JPS60184614A - Method for desiliconizing molten iron - Google Patents

Method for desiliconizing molten iron

Info

Publication number
JPS60184614A
JPS60184614A JP4084584A JP4084584A JPS60184614A JP S60184614 A JPS60184614 A JP S60184614A JP 4084584 A JP4084584 A JP 4084584A JP 4084584 A JP4084584 A JP 4084584A JP S60184614 A JPS60184614 A JP S60184614A
Authority
JP
Japan
Prior art keywords
desiliconization
molten iron
skimmer
desiliconizing
blast furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP4084584A
Other languages
Japanese (ja)
Other versions
JPH0435525B2 (en
Inventor
Hiroshi Shitoda
浩 紫冨田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP4084584A priority Critical patent/JPS60184614A/en
Publication of JPS60184614A publication Critical patent/JPS60184614A/en
Publication of JPH0435525B2 publication Critical patent/JPH0435525B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C1/00Refining of pig-iron; Cast iron
    • C21C1/04Removing impurities other than carbon, phosphorus or sulfur

Abstract

PURPOSE:To perform surely desired desiliconization in a blast furnace hearth so as to deal with desiliconization and dephosphorization of a large amt. of molten iron by adding respectively desiliconizing agents to the molten iron between the tap hole on the tapping spout and skimmer of the blast furnace and between the skimmer and torpede to effect desiliconization in two stages. CONSTITUTION:The molten iron 8 discharged from a tap hole 2 of a blast furnace 1 is separated to the molten iron 8 and slag 8-2 by a skimmer 4 provided in a tapping spout 3. The molten iron 8 is fed on a molten iron spout 5 on the down stream of the skimmer 4 to a torpedo car 7. A desiliconizing agent is added to the molten iron in the spout 3 from the hole 2 to the skimmer 4 preferably at a point near the hole 2. A desiliconizing agent 9-2 is added to the molten iron 8 separated of blast furnace slag and desiliconizing slag in the skimmer 4 after the primary desiliconization prior to falling into a torpedo car 7 to execute secondary desiliconization. The reduction of (Si) in the high Si-content molten iron 8 tapped from the furnace 1 to <=0.15% required for dephosphorization of the molten iron in the blast furnace hearth is made substantially possible by such two-stages of the desiliconization treatment.

Description

【発明の詳細な説明】 発明の技術分野 この発明は高炉から出銑した溶銑の脱珪処理を出銑樋に
おいて効率よく行なう溶銑の脱珪方法に関する。
DETAILED DESCRIPTION OF THE INVENTION Technical Field of the Invention The present invention relates to a method for desiliconizing hot metal tapped from a blast furnace, in which desiliconization of hot metal is efficiently carried out in a tap sluice.

従来技術とその問題点 溶銑J″−備処理法の一つに、高炉の出銑樋内に脱珪剤
を投入して溶銑の脱珪処理を行なう樋脱珪法が最近よく
利用されている。例えば、特公昭58−56723号で
知られるごとく、高炉の出銑口から出銑された溶銑中に
脱珪剤を添加し、−緒に流れて行く間の自然な混合を利
用して溶銑中の含有珪素を酸、化除去する方法が知られ
ている。この他、この種の樋脱珪方法には種々の手段が
とられているが、従来の樋脱珪方法はいずれも溶銑とス
ラグを分離するスキンマーの下流において脱珪剤を添加
している。これは、スラグ分離後の方が脱珪効率が高い
ことによる。しかし、スキンマー下流における脱珪剤の
添加のみでは以下に示す問題がある。
Conventional technology and its problems One of the hot metal J''-preparation treatment methods that has recently been widely used is the trough desiliconization method, which desiliconizes hot metal by introducing a desiliconizing agent into the tap trough of a blast furnace. For example, as known from Japanese Patent Publication No. 58-56723, a desiliconizing agent is added to the hot metal tapped from the taphole of a blast furnace, and the natural mixing of the hot metal as it flows is utilized to remove the molten metal. A method is known in which the silicon contained in the gutter is removed by acidification.In addition, various methods have been used for this type of gutter desiliconization method, but all of the conventional gutter desiliconization methods involve using hot metal and hot metal. A desiliconizing agent is added downstream of the skinmer that separates the slag.This is because the desiliconizing efficiency is higher after slag separation.However, adding a desiliconizing agent only downstream of the skinmer causes the following problems. There is.

すなわち、出銑(St)の変動に対応しきれないことで
ある。例えば、出銑(St)が平均9.45%で、処理
後(Si”)目標が0.25%の場合、高炉炉況変動に
より出銑〔Si〕が0.60 %になると、処理後(S
()0.25%達成は困難である。また、次工程で溶銑
脱燐を実施する場合、処理後〔S1〕は極力低いことが
望まれ、〔Sl〕≦0.15%が必要とされる。しかし
、スキンマー下流のみでの脱珪処理ではこのレベルを安
定して達成することは困難である。
In other words, it is not possible to cope with fluctuations in tap iron (St). For example, if the average tap iron (St) is 9.45% and the target after treatment (Si) is 0.25%, if the iron tap [Si] becomes 0.60% due to fluctuations in blast furnace conditions, the (S
() It is difficult to achieve 0.25%. Furthermore, when hot metal dephosphorization is performed in the next step, it is desirable that [S1] after the treatment be as low as possible, and [Sl]≦0.15% is required. However, it is difficult to stably achieve this level by desiliconization treatment only downstream of the skinmer.

これらの対策として、従来はトーピード脱珪等を利用し
て調整が行なわれているが、工程増、処理時間増から大
量の処理には不向きであった。
Conventionally, as a countermeasure against these problems, adjustment has been carried out using torpedo desiliconization, etc., but this is not suitable for large-scale processing because it increases the number of steps and processing time.

発明の目的 この発明は、従来のr4jl記実情に鑑みてなされたも
ので、大;ルの溶銑脱珪・脱燐に対応ずべ(、高炉鋳床
において確実に(St)≦(1,15%を達成し得る溶
銑の樋脱珪法を提案することを目的とするものである。
Purpose of the Invention The present invention has been made in view of the actual situation of conventional R4JL, and is capable of dealing with the desiliconization and dephosphorization of hot metal of large quantities. The purpose of this study is to propose a method for desiliconizing hot metal troughs that can achieve the following.

発明の開示 この発明に係る溶銑の脱珪方法は、高炉鋳床において、
出銑口からスキン゛7−に至る間で脱珪剤を添加しCI
1次脱珪行ない、さらにス■ンマーから1・−1−+−
Fに至る間で脱珪剤を添加し゛C2次脱珪を行な)こと
を特徴とするものである。
DISCLOSURE OF THE INVENTION The method for desiliconizing hot metal according to the present invention includes:
Adding a desiliconizing agent between the tap hole and the skin 7-
First desiliconization, then 1・-1−+− from Summer
It is characterized in that a desiliconizing agent is added during the process up to F (secondary desiliconization is performed).

すなわちこの発明は、鋳床脱珪においC従来実施されこ
いlx IJsつたスヤンマート、1A[にC脱珪剤を
添加する1次脱珪と、スキンマード流における2次脱珪
とのいわゆる2段脱珪処理により、処理後(、’ Si
 J < l)、15%を達成する方法である。
In other words, the present invention provides a so-called two-stage desiliconization method in which a desiliconization agent is added to a cast-floor desiliconization process, which has not been conventionally carried out in the past, including a primary desiliconization process in which a C desiliconization agent is added to a casthouse desiliconization process, and a secondary desiliconization process in a Skimmer flow. By processing, after processing (,' Si
J < l), this method achieves 15%.

以下、この発明法を図面を参照しつつ詳細に説明するっ 第1図において、(1)は高炉、(2]は出銑口、(3
)は出銑樋、(4)はスキンマー、(5)は溶銑樋、(
6)は排滓口、(7)はトーピードカーをそれぞれ示す
。すなわち、高炉(1)の出銑口(2)より排出する溶
銑(8)は出銑樋(3)内に設置されているスキンマー
(4)にテ溶銑(8)とスラグ(8−2)が分離され、
スラグ(8−2)は排滓口(6)より排出し、溶銑(8
)はスキンマー(4)の下流の溶銑樋(5)を流れてト
ーピードカー(7)に至る。
This invention method will be explained in detail below with reference to the drawings. In Figure 1, (1) is the blast furnace, (2) is the taphole, (3)
) is the tap runner, (4) is the skimmer, (5) is the hot metal runner, (
6) shows the slag outlet, and (7) shows the torpedo car. That is, the hot metal (8) discharged from the taphole (2) of the blast furnace (1) is transferred to the skinmer (4) installed in the taphole (3), where the hot metal (8) and slag (8-2) are discharged. is separated,
Slag (8-2) is discharged from the slag discharge port (6), and hot metal (8-2) is discharged from the slag discharge port (6).
) flows through the hot metal sluice (5) downstream of the skimmer (4) and reaches the torpedo car (7).

この発明は1次脱珪として、出銑口(2)よりスキンマ
ー(4)に至るまでの出銑樋(3)において脱珪剤(9
−1)を添加する。この1次脱珪において脱珪剤を添加
する場所は特に限定するものではないが、通常スキンマ
ー(4)までは溶銑(8)−ヒをスラグ(8−2)が覆
つ°Cおり自然混合では脱珪効率の低ドが考えられるの
で、実際には出銑口(2)に近い所が望ましい。
This invention is a primary desiliconization process in which a desiliconizing agent (9
-1) is added. The place where the desiliconizing agent is added in this primary desiliconization is not particularly limited, but usually up to the skimmer (4), the slag (8-2) covers the hot metal (8)-H and is mixed naturally. Since desiliconization efficiency may be low in this case, a location close to the taphole (2) is actually desirable.

特に出銑口から流下する溶銑の落丁点に脱珪剤を添加す
ればより効果的である。その他、脱珪を促進させる方法
としては、例えば出銑口カバーを利用してN2ガスまた
は空気等と共に固形脱珪剤をインジェクションする方法
や、出銑樋に落差をつけ、その落バモによっC生l゛る
攪拌流に脱珪剤を捲込ませる方法等を採用することもで
きる。なお、この1次脱珪における脱珪剤の添加逝とし
ては、(Si’J含有り目こ応じて定めることになるが
、この段階ではn11記した1…り溶銑がスラグで覆わ
れ°Cいるので、脱珪剤がスラグに捕捉されやすい。従
って、多量に添加しCもそれがすべて反応するとは限ら
ないので、溶銑M、(Si)含有竜に応じ適当に加減し
て添加する。
In particular, it is more effective if a desiliconizing agent is added to the drop point of the hot metal flowing down from the taphole. Other methods to promote desiliconization include, for example, using a taphole cover to inject a solid desiliconizing agent together with N2 gas or air, or by adding a head to the tap sluice to reduce the carbon It is also possible to adopt a method in which a desiliconizing agent is stirred into the generated stirring flow. The addition rate of the desiliconizing agent in this primary desiliconization will be determined depending on the Si'J content, but at this stage, the molten pig iron will be covered with slag. Therefore, if a large amount of C is added, not all of it will react, so add it in an appropriate amount depending on the hot metal M and (Si) content.

このようにして1次脱珪された溶銑(8)はスキンマー
(4)にて高炉スラグと脱珪スラグが分離されて溶銑樋
(5)へ流れるが、ここでトーピードカー(7)に落ド
する前の溶銑(8)に脱珪剤(9−2)を添加して2次
脱珪を行なう。この段階における脱珪剤の添加賞につい
ては前記1次脱珪処理後(Si) 喰に応じC/P:定
1−1その添加方法はN、ガス等と共に吹込むインジェ
クション方式等を用いることもできる。
The hot metal (8) that has undergone primary desiliconization in this way is separated into blast furnace slag and desiliconized slag by the skimmer (4) and flows to the hot metal sluice (5), where it falls into the torpedo car (7). Secondary desiliconization is performed by adding a desiliconizing agent (9-2) to the previous hot metal (8). Regarding the addition of the desiliconizing agent at this stage, after the first desiliconizing treatment (Si), depending on the amount, C/P: constant 1-1 can be added by injection method, etc. in which it is blown in together with N, gas, etc. can.

L記のごとく、この発明はスキンマーのH流トド流で脱
1上処理を行なうので、高炉から出銑した+ffl〔5
iJA有溶銑中の(Si’)を溶銑脱燐に必要^される
0、15%以下に高炉鋳床において達成することが十分
可能である。従って、この発明によれば、工程増、処理
時間増の問題が解決されることにより、大量の溶銑脱珪
処理が”I能となる。なお、この発明法における脱珪剤
は製鉄ダスト、ミルスケール、粉鉱石、焼結鉱粉等の酸
化鉄系、およびMnO系あるいは02含有ガス等である
As described in L, this invention performs the de1 treatment using the H flow of the skimmer, so that the +ffl [5
It is fully possible to achieve (Si') in iJA hot metal to 0.15% or less, which is required for hot metal dephosphorization, in a blast furnace cast bed. Therefore, according to this invention, by solving the problems of increased process steps and increased processing time, it becomes possible to desiliconize a large amount of hot metal. These include iron oxide-based gases such as scale, fine ore, and sintered ore powder, and MnO-based or 02-containing gases.

次に、この発明の実施例について説明する。Next, embodiments of the invention will be described.

実 施 例 高炉から出銑される第1表に示す成分を有する溶銑(温
度1510”C)に対し、スキンマー上流の出銑樋上で
脱珪剤(平均粒度5朋の焼結粉)をインジェクション方
式(エアー圧2にダ/c+l)で20ks+/T吹込ん
で1次脱珪処理し、さらに1次脱珪処理後の溶銑に対し
、スキンマー下流の溶銑樋上で同じ脱珪剤を15 kg
/ T投入して2次脱珪処理した。
Example A method in which a desiliconizing agent (sintered powder with an average particle size of 5 mm) is injected onto the tap sluice upstream of the skinmer into hot metal (temperature 1510"C) having the components shown in Table 1 that is tapped from a blast furnace. (air pressure 2 to da/c+l) for 20ks+/T to carry out primary desiliconization treatment, and then 15 kg of the same desiliconizing agent was applied to the hot metal after the primary desiliconization treatment on the hot metal trough downstream of the skinmer.
/T was charged for secondary desiliconization treatment.

本実施例における1次脱珪処理後の溶銑成分と2次脱珪
処理後の溶銑成分を第2表に示す。
Table 2 shows the hot metal components after the primary desiliconization treatment and the hot metal components after the secondary desiliconization treatment in this example.

第2表より明らかなごとく、この発明の2段脱珪処理に
より、高(Si)含何溶銑中のCs1)を高炉鋳床にお
い−ro、151以下に脱珪することができた。
As is clear from Table 2, the two-stage desiliconization treatment of the present invention was able to desiliconize Cs1) in the high (Si) content hot metal to -ro, 151 or less in the blast furnace cast bed.

第1表 脱珪的溶銑の成分(%) 第2表 脱珪後溶銑の成分(%)Table 1: Composition of desiliconizing hot metal (%) Table 2 Composition of hot metal after desiliconization (%)

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明の一実施例を示す概略図である。 l・・・高炉、2・・・出銑口、3・・・出銑樋、4・
・・スギ/マー、5・・・溶銑樋、6・・・排滓口、7
・・・トーピードカー、8・・・溶銑、9−1.9−2
・・・脱珪剤。 第1図
FIG. 1 is a schematic diagram showing an embodiment of the present invention. l...blast furnace, 2...tapping hole, 3...tapping sluice, 4...
... Cedar/Mar, 5...Hot metal gutter, 6...Slag discharge port, 7
...Torpedo car, 8...Hot metal, 9-1.9-2
...Desiliconizing agent. Figure 1

Claims (1)

【特許請求の範囲】[Claims] 高炉出銑樋トで溶銑の脱珪処理を行なう方法において、
出銑口からスキンマーに至る間で脱珪剤を添加して1次
脱珪を行ない、さらにスキンマーからトーピードに至る
間で脱珪剤を添加して2次脱珪を行なうことを特徴とす
る溶銑の脱珪方法。
In a method for desiliconizing hot metal in a blast furnace tap culvert,
Hot metal characterized in that a desiliconizing agent is added between the taphole and the skinmer to perform primary desiliconization, and a desiliconizing agent is further added between the skinmer and the torpedo to perform secondary desiliconization. desiliconization method.
JP4084584A 1984-03-02 1984-03-02 Method for desiliconizing molten iron Granted JPS60184614A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4084584A JPS60184614A (en) 1984-03-02 1984-03-02 Method for desiliconizing molten iron

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4084584A JPS60184614A (en) 1984-03-02 1984-03-02 Method for desiliconizing molten iron

Publications (2)

Publication Number Publication Date
JPS60184614A true JPS60184614A (en) 1985-09-20
JPH0435525B2 JPH0435525B2 (en) 1992-06-11

Family

ID=12591924

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4084584A Granted JPS60184614A (en) 1984-03-02 1984-03-02 Method for desiliconizing molten iron

Country Status (1)

Country Link
JP (1) JPS60184614A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63213615A (en) * 1987-02-27 1988-09-06 Kobe Steel Ltd Desiliconizing method in molten iron trough with multi step

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102112625B1 (en) * 2018-07-24 2020-05-19 주식회사 포스코 Device for decreasing silicon content in hot metal

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63213615A (en) * 1987-02-27 1988-09-06 Kobe Steel Ltd Desiliconizing method in molten iron trough with multi step

Also Published As

Publication number Publication date
JPH0435525B2 (en) 1992-06-11

Similar Documents

Publication Publication Date Title
CA1223740A (en) Method for the production of iron
RU2077595C1 (en) Method and apparatus (alternatives) for producing iron and/or alloys thereof from iron oxide materials
CN103397146A (en) Production method of pipeline steel
CN101403023A (en) Ultra-deep desulfuration method for hot metal
JPS60184614A (en) Method for desiliconizing molten iron
EP2039788A1 (en) Dephosphorization method in the process of smelting ni-cr pig iron from a nickel oxide ore
JPH0474410B2 (en)
JPS5864307A (en) Desiliconization method for molten iron
JP3772918B2 (en) Dephosphorization method of hot metal in converter type refining vessel
JP2672588B2 (en) Hot Metal Pretreatment Method in Blast Furnace Castings
JPH05156338A (en) Method for reusing low phosphorus converter slag
JPS6318009A (en) Method and apparatus for pretreatment of molten iron
AU597861B2 (en) Process for continuous purification of hot metal
JP3305898B2 (en) Short-time reforming method of steelmaking slag
JPH08269533A (en) Desulfurization refining method of molten steel
JPS5839716A (en) Treatment of molten iron
JPH11100608A (en) Method for desiliconizing and desulfurizing molten iron
JPH0582445B2 (en)
JPH11269525A (en) Desiliconization of molten iron by addition of desiliconizing agent
JP2842248B2 (en) Hot metal desulfurization method
JP3531480B2 (en) Hot metal dephosphorization method
JPS6318010A (en) Method and apparatus for pretreatment of molten iron
CN117625882A (en) Production method for reducing surface quality defects of cast pig iron white and shrinkage pit iron beans
JPS60234909A (en) Method for adding desiliconizing agent
JPH0892614A (en) Pretreatment of molten iron by discharging low basicity slag