JPS60150554A - Nonaqueous electrolyte cell - Google Patents
Nonaqueous electrolyte cellInfo
- Publication number
- JPS60150554A JPS60150554A JP59005423A JP542384A JPS60150554A JP S60150554 A JPS60150554 A JP S60150554A JP 59005423 A JP59005423 A JP 59005423A JP 542384 A JP542384 A JP 542384A JP S60150554 A JPS60150554 A JP S60150554A
- Authority
- JP
- Japan
- Prior art keywords
- positive electrode
- battery
- bismuth oxide
- active material
- iron disulfide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
（イ）産業上の利用分野
本発明は一硫化鉄を正極活物質とする１非水電解液電池
に関す−るものである。DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application The present invention relates to a non-aqueous electrolyte battery using iron monosulfide as a positive electrode active material.
ＣＵ） 従来技術
リブウｌ１、ナトリウム或いはこれらの合金を負極活物
質とし、金属の酸化物、硫化物、塩化物や・・【７ゲン
炭素などを正極活物質とし、プロビレ）カーボネート、
ンープチルラク］−ン、１２／メトキ、・エタンなとの
有機溶媒に過塩素酸リブラム、ポウフン化リチウム、ア
ルミニウムリグラムなどの無機塩を溶解したるものを電
解液として用いる非水電解液電池は高エネルギー密度を
有し、目、自己放電が少ないという利点をイ１するため
、近年、特に注目されており、現在までに二酸化マンガ
ン、フン化炭素を正極活物質とする３、０ｖ系の非水電
解液電池か提案され工いる。CU) Conventional technology: sodium or an alloy thereof is used as the negative electrode active material, and metal oxides, sulfides, chlorides, etc. are used as the positive electrode active material, carbonate,
Non-aqueous electrolyte batteries, which use an electrolyte prepared by dissolving inorganic salts such as libram perchlorate, lithium poufonide, and aluminum ligram in an organic solvent such as It has attracted particular attention in recent years due to its advantages of high energy density and low self-discharge.Currently, 3.0V non-aqueous non-aqueous batteries using manganese dioxide and carbon fluoride as positive electrode active materials have been attracting attention in recent years. Electrolyte batteries have been proposed and are being developed.
力、例えは特公昭５６−３６７９４号公報に開示され又
いるように正極活物質と（、てニー、硫化鉄（ＦｅＳ２
）を用いれは、１．５Ｖ系の一１１水゛屯解戒電池が得
られ、既存の乾電池やアルカＩ）乾電池と代−ｔ＋ Ｌ
〉る利点がある。For example, as disclosed in Japanese Patent Publication No. 56-36794, the positive electrode active material
) can be used to obtain a 1.5V type 111 water battery, which can be used with existing dry batteries or Alka I) dry batteries.
It has the advantage of
（ハ）発明の目的
本発明は特に二硫化鉄を正極活物質とする１、５■系非
水゛屯解液Ｉト池の電池特性を引する５−とを目的とす
る。(c) Purpose of the Invention The present invention is particularly aimed at (5) which brings out the battery characteristics of a 1,5-type non-aqueous solution I battery using iron disulfide as a positive electrode active material.
（ニ） 発明の構成
本発明はリチウム、ナトリウム或いはこＪｌら０″）合
金を活物質とずζ）負極と、二゛硫１ヒ鉄を活物質とす
る正極と、非水電解液とを備え乙ものでめ−。(d) Structure of the Invention The present invention uses lithium, sodium, or an alloy thereof as an active material, a negative electrode, a positive electrode using ferric disulfide as an active material, and a non-aqueous electrolyte. Be prepared.
て、前記正極に酸化ビスマスを添加した−とを特徴とす
る非水電解液電池にある。The present invention provides a non-aqueous electrolyte battery, characterized in that bismuth oxide is added to the positive electrode.
（ポ） 実施例 以下本発明電池の実施例についＴ、訂述１ろ。(Po) Example Examples of the battery of the present invention will be described below.
市販二硫化鉄（ＦｅＳ ２）に酸化ヒスマス（Ｂｉ□０
３）を１０重量％混合した混合物に、導゛〔剤、−シて
ｒ」・サレンフラノク及び黒鉛を１０ｆｆｉ量％、結む
剤としてフン素樹脂粉末を５重量％を加え充分ｌｋａ合
シー〔なるＩＥ極合剤を約１トノ／ｃ＋ｎ２のｌｆｚ力
で加ｒｔ成型し径１５．０ ＋ｎｍ、 Ｂみ１．１１１
１ｍのペレｙ ｈを得、ぞの後このぺＬ）ｌを２００〜
３００℃の温度で焼成し丁正極とＡる。Hismuth oxide (Bi□0) is added to commercially available iron disulfide (FeS2).
3) to a mixture of 10% by weight, 10% by weight of a conductive agent, Salenfuranok, and graphite, and 5% by weight of fluororesin powder as a binding agent were added to form a sufficient binding agent. The IE polar mixture was rt-molded with a lfz force of approximately 1ton/c+n2 to a diameter of 15.0 + nm and a B diameter of 1.111.
Get 1m of Peley h, and after that, this Peley L)l is 200 ~
The positive electrode was fired at a temperature of 300°C.
負極はリチウム板を０６胴の厚みに圧延し１、−の圧延
板を径１５．０ｍｍに打抜いたもの〔ある。又電解液は
ブーピレンカーボネイトと１２シメトキ７・上タンとの
混合溶媒にホウフ、・化リブ−ラムを１モル／９溶解さ
セたものである。The negative electrode was made by rolling a lithium plate to the thickness of the 06 cylinder and punching out the 1, - rolled plate to a diameter of 15.0 mm. The electrolytic solution was prepared by dissolving 1 mol/9 of houfu, chlorine and libram in a mixed solvent of bupylene carbonate and 12-hydrocarbonate.
第１図は本発明電池の断面図を示し、（１）は正極であ
って正極缶（２λの内底面に正極集１に陸土３）を介し
て圧接されている。又、（４ンは負極でおっ〔負極缶（
５）の内底面に負極集電体（６）を介して圧着きれてい
る。（７）はポリプロピレン不織布よりなるセパレータ
、（８）は絶縁バンキングである。FIG. 1 shows a cross-sectional view of the battery of the present invention, in which (1) is a positive electrode, which is pressure-welded to the inner bottom surface of a positive electrode can (2λ) via a positive electrode assembly 1 and land 3. Also, (the 4th one is the negative electrode) [the negative electrode can (
5) is completely crimped to the inner bottom surface of the electrode through the negative electrode current collector (6). (7) is a separator made of polypropylene nonwoven fabric, and (8) is an insulating bank.
第２図は本発明電池（Ａ＞と従来電池（Ｂ）とを２０°
Ｃにおいて５．６にΩ定負荷放電した時の放電特性及び
内部抵抗特性を比較したものである。Figure 2 shows the battery of the present invention (A>) and the conventional battery (B) at 20 degrees.
This is a comparison of the discharge characteristics and internal resistance characteristics when discharging at a constant load of 5.6 Ω at C.
尚、従来電池（Ｂ）の二硫化欽正極には酸化ビスマスは
添加されていない。Note that bismuth oxide is not added to the disulfide positive electrode of the conventional battery (B).
第２区より明白なるように、本発明電池（Ａ＞は従来電
％ （Ｂ ）に比し１放電後期における内８１１抵抗の
ト昇が迎制され、放電特性が改善されていることがわか
る。As is clear from the second section, the battery of the present invention (A>) has an increase in resistance of 811 in the latter half of one discharge compared to the conventional battery (B), indicating that the discharge characteristics are improved. .
−の理由を考察するに、二硫化鉄ｑ１独の従来電池の場
合には、理由は詳かでないか放電後期において放電生成
物の増加を因として内部抵抗が増加するものと考えられ
るのに対し、本発明電池の場合は、放電後期において添
加剤としての酸イしビス１スが反応に関与し、この酸化
ビスマスの反応生成物が正極の内部抵抗の上昇を抑制判
るように作用するものと考えられる。- Considering the reason for this, in the case of conventional batteries using iron disulfide q1, it is thought that the internal resistance increases either because the reason is unknown or because of an increase in discharge products in the late stage of discharge. In the case of the battery of the present invention, bismuth oxide as an additive participates in the reaction in the latter stage of discharge, and the reaction product of this bismuth oxide acts to suppress the increase in internal resistance of the positive electrode. Conceivable.
尚、酸化ヒスマスの添加量とし丁は正極ｒＪｉ量に対し
て少なくとも１０重量％以上添加しないと効果は不充分
であり、又３００重量％以上添加すると正極中の主油物
質である二硫化鉄の充填量が減少するためａｔ−するべ
きである。Note that the effect is insufficient unless the amount of hismuth oxide added is at least 10% by weight based on the amount of rJi in the positive electrode, and if it is added in excess of 300% by weight, iron disulfide, which is the main oil substance in the positive electrode, is It should be at- because the filling amount will decrease.
依って、酸化ビスマスの添加量とし１は型棒重量に対し
て１０〜３００重量％程度が好ましい。Therefore, the amount of bismuth oxide added is preferably about 10 to 300% by weight based on the weight of the mold bar.
（へ）発明の効果
本発明電池によれは、二硫化鉄を活物質と１６正極に酸
化ビスマスを添加したので放電後期における内部抵抗の
１月が抑制され、放’ｔ’＋＋性が改善されるものであ
り、特に既存の乾’ｉｔｓやアルカｊｌ乾電池の電池電
圧とほぼ同様の電池電圧を山−４る１、５Ｖ系非水電解
液電池の実用化に貿するとごろ極めて犬である。(f) Effects of the Invention In the battery of the present invention, since iron disulfide is added as an active material and bismuth oxide is added to the positive electrode, the internal resistance in the late stage of discharge is suppressed, and the release 't'++ property is improved. This is especially true when it comes to practical use of 1.5V non-aqueous electrolyte batteries, which have a battery voltage that is almost the same as that of existing dry batteries and Alka JL dry batteries.
４、 図面のｉｎ 、ｊｉ！−な説明
第１図は木登ｔｌＪｌ電池の縦断面図、第２図は本発明
電池と従来電池との電池特性比較図工゛ある。4. Drawing in, ji! - Explanation: Figure 1 is a longitudinal cross-sectional view of the Kibo tlJl battery, and Figure 2 is a comparison diagram of battery characteristics between the battery of the present invention and a conventional battery.
（１） 正極、（２）・・・正極缶、（３）・ 正極集
電体、（４）・・・負極、（５）・ ・負極化、（６）
・負極集電体、（７）・セパレータ、く８）・・ 絶縁
バッキング、（Ａ＞ ・・本発明電池、（Ｂ） 従来電
池。(1) Positive electrode, (2)... Positive electrode can, (3)・ Positive electrode current collector, (4)... Negative electrode, (5)... Negative electrode, (6)
- Negative electrode current collector, (7) - Separator, (8)... Insulating backing, (A>...Battery of the present invention, (B) Conventional battery.
出願人 三洋′ｒ４Ｌ機株式会社 代理人 弁理士 佐野静夫Applicant: Sanyo'r4L Machine Co., Ltd. Agent: Patent Attorney Shizuo Sano
Claims (1)
とずイ）負極と、二硫化ａ：を活物質とず乙１［極と、
非水電解液とを備えるものぐあン又、Ｉｉｉ記正極に酸
化ビスマスを添加したことを特徴とする非水電解液電池
。■ Lithium, sodium, or an alloy thereof is used as the active material. A) Negative electrode and disulfide a: are used as the active material.
A non-aqueous electrolyte battery, characterized in that bismuth oxide is added to the positive electrode according to (iii).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59005423A JPS60150554A (en) | 1984-01-13 | 1984-01-13 | Nonaqueous electrolyte cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59005423A JPS60150554A (en) | 1984-01-13 | 1984-01-13 | Nonaqueous electrolyte cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS60150554A true JPS60150554A (en) | 1985-08-08 |
Family
ID=11610754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59005423A Pending JPS60150554A (en) | 1984-01-13 | 1984-01-13 | Nonaqueous electrolyte cell |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60150554A (en) |
-
1984
- 1984-01-13 JP JP59005423A patent/JPS60150554A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5948512B2 (en) | Lithium-molten salt battery with transition metal chalcogenide anode | |
| JP2001210366A (en) | Nonaqueous electrochemical device and its electrolytic solution | |
| CN104078704A (en) | Secondary aluminium cell and non-aqueous electrolyte thereof | |
| JPS60150554A (en) | Nonaqueous electrolyte cell | |
| JPH03196467A (en) | Secondary battery | |
| JPH0355770A (en) | Lithium secondary battery | |
| JPS6166363A (en) | Nonaqueous electrolyte cell | |
| JP2686072B2 (en) | Non-aqueous electrolyte battery | |
| JPS60160566A (en) | Nonaqueous electrolyte battery | |
| JPS60150553A (en) | Nonaqueous electrolyte cell | |
| JPS60150555A (en) | Nonaqueous electrolyte cell | |
| JPS60154463A (en) | Nonaqueous electrolyte battery | |
| JPH0350385B2 (en) | ||
| JP2708887B2 (en) | Non-aqueous electrolyte battery | |
| JPS61181072A (en) | Non-aqueous electrolyte battery | |
| JPS6352749B2 (en) | ||
| JPH0770316B2 (en) | Battery | |
| JPS59165372A (en) | Nonaqueous electrolyte secondary battery | |
| JPH02267871A (en) | Nonaqueous electrolyte secondary cell | |
| JPH07105233B2 (en) | Organic electrolyte battery | |
| JPH02253560A (en) | Battery | |
| JPS6142862A (en) | Nonaqueous electrolyte battery | |
| JPS63307662A (en) | Organic electrolyte battery | |
| JPH0719622B2 (en) | Non-aqueous electrolyte secondary battery | |
| JPS6142858A (en) | Nonaqueous electrolyte battery |