniformly in a short time.
（発明の構成）
すなわち、本発明は
に８
（式中で、ＲＸは水素原子、メチル基またはメトキシ基
、Ｒ言ｉ −ＣＨ，ＯＨ基、 −ＣＨ，ＣＨ，ＯＨ基。(Structure of the Invention) That is, the present invention provides the following: (In the formula, RX is a hydrogen atom, a methyl group or a methoxy group, and R is a -CH,OH group, -CH,CH,OH group.
−ＣＨ二ＣＨＣＨ，ＯＨ基または一０ＣＲ，ＣＨ＊ＯＨ
基を表わす。）
Ｃ表わされる芳香族アルコールとキサンタンガムと酸性
染料と酸と水を含有しており、そして、前記芳香族アル
コールと水との重量比が３／９７〜８０／２０であるこ
とを特徴とする染毛剤である。-CH2CHCH,OH group or one0CR,CH*OH
represents a group. ) A dye containing an aromatic alcohol represented by C, xanthan gum, an acid dye, an acid, and water, and wherein the weight ratio of the aromatic alcohol to water is 3/97 to 80/20. It is a hair conditioner.
（精鍼の具体的な説明）
本発明で使用される前記一般式嚇で示される芳香族アル
コールとしては、例えばベンジルアルコール、フェネチ
ルアルコール、γ−フェニルプロピルアルコール、、桂
皮アルコール、アニスアルコール、Ｐ−メチルベンジン
アルコール、α−α−ジメチルフェネチルアルコール、
α−フェニルエタノール、フェノキシエタノールなどが
挙げられる。前記芳香族アルコールの含有量（配合量）
は、組成物全量に対して１．５〜７９．２重社％である
。(Specific explanation of seinatsu) Examples of the aromatic alcohol represented by the general formula used in the present invention include benzyl alcohol, phenethyl alcohol, γ-phenylpropyl alcohol, cinnamon alcohol, anise alcohol, P- Methylbenzine alcohol, α-α-dimethylphenethyl alcohol,
Examples include α-phenylethanol and phenoxyethanol. Content (blended amount) of the aromatic alcohol
is 1.5 to 79.2% based on the total amount of the composition.
水との重量比は３／９７〜８０／２０であり、好ましく
は５／９５〜６０／４０の範囲内である。The weight ratio with water is 3/97 to 80/20, preferably 5/95 to 60/40.
前記一般式世て示される芳香族アルコールと水との重量
比を前記の特定量以外で用いると、前記染毛完了時間は
著るしく遅くなり、染色所要時間を短縮する事ができず
、染色堅牢度も著るしく低下するため、好ましくない。If the weight ratio of aromatic alcohol and water shown in the general formula is used in a range other than the specified amount, the hair dyeing completion time will be significantly delayed, the dyeing time cannot be shortened, and the dyeing process will be delayed. It is not preferable because the fastness is also significantly reduced.
本発明で使用するキサンタンガムは、Ｄ−グルコース、
Ｄ−マンノース、Ｄ−グルクロン酸カラ成る多糖類で、
その構成比は一般に２．８：２：２であり、一部アセチ
ル化（約４．７％）されてあり、約３％のピルビン酸を
含み、分子量は１０’以上といわれている。例えば、米
国ＫＥＬＣＯ社からケルトロール（ＫＥＬＴＲＯＬ）と
いう商品名で市販されている。The xanthan gum used in the present invention includes D-glucose,
A polysaccharide consisting of D-mannose and D-glucuronic acid.
Its composition ratio is generally 2.8:2:2, it is partially acetylated (about 4.7%), contains about 3% pyruvic acid, and has a molecular weight of 10' or more. For example, it is commercially available from KELCO, USA under the trade name KELTROL.
キサンタンガムの含有量（配合量）は組成物全量に対し
て０．５〜３．５重量％であり、好ましくは１．０〜２
．０重量％である。The content (blending amount) of xanthan gum is 0.5 to 3.5% by weight based on the total amount of the composition, preferably 1.0 to 2% by weight.
．． It is 0% by weight.
本発明で使用する酸性染料は、タール色素であり、化学
構造から大別すると、ニトロ染料、アゾ染料、ニトロン
染料、トリフェニルメタン染料。The acidic dyes used in the present invention are tar dyes, and can be roughly classified into nitro dyes, azo dyes, nitrone dyes, and triphenylmethane dyes based on their chemical structures.
キサンチン染料、キノリン染料、アントラキノン染料、
インジゴイド染料などが挙げられざ。xanthine dyes, quinoline dyes, anthraquinone dyes,
Examples include indigoid dyes.
酸性染料の含有量（配合量）は、組成物全量に対して通
常０．０１〜２０重量％である。The content (compounding amount) of the acidic dye is usually 0.01 to 20% by weight based on the total amount of the composition.
本発明のＰＨ調整に使用する酸としては、例えば酒石酸
、酢酸、クエン酸、修酸等の有機酸及びリン酸、塩酸等
の無機酸などが挙げられるが、特にこれらに限るもので
はない。酸の含有量（配合量）は、組成物のＰＨが１．
２〜４．０に調整するにたる必要凰である。Examples of acids used for pH adjustment in the present invention include, but are not limited to, organic acids such as tartaric acid, acetic acid, citric acid, and oxalic acid, and inorganic acids such as phosphoric acid and hydrochloric acid. The acid content (blended amount) is determined when the pH of the composition is 1.
It is necessary to adjust it to between 2 and 4.0.
本発明に使用する水の含有量は、組成物全量に対して１
０．０〜９７重量％である。The content of water used in the present invention is 1% based on the total amount of the composition.
It is 0.0 to 97% by weight.
また、本発明の染毛剤は、系の安定性、ＰＨ値を損わな
い範囲であれば、上記の必須成分の他に防腐剤、キレー
ト剤、香料などを配合する事も可能である。Furthermore, the hair dye of the present invention may contain preservatives, chelating agents, fragrances, etc. in addition to the above-mentioned essential components, as long as they do not impair system stability or pH value.
（発明の効果）
上記の如く、本発明の染毛剤は毛髪を短時間でかつ均一
に染着して、染色所要時間を短縮し、しかも、染色堅牢
度を向上し得るものであり、その作用効果は著るしく、
商品価値は極めて高い。(Effects of the Invention) As described above, the hair dye of the present invention can dye hair uniformly in a short time, shorten the dyeing time, and improve color fastness. The effect is remarkable,
The product value is extremely high.
（実施例）
以下実施例によって、本発明を更に詳細に説明する。尚
、実施例に示した部とは重量部を％とは重量％を意味す
る。(Example) The present invention will be explained in more detail with reference to Examples below. In addition, parts shown in Examples means parts by weight, and % means weight %.
実施例に示した染毛完了時間（染着速度）、染毛状態、
染色堅牢度の試験法は下記の通りである。Hair dyeing completion time (dying speed), hair dyeing state,
The color fastness test method is as follows.
ｆｉｌ染色完了時間（染着速度）
毛束（白色毛髪の束）２ｙを、試料染液（３０℃）の中
に浸漬して、該染液を毛髪に含浸した後、３０℃の恒温
室内に放置し、所定時間毎に取出して、水洗し、風乾す
る。この染毛束について高速色差計（村上色材■製）を
用いて測色を行ない、染毛束のＸ、Ｙ、Ｚ（＊をハンタ
ー（Ｈｕｎｔｅｒ ）のＬａｂ表色茶色系換し、染色前
の白毛束どの色差を測定し、色差がほぼ一定となった時
点（色差の変曲点）を染毛完了時間とした。表示した数
値の小さい程（染色完了時間（分）の短かい程）、毛髪
の染色速度が早いことを意味する。fil dyeing completion time (dying speed) A hair bundle (white hair bundle) 2y is immersed in a sample dye solution (30°C), and after impregnating the hair with the dyeing solution, it is placed in a thermostatic chamber at 30°C. Leave it alone, take it out at regular intervals, wash it with water, and air dry it. The color of this dyed hair bundle was measured using a high-speed color difference meter (manufactured by Murakami Shikizai ■), and the X, Y, Z (* was changed to Hunter's Lab color system brown system) before dyeing. The color difference of each white hair bundle was measured, and the time when the color difference became almost constant (the inflection point of the color difference) was taken as the hair dyeing completion time.The smaller the displayed value (the shorter the dyeing completion time (minutes)) ), which means that the hair dyeing speed is fast.
（２）染色状態
専門検査員３人によって、染色した毛髪の色相を肉眼観
察すると共に均染状態（むら染めの有無２および発色状
態（正常に発色しているかどうか）を調べた。(2) Three dyeing condition specialist inspectors visually observed the hue of the dyed hair and examined the level dyeing condition (presence or absence of uneven dyeing2) and the coloring condition (whether the color is developing normally).
（３）染色堅牢性（洗髪堅牢性）
前記＋１１の染色完了時間試験のところで得られた染色
した毛髪をラウリル硫酸ナトリウムの５％水溶液（３０
℃）の中に浸漬して、１０回の手もみ洗いを行なった後
、水洗し、風乾した。(3) Dyeing fastness (washing fastness) The dyed hair obtained in the above +11 dyeing completion time test was treated with a 5% aqueous solution of sodium lauryl sulfate (30%
℃), washed by hand 10 times, washed with water, and air-dried.
これを１回として、２０回繰り返した後、次式にて洗髪
試験後の褪色率を求めた。After repeating this 20 times, the fading rate after the hair washing test was determined using the following formula.
褪色率２０％までを「良好」、２１〜５０％未満を「不
良」、５０％以上を「着るしく不良」として表わした。A fading rate of up to 20% was rated as "good", a rate of 21% to less than 50% was rated as "poor", and a rate of 50% or more was rated as "unwearable".
実施例 １
キサンタンガム１．０部及び水７１部を均一に溶解し、
この溶液の中にベンジルアルコール２２部。Example 1 1.0 part of xanthan gum and 71 parts of water were uniformly dissolved,
22 parts of benzyl alcohol into this solution.
酸性染料の紫色４０１号（Ｃ，Ｉ庭６０７３０）１．０
部、クエン酸５．０部を添加して、均一に攪拌混合して
青色系の染毛剤を調整した。得られた染毛剤のＰＨは３
．３であった。Acid dye purple No. 401 (C, I Niwa 60730) 1.0
1 part, and 5.0 parts of citric acid were added thereto and uniformly stirred and mixed to prepare a blue hair dye. The pH of the obtained hair dye is 3
．． It was 3.
この染毛剤を使用して染着性、染色堅牢性などの諸試験
について評価した。その結果、染毛完了時間は１０分で
、染着速度は極めて早く、毛髪は青色（正常の色調）に
均一に染色されていた。堅牢性試験後も１０色を呈し、
かつ正常の色調を保ち、染色堅牢性は長汀であった。Using this hair dye, various tests such as dyeability and color fastness were evaluated. As a result, it took 10 minutes to complete the hair dyeing, the dyeing speed was extremely fast, and the hair was uniformly dyed blue (normal tone). Even after the fastness test, it exhibits 10 colors,
Moreover, the color tone remained normal, and the color fastness was excellent.
比較例 ・１
キサンタンガムを使用しない他は、実施例１と同様に行
なって、比較の染毛剤を調整した。Comparative Example 1 A comparative hair dye was prepared in the same manner as in Example 1, except that xanthan gum was not used.
この染毛剤を使用して前記の諸試験を行なった結果、染
毛完了時間は５０分で染着速度は遅かった。毛髪は略々
均一に、かつ青色に染色されていたが、堅牢性試験後の
褪色は著るしく、堅牢性は著るしく不良であった。As a result of conducting the above-mentioned tests using this hair dye, the hair dyeing completion time was 50 minutes and the dyeing speed was slow. Although the hair was dyed almost uniformly and blue, the color fading after the fastness test was significant, and the fastness was extremely poor.
実施例 ２
ベンジルアルコールと水の総置は一定としたまま、比率
をｉｉ表の如く、種々変化させる他は実施例１と同様に
行ない、その結果を第１表に示した。Example 2 The same procedure as in Example 1 was carried out except that the ratios of benzyl alcohol and water were kept constant as shown in Table ii, and the results are shown in Table 1.
第 １ 表
実施例 ３
キサンタンガム０．５部及び水８０部を均一に溶解し、
この溶液の中に７エネチルアルコール１０゜３部、ｄシ
性染料の橙色２０５号（Ｃ，ｌ雇１５５１０）０．９部
、酸性染料の紫色４０１号（Ｃ，１扁：６０７３０）０
．３部、コバ７酸８部を添加して、均一に攪拌混合して
赤褐色系の染毛剤を調製した。Table 1 Example 3 0.5 parts of xanthan gum and 80 parts of water were uniformly dissolved,
Into this solution are 10° 3 parts of 7-enethyl alcohol, 0.9 parts of d-crystalline dye Orange No. 205 (C, 15510), and 0.9 parts of acidic dye Purple No. 401 (C, 1:60730).
．． 3 parts and 8 parts of coba-7 acid were added thereto and uniformly stirred and mixed to prepare a reddish-brown hair dye.
得られた染毛剤のＰＨは３．１であった。The pH of the obtained hair dye was 3.1.
この染毛剤を使用して染着性、染色堅牢性な矛の諸試験
について評価した。その結果、染毛完了時間は１０分で
、染着速度は極めて早く、毛先は赤褐色（正常の色調）
に均一に染色されていた。Using this hair dye, various tests on dyeability and color fastness were evaluated. As a result, hair dyeing took only 10 minutes, the dyeing speed was extremely fast, and the ends of the hair were reddish brown (normal color tone).
were uniformly stained.
堅牢性試験後も濃色を呈し、かつ正常の色調を保ち、染
色堅牢性は良好であった。Even after the fastness test, it exhibited a deep color and maintained a normal color tone, and the color fastness was good.
実施例 ４
キサンタンガム１．０部及び水７５．７５部を均一に溶
解し、この溶液の中にアニスアルコール２０部、酸性染
料の褐色２０１号（Ｃ，Ｉ！２０１７０）０．４部、酸
性染料の黄色４号（Ｃ，Ｉム１９１４０）０．３部、酸
性染料の黒色４０１号（Ｃ。Example 4 1.0 part of xanthan gum and 75.75 parts of water were uniformly dissolved, and in this solution were added 20 parts of anise alcohol, 0.4 part of acid dye Brown No. 201 (C, I! 20170), and acid dye. Yellow No. 4 (C, Im 19140) 0.3 parts, acid dye Black No. 401 (C.
Ｉｎ２０４７０ ）ヲ０．０５ｍ、 ！Ｊ ：４２．５
ｍヲ添加して均一に攪拌混合して本発明の黒色系の染毛
剤を調整した。得られた染毛剤のＰＨは約２．１であっ
た。。In20470) wo 0.05m, ! J:42.5
A black hair dye of the present invention was prepared by adding m and stirring and mixing uniformly. The pH of the obtained hair dye was approximately 2.1. .
この染毛剤を使用して染着性、染色堅牢性などのｌｉｔ
試験について評価した。その結果、染毛完了時間は１０
分で、染着速度は極めて早く、毛髪は黒色（正常の色調
）に均一に染色されていた。堅牢性試験後も濃２色を呈
し、かつ正常の色調を保ち、染色堅牢性は良好であった
。This hair dye can be used to improve dyeability, color fastness, etc.
The test was evaluated. As a result, the hair dyeing completion time is 10
Within minutes, the dyeing speed was extremely fast and the hair was uniformly dyed black (normal tone). Even after the fastness test, it exhibited two deep colors and maintained its normal color tone, showing good color fastness.
比較例 ２
キサンタンガムの代りにヒドロキシエチルセルロースを
使用する他は、実施例１と同様に行なって比較の染毛剤
を調整した。Comparative Example 2 A comparative hair dye was prepared in the same manner as in Example 1, except that hydroxyethyl cellulose was used instead of xanthan gum.
この染毛剤を使用して前記の諸試験を行なった結果、染
毛完了時間は３０分で染着速度は遅かった。毛髪は略々
均一に、かつ青色に染色されていたが、堅牢性試験後に
褐色を認め、堅牢性は不良であった。As a result of conducting the above-mentioned tests using this hair dye, the hair dyeing completion time was 30 minutes and the dyeing speed was slow. Although the hair was dyed almost uniformly and blue, a brown color was observed after the fastness test, and the fastness was poor.
又、この染毛剤の長期保存品（３５℃、６力月）は、さ
らに著るしく染色性、堅牢性が低下した。Furthermore, when this hair dye was stored for a long time (35° C., 6 months), the dyeability and fastness were even more significantly reduced.
比較例 ３
キサンタンガムの代りにカルボキシメチルセルロースを
使用する他は、実施例１と同様に行なって比較の染毛剤
を調整した。Comparative Example 3 A comparative hair dye was prepared in the same manner as in Example 1, except that carboxymethyl cellulose was used instead of xanthan gum.
この染毛剤を使用して前記の諸試験を行なった結果、染
毛完了時間は４０分で染着速度は遅かった。毛髪は略々
均一に、かつ青色に染色されていたが、堅牢性試験後の
褪色は著るしく、堅牢性は不良であった。As a result of conducting the above-mentioned tests using this hair dye, the hair dyeing completion time was 40 minutes and the dyeing speed was slow. Although the hair was dyed almost uniformly in blue, the color fading after the fastness test was significant and the fastness was poor.
比較例 ４
ベンジルアルコールの代りにエタノールを使用する他は
、実施例１と同様に行なって比較の染毛剤を調整した。Comparative Example 4 A comparative hair dye was prepared in the same manner as in Example 1, except that ethanol was used instead of benzyl alcohol.
この染毛剤を使用して前記の諸試験を行なった結果、染
毛完了時間は５０分で染着速度は遅かった。As a result of conducting the above-mentioned tests using this hair dye, the hair dyeing completion time was 50 minutes and the dyeing speed was slow.
毛髪は略々均一に、かつ青色に染色されていたが、堅牢
性試験後の褪色は奢るしく、堅牢性１１Ｆ着るしく不良
であった。Although the hair was dyed almost uniformly and blue, the color fading after the fastness test was unsatisfactory, and the fastness was 11F, which was unsuitable.
比較例 ５
ベンジルアルコールの代りにスチレン、グリコールを使
用する他は、実施例１と同様に行なって、比較の染毛剤
を調整した。Comparative Example 5 A comparative hair dye was prepared in the same manner as in Example 1, except that styrene and glycol were used instead of benzyl alcohol.
この染毛剤を使用して前記の諸試験を行なった結果、染
毛完了時間は３０分で染着速度は遅かった６毛髪は略々
均一に、かつ青色に染色されていたが、堅牢性試験後に
褪色を認め、堅牢性は不良であった。As a result of conducting the above-mentioned tests using this hair dye, it was found that the completion time of hair dyeing was 30 minutes and the dyeing speed was slow.6 The hair was dyed almost uniformly and blue, but the color fastness was poor. Fading was observed after the test, and the fastness was poor.
手続補正書（自発）
」、事件の表示
昭和５９年特許願第１４１１２１号
２、発明の名称
染毛剤
８、補正をする者
事件との間係 特許出願人
住所 東京都墨田区墨田五丁目１７番４号〒５８４ 大
阪市部島区友淵町１丁目５番９０号鉾紡株式会社特許部
電話（０６）９２１−１２５１
６、補正の内容
（１）明細書、第２頁第１６行に記−の「完了」を「完
了」に補正する。Procedural Amendment (Spontaneous)”, Case indication 1982 Patent Application No. 141121 2, Name of invention Hair dye 8, Person making the amendment Relationship with the case Patent applicant address 17 Sumida 5-chome, Sumida-ku, Tokyo No. 4 1-5-90 Tomobuchi-cho, Bejima-ku, Osaka 584 Hokobo Co., Ltd. Patent Department Telephone (06) 921-1251 6. Contents of amendment (1) Specification, page 2, line 16 Correct "Complete" in the description to "Complete".
Claims (1)
基、Ｒ＿２は−ＣＨ＿２ＯＨ＿基、−ＣＨ＿２ＣＨ＿２
ＯＨ基、▲数式、化学式、表等があります▼基、−ＣＨ
＿２ＣＨ＿２ＣＨ＿２ＯＨ基、▲数式、化学式、表等が
あります▼基、▲数式、化学式、表等があります▼基、
▲数式、化学式、表等があります▼基、 −ＣＨ＝ＣＨ・ＣＨ＿２ＯＨ基または−ＯＣＨ＿２ＣＨ
＿２ＯＨ基を表わす。 で表わされる芳香族アルコールとキサンタンガムと酸性
染料と酸と水を含有しており、そして、前記芳香族アル
コールと水との重量比が３／９７〜８０／２０であるこ
とを特徴とする染毛剤。(1) General formula below ▲ Numerical formula, chemical formula, table, etc. ▼ (In the formula, R_1 is a hydrogen atom, methyl group or methoxy group, R_2 is -CH_2OH_ group, -CH_2CH_2
There are OH groups, ▲mathematical formulas, chemical formulas, tables, etc.▼ groups, -CH
＿2CH_2CH_2OH group, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ group, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ group,
▲There are mathematical formulas, chemical formulas, tables, etc.▼ Group, -CH=CH・CH_2OH group or -OCH_2CH
_2OH group. A hair dye containing an aromatic alcohol represented by: agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14112184A JPS6122007A (en) | 1984-07-06 | 1984-07-06 | Hair dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14112184A JPS6122007A (en) | 1984-07-06 | 1984-07-06 | Hair dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6122007A true JPS6122007A (en) | 1986-01-30 |
| JPH0232253B2 JPH0232253B2 (en) | 1990-07-19 |
Family
ID=15284641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14112184A Granted JPS6122007A (en) | 1984-07-06 | 1984-07-06 | Hair dye |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6122007A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6153211A (en) * | 1984-08-21 | 1986-03-17 | Kanebo Ltd | Hair dye |
| JPH05105615A (en) * | 1991-02-15 | 1993-04-27 | Shiseido Co Ltd | Acidic dyeing composition for hair |
| WO2000076468A1 (en) * | 1999-06-10 | 2000-12-21 | Kanebo, Limited | Method for applying hair dye |
| US7166136B2 (en) | 2001-01-09 | 2007-01-23 | Shiseido Company, Ltd. | Hairdye preparation |
| DE102013202541A1 (en) | 2013-02-18 | 2014-08-21 | Sms Siemag Ag | Method for detecting interruption of drive train in rolling stand for rolling rolled stock, involves providing angular speed of drive shaft of drive, and determining initial point and end time of time interval |
| WO2022190834A1 (en) * | 2021-03-12 | 2022-09-15 | ホーユー株式会社 | Hair coloring composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5291028A (en) * | 1976-01-28 | 1977-08-01 | Kindai Kagaku Kk | Dyeing agents for keratin series fibers |
| JPS5512407A (en) * | 1978-07-12 | 1980-01-29 | Nippon Seiko Kk | Method of compensating error in measuring circle of arc and meter with compensator |
| JPS59108710A (en) * | 1982-12-13 | 1984-06-23 | Kao Corp | Hair cosmetic |
-
1984
- 1984-07-06 JP JP14112184A patent/JPS6122007A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5291028A (en) * | 1976-01-28 | 1977-08-01 | Kindai Kagaku Kk | Dyeing agents for keratin series fibers |
| JPS5512407A (en) * | 1978-07-12 | 1980-01-29 | Nippon Seiko Kk | Method of compensating error in measuring circle of arc and meter with compensator |
| JPS59108710A (en) * | 1982-12-13 | 1984-06-23 | Kao Corp | Hair cosmetic |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6153211A (en) * | 1984-08-21 | 1986-03-17 | Kanebo Ltd | Hair dye |
| JPH0553771B2 (en) * | 1984-08-21 | 1993-08-10 | Kanebo Ltd | |
| JPH05105615A (en) * | 1991-02-15 | 1993-04-27 | Shiseido Co Ltd | Acidic dyeing composition for hair |
| WO2000076468A1 (en) * | 1999-06-10 | 2000-12-21 | Kanebo, Limited | Method for applying hair dye |
| US7166136B2 (en) | 2001-01-09 | 2007-01-23 | Shiseido Company, Ltd. | Hairdye preparation |
| DE102013202541A1 (en) | 2013-02-18 | 2014-08-21 | Sms Siemag Ag | Method for detecting interruption of drive train in rolling stand for rolling rolled stock, involves providing angular speed of drive shaft of drive, and determining initial point and end time of time interval |
| WO2022190834A1 (en) * | 2021-03-12 | 2022-09-15 | ホーユー株式会社 | Hair coloring composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0232253B2 (en) | 1990-07-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |