JPS5996545A - Information recording carrier - Google Patents
Information recording carrierInfo
- Publication number
- JPS5996545A JPS5996545A JP57206123A JP20612382A JPS5996545A JP S5996545 A JPS5996545 A JP S5996545A JP 57206123 A JP57206123 A JP 57206123A JP 20612382 A JP20612382 A JP 20612382A JP S5996545 A JPS5996545 A JP S5996545A
- Authority
- JP
- Japan
- Prior art keywords
- lacquer
- radiation
- information recording
- plastic substrate
- recording carrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004922 lacquer Substances 0.000 claims abstract description 34
- 239000000758 substrate Substances 0.000 claims abstract description 21
- 229920003023 plastic Polymers 0.000 claims abstract description 15
- 239000004033 plastic Substances 0.000 claims abstract description 13
- 230000005855 radiation Effects 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 6
- -1 isoglopanol Chemical compound 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 claims description 3
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 229940043232 butyl acetate Drugs 0.000 claims 1
- 239000011368 organic material Substances 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 7
- 238000003847 radiation curing Methods 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 3
- 238000010894 electron beam technology Methods 0.000 abstract description 3
- 150000005691 triesters Chemical class 0.000 abstract description 3
- DKEGCUDAFWNSSO-UHFFFAOYSA-N 1,8-dibromooctane Chemical compound BrCCCCCCCCBr DKEGCUDAFWNSSO-UHFFFAOYSA-N 0.000 abstract description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 2
- 150000005690 diesters Chemical class 0.000 abstract description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract description 2
- 239000004417 polycarbonate Substances 0.000 abstract description 2
- 229920000515 polycarbonate Polymers 0.000 abstract description 2
- 239000004926 polymethyl methacrylate Substances 0.000 abstract description 2
- MSAHTMIQULFMRG-UHFFFAOYSA-N 1,2-diphenyl-2-propan-2-yloxyethanone Chemical compound C=1C=CC=CC=1C(OC(C)C)C(=O)C1=CC=CC=C1 MSAHTMIQULFMRG-UHFFFAOYSA-N 0.000 abstract 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 11
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 150000002923 oximes Chemical class 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 239000000969 carrier Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 3
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- PWMWNFMRSKOCEY-UHFFFAOYSA-N 1-Phenyl-1,2-ethanediol Chemical compound OCC(O)C1=CC=CC=C1 PWMWNFMRSKOCEY-UHFFFAOYSA-N 0.000 description 1
- FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005323 electroforming Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B23/00—Record carriers not specific to the method of recording or reproducing; Accessories, e.g. containers, specially adapted for co-operation with the recording or reproducing apparatus ; Intermediate mediums; Apparatus or processes specially adapted for their manufacture
- G11B23/0057—Intermediate mediums, i.e. mediums provided with an information structure not specific to the method of reproducing or duplication such as matrixes for mechanical pressing of an information structure ; record carriers having a relief information structure provided with or included in layers not specific for a single reproducing method; apparatus or processes specially adapted for their manufacture
- G11B23/0064—Intermediate mediums, i.e. mediums provided with an information structure not specific to the method of reproducing or duplication such as matrixes for mechanical pressing of an information structure ; record carriers having a relief information structure provided with or included in layers not specific for a single reproducing method; apparatus or processes specially adapted for their manufacture mediums or carriers characterised by the selection of the material
Landscapes
- Optical Record Carriers And Manufacture Thereof (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の技術分野ｊ
本発明はプラスデック基板の」−に、信号ビットを有す
る放射線硬化性ラッカ一層を設けたビデオディスクやデ
ンタルオーディオディスク用の情報記録担体に関する。TECHNICAL FIELD OF THE INVENTION The present invention relates to an information record carrier for video discs and dental audio discs, in which a plus deck substrate is provided with a single layer of radiation-curable lacquer having signal bits.
一般にビデオディスクやデジタルオーディオディスク用
の情報記録担体け、表面に多数の信号ビットが形成され
たディスクで、従来は射出成形法やコンブレジョン′成
形法等により製造されているしかるにこれらの方法は製
造装植が大型である土、しかも転写精１ｆ（が低いなど
の欠点があった。In general, information recording carriers for video discs and digital audio discs are discs with a large number of signal bits formed on their surfaces. Conventionally, they are manufactured by injection molding, combination molding, etc. However, these methods are difficult to manufacture. There were disadvantages such as soil with large planting size and low transfer quality (1F).
これらの点を改善するため信号ビットを放射純硬化性ラ
ッカ一層に形成する転写力法が特開昭５１−１４０６０
１ 号公報、特開昭５３−１１．６１．０５号公報、
特開昭５４−１３０９０２号公報、特開昭５４−１３８
４０６号公報、特開昭５５−４７９３号公報等に開示さ
れている。In order to improve these points, a transfer force method in which signal bits are formed in a single layer of radiation-curing lacquer was proposed in Japanese Patent Application Laid-Open No. 14060/1983.
1 Publication, JP-A-53-11.61.05,
JP-A-54-130902, JP-A-54-138
This method is disclosed in Japanese Patent Publication No. 406, Japanese Unexamined Patent Publication No. 55-4793, and the like.
この方法は原盤またはスタンパ−（電鋳法により原盤か
ら転写されて出来た金屑成形型）などの転写用母型の表
面に液状の放射Ｍ＠化性ラッカー層を薄く設け、このラ
ッカ一層の上に無色透明なプラスチック基板を載せて、
ラッカ一層を挾持した状卵で放射線を照射［７てラッカ
ー八”弓とこＪｌと一体に接合したプラスデック基板を
転写用［１型から剥離して情報記録担体を製造するもの
である。This method involves applying a thin layer of liquid radiant M@-containing lacquer on the surface of a master mold for transfer, such as a master disc or a stamper (a metal scrap mold made by transferring from a master disc by electroforming). Place a colorless transparent plastic substrate on top,
Radiation is irradiated with a laminated egg holding a single layer of lacquer [7] The Plus Deck substrate, which is integrally bonded with a lacquer 8" bow-toe Jl, is peeled off from the mold 1 for transfer to produce an information recording carrier.
［２かし２ながら、従来の情報記録担体は放ｎ１線硬化
性ラッカーとして、一般に不飽和結合にもつモノマーや
スリゴマーが、特に低分子モノ、ジ、トリ又はテトラア
クリル酸エステルが好適なモノマーとして用いられてい
るが、プラスチック基板（／ｉに注型アクリル板）七の
密着性が悪い。[2However, conventional information recording carriers are generally used as N1 radiation-curable lacquers, typically monomers or sligomers having unsaturated bonds, particularly low-molecular-weight mono-, di-, tri- or tetra-acrylic acid esters as suitable monomers. However, the adhesion of the plastic substrate (cast acrylic plate /i) is poor.
このため、情報記録担当を長時間使用し７ていると、特
に高湿や高温の環境中で使用していると放射線硬化ラッ
カ一層が次第に基板との界面から剥離してくる問題があ
る。For this reason, if the information recording device is used for a long time, especially in a high humidity or high temperature environment, there is a problem in that the radiation-cured lacquer layer gradually peels off from the interface with the substrate.
本発明は、かかる点に鑑みなされたもので、高湿、高温
中において長期間使用しても、信号ビットを形成された
放射線硬化ラッカ一層と基板との密着性が維持され、長
寿命化を図ることができる情報記録担体を折供すること
を目的とする。The present invention has been developed in view of these points, and even when used for long periods of time in high humidity and high temperatures, the adhesion between the radiation-cured lacquer layer on which the signal bits are formed and the substrate is maintained, resulting in a longer service life. The purpose is to provide information recording carriers that can be used to record information.
本発明の特徴Ｖ１放射線硬化性ラッカーの一成分として
プラスチック基板な溶解する能力をもつ有機溶媒を含有
させることにある。A feature of the present invention is the inclusion of an organic solvent capable of dissolving plastic substrates as a component of the V1 radiation-curable lacquer.
放射線硬化性化合物としては、一般にアクリル酸ないし
けメタクリル酸のモノニスデル、ジエステル、トリエス
テル、あるいはトリエステル・のモノマーやオリゴマ二
が好しく、例えば、ｎ−ブチルアクリレート、ヘキシル
アクリレート、２−エチルへキシルアクリレート、フコ
ユニルアクリレート、ジエチレングリコールジアクリレ
ート、テトラエヂレングリコールジアクリレート、トリ
メチロールプロパントリアクリレート、ペンタエリスリ
トールトリアクリレート、ペンクエリスリトールテトラ
アクリレート、エポキシアクリレート。As the radiation-curable compound, monomers or oligomers of acrylic acid, diester, triester, or triester of acrylic acid, methacrylic acid, etc. are generally preferred, such as n-butyl acrylate, hexyl acrylate, and 2-ethylhexyl. Acrylate, fucounyl acrylate, diethylene glycol diacrylate, tetraethylene glycol diacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate, penquerythritol tetraacrylate, epoxy acrylate.
ポリエステルアクリレート、ブタジェンアクリレート等
が挙げられる。またその他にポリエチレン化合物とポリ
チオール化合物との混合物でも良い。Examples include polyester acrylate and butadiene acrylate. In addition, a mixture of a polyethylene compound and a polythiol compound may also be used.
放射線源としては電子線、γ線や紫外線等が用いられる
が、紫外ａを用いる場合には、放射線硬化性ラッカーの
一成分として光開始剤、たとえばベンゾインイソブチル
エーテル、ペンゾインイソグロビルエーテル等を添加す
る必要がある。Electron beams, gamma rays, ultraviolet rays, etc. are used as radiation sources, but when ultraviolet a is used, a photoinitiator such as benzoin isobutyl ether, penzoin isoglobyl ether, etc. is used as a component of the radiation-curable lacquer. need to be added.
本発明に用いられるプラスチック基板とは、利質的にポ
リメチルメタクリレート、ポリカーボネート、塩ビ・酢
ビ共重合体等である。The plastic substrate used in the present invention is preferably polymethyl methacrylate, polycarbonate, vinyl chloride/vinyl acetate copolymer, or the like.
また、本発明におけるプラスチック基板を溶解する能力
をもつ有機溶剤としては、アセトン、インプロパツール
、トルコン、キシレン、酢酸ブチル等が挙げられる。こ
の可溶性溶媒は単−溶Ｉす２で用いてもよく混合溶媒で
用いてもよい。この有機溶剤の含有上は一般に３０％以
下が好しい。これ以上含有側が増えると、プラスチック
基板を劣化しすぎたり、放射線硬化に時間がかかる。Further, examples of the organic solvent having the ability to dissolve the plastic substrate in the present invention include acetone, Impropatol, Torcon, xylene, butyl acetate, and the like. This soluble solvent may be used as a single soluble solvent or as a mixed solvent. The content of this organic solvent is generally preferably 30% or less. If the content increases further than this, the plastic substrate will deteriorate too much and radiation curing will take a long time.
次に転写方法を第１図で説明すると、プラスチック基板
（１）の上に前記組成の放射線硬化付ラッカ一層（２）
を塗布し、放置又は加熱により含有した有機溶剤を蒸発
さぜ、放射線で硬化する成分のみを残す。次に表面に信
号ピット（３）を形成した原盤またはスタンバ−など転
写用母型（４）を、スペーサ−（５）で周縁を囲まれた
放射線硬化ラッカ一層（２）の上に載せる。この後、透
明なプラスチック基板（１）の上から紫外線や電子線な
どの放射線（６）を照射すると前記ラッカ一層（２）が
硬化し、信ηビット（３）が転写される。Next, the transfer method will be explained with reference to FIG.
is applied, and the organic solvent contained is evaporated by standing or heating, leaving only the components that can be cured by radiation. Next, a transfer master mold (4) such as a master or stub bar with signal pits (3) formed on its surface is placed on the radiation-curing lacquer layer (2) surrounded by spacers (5). Thereafter, when the transparent plastic substrate (1) is irradiated with radiation (6) such as ultraviolet rays or electron beams, the lacquer layer (2) is cured and the digital bits (3) are transferred.
次に信号ビット（３）が表面に転写された硬化ラッカ一
層（２）を、プラスチック基板＋１１ごと転写用母型（
２）から剥離する２この後、硬化ラッカ一層の」−に金
属の反射膜金蒸着等により形成し、反射率の変化によυ
、光学的に読み取りがｎｆ能な情報記録担体を得ること
ができる。Next, the hardened lacquer layer (2) with the signal bit (3) transferred to the surface is applied to the transfer matrix (2) together with the plastic substrate +11.
2) Peel off from 2) After this, a metal reflective film is formed by gold evaporation on top of the hardened lacquer, and changes in reflectance cause υ
, an optically readable information recording carrier can be obtained.
なお本発明は、上記の如く信号ビットの転写だけでなく
、スパイラル状の”案内溝″を転写して光学的に書き込
みのできる情報ｎ１録１工」体にも適用することができ
る。The present invention can be applied not only to the transfer of signal bits as described above, but also to an information recorder that can be written optically by transferring a spiral "guide groove."
次に本発明の具体的実施例につき説明する。 Next, specific examples of the present invention will be described.
実施例１ トリエチレングリコールジアクリレー） ３０ 部。Example 1 triethylene glycol diacrylate) 30 parts.
ペンタエフスリトールトリアクリレート３０部。30 parts of pentaefthritol triacrylate.
アセトン２０部、エポキシアクリレ−） ２０ 部に光
開始剤１−フェニル−１，２−フロパンジオン−２−（
０−エトキシカルボニル）オキシム（通称カンタキュア
ＰＩ）Ｏ） ｔ ２部加えてよ＜ ４１２拌し−Ｃ１微
細なごみや不純物をろ過し次放射糾硬化性ラッカーを調
整した。このラッカー液をアクリル板の土に塗布し、し
ばらく放置してアセトンを蒸発させ、更に赤外線ランプ
′ｆｆ１ｏ分間ｆｌｎ ｊＪｌｌ、た後、こノ土ニニツ
ケルスタンパ−を取ねたイ（、紫外線を照射して、前記
ラッカ一層を硬化さぜた５、この後ニラクールスタンパ
−から剥離した後、信号ビットが転写された硬化ラッカ
一層の表面にＡ／＝を蒸着して１ＦＪ ′！１３（ｒｉ
Ｊ （１，４／’ 、 Ｈさ０．９１１ 、深さ０．１
１ ／’ ） ｉ１録担体を！！！潰した。The photoinitiator 1-phenyl-1,2-furopanedione-2-(
Add 2 parts of 0-ethoxycarbonyl)oxime (commonly known as Cantacure PI) O) and stir for 412 minutes. -C1 Fine dust and impurities were filtered out, and then a radiation hardenable lacquer was prepared. This lacquer solution was applied to the soil of the acrylic plate, left for a while to evaporate the acetone, and then heated with an infrared lamp for 10 minutes. Then, the lacquer layer was cured 5. After peeling off from the Niracool stamper, A/= was vapor deposited on the surface of the cured lacquer layer to which the signal bits had been transferred, and 1FJ'!13(ri
J (1,4/', H 0.911, depth 0.1
1/') i1 recording carrier! ! ! I crushed it.
この場合、ニッケルスタンパ−との離型性および得られ
た情報記録担体の信号ビットの転写効率並びに硬化ラッ
カ一層とアクリル板との密着性を夫々調べ、その結果金
第１表に示した。々お信号ピットの転写効率は以下のよ
うにして調らべた。In this case, the releasability from the nickel stamper, the transfer efficiency of the signal bits of the obtained information recording carrier, and the adhesion between the hardened lacquer layer and the acrylic plate were investigated, and the results are shown in Table 1. The transfer efficiency of each signal pit was investigated as follows.
転写してできたＡ４蒸着情報配録担体にビーム径を約１
．６μφにしほった波長７８０μｍの半＞ｉ、体レーザ
を掃引させて信号ビットの有無を反射率の変化で再生さ
せ、その反射率の変化の度合を相対値で示し念。反射率
の変化の１１“１合が大きい方が転写効率−より良いと
いうことが言える。The beam diameter is set to approximately 1 on the A4 evaporation information recording carrier created by transfer.
．． By sweeping the body laser at a wavelength of 780 μm, which is set to 6 μφ, the presence or absence of a signal bit is reproduced by a change in reflectance, and the degree of change in reflectance is expressed as a relative value. It can be said that the larger the 11"1 ratio of the change in reflectance, the better the transfer efficiency.
また、硬化ラッカ一層とアクリル板との密着性の評価は
クロス力ットテーブテス） ＡＳＴＭ−Ｉ）・３３５９
−７６で行った１、
実施例２
トリエチレングリコールジアクリレート２０部。In addition, the adhesion between a single layer of cured lacquer and an acrylic board can be evaluated using cross-cut tape test ASTM-I) 3359.
-76 Example 2 20 parts of triethylene glycol diacrylate.
アクリル酸エヂルカルビトール３０ 部、アセトン３０
部、エポキシアクリレ−１・２０部に光開始剤１−フェ
ニル−１，２−プロパンジオン−２−（〇−エトギシ力
ルボニル）オキシム（カンタキコーアＰＤＯ） ｉ ２
部加えて放射１ｆＱ硬化性ラッカーを調整した。実施例
１と同様に、このラッカー液を用いて情報記録１１１体
ｆ体製：し、た。この情報記録担体の評価結果を第１表
に示す。30 parts of edyl carbitol acrylate, 30 parts of acetone
part, 1.20 parts of epoxy acrylate, photoinitiator 1-phenyl-1,2-propanedione-2-(〇-ethoxycarbonyl)oxime (Kantakicor PDO) i 2
In addition, a radiation 1fQ curable lacquer was prepared. As in Example 1, 111 information recording bodies were manufactured using this lacquer liquid. Table 1 shows the evaluation results of this information recording carrier.
比較例１ トリエチレングリコールジアクリレー） ３０ 部。Comparative example 1 triethylene glycol diacrylate) 30 parts.
アクリル酸エチル力Ａ・ビＦ−ル５０部、エポキシアク
リレート２０部、■−フェニルー１，２−プロパンシ刊
ンー２−（０−エトキシカッ１ボニル）オキシム（カン
タヤユアＰＤＯ） ２部からなる放射線硬化性ラッカー
を用いて実施例１と四扛に情報記録担体を試作し、Ｎ’
Ｆ価］−５た結県を第１表に示−ｆ−８比較例２
トリエチレングリコール７５ 部、ペンタ丁すスリトー
ルトリアクリレート２５部に光開始剤１−フェニル−１
，２−プロパンジオン−２−（０−エトキシカルボニル
）オキシム（カンクキコーアＰＤＯ）全２部ＩＪＩＩえ
て調製された放射線硬化性ラッカー百・用いて、実施例
１と同様に情停記録和体全第１表からも明らかなように
、本発明のように放射線硬化性ラッカーの一成分として
フラスチツク基板を溶解する能力全もつ有機溶剤全含有
させることにより、ラッカ一層と基板との密着性が大幅
に向上される。Radiation-curable lacquer consisting of 50 parts of ethyl acrylate A/B, 20 parts of epoxy acrylate, and 2 parts of phenyl-1,2-propane-2-(0-ethoxycarbonyl) oxime (Kantayaur PDO). Using Example 1 and Shikaku, an information recording carrier was prototyped, and N'
F value]-5 is shown in Table 1-f-8 Comparative Example 2 75 parts of triethylene glycol, 25 parts of penta-thritol triacrylate, and photoinitiator 1-phenyl-1
, 2-Propanedione-2-(0-ethoxycarbonyl)oxime (Kankukikoa PDO) All two parts IJII and the radiation-curable lacquer 100 were prepared in the same manner as in Example 1. As is clear from the table, the adhesion between the lacquer layer and the substrate is greatly improved by including all the organic solvents capable of dissolving the plastic substrate as a component of the radiation-curable lacquer as in the present invention. Ru.
第１図は本発明による悄’（ＩＩ ｆｌｌ：録４１！体
の転写法を説明するための図である。
■・・・ブヲスチツク基板
２・・・放射線硬化性ラッカ一層
３・・・信号ピット ４・・・転写用Ｎ型５・・・
スペーサ−６・・／ｉ◇別線FIG. 1 is a diagram for explaining the method of transferring the image according to the present invention. ■...Visual stick board 2...Radiation-curable lacquer layer 3...Signal pits 4... N type for transfer 5...
Spacer-6.../i◇Separate line
Claims (2)
射線により硬化するラッカ一層を設け、更にその上から
プラスチック基板で前記ラッカ一層を挾持［また状態で
放射線を照射してラッカ一層を硬化させ、これを転写用
母型から剥離してビット又は案内溝を転写した情報記録
担体において、前記放射線硬化性ラッカーの一成分とし
て、プラスチック基板表面を部分的に溶解する６）ｉ力
をもつ有機溶媒を含有さ・げたことを特徴とする情報記
録担体。(1) A layer of lacquer that is cured by radiation is placed on a transfer matrix such as a master disc or a stambar, and then the layer of lacquer is sandwiched between plastic substrates. In the information recording carrier on which bits or guide grooves are transferred by peeling this off from the transfer matrix, an organic material having 6) i-power that partially dissolves the surface of the plastic substrate is used as a component of the radiation-curable lacquer. An information recording carrier characterized by containing a solvent.
有機溶媒として、”アセトン、イソグロパノール。 トルエン、キシレン、酢酸ブヂル、のうち少なくの とも一種全含有させたことを特徴とする！１′ｉｎ′１
′潤求範囲第１項記載の情報記録担体。(2) The organic solvent capable of dissolving the plastic substrate is characterized in that it contains at least one of acetone, isoglopanol, toluene, xylene, and butylacetate!1'in'1
'The information recording carrier according to item 1 of the desired scope.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57206123A JPS5996545A (en) | 1982-11-26 | 1982-11-26 | Information recording carrier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57206123A JPS5996545A (en) | 1982-11-26 | 1982-11-26 | Information recording carrier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5996545A true JPS5996545A (en) | 1984-06-04 |
Family
ID=16518169
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57206123A Pending JPS5996545A (en) | 1982-11-26 | 1982-11-26 | Information recording carrier |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5996545A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63100635A (en) * | 1986-06-20 | 1988-05-02 | Pioneer Electronic Corp | Optical information recording carrier |
-
1982
- 1982-11-26 JP JP57206123A patent/JPS5996545A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63100635A (en) * | 1986-06-20 | 1988-05-02 | Pioneer Electronic Corp | Optical information recording carrier |
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