JPS60261575A - Partial painting method of plastic molded article - Google Patents

Partial painting method of plastic molded article

Info

Publication number
JPS60261575A
JPS60261575A JP11811484A JP11811484A JPS60261575A JP S60261575 A JPS60261575 A JP S60261575A JP 11811484 A JP11811484 A JP 11811484A JP 11811484 A JP11811484 A JP 11811484A JP S60261575 A JPS60261575 A JP S60261575A
Authority
JP
Japan
Prior art keywords
resin
paint
primer
painted
mold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11811484A
Other languages
Japanese (ja)
Inventor
Masafumi Ono
雅史 大野
Tadahiko Morigaki
森垣 忠彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissan Motor Co Ltd
Original Assignee
Nissan Motor Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Motor Co Ltd filed Critical Nissan Motor Co Ltd
Priority to JP11811484A priority Critical patent/JPS60261575A/en
Publication of JPS60261575A publication Critical patent/JPS60261575A/en
Pending legal-status Critical Current

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  • Application Of Or Painting With Fluid Materials (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To make the parting line clear by coating a primer on the masked inner peripheral surface, removing the masking, clamping the mold, injecting a resin, masking the part not to be painted, and then overcoating. CONSTITUTION:A masking member is furnished to the inner peripheral surface of a cavity 1, a primer paint 5a is previously mold-coated, and the primer paint is closely adhered to the surface to be painted of a plastic molded article when the plastic is molded. Simultaneously, the end surface of the primer paint at the parting line of the part not to be painted is completely covered with the resin and a paint 5b. Consequently, the primer paint is not exposed at the parting line part, and the resistance of the coated film to solvents is improved.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、例えば自動車の樹脂バンパー等のような樹脂
成形品を部分的に塗装J−る方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for partially painting a resin molded article, such as a resin bumper for an automobile.

(先行技術) 金属製品ないし樹脂製品等、各種製品の塗装面の一部分
のみを着色する場合には、塗装作業時に塗装面のうちの
一部分のみを露呈し、他の非塗装部を被覆して塗装する
(Prior art) When coloring only a part of the painted surface of various products such as metal products or resin products, only a part of the painted surface is exposed during the painting process, and other non-painted parts are covered and painted. do.

このような部分塗装を行うに(よ一般に7スキングテー
ブあるいはマスキング治具で製品を部分的に被覆した状
態で、スプレーガンを用いて塗料を噴霧するいわゆるス
プレー式塗装方法がとられている。このスプレー式の塗
装方法ta第12図(A>に示すように、まず前記製品
例えばバンパーWの非塗装部1(破線で囲む領域)に耐
熱性、耐溶剤性のマスキングテープ2を貼着する。
To perform such partial painting, a so-called spray painting method is used, in which the product is partially covered with a 7-sking table or masking jig, and then the paint is sprayed using a spray gun. As shown in FIG. 12 (A), a heat-resistant and solvent-resistant masking tape 2 is first applied to the non-painted area 1 (area surrounded by broken lines) of the product, for example, the bumper W.

次に第12図(B)に示すようにこのバンパーWの表面
を全体にわたりスプレーガン3でプライマー塗料5aを
噴霧して、プライマー塗装を行う。
Next, as shown in FIG. 12(B), the primer paint 5a is sprayed over the entire surface of the bumper W using the spray gun 3 to perform primer coating.

このプライマー塗装したものを雰囲気温度約120℃の
乾燥炉内に10分程度入れて焼付乾燥させ(塗料によっ
ては常温の場合もある)、このプライマー塗料5aをバ
ンパーWに確実に密着させる。
The primer coated product is placed in a drying oven at an ambient temperature of about 120° C. for about 10 minutes and baked to dry (depending on the paint, it may be at room temperature) to ensure that the primer paint 5a adheres to the bumper W.

さらに第12図(C)に示すようにこのプライマー塗料
5aの上に上塗り塗料5bをスプレーガン4で噴霧し、
これを雰囲気渇瓜約120℃の乾燥炉内で20分程度乾
燥させ、プライマー塗料と」二塗り塗装との密着性を高
める。
Furthermore, as shown in FIG. 12(C), a top coat 5b is sprayed onto the primer paint 5a using a spray gun 4,
This is dried in a drying oven at a temperature of about 120°C for about 20 minutes to improve the adhesion between the primer paint and the second coat.

最後に第12図(D )に示すように前述のマスキング
テープ2を剥離する。マス4−ングデー12を除去づれ
ば、第12図(E)に示ずJ、うに、非塗装部1には塗
料が付着していないバンパーWが得られることになる。
Finally, as shown in FIG. 12(D), the masking tape 2 described above is peeled off. If the mass 4-ing day 12 is removed, a bumper W with no paint attached to the non-painted portion 1 will be obtained, as shown in FIG. 12(E).

ところが、このような塗装方法によって塗装されたバン
パーWでは、第12図(「)に示づように塗膜5の端面
6において耐溶剤性の悪いプライマー塗料5aが外部に
露?するため、塗装見切り線部が不明確になるという問
題点がある。
However, in the bumper W painted by such a painting method, as shown in FIG. There is a problem that the parting line becomes unclear.

(発明の目的) 本発明は、−[述した問題点に着目してなされたもので
、塗装した後の見切り線が明確になり、しかも塗装作業
も迅速かつ簡単に行うことができる樹脂成形品の部分塗
装方法を提供することを目的i どする。
(Purpose of the Invention) The present invention has been made by focusing on the above-mentioned problems, and provides a resin molded product that has a clear parting line after painting and can be painted quickly and easily. The purpose of the present invention is to provide a partial painting method.

(発明の構成) 上記目的を達成するために、本発明では、樹脂成形を行
う前に、予めキャビティ内周面にプライマー塗料を塗布
し、樹脂成形をおこなったときに、このプライマー塗料
が樹脂成形品の表面にモールドコートされるとともに非
塗装部の見切り線部分ではプライマー塗料の端面を樹脂
と上塗り塗料とで覆い隠すようにした点を特徴とするも
のである。
(Structure of the Invention) In order to achieve the above object, in the present invention, before performing resin molding, a primer paint is applied in advance to the inner peripheral surface of the cavity, and when resin molding is performed, this primer paint is applied to the resin molding. It is characterized in that the surface of the product is mold-coated, and the end surfaces of the primer paint are covered with resin and top coat paint at the parting line portion of the unpainted part.

(実施例) 以下、本発明方法の一実施例を図面に基づいて詳細に説
明する。
(Example) Hereinafter, an example of the method of the present invention will be described in detail based on the drawings.

本発明方法はモールドコート処理を利用して塗装を行う
ものである。ここにモールドコート処理とは樹脂成形品
を作るときに使用する成形金型のキャビティ内に予め塗
料を塗布し、次に樹脂をインジェクションしたとき、樹
脂表面に塗料を密着させる方法をいう。
The method of the present invention performs painting using a mold coating process. Mold coating treatment here refers to a method in which paint is applied in advance to the cavity of a mold used to make a resin molded product, and then when resin is injected, the paint adheres to the resin surface.

ただし、このモールトコ−1へ処理を行うに当り、樹脂
成形品用の樹脂基材の種類によっては塗装工程が多少相
違するため、以下の説明は便宜的に樹脂基材として通常
のポリプロピレンを用いて樹脂3− バンパーを成形する場合について説明する。なお第12
図(A)〜(F)に示す部材と同一部材には同一符号を
使用する。
However, when processing this Moltco-1, the coating process differs slightly depending on the type of resin base material for the resin molded product, so the following explanation uses ordinary polypropylene as the resin base material for convenience. Resin 3 - The case of molding a bumper will be explained. Furthermore, the 12th
The same reference numerals are used for the same members as those shown in Figures (A) to (F).

まず、第1図(△)に示す成形金型10を予め約70℃
程度に加熱した状態でキャビティ内周面10aにM型剤
(ワックスを主成分とゴるもの)11を塗布し、これを
拭きとる。第1図(B)は離型剤11のWみが多少誇張
して開示されているが、この1m型剤11はキャピテイ
内周面10a全体にわたって均等に膜状に塗布されてい
る。
First, the molding die 10 shown in FIG. 1 (△) is heated to about 70°C
An M-type agent (based on wax as a main component) 11 is applied to the inner circumferential surface 10a of the cavity in a moderately heated state, and this is wiped off. Although the W shape of the mold release agent 11 is somewhat exaggerated in FIG. 1(B), the 1m mold agent 11 is evenly applied in a film over the entire inner peripheral surface 10a of the cavity.

次に第2図(A)に示ずようにこのキャビティ内周面1
0aの所定位置に所定の肉#11を有するマスキングテ
ープ2(又はマスキング冶具を用いでもよい)を貼着す
る。
Next, as shown in FIG. 2(A), this cavity inner peripheral surface 1
A masking tape 2 (or a masking jig may be used) having a predetermined meat #11 is attached to a predetermined position of 0a.

第3図(A)はプライマー塗装工程を示すもので、この
工程では離型剤11どマスキングテープ2を1ライマー
塗料58が均一な厚さ[2で覆うようにスプレー刀゛ン
3で塗布する。このプライマー塗料5aを塗布した後に
セツティングタイムを約5分とり、プライマー塗料58
中の溶剤が完全4− に蒸発した状態で前記マスキングテープ2を取り外す。
Figure 3 (A) shows the primer coating process, in which a spray knife 3 is used to coat a masking tape 2 with a release agent 11 and a primer paint 58 to a uniform thickness. . After applying this primer paint 5a, take a setting time of about 5 minutes and apply the primer paint 58.
The masking tape 2 is removed after the solvent inside has completely evaporated.

なお、このマスキングテープ2は前記離型剤11がキャ
ピテイ内周面10aとの間に介在しているために比較的
容易に剥離できる。また、このマスキングテープ2は熱
変形も負(〕ず上塗り塗料の溶剤にも侵されていないの
で再利用することも可能である。
Note that this masking tape 2 can be peeled off relatively easily because the mold release agent 11 is interposed between the masking tape 2 and the cavity inner circumferential surface 10a. Furthermore, this masking tape 2 is not subject to thermal deformation and is not affected by the solvent of the top coat, so it can be reused.

このマスキングテープ2が除去された後の固定側金型1
0に、第4図に示すようにコア側金型12を型締めする
。この型締めによって生じたキャビティ13は、単に断
面逆コ字状をしたものではなく、プライマー塗料5aの
肉厚12だけその一部が突出しており、しかもこの突出
した部分13aはプライマー塗料5aの表面14とはほ
ぼ面一となっている。
Fixed side mold 1 after this masking tape 2 is removed
0, the core side mold 12 is clamped as shown in FIG. The cavity 13 created by this mold clamping does not simply have an inverted U-shaped cross section, but a part of it protrudes by the thickness 12 of the primer paint 5a, and this protruding part 13a is the surface of the primer paint 5a. It is almost on the same level as 14.

第5図は射出成形装置Mの概略断面図であり、この射出
成形装置Mのキャビティ13内に約40℃に加熱されて
流動性をもった樹脂をインジェクションする。この樹脂
15は約0.5分で固化する。この樹1115とプライ
マー塗料5aとはアンカー効果により強固に密着し、し
かもプライマー塗料5aは離型剤11を介して固定金型
10と接しているため、この金型10,12内から固化
した樹脂バンパーWを取り出す場合も、プライマー塗料
5aが固定金型10に付着し、樹脂バンパーWからプラ
イマー塗料11が剥離するという虞れは全くない。
FIG. 5 is a schematic cross-sectional view of an injection molding device M, in which resin heated to about 40° C. and made fluid is injected into a cavity 13 of the injection molding device M. This resin 15 solidifies in about 0.5 minutes. This tree 1115 and the primer paint 5a are firmly attached due to the anchor effect, and since the primer paint 5a is in contact with the fixed mold 10 via the mold release agent 11, the resin solidified from within the molds 10, 12 Even when the bumper W is taken out, there is no fear that the primer paint 5a will adhere to the fixed mold 10 and the primer paint 11 will peel off from the resin bumper W.

この金型10,12内から取り出した樹脂バンパーWは
、第6図(A)(B)に示すように、プライマー塗料5
aの表面14と樹脂バンパーWの非塗装部1の表面1a
とがほぼ面一となったものとなる。づ−なわち、耐溶剤
性が悪いプライマー塗料5aの端面6はバンパーの基材
である樹脂15によって覆われていることになるので、
この塗装方法にJ34Jる現段階では少なくともこの端
面6に関する限り、児切り線が不明確になるという事態
は防止されることになる。
The resin bumper W taken out from the molds 10 and 12 is coated with primer paint 5 as shown in FIGS.
a surface 14 and the surface 1a of the non-painted part 1 of the resin bumper W
and are almost flush. In other words, since the end surface 6 of the primer paint 5a with poor solvent resistance is covered with the resin 15 which is the base material of the bumper,
At the current stage of applying this coating method, at least as far as this end face 6 is concerned, the situation where the cut line becomes unclear can be prevented.

:1 ′″11脂t:y t< −W″対6第7図(A
)1°示すように、マスキング治具16をセットづる。
:1 ''11 fat t:y t<-W'' vs. 6 Figure 7 (A
) 1° Set the masking jig 16 as shown.

このマスキング治具16は前記非塗装部1の外周よりわ
ずかに小さいものを用いる。
This masking jig 16 is slightly smaller than the outer circumference of the non-coated portion 1.

このマスキング治具16をセラ1〜した樹脂バンパーW
を第8図に示すようなキャスター17上に設けた回合1
Bに載置し、この樹脂バンパーWの塗装面に刻して上塗
り塗料5bをスプレーガン4によって吹きつける。この
上塗り塗装後、樹脂バンパーW@雰囲気濡aが120℃
の炉中に約20分入れ焼付番プを行う等、常法によって
塗膜を形成さゼる。
Resin bumper W with this masking jig 16
is installed on the caster 17 as shown in FIG.
B, and the painted surface of this resin bumper W is engraved and top coat paint 5b is sprayed with a spray gun 4. After this top coat, the resin bumper W@atmospheric wetness a is 120℃
A coating film is formed by a conventional method such as placing it in a furnace for about 20 minutes and baking it.

次に、第9図に示すように前記マスキング治具16を樹
脂バンパーWから外す。このマスキング治具16は前述
のように非塗装部1よりわずかに小さいものを使用して
いるために、このマスキング治具16を取外せば、上塗
り塗料5bは第10図に多少誇張して示すように上塗り
塗料5bの一部が非塗装部1上に)lき上った状態で突
出する。
Next, as shown in FIG. 9, the masking jig 16 is removed from the resin bumper W. As described above, this masking jig 16 is slightly smaller than the non-painted area 1, so when this masking jig 16 is removed, the top coat 5b is shown somewhat exaggerated in FIG. As shown in FIG.

これは上塗り塗料51)の剥離強度が下記(1)式の関
係にあるから生じるものである。なお、この(1)式の
詳細は下記する表に示しである。
This occurs because the peel strength of the top coat 51) satisfies the relationship expressed by the following equation (1). The details of this formula (1) are shown in the table below.

7− プライマー塗装面との剥離強度(A) ン 塗膜強度(
B) 〉 プライマー非塗装面の剥離強度(C)・・・
・・・・・・(1) すなわち、上記(1)式から明らかなように、上塗り塗
料5bはプライマー塗料5aとは相当強固に密着してい
るが、樹脂バンパーWの非塗装部8− 1との密着度は弱いために、前記マスキング治具16の
剥離に伴ってマスキング冶具16外周の」ニ塗り塗料5
bが引き上げられ、破断ザることになる。
7- Peel strength with primer coated surface (A) N Paint film strength (
B) 〉 Peel strength of primer-unpainted surface (C)...
...(1) That is, as is clear from the above equation (1), the top coat paint 5b adheres to the primer paint 5a quite firmly, but the non-painted portion 8-1 of the resin bumper W Since the degree of adhesion with the masking jig 16 is weak, as the masking jig 16 peels off, the "double paint 5" on the outer periphery of the masking jig 16 is removed.
b will be pulled up and break.

このように上塗り塗料5hが非塗装部1上にまで突出す
るということは、取りも直さずプライマー塗料5aが外
部に全く露呈しないことを意味し、耐溶剤性の悪いプラ
イマー塗料5aを樹脂バンパーWの樹脂15と上塗り塗
料5bとにより封じ込め、溶剤がプライマー塗料5aに
接触しないようにしている。
The fact that the top coat 5h protrudes above the non-painted area 1 in this way means that the primer paint 5a is not exposed to the outside at all without removing it. The resin 15 and the top coating 5b prevent the solvent from coming into contact with the primer coating 5a.

最後に、この突出した上塗り塗料511にカッター等を
用いて切断J−れば、第11図に示すような塗装見切り
線部が明確な樹脂バンパーW4!:得ることができる。
Finally, by cutting the protruding top coat 511 using a cutter or the like, a resin bumper W4 with a clear paint parting line as shown in FIG. 11 is obtained! :Obtainable.

なお、上述した実施例の他【こ樹脂バンパー用の塞材と
しては前記表にも示すように塗装用ボリプDピレン、R
IMウレタン等を使用覆ることもで・きる。また、本実
施例ではマスキング部材を取付(プるに先立ってキャビ
ティ内周面に蘭型剤を塗布したが、内周面にテフロン加
工を施したもの、もしくは頗型竹の良い樹脂を使用した
場合等には必要ない。
In addition to the above-mentioned examples, as the sealing material for the resin bumper, as shown in the table above, paint volip D-pyrene, R-
It can also be covered with IM urethane, etc. In addition, in this example, the masking member was attached (prior to pulling, an orchid type agent was applied to the inner circumferential surface of the cavity, but the inner circumferential surface was coated with Teflon, or a resin with a good cross-section shape was used. It is not necessary in some cases.

(発明の効果) 以上の説明より明らかなように、本発明方法によればキ
ー・ビティ内周面にマスキング部材を取付(JIこ(殻
プライマー塗¥ミ1を予めモールドニコ−1〜してa3
ぎ、樹脂成形時にこのプライマー塗料を樹脂成形品の塗
装面に密着させるとともに非塗装部の見切り線部分では
このプライマー塗料の端面を前記樹脂と上塗り塗料とで
覆い隠すようにしたため、児切り線部分にプライマー塗
料が露出l!す′、塗膜の耐溶剤性が向上づることがで
きるため塗装にとってはきわめて重要な塗装見切り線部
をきわめて明確にすることができることになる。
(Effects of the Invention) As is clear from the above explanation, according to the method of the present invention, a masking member is attached to the inner circumferential surface of the key bit (JI) (shell primer coating 1 is preliminarily coated with Mold Nico-1). a3
During resin molding, this primer paint was brought into close contact with the painted surface of the resin molded product, and at the parting line part of the non-painted part, the end face of this primer paint was covered with the resin and top coat, so that the parting line part Primer paint is exposed! Since the solvent resistance of the paint film can be improved, the paint separation line, which is extremely important for painting, can be made very clear.

【図面の簡単な説明】[Brief explanation of the drawing]

第1へ・3図(△)は、本発明方法の一実施例を工程別
に示す要部斜視図、第1〜3図(B)は前1) :(記第1〜3図(△)中に示す−3−B線に沿う断面
図、第4図は同実施例の型締め状態を示す断面図、=1
1− 持前出願人 日産自動車株式会杉 第5図は射出成形装置の断面概略図、第6,7図(A)
は同実施例のざらに伯の工程におGプる要部斜視図、第
6,7図(B)は前記第6,7図(Δ)に示すB−B線
に沿う断面図、第8因は同実施例の上塗り塗装工程を示
す概略斜視図、第9図は同実施例のマスキング治具を外
した状態を示す斜視図、第10図は第9図のx−X線に
沿う断面図、第11図は同実施例におlプる塗装完了状
態の樹脂バンパーを示す断面図、第12図(A)〜(E
)は従来の部分塗装方法を工程別に示す要部斜視図、第
12図(F)は同方法により塗装を完了した状態のバン
パーを示す断面図である。 1・・・非塗装部、 2・・・マスキングテープ、5・
・・塗膜、 5a・・・プライマー塗料、5b・・・上
塗り塗料、 6・・・端面、10・・・キャビ側金型、
10a・・・キャビティ内周面、11・・・離型剤、1
2・・・コア側金型、13・・・キャビティ、 15・
・・樹脂、16・・・マスキング治具、W・・・樹脂バ
ンパー。 12− 13− 区 寸 田 ≧1 −
Figures 1 and 3 (△) are perspective views of essential parts showing one embodiment of the method of the present invention step by step; Figures 1 to 3 (B) are front 1): (Figures 1 to 3 (△)) 4 is a cross-sectional view showing the mold clamping state of the same example, =1
1- Applicant: Nissan Motor Co., Ltd. Cedar Figure 5 is a cross-sectional schematic diagram of an injection molding device, Figures 6 and 7 (A)
6 and 7 (B) are cross-sectional views taken along the line B-B shown in FIGS. 6 and 7 (Δ), and FIG. The 8th factor is a schematic perspective view showing the top coating process of the same example, Fig. 9 is a perspective view showing the state in which the masking jig of the same example is removed, and Fig. 10 is along the x-X line of Fig. 9. 11 is a sectional view showing a resin bumper in a painted state according to the same embodiment, and FIGS. 12(A) to (E)
) is a perspective view of a main part showing a conventional partial painting method step by step, and FIG. 12(F) is a sectional view showing a bumper in a state where painting is completed by the same method. 1... Non-painted part, 2... Masking tape, 5...
... Paint film, 5a... Primer paint, 5b... Top coat paint, 6... End surface, 10... Cavity side mold,
10a... Cavity inner peripheral surface, 11... Mold release agent, 1
2... Core side mold, 13... Cavity, 15.
...Resin, 16...Masking jig, W...Resin bumper. 12- 13- Kusuda≧1-

Claims (1)

【特許請求の範囲】 成形金型のキャビティ内周面の一部にマスキング部材を
取付ける工程と、このキャビティ内周面にプライマー塗
装を塗布する工程と、前記マスキング部材を除去した後
にコア側金型を型締めし、キャビティ内に樹脂を射出す
る工程と、この型内から樹脂成形品を取り出し、塗装面
のうち非*装部にマスキング治具を取付【プる工程と、
前記塗装面に上塗り塗料を塗布し、焼付を行う工程と、
前記マスキング治具を剥mする工程とからなる樹脂成形
品の部分塗装方法。
[Claims] A step of attaching a masking member to a part of the inner circumferential surface of the cavity of a molding die, a step of applying a primer coating to the inner circumferential surface of the cavity, and a step of attaching a masking member to a part of the inner circumferential surface of the cavity of the mold, and after removing the masking member, a step of attaching a masking member to a part of the inner circumferential surface of the cavity of the mold. A process of clamping the mold and injecting resin into the cavity, a process of taking out the resin molded product from the mold, and attaching a masking jig to the non-applied area of the painted surface,
a step of applying a top coat to the painted surface and baking it;
A method for partially painting a resin molded product, comprising the step of peeling off the masking jig.
JP11811484A 1984-06-11 1984-06-11 Partial painting method of plastic molded article Pending JPS60261575A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11811484A JPS60261575A (en) 1984-06-11 1984-06-11 Partial painting method of plastic molded article

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11811484A JPS60261575A (en) 1984-06-11 1984-06-11 Partial painting method of plastic molded article

Publications (1)

Publication Number Publication Date
JPS60261575A true JPS60261575A (en) 1985-12-24

Family

ID=14728370

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11811484A Pending JPS60261575A (en) 1984-06-11 1984-06-11 Partial painting method of plastic molded article

Country Status (1)

Country Link
JP (1) JPS60261575A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0639860A (en) * 1992-03-02 1994-02-15 Shatai Kogyo Kk Production of substrate treatment layer integrally molded reinforced plastic and molded product

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0639860A (en) * 1992-03-02 1994-02-15 Shatai Kogyo Kk Production of substrate treatment layer integrally molded reinforced plastic and molded product

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