JPS6017067A - Method for providing gold color of plastic surface - Google Patents
Method for providing gold color of plastic surfaceInfo
- Publication number
- JPS6017067A JPS6017067A JP12376183A JP12376183A JPS6017067A JP S6017067 A JPS6017067 A JP S6017067A JP 12376183 A JP12376183 A JP 12376183A JP 12376183 A JP12376183 A JP 12376183A JP S6017067 A JPS6017067 A JP S6017067A
- Authority
- JP
- Japan
- Prior art keywords
- plastic surface
- yellow
- plastic
- gaseous
- gold color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0015—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterized by the colour of the layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0021—Reactive sputtering or evaporation
- C23C14/0036—Reactive sputtering
Abstract
Description
【発明の詳細な説明】
本発明け、プラスチック表面（黄金色を与える方法に関
する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for imparting a golden color to plastic surfaces.
装飾品またけ時計等のケースにおいて、プラスチックの
表面に黄金色の光沢を与える場合、一般にはプラスチッ
クの素地上にアルミニウムを蒸着又はスパッタリングに
より形成し、その上でその上に黄色の塗料を塗装し、最
後に透明の侶謹コーティング膜を形成する方法が一般的
である。しかしこの方法は工程数が多い欠点があった。To give the plastic surface a golden luster in the cases of ornamental watches, etc., aluminum is generally formed on the plastic base by vapor deposition or sputtering, and then a yellow paint is applied on top of that. A common method is to finally form a transparent coating film. However, this method had the drawback of requiring a large number of steps.
本発明け、プラスチック表面に黄金色の光沢が簡単ＶＣ
得られるようにすることを目的とするものである。With this invention, it is easy to create a golden luster on the plastic surface.
The purpose is to make it possible to obtain.
実施例について押切すると、プラスチック素材としては
黄色のＡＢＳ樹脂を使用し、その上にアルゴンと少量の
酸素とを導入ガスとして、真空ベルジャ内で上記プラス
チック表面にチタンの反応性スパ・ツタリングを行った
。In the example, yellow ABS resin was used as the plastic material, and titanium was reactively sputtered onto the surface of the plastic in a vacuum belljar using argon and a small amount of oxygen as gases introduced thereon. .
反応性ユバ９タリングの条件
ターゲ・ノド チタン
真空ＩＩ ５ｘ１０−’Ｔｏττ以下
０圧 （２〜Ｂ） ｘ １０−’ ＴｏｒｒＡｒ圧 ５
×１０″′ＢＴｏｒｒ
高周波入力パワー ８００Ｗ
処理時間 〜 ｍｔｎ
この反応性スパー７４リングによってプラスチッり表面
ＶＣ２００〜３００オン〃°ヌトロームの酸化チｌン購
が形成され、黄金色の光沢を呈１７た。これ−酸化チタ
ン嘩が薄青味がかった透明をし、それが金属党派を有［
７ていることと、プラスチック素材の色とが融合して黄
金色の光沢を呈するものと思わｈる。Conditions for reactive Yuva9taling Target/nod Titanium vacuum II 5x10-'Toττ or less 0 pressure (2~B) x 10-'TorrAr pressure 5
×10″'BTorr High frequency input power 800W Processing time ~ mtn This reactive spar 74 ring formed a tin oxide layer on the plastic surface with a VC of 200 to 300 on, giving it a golden luster17. -Titanium oxide is transparent with a bluish tinge, and it has metallic particles [
I believe that the combination of the color of the plastic material and the color of the plastic material gives it a golden luster.
またチ〃ン旬外にも二・ソケル、銅につ（ハても十５ビ
とほぼ回等の冬作で黄金色の光沢が得られることを確認
した。プラスチ９りけＡＢ’Ｓ以外で本黄色士たけそれ
に近い色のものであれば適用可能である。また上記条件
において、入力パワーと処理時間け２００〜３００オン
グストロームの膜厚ヲ得る一例に過ぎず、適宜に変更す
ることができる。It has also been confirmed that a golden luster can be obtained with winter crops such as 2, Sokel, and Copper Nitsu (at least 15 Bis). It can be applied as long as the color is close to that of the actual yellow color.In addition, under the above conditions, the input power and processing time are only an example of obtaining a film thickness of 200 to 300 angstroms, and can be changed as appropriate. .
この発明によれば、スパッタリングの工程だけでプラス
チック表面に全光沢を簡単に与えることができ、金メ・
ツキの代替として装飾品や時計ケースに低コストで利用
できる。According to this invention, full gloss can be easily imparted to the plastic surface with just the sputtering process, and gold plated and
It can be used as a low-cost substitute for decorations and watch cases.
以 上 出願人 株式会社 精 工 舎 代理人 弁理士 最上 務 ３−that's all Applicant Seikosha Co., Ltd. Agent Patent Attorney Mogami 3-
Claims (1)
ッケル、銅の中のいずれかの金属を、黄色またはそれに
近い色のプラスチック表面に反応性スパッタリングし、
上記プラスチック表面に上記金属の酸化膜を２００〜３
００オングストロームの厚さで形成することを特徴とす
るプラスチック表面に黄金色を与える方法、Argon and a small amount of oxygen are introduced as gases to reactively sputter a metal among titanium, nickel, and copper onto a yellow or nearly yellow plastic surface.
An oxide film of the above metal is applied to the surface of the above plastic by 200 to 3
A method for imparting a golden color to a plastic surface, the method comprising: forming a plastic surface with a thickness of 0.00 angstroms;
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12376183A JPS6017067A (en) | 1983-07-07 | 1983-07-07 | Method for providing gold color of plastic surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12376183A JPS6017067A (en) | 1983-07-07 | 1983-07-07 | Method for providing gold color of plastic surface |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6017067A true JPS6017067A (en) | 1985-01-28 |
| JPH0369988B2 JPH0369988B2 (en) | 1991-11-06 |
Family
ID=14868625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12376183A Granted JPS6017067A (en) | 1983-07-07 | 1983-07-07 | Method for providing gold color of plastic surface |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6017067A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3263735A1 (en) * | 2016-06-30 | 2018-01-03 | Valeo Vision | Metallised part comprising a layer of copper oxide |
| US10073141B2 (en) | 2014-07-25 | 2018-09-11 | Eaton Electrical Equipment Co., Ltd. | Detecting method and apparatus for abnormal electrical connection in main circuit of switchgear |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4919061A (en) * | 1972-06-12 | 1974-02-20 | ||
| JPS5466385A (en) * | 1977-11-08 | 1979-05-28 | Seiko Epson Corp | Outer parts for pocket watch |
-
1983
- 1983-07-07 JP JP12376183A patent/JPS6017067A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4919061A (en) * | 1972-06-12 | 1974-02-20 | ||
| JPS5466385A (en) * | 1977-11-08 | 1979-05-28 | Seiko Epson Corp | Outer parts for pocket watch |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10073141B2 (en) | 2014-07-25 | 2018-09-11 | Eaton Electrical Equipment Co., Ltd. | Detecting method and apparatus for abnormal electrical connection in main circuit of switchgear |
| EP3263735A1 (en) * | 2016-06-30 | 2018-01-03 | Valeo Vision | Metallised part comprising a layer of copper oxide |
| FR3053343A1 (en) * | 2016-06-30 | 2018-01-05 | Valeo Vision | METALLIZED PIECE COMPRISING A COPPER OXIDE LAYER |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0369988B2 (en) | 1991-11-06 |
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