JPS60177572A - Sealed lead storage battery - Google Patents
Sealed lead storage batteryInfo
- Publication number
- JPS60177572A JPS60177572A JP59031644A JP3164484A JPS60177572A JP S60177572 A JPS60177572 A JP S60177572A JP 59031644 A JP59031644 A JP 59031644A JP 3164484 A JP3164484 A JP 3164484A JP S60177572 A JPS60177572 A JP S60177572A
- Authority
- JP
- Japan
- Prior art keywords
- current collector
- electrode plate
- plates
- negative electrode
- negative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/12—Construction or manufacture
- H01M10/14—Assembling a group of electrodes or separators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明ｉｊ二、トＩＪクル充電や浮動充電状態で使用さ
れ、停電時には負荷に信頼性の高い安定な電力を供給す
る電源、あるいはポータプル機器の電源に使用される密
閉形鉛蓄電池の特に極板群の改良に関するものである。[Detailed Description of the Invention] Industrial Application Fields The present invention is a power supply that is used in an IJ cycle charging or floating charging state and supplies reliable and stable power to a load in the event of a power outage, or a power supply for portable equipment. This invention relates to the improvement of the electrode plate group of sealed lead-acid batteries used for.
従来例の構成とその問題点
この種の密閉形鉛蓄電池は、充電中に発生する酸素ガス
全負極板に吸収させる密閉方式を採用しているため、極
板には自己放電量の少ない鉛−カルシウム合金あるいは
鉛−カルシウム−錫合金が使用されている。 ７
この種の鉛−カルシウム系合金は、従来の鉛−アンチモ
ン系合金に比べて、過充電による表面腐食量は少ないが
、局部的な腐食が大きく、正極板の格子体内部まで腐食
され、その腐食生成物の膨張により極板の伸びが大きく
なる欠点を有し−Ｃいる。このため、過充電による正極
板の腐食により、正惨板の上部が伸びて負極板の集電休
部と短絡し早期に容量が低下する原因となっている。Conventional structure and its problems This type of sealed lead-acid battery uses a sealed method in which all the oxygen gas generated during charging is absorbed by the negative electrode plate. Calcium alloys or lead-calcium-tin alloys are used. 7 This type of lead-calcium alloy has less surface corrosion due to overcharging than conventional lead-antimony alloys, but local corrosion is large and the inside of the lattice of the positive electrode plate is corroded. -C has the disadvantage that the expansion of the corrosion products increases the elongation of the electrode plate. Therefore, due to corrosion of the positive electrode plate due to overcharging, the upper part of the positive electrode plate stretches and short-circuits with the current collecting portion of the negative electrode plate, causing an early decrease in capacity.
発明の目的
本発明は、上記のような正極板の伸ひによる止極板と負
極集電体との短絡を防止し、長寿命の密閉形鉛蓄？ＩＬ
池を提供することを目的とする。Purpose of the Invention The present invention provides a long-life sealed lead-acid battery that prevents the short circuit between the stop plate and the negative electrode current collector due to the elongation of the positive electrode plate as described above. IL
The purpose is to provide a pond.
発明の構成
上記目的を達するため本発明は、極板群の端面において
負極板相互を接続する負極集電体と正極板との間に絶縁
層を設けるものである。この構成により、腐食によって
生じる正極板の伸びによる媛絡全防止１−１密閉形鉛蓄
電池の寿命を大幅に延長することができる。Structure of the Invention In order to achieve the above object, the present invention provides an insulating layer between the negative electrode current collector and the positive electrode plate that connect the negative electrode plates to each other at the end face of the electrode plate group. With this configuration, it is possible to significantly extend the life of the 1-1 sealed lead-acid battery, which completely prevents leakage due to elongation of the positive electrode plate caused by corrosion.
実施例１の説明
第１図は、第１の実施例を示す斜視図で、櫛形の絶縁機
Ｚ、−負極集電体と正極板の間に入れた極板！ＩＴ構造
を・示している。１は鉛−カルシウム合金の格子体Ｖｃ
作作物物質二酸化鉛全保持させた正極板、２は格子体に
作用物質の海綿状鉛を保持させた負極板、３ ＆：ｌ：
正極４）ｉｌと負極板２を分離するとともに電解液を保
持する機能をもつガラス繊維を主とするセパレータであ
る。４はこの体板群の上面に突出する負極板の耳部であ
り、これらは負極集電体６によって相互に接続されてい
る。６は正極板の耳部、７はそれらの耳部全相互に接続
する正極集電体である。Description of Embodiment 1 FIG. 1 is a perspective view showing the first embodiment, which includes a comb-shaped insulator Z, an electrode plate inserted between a negative electrode current collector and a positive electrode plate! Shows the IT structure. 1 is a lead-calcium alloy lattice body Vc
2 is a positive electrode plate in which all the crop material lead dioxide is retained; 2 is a negative electrode plate in which the lattice body retains the active substance spongy lead; 3 &:l:
This is a separator mainly made of glass fiber that has the function of separating the positive electrode 4) il and the negative electrode plate 2 and retaining the electrolyte. Reference numeral 4 denotes the ears of the negative electrode plates protruding from the upper surface of this body plate group, and these are interconnected by a negative electrode current collector 6. Reference numeral 6 denotes an ear portion of the positive electrode plate, and 7 represents a positive electrode current collector that connects all of these ear portions to each other.
８は負極集電体６と正極板１とを絶縁する絶縁板であり
、負極板２の耳部４を挿入する切欠き９ｆ：有する櫛形
に成形されたものである。絶縁板８の月料には、ポリ塩
化ビニル、ポリプロピレン、ポリエチレン等の合成樹脂
が用いられる。Reference numeral 8 denotes an insulating plate that insulates the negative electrode current collector 6 and the positive electrode plate 1, and is formed into a comb shape having a notch 9f into which the ear portion 4 of the negative electrode plate 2 is inserted. For the monthly charge of the insulating plate 8, synthetic resin such as polyvinyl chloride, polypropylene, polyethylene, etc. is used.
第２図は第２の実施例を示すもので、負極集１１１゜体
６の下面にエポキシ系の接着剤を塗布して絶縁）脅１ｏ
を設けた例である。この絶縁層は、正極板１の上面に設
けてもよい。FIG. 2 shows a second embodiment, in which an epoxy adhesive is applied to the bottom surface of the negative electrode assembly 111 to insulate it.
This is an example where . This insulating layer may be provided on the upper surface of the positive electrode plate 1.
次に、第１図のようにポリ塩化ビニル製絶縁板８を設け
た１ ２ｖ、４０Ａｈ ノ密閉形鉛蓄′ＩＬ３池ａと、
絶縁板８を設けない比較例の電池ｂＶＣついて、周囲温
度４０℃、過充電電流２．ＯＡの条件で加速寿命試験を
実施した時の容量変化を第３図に示す。Next, as shown in Fig. 1, a 12V, 40Ah sealed lead-acid 'IL3 pond a was provided with a polyvinyl chloride insulating plate 8,
Regarding the battery bVC of the comparative example without the insulating plate 8, the ambient temperature was 40°C and the overcharge current was 2. Figure 3 shows the change in capacity when an accelerated life test was conducted under OA conditions.
この結果より、本発明による電池ａは、比較例の電池す
より約６０チ寿命が伸びることが明らかである。このよ
うに、本発明によえ１ば、正棒板の格子腐食の伸びによ
る負極集電体との短絡を防止できるので、正極格子腐食
の激しい高温状態や過充電状態での蓄電池使用において
も電池寿命を大幅に伸Ｖ、１１すという効果を有する。From this result, it is clear that the battery a according to the present invention has a longer lifespan by about 60 inches than the battery of the comparative example. As described above, according to the present invention, it is possible to prevent a short circuit with the negative electrode current collector due to the elongation of the corrosion of the positive electrode grid, even when the storage battery is used in a high temperature state or an overcharged state where the positive electrode grid corrosion is severe. This has the effect of significantly extending battery life.
発明の効果
以」−のように本発明によれば次の効果を得ることがで
きる。Effects of the Invention According to the present invention, the following effects can be obtained.
（１）正極板格子の伸びによる短絡を防止でき、蓄電池
寿命が向上する。(1) Short circuits due to elongation of the positive electrode grid can be prevented, and the battery life can be improved.
ｅ）正極格子腐食の激しい高温状態や過充電状態で蓄電
池を使用して正極板格子が伸びても、短絡による寿命低
下を防、止できる０e) Even if the positive electrode plate grid stretches due to use of a storage battery in high temperature conditions where the positive electrode grid is severely corroded or in an overcharged state, it can prevent short circuits from reducing the lifespan.
第１図は本発明の第１の実施例における密閉形従来構成
の電池を加速寿命試験で比較した時の容量特性図である
。
１・・・・・・正極板、２・・・・・・負極板、３・・
・・・・セパレータ、４・・・・・・負極板の耳部、５
・・・・・・負極集電体、８・・・・・・絶縁板、９・
・・・・・切欠き、１０・・・・・・絶縁物層。
第 １ 図
第 ３ 図
通たｅ時間（耳）FIG. 1 is a capacity characteristic diagram when comparing the sealed conventional battery according to the first embodiment of the present invention in an accelerated life test. 1... Positive electrode plate, 2... Negative electrode plate, 3...
... Separator, 4 ... Ear part of negative electrode plate, 5
...Negative electrode current collector, 8...Insulating plate, 9.
...Notch, 10...Insulator layer. Figure 1 Figure 3 Time passed (ear)
Claims (1)
ケ板ノ１１と、極板群の端面において負極板相互を接わ
″しする負極集電体とを備え、前記負極集電２体とこれ
に対向する正極板との間に絶縁層を設けたことを特徴と
する密閉形鉛蓄電池。 （搬 前記絶ト；（層が、前記集電体に接続される極板
耳部を挿入する切欠きを設けた櫛形の合成樹脂板で構成
された特許請求の範囲第１項記載の密閉形鉛系′市、池
。 （３）前記絶縁層が、前記集電体の内面または集電体と
対向する正極板の端面に塗布された合成樹脂層で構成さ
れた特許請求の範囲第１項記載の密閉形鉛蓄電池０[Claims] (1) 4 composed of a city electrode plate, a negative electrode plate, and a separator.
11, and a negative electrode current collector that connects the negative electrode plates to each other at the end face of the electrode plate group, and an insulating layer is provided between the two negative electrode current collectors and the positive electrode plate facing the negative electrode current collectors. A sealed lead-acid battery characterized in that the layer is made of a comb-shaped synthetic resin plate provided with a notch into which an electrode plate tab connected to the current collector is inserted. A sealed lead-based battery according to claim 1. (3) The insulating layer is a synthetic resin layer coated on the inner surface of the current collector or on the end surface of the positive electrode plate facing the current collector. A sealed lead-acid battery according to claim 1 consisting of
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59031644A JPS60177572A (en) | 1984-02-22 | 1984-02-22 | Sealed lead storage battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59031644A JPS60177572A (en) | 1984-02-22 | 1984-02-22 | Sealed lead storage battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS60177572A true JPS60177572A (en) | 1985-09-11 |
Family
ID=12336905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59031644A Pending JPS60177572A (en) | 1984-02-22 | 1984-02-22 | Sealed lead storage battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60177572A (en) |
-
1984
- 1984-02-22 JP JP59031644A patent/JPS60177572A/en active Pending
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