JPS60211777A - Manufacture of battery - Google Patents
Manufacture of batteryInfo
- Publication number
- JPS60211777A JPS60211777A JP59065212A JP6521284A JPS60211777A JP S60211777 A JPS60211777 A JP S60211777A JP 59065212 A JP59065212 A JP 59065212A JP 6521284 A JP6521284 A JP 6521284A JP S60211777 A JPS60211777 A JP S60211777A
- Authority
- JP
- Japan
- Prior art keywords
- electrodes
- electrolyte
- battery
- charging
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/08—Selection of materials as electrolytes
- H01M10/10—Immobilising of electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
Abstract
Description
【発明の詳細な説明】
a、産業上の利用分野
本発明はバッテリーの製造方法であって、更に詳しくは
、極板間及び周辺に特殊な電解膠質を形成した完成品に
よって短時間充電を可能とし、低温下での効率低下を防
止しその取扱いを便宜ならしめた新規バッテリーを製造
する方法に関するものである。[Detailed Description of the Invention] a. Industrial Application Field The present invention is a method for manufacturing a battery, and more specifically, a finished product in which a special electrolytic glue is formed between and around the electrode plates, which enables short-time charging. The present invention relates to a method for manufacturing a new battery that prevents a decrease in efficiency at low temperatures and facilitates its handling.
b、従来技術
従来型バッテリーにおいては鉛蓄電池においても、また
、アルカリ蓄電池においても陰極板、陽極板間にて電荷
を担持する媒体として電解液を必要とし、その為充電時
間としてかなりの時間を要し、また、寒冷地においては
、低温のため放電効率が低下する等、従来のバッテリー
の取扱いを特に不便にしているものであった。b. Prior Art Conventional batteries, both lead-acid batteries and alkaline batteries, require an electrolytic solution as a medium to carry charge between the cathode plate and the anode plate, and therefore require a considerable amount of charging time. Furthermore, in cold regions, the discharge efficiency decreases due to the low temperature, making handling of conventional batteries particularly inconvenient.
C1発明の目的
本発明は前記従来型バッテリーの各支障を解消するもの
で、極板間及び周辺に電解液と同様の作用をする電解膠
質を形成して充電に要する時間を短縮し、低温下での効
率低下を防止しその取扱いを異常に便宜にする新規のバ
ッテリーの提供を目的とするものである。C1 Purpose of the Invention The present invention solves each of the problems of the conventional battery, and aims to shorten the time required for charging by forming an electrolytic gel that acts similarly to an electrolyte between and around the electrode plates, and to reduce the charging time at low temperatures. The object of the present invention is to provide a new battery that prevents a decrease in efficiency and makes its handling unusually convenient.
d0発明の構成と作用
この発明はまず比重1.00〜1.20(15℃)に調
整した稀硫酸を準備し、膠質形成の構造中心となるケイ
酸ナトリウム溶液、二酸化ケイ素膠質硬液の調整と充放
電特性向上のための水酸化ナトリウム溶液にバリウム、
アルミニウム、カリウム、ジルコニア、チタニウム、カ
ルシウム、ゲルマニウム、マグネシウム等の各金属塩を
溶解もしくは懸濁し、充分冷却した先の稀硫酸に0.5
〜10%(W/’Vl相当、強攪拌を行い静かに注加し
たものを原電解液とするくなお、文中W/Vとは重量又
は容量パーセントの意味である。)。d0 Structure and operation of the invention This invention first prepares dilute sulfuric acid with a specific gravity of 1.00 to 1.20 (15°C), and prepares a sodium silicate solution and silicon dioxide colloid hard liquid, which are the structural center of colloid formation. and barium in sodium hydroxide solution to improve charge/discharge characteristics.
Dissolve or suspend each metal salt such as aluminum, potassium, zirconia, titanium, calcium, germanium, magnesium, etc., and add 0.5% to dilute sulfuric acid after sufficiently cooling.
~10% (equivalent to W/'Vl, the raw electrolyte is one that is stirred vigorously and then gently added. In this text, W/V means weight or volume percent.)
次いで新しい又は放電後に電解液を抜き取ったペースト
式あるいはクラット式極板を使用する蓄電池容器(電解
液のみを備えない完成蓄電池容器)に上記原電解液を注
入し、蓄電池容器への原電解液の注入完了後に約5時間
当該蓄電池に通常の充電を加え、当該約5時間の充電完
了後に約3時間当該蓄電池を放置し自然放電すると当該
充電工程及びその後の放電工程によって変化する陽陰極
板での酸化還元作用と反応熱によって極板間及び周辺に
ケイ酸を骨格の中心としそこにアルミニウム、ナトリウ
ム、マグネシウム、カルシウム、等の金属イオンが結合
し更にその末端基に硫酸根が結合しているゼラチン状で
多孔質の電解膠質が形成され、本発明の新規なバッテリ
ーが完成する。Next, the raw electrolyte is injected into a new storage battery container (completed storage battery container that does not contain only electrolyte) using a paste-type or crat-type electrode plate from which the electrolyte has been removed after discharge, and the raw electrolyte is poured into the storage battery container. After charging is completed, the storage battery is charged normally for about 5 hours, and after the completion of charging for about 5 hours, the storage battery is left for about 3 hours to naturally discharge. Gelatin is made of silicic acid as the center of the skeleton between and around the electrode plates due to redox action and reaction heat, and metal ions such as aluminum, sodium, magnesium, calcium, etc. are bound thereto, and sulfate groups are bound to the terminal groups. A porous electrolytic colloid is formed, and the novel battery of the present invention is completed.
本発明では極板を仕切る隔離板の細孔部にも電解膠質が
形成されるため、物理的衝撃による作用物質の剥脱を防
ぎ極板上部は電解膠質に覆われるため水分の蒸散を防ぎ
極板性能の低下を有効に防止することができる。また、
充放電における電解液の対流と生成ガスの飛散抑制を電
解膠質が行うため電解液必要量がごく少なく充電特性に
優れるものである。さらに電解膠質細孔部に高濃度の8
2804が保持されるため厳寒期での放電特性にも優れ
るものである。また、膠質化しない余剰の電解液(残留
した原電解液)を抜き取って液なしバッテリーとしての
使用も可能である。In the present invention, electrolytic colloid is also formed in the pores of the separator that partitions the electrode plates, which prevents the active substance from peeling off due to physical impact.The upper part of the electrode plate is covered with electrolytic colloid, which prevents water evaporation and prevents the electrode plate from evaporating. Deterioration in performance can be effectively prevented. Also,
Since the electrolytic colloid suppresses the convection of the electrolyte and the scattering of generated gas during charging and discharging, the amount of electrolyte required is extremely small and the charging characteristics are excellent. In addition, a high concentration of 8 is present in the pores of the electrolytic colloid.
Since 2804 is maintained, it has excellent discharge characteristics even in the coldest season. It is also possible to extract excess electrolyte (residual raw electrolyte) that does not turn into colloid and use it as a liquid-free battery.
e0発明の効果
本発明はバッテリーの極板周辺に特殊な電解膠質を形成
させることにより充電は短時間で完了し特に寒冷地での
効率低下の防止及び乾燥地での水分蒸散防止など諸取扱
いが非常に便宜になる等の特徴を特徴する
特許出願人 安 藤 功 −e0Effects of the Invention The present invention forms a special electrolyte around the electrode plates of the battery, so that charging can be completed in a short time, and it can be handled in various ways, such as preventing a drop in efficiency, especially in cold regions, and preventing moisture evaporation in dry regions. Isao Ando - Patent applicant with features such as being very convenient.
Claims (1)
にアルミニウム、ジルコニウム、カリウム、バリウム、
カルシウム、マグネシウム、ゲルマニウム、ニオブ及び
チタニウム等の金属塩を溶解しもしくは懸濁させたもの
を。 稀硫酸に混合してなる原電酢液をバッテリー内に注入し
、該原電酢液のバッテリー内への注入後に充電を行いこ
れにより極板周辺に電解膠質を形成することを特徴とす
るバッテリーの製造方法。[Claims] 1. Aluminum, zirconium, potassium, barium,
Dissolved or suspended metal salts such as calcium, magnesium, germanium, niobium, and titanium. Manufacturing a battery characterized by injecting a raw vinegar solution mixed with dilute sulfuric acid into the battery, charging after injecting the raw vinegar solution into the battery, and thereby forming electrolytic colloid around the electrode plates. Method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59065212A JPS60211777A (en) | 1984-04-03 | 1984-04-03 | Manufacture of battery |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59065212A JPS60211777A (en) | 1984-04-03 | 1984-04-03 | Manufacture of battery |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS60211777A true JPS60211777A (en) | 1985-10-24 |
Family
ID=13280378
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59065212A Pending JPS60211777A (en) | 1984-04-03 | 1984-04-03 | Manufacture of battery |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60211777A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2494628A (en) * | 2011-09-07 | 2013-03-20 | Solaris Holdings Ltd | Dopant for electrolyte |
US8771871B2 (en) | 2005-09-27 | 2014-07-08 | The Furukawa Battery Co., Ltd. | Lead storage battery and manufacturing method of the same |
CN108461830A (en) * | 2018-04-26 | 2018-08-28 | 天能集团(河南)能源科技有限公司 | A kind of lead-acid accumulator additive of mild condition and its preparation method and application |
KR102103311B1 (en) * | 2018-10-23 | 2020-04-23 | 주식회사 한국아트라스비엑스 | A method of manufacturing an electrolyte of a lead-acid battery capable of providing a stable durability cycle |
-
1984
- 1984-04-03 JP JP59065212A patent/JPS60211777A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8771871B2 (en) | 2005-09-27 | 2014-07-08 | The Furukawa Battery Co., Ltd. | Lead storage battery and manufacturing method of the same |
GB2494628A (en) * | 2011-09-07 | 2013-03-20 | Solaris Holdings Ltd | Dopant for electrolyte |
GB2494628B (en) * | 2011-09-07 | 2014-08-06 | Solaris Holdings Ltd | Method of secondary power source capacity increasing |
US9799923B2 (en) | 2011-09-07 | 2017-10-24 | Solaris Holdings Limited | Method of increasing secondary power source capacity |
CN108461830A (en) * | 2018-04-26 | 2018-08-28 | 天能集团(河南)能源科技有限公司 | A kind of lead-acid accumulator additive of mild condition and its preparation method and application |
KR102103311B1 (en) * | 2018-10-23 | 2020-04-23 | 주식회사 한국아트라스비엑스 | A method of manufacturing an electrolyte of a lead-acid battery capable of providing a stable durability cycle |
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