JPS60130023A - Electrode filament - Google Patents

Electrode filament

Info

Publication number
JPS60130023A
JPS60130023A JP58236024A JP23602483A JPS60130023A JP S60130023 A JPS60130023 A JP S60130023A JP 58236024 A JP58236024 A JP 58236024A JP 23602483 A JP23602483 A JP 23602483A JP S60130023 A JPS60130023 A JP S60130023A
Authority
JP
Japan
Prior art keywords
coating
discharge
metal wire
coating material
matrix
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58236024A
Other languages
Japanese (ja)
Inventor
Kiyoshi Inoue
潔 井上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inoue Japax Research Inc
Original Assignee
Inoue Japax Research Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inoue Japax Research Inc filed Critical Inoue Japax Research Inc
Priority to JP58236024A priority Critical patent/JPS60130023A/en
Publication of JPS60130023A publication Critical patent/JPS60130023A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02Main electrodes
    • H01J1/13Solid thermionic cathodes
    • H01J1/14Solid thermionic cathodes characterised by the material
    • H01J1/148Solid thermionic cathodes characterised by the material with compounds having metallic conductive properties, e.g. lanthanum boride, as an emissive material

Landscapes

  • Solid Thermionic Cathode (AREA)

Abstract

PURPOSE:To obtain an electrode filament with high efficiency by depositing and forming an LaB6 coating layer for a thermion emission material on a matrix metal wire using the discharge coating. method. CONSTITUTION:A surface coating layer 2 made of LaB6 is formed on the surface of a tungusten wire 1 at a thickness below 10 microns using the discharge coating method. The discharge coating uses a method in which while a coating material electrode and a metal wire are being made to touch, separated, oscillated or rotated and slided, discharge is generated between both and the coating material is deposited to a matrix metal wire, a method in which a coating material wire is dissolved and scattered by shock discharge and is made to collide against the matrix metal wire, a method in which coating material powder is jetted by shock discharge and is made to collide against the matrix and is deposited and applied, a method in which shock discharge is performed between the coating material electrodes opposed to the matrix, and such. As a result, the coating layer can be formed on the surface of the matrix metal wire as the LaB6 compound without decomposing the coating material LaB6 and the coating layer that is deposited to the matrix and is coupled tightly can be obtained.

Description

【発明の詳細な説明】 本発明は耐熱性金属線から成る電球用フィラメントまた
は放電灯電極の改良に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to improvements in lamp filaments or discharge lamp electrodes made of heat-resistant metal wires.

在来の白熱電球用フィラメントは、耐熱性金属線を用い
、普通タングステン線のコイルフィラメントの表面に電
子放出性物質のバリウム、ストロンチウム、カルシウム
を主体とした酸化物に少量の酸化ジルコニウムなどを添
加したものを塗布して用いる。また電球内を真空、高圧
水銀もしくは高圧ナトリウム雰囲気またはアルゴンなど
特殊気体充填をしたものなどが用いられた。こうして、
単位電力当りの高照度数、例えば、ルーメン/Wが得ら
れるように改良された。これを、さらに顕著に良好にす
るために、本発明は、公知の耐熱性金属線であって高電
子放出線を用いた場合に、その表面に放電を利用してL
aB5の薄い被覆層を溶着して形成したものである。
Conventional filaments for incandescent light bulbs use heat-resistant metal wire, with a small amount of zirconium oxide added to the surface of the coiled filament, which is usually made of tungsten wire, and oxides mainly containing electron-emitting substances such as barium, strontium, and calcium. Apply something and use it. In addition, bulbs with a vacuum, high-pressure mercury or sodium atmosphere, or a special gas such as argon were used. thus,
Improvements have been made so that high illuminance per unit power, for example, lumens/W, can be obtained. In order to improve this even more significantly, the present invention proposes that when a known heat-resistant metal wire is used and a high electron emission beam is used, a discharge is applied to the surface of the wire.
It is formed by welding a thin coating layer of aB5.

本発明の一実施例について説明する。第1図と第2図は
本発明の電球用フィラメントの標準的モデルの断面図で
ある。
An embodiment of the present invention will be described. 1 and 2 are cross-sectional views of a standard model of a filament for a light bulb according to the present invention.

本発明は、耐熱性金属として、タングステン、タンタル
、白金、イリジウムのような溶融点が高く導電性で電子
放出性材を用いる。第1図で示す例では、中心材1とし
てタングステンを用いる場合、タングステン線1の所要
直径のものの表面に6ホウ化ランタン(LaBa )を
10ミクロン以下の厚さで、放電被覆方法を使用して、
表面被覆層2を形成した。第2図の例では、中心材1と
して耐熱性材として用いるような場合、例えば、タング
ステン線lの所要直径のものの表面に10ミクロンの厚
さでイリジウムのメッキ層3を形成し、その表面にホウ
素を拡散する割合が少ない6ホウ化ランタンを10ミク
ロン以下の厚さで前記の第1図の場合と同様に表面被覆
層2を形成した。この場合のほかに、中心材1としてタ
ンタルのフィラメントを用い表面に被覆したイリジウム
層3を形成しホウ化物被覆層2を形成したもの、前記の
中心材1としてタングステンのフィラメントlに白金被
覆層3を同様に形成し6ホウ化ランタン薄膜層2を形成
したものなどを用いることができる。
In the present invention, as the heat-resistant metal, a material having a high melting point, conductivity, and electron emitting property, such as tungsten, tantalum, platinum, or iridium, is used. In the example shown in Fig. 1, when tungsten is used as the core material 1, lanthanum hexaboride (LaBa) is coated on the surface of the tungsten wire 1 with a required diameter to a thickness of 10 microns or less using an electrical discharge coating method. ,
A surface coating layer 2 was formed. In the example shown in Fig. 2, when the core material 1 is used as a heat-resistant material, for example, an iridium plating layer 3 with a thickness of 10 microns is formed on the surface of a tungsten wire 1 having a required diameter. The surface coating layer 2 was formed using lanthanum hexaboride, which has a low diffusion rate of boron, to a thickness of 10 microns or less in the same manner as in the case of FIG. 1 above. In addition to this case, there are also cases in which a tantalum filament is used as the core material 1, an iridium layer 3 is formed on the surface thereof, and a boride coating layer 2 is formed, and a tungsten filament is used as the core material 1 and a platinum coating layer 3 is formed on the surface. A lanthanum hexaboride thin film layer 2 formed by forming the lanthanum hexaboride thin film layer 2 can be used.

また、中心材1としてタリウムのフィラメント、白金の
フィラメント、タンタルのフィラメントを用い希土類ホ
ウ化物を被覆した場合も、良好な結果が得られた。また
更にモリブデン、ニッケル、鉄等も用いられる。次に、
本発明のタングステンのフィラメント1に白金の10ミ
クロン厚さ3をメッキし、その上面に6ホウ化ランタン
2を被覆して電球線としたもの(表中のN15)を、他
の在来の線を用いたものとルーメン/Wを比較して第1
表に示した。きわめて顕著に輝度効率が向上した。
Good results were also obtained when a thallium filament, a platinum filament, or a tantalum filament was used as the core material 1 and coated with a rare earth boride. Furthermore, molybdenum, nickel, iron, etc. are also used. next,
The tungsten filament 1 of the present invention is plated with platinum to a thickness of 10 microns, and the top surface is coated with lanthanum hexaboride 2 to make a light bulb wire (N15 in the table), compared to other conventional wires. Comparing the lumen/W with that using
Shown in the table. The luminance efficiency has been significantly improved.

なお、放電被覆は被覆材電極と金属線とを接触開離振動
もしくは回転摺動させながら両者間に放電1表 本発明
のものと在来のものの比較電を発生して被覆材を母材金
属線に溶着する方法、被覆材ワイヤを衝撃放電にょシ溶
解飛散させて母材金属線に衝突被覆させること、もしく
は被覆材粉末を衝撃放電にょシ噴射させ母材に衝突させ
て溶着被覆させる方法、または母材に対向した被覆材電
極間で衝撃放電を行なう方法等が用いられ、被覆材のL
aBaを分解させることな(LaB6化合物のま\母材
金属線の表面に被覆層を形成でき、母材に溶着して強固
に結合する被覆層が得られる。被覆厚さは実験では0.
1〜0.8mmであったが、更に厚く被覆する工夫が望
まれる。
In addition, the discharge coating is made by subjecting the coating material electrode and the metal wire to contact/release vibration or rotational sliding to generate a discharge between them. A method of welding the coating material to the wire, a method of melting and scattering the coating material wire by impact discharge and applying impact coating to the base metal wire, or a method of welding and coating the coating material powder by spraying the coating material powder by impact discharge and causing it to collide with the base metal wire. Alternatively, a method of performing impact discharge between electrodes of the coating material facing the base material is used, and the L of the coating material is
A coating layer can be formed on the surface of the base metal wire without decomposing aBa (LaB6 compound), and a coating layer that is firmly bonded to the base metal by welding can be obtained.
Although the thickness was 1 to 0.8 mm, it is desirable to devise an even thicker coating.

放電灯電極として用いた場合、螢光塗料を塗布したガラ
ス管内にAr十水銀の封入ガス内に挿入して実験したと
き、耐用寿命は6000 H以上、色温度は約2800
 Kと高く、効率が32%(52KHz )、13W、
725Oルーメンであった。
When used as a discharge lamp electrode, the service life was over 6000 H and the color temperature was approximately 2800 H when tested by inserting it into a glass tube coated with fluorescent paint and filled with Ar mercury.
K, high efficiency of 32% (52KHz), 13W,
It was 725O lumens.

このように本発明では放電被覆を利用して熱電子放出性
物のLaB5の被覆層を母材金属線に溶着して形成した
から効率の高い電極フィラメントが得られ、且つ寿命が
高く良好な電極が得られる効果がある。
In this way, in the present invention, a coating layer of LaB5, which is a thermionic emissive material, is welded to a base metal wire using a discharge coating, so that a highly efficient electrode filament can be obtained, and a good electrode with a long life can be obtained. There is an effect that can be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図と第2図は本発明の一実施例のモデルの断面図。 1・・・中心のフィラメント 2・・・6ホウ化ランタン被覆層 3・・・被覆金属層 特許出願人 株式会社 弁上ジャパックス研究所代 理
 人 弁理士 中 西 − #1lvl 算2 図
1 and 2 are cross-sectional views of a model according to an embodiment of the present invention. 1... Center filament 2... 6 Lanthanum boride coating layer 3... Covering metal layer Patent applicant Bengami Japax Research Institute Agent Patent attorney Nakanishi - #1lvl Calculation 2 Figure

Claims (1)

【特許請求の範囲】[Claims] タングステンなどの耐熱金属線材の表面に放電を利用し
て熱電子放出性物質のLaB sから成る薄い被覆層を
溶着して形成したことを特徴とした電極フィラメント。
An electrode filament characterized by forming a thin coating layer made of LaBs, a thermionic emission material, on the surface of a heat-resistant metal wire such as tungsten using electric discharge.
JP58236024A 1983-12-16 1983-12-16 Electrode filament Pending JPS60130023A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58236024A JPS60130023A (en) 1983-12-16 1983-12-16 Electrode filament

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58236024A JPS60130023A (en) 1983-12-16 1983-12-16 Electrode filament

Publications (1)

Publication Number Publication Date
JPS60130023A true JPS60130023A (en) 1985-07-11

Family

ID=16994630

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58236024A Pending JPS60130023A (en) 1983-12-16 1983-12-16 Electrode filament

Country Status (1)

Country Link
JP (1) JPS60130023A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60200434A (en) * 1984-03-23 1985-10-09 Inoue Japax Res Inc Cathode filament

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60200434A (en) * 1984-03-23 1985-10-09 Inoue Japax Res Inc Cathode filament
JPH0354825B2 (en) * 1984-03-23 1991-08-21

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