JPS60135578A - Manufacture of artificially patinated embossed roofing material - Google Patents
Manufacture of artificially patinated embossed roofing materialInfo
- Publication number
- JPS60135578A JPS60135578A JP24963683A JP24963683A JPS60135578A JP S60135578 A JPS60135578 A JP S60135578A JP 24963683 A JP24963683 A JP 24963683A JP 24963683 A JP24963683 A JP 24963683A JP S60135578 A JPS60135578 A JP S60135578A
- Authority
- JP
- Japan
- Prior art keywords
- roofing material
- copper
- embossed
- patina
- mixed aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
- C23C22/52—Treatment of copper or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
Description
【発明の詳細な説明】
〔技術分野〕
本発明は1禄イ色の疑しい外観を有する工=ノボス調人
工、碌を屋根材の慎4法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to the four methods of roofing materials, which are artificial roofing materials having a suspicious appearance.
cat来、緑lFを人工的に綱板表面に発生させて人工
様が屋根材を4!8!蹟するにあたっては、祠屋根材を
塩rヒアン七シ水@液等のl故背液に浸漬した後、引上
げて液を切った後室内で乾燥させ、そして人工1碌育を
発生させた後、表1酊にクリヤーを塗装して製造する方
法や、あるいは銅屋根材VC緑g液をはん点状にスプレ
ーした後、乾燥して人工、禄肯を表面に発生させ、その
後クリヤーを塗装する方法が一役に行なわれている。と
ころが、前者の方法に矛)って汀、何室根材の全面に人
工、緑青が発生し、自然1.求イび)ような黒とイ白巳
の、−A10は濯むべくもなく、また後者の方法をてあ
っては銅色の上にはん点状に人工、′、★イが付着しC
おり、巳か不自然で天然緑イとはかけはなれているもつ
であった。Since then, green lF has been artificially generated on the surface of the rope boards, and artificial roofing materials have been used for 4!8! To do this, the shrine roofing material is immersed in backwater such as salt water, water, etc., then pulled up, drained of the liquid, dried indoors, and artificially grown. , Table 1 Method of manufacturing by painting clear on the surface of the roof, or after spraying copper roofing material VC green g liquid in dots, drying to generate an artificial stain on the surface, and then painting with clear. The method of doing so is helpful. However, the former method suffers from artificial patina on the entire surface of the soil and the natural patina. -A10, which has a black and white color like the one shown in the picture above, cannot be rinsed, and when using the latter method, artificial spots such as ',', and 'A' are deposited on the copper color. C
It looked like a snake, but it was unnatural and a far cry from its natural green color.
本発明rま上記の点に鑑みて成されたものであって、天
然緑イに近1以し1.爾品1曲1直を1犠めることので
きるニジポス調人工緑+r41艮材の製造法を提供する
ことを目的とするものである。The present invention has been made in view of the above points, and is similar to natural greenery.1. The object of the present invention is to provide a method for producing rainbow-like artificial greenery + R41 bamboo material that can be used for one song and one shift.
〔光1pJの開示〕
すなわら、本発明のニジポス調へ工祿−イ屋根材の製造
法は、表面に凹凸、3)が形成さノtたニジポス綱屋根
材の表面を硫化処理し、この硫化処理さ1tZc、!1
1a屋4艮拐、2)の表1用に1訛比調(4)を腐1辿
させる薬剤と嫌に発生剤との混合水溶液(5)全処理す
めこと全特徴とするもつで、硫化処Jlj r! !豆
根材′2)の凹部(6)にイ昆訃水溶f夜16)が矛盾
に溜るために硫化鋼(4)を腐、1虫して禄g化し、ま
た鋼屋根材(2)の凸部(7)は!心・偵が少ないた3
hンこ峠1ヒplJi41の黒色かそ力牛寸洩り、その
、結果ニジポス四部・6)の8白色と凸部(7)の黒色
とか艮〈A7Il′口することになって上、jC目的を
達成しkものである。[Disclosure of 1 pJ of light] In other words, the method for manufacturing the Nijiposu roofing material of the present invention includes sulfurizing the surface of the Nijiposu roofing material in which unevenness is not formed on the surface. This sulfurization treatment is 1tZc! 1
1a store 4 was removed, 2) for Table 1, a mixed aqueous solution of a drug that traces 1 accent ratio (4) and a nuisance generating agent (5) complete treatment, and sulfurization. Where Jlj r! ! The sulfurized steel (4) rots, rots and becomes rusty due to the accumulation of water-soluble insects (16) in the recesses (6) of the bean root material (2), and the steel roofing material (2). The convex part (7) is! Heart/Detection is low 3
The black part of the 41st part of the Nijiposu 6) is white and the black part of the convex part (7) of the 8th part of the Nijiposu part 6) is the black part of the 41st part of the Nijiposu. It has achieved k things.
以下4.元tす1を寿、血汐lにより1羊述する。ニジ
ポス網屋根材2jには全uirに亘′つて倣、割な凹凸
:3)が形1戊されており、このニジポス綱屋根材′2
)の表面は第1図に示すように硫化処理してあって黒色
にしである。混合水溶jT!i 15] i”を硝酸銅
と賞塩又は硫酸銅と食塩7)ヌ1]さ可を化銅を腐d虫
させるような栗な11と、塩化アシtシのン目さ1球イ
発生剤とを配合したもので組成されており、この混合水
溶液+5)を表面にイ流化銅14)の破膜が形成された
g111屋根材;2)上に塗布すると、42図乃至ゑ4
図に示すように薬剤で庇化銅)4)を腐−1虫して剥離
さぜると共[緑゛^′発生剤で茗・4表面に人工林ぎ1
8)を発生させることかでさるものである。上記ニジポ
ス銅屋根材12)をこの混合水溶液(6)中に浸漬し、
その後、液15)よりニジポス鋼屋根材(2)を引上げ
て乾燥する。その際上記表面の廓化人工緑W18)の剥
離を防ぐために屋根材(2)の表面に通盾行なわれてい
る如くアクリル系、ウレタシ系、メラ三シ系、ニトロセ
ルロース系、アル+゛ソド系等のクリヤーを塗布してニ
ジポス調人工緑宵屋根材を得るのである。Below 4. Yuan tsu 1 is shou, blood is 1 and 1 yen is described. The Nijipos net roofing material 2j has a pattern of unevenness: 3) shaped like 1 over the entire uir, and this Nijiposu net roofing material'2
) has been sulfurized and blackened as shown in Figure 1. Mixed water soluble jT! i 15] I" with copper nitrate and salt or copper sulfate and common salt 7) Nu1] A chestnut 11 that rots copper and 1 bulb of chloride acid. When this mixed aqueous solution + 5) is applied to G111 roofing material with a ruptured film of copper sulfide 14) formed on the surface;
As shown in the figure, the copper oxide (4) was rotted with a chemical agent and peeled off.
8). Immersing the Nijiposu copper roofing material 12) in this mixed aqueous solution (6),
Thereafter, the Nijipos steel roofing material (2) is pulled up from the liquid 15) and dried. At that time, in order to prevent the peeling of the artificial greenery W18) on the surface, a shield is applied to the surface of the roofing material (2), such as acrylic, uretashi, melasian, nitrocellulose, al + A rainbow-like artificial green roofing material is obtained by applying a clear coating such as a clear material such as a paint.
しかして、硫化処理された銅屋根材(2)を混合水溶液
(5)中に浸漬すると、表面の硫化銅(4)が非常に微
細な点状に剥離し、黒喝色硫化銅14)表面に微細な点
状の銅下地が現われてここが緑W発生液で緑育化される
ものであるが、表面に凹凸(3)が形成されたエンボス
鋼屋根材(2)を用いることにより、四部16)に混合
水溶液(5)が溜り易く凸部(7)には混合水溶g (
51が溜り維いために、四部(6)では人工林A’18
)が色群やかに発生するのに対して凸部(7)ではあま
り発生せず、四部(6)の!白色と凸部(7)の黒調と
が良く調和した天然緑背に近似するニジポス調人工緑#
屋根材が得られるものである。また、表面がエンボスに
形成されているため表〔mには機械的な引っ掛りかでき
てアンカー効果により人工緑育(8)が表面から剥離し
難いものであり、さらにニジボスの凹部+61に人工林
W(8)が発生しているために運搬時には摩擦等によっ
て人工林t18)部分が剥離することがないものである
。However, when the sulfurized copper roofing material (2) is immersed in the mixed aqueous solution (5), the copper sulfide (4) on the surface peels off into very fine dots, and the black copper sulfide 14) surface peels off. Fine dots of copper undercoat appear on the surface of the roof, which will be greened with the green W-generating solution. By using embossed steel roofing material (2) with unevenness (3) formed on the surface, The mixed aqueous solution (5) tends to accumulate in the fourth part 16), and the mixed aqueous solution g (
In order to maintain the accumulation of 51 trees, artificial forest A'18 was created in Part 4 (6).
) occurs in the color group, but it does not occur much in the convex part (7), and in the fourth part (6)! Artificial rainbow-like green that approximates the natural green back where the white color and the black tone of the protrusions (7) harmonize well #
Roofing material can be obtained. In addition, since the surface is embossed, the artificial greenery (8) is difficult to peel off from the surface due to the anchoring effect due to the mechanical catch on the surface of the table [m]. Because the forest W(8) is generated, the artificial forest t18) part will not peel off due to friction etc. during transportation.
上記のように本発明は、エンボス鋼屋根材の表面を硫化
処理し、硫化処理された銅屋根材の表面に硫化鋼を腐蝕
させる架剤と緑背発生剤との混合水溶液を処理したので
、エンボスの四部が混合水溶液によって特に処理されて
四部には人工緑背が形成され凸部には硫化鋼の黒色が残
ることになり、ニジボス凹部の育白色と凸部の黒色とが
良く調和した天然緑fVc近似するニジポス調人工緑青
屋根材を得ることができ、商品I[IfI直を1%める
ことかできるものである。As described above, in the present invention, the surface of the embossed steel roofing material is sulfurized, and the surface of the sulfurized copper roofing material is treated with a mixed aqueous solution of a cross-linking agent and a green backing agent that corrode the sulfurized steel. The four parts of the emboss are specially treated with a mixed aqueous solution to form an artificial green back on the four parts, and the black color of sulfurized steel remains on the convex part, resulting in a natural color that harmonizes well with the bright white color of the concave part of the rainbow boss and the black of the convex part. It is possible to obtain a rainbow-like artificial patina roofing material that approximates the green fVc, and it is possible to reduce the product I[IfI direct by 1%.
第1図乃至44図は本発明−実癩例の製造法を示す壺g
A断面図であって、(2)は銅屋根材、(3)は凹凸、
(4)は硫化鋼、15)は混合水溶液である。
代理人 弁理士 石 1)長 七Figures 1 to 44 are jars showing the present invention - the method for producing leprosy samples.
A sectional view, (2) is copper roofing material, (3) is unevenness,
(4) is sulfide steel, and 15) is a mixed aqueous solution. Agent Patent Attorney Ishi 1) Choshichi
Claims (1)
面を硫化9八理L2、この商化処理された鋼屋根材の表
面に硫化制を腐5独させる薬剤と緑育発生削との混合水
溶液を肌理することを待機とするエンボス調人工緑イ屋
根材の製造法。1) Sulfurizing the surface of the embossed steel roofing material, which has unevenness formed on the surface, using sulfurizing agent 98-ri L2, and applying a chemical that rots the sulfurization system to the surface of this commercially treated steel roofing material and removing green growth. A method for producing an embossed artificial green roofing material by preparing an aqueous solution mixed with the embossed green roofing material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24963683A JPS60135578A (en) | 1983-12-23 | 1983-12-23 | Manufacture of artificially patinated embossed roofing material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24963683A JPS60135578A (en) | 1983-12-23 | 1983-12-23 | Manufacture of artificially patinated embossed roofing material |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS60135578A true JPS60135578A (en) | 1985-07-18 |
Family
ID=17195968
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP24963683A Pending JPS60135578A (en) | 1983-12-23 | 1983-12-23 | Manufacture of artificially patinated embossed roofing material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60135578A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63832U (en) * | 1986-06-20 | 1988-01-06 | ||
JPH03103252U (en) * | 1989-12-04 | 1991-10-28 | ||
US5160381A (en) * | 1991-06-26 | 1992-11-03 | Fumigation Maritime Ltee | Method for forming artificially and rapidly patina on copper, products thereof and solutions therefor |
EP0769569A3 (en) * | 1995-10-20 | 1997-09-17 | Km Europa Metal Ag | Process for stabilisation of a patina layer |
DE19851747C2 (en) * | 1997-11-17 | 2003-10-30 | Sambo Copper Alloy Co | Process for the production of an artificially patinated copper material |
KR20030088550A (en) * | 2002-05-13 | 2003-11-20 | 김부현 | manufacturing method of oxidized copper plate for construction materials |
-
1983
- 1983-12-23 JP JP24963683A patent/JPS60135578A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63832U (en) * | 1986-06-20 | 1988-01-06 | ||
JPH045315Y2 (en) * | 1986-06-20 | 1992-02-14 | ||
JPH03103252U (en) * | 1989-12-04 | 1991-10-28 | ||
US5160381A (en) * | 1991-06-26 | 1992-11-03 | Fumigation Maritime Ltee | Method for forming artificially and rapidly patina on copper, products thereof and solutions therefor |
EP0769569A3 (en) * | 1995-10-20 | 1997-09-17 | Km Europa Metal Ag | Process for stabilisation of a patina layer |
DE19851747C2 (en) * | 1997-11-17 | 2003-10-30 | Sambo Copper Alloy Co | Process for the production of an artificially patinated copper material |
KR20030088550A (en) * | 2002-05-13 | 2003-11-20 | 김부현 | manufacturing method of oxidized copper plate for construction materials |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS60135578A (en) | Manufacture of artificially patinated embossed roofing material | |
JPS5532332A (en) | Particle pattern coat forming method | |
DE69833527D1 (en) | Cold plating process for forming a polycrystalline zinc-iron layer by mechanical spraying of a composite material | |
US2056399A (en) | Coating process and coated article | |
JPS62180080A (en) | Production of protective film for black galvanized steel sheet | |
US3669766A (en) | Formation of coating on copper containing materials | |
JPS6043435B2 (en) | How to generate artificial patina | |
KR20200145130A (en) | Method for coloring stainless steel and paratus for exfoliating skin produced therefrom | |
JP2527344B2 (en) | Painting method | |
CA2176291C (en) | Method for surface treatment of a metallic material | |
JPH04325689A (en) | Formation of patina coating film | |
JPS6030754B2 (en) | How to brighten chrome plating | |
JPS6022066B2 (en) | Surface treatment method for copper products | |
JPS56131375A (en) | Composition for forming food-coating film, and method for forming food-coating film | |
JPH02118058A (en) | Ornamental coloring method | |
JPS55110779A (en) | Method for generation of artificial verdigris | |
KR100674147B1 (en) | Gold-plated Pollack and Method for plating thereof | |
SU1677074A1 (en) | Method of producing pellets | |
JP2899353B2 (en) | How to color zinc and zinc alloys | |
JPH06128054A (en) | Method for fixing substance to cement concrete and substance-fixed cement concrete | |
JPS5558386A (en) | Zinc-trivalent chrome electric plating bath | |
JPS62253774A (en) | Method for accelerating formation of patina film | |
JPH0662896B2 (en) | Paint for mother of pearl shell | |
JPS5588885A (en) | Coating method for generating verdigris | |
JPH04329884A (en) | Artificial verdigris liquid |