JPS5990806A - Working method of fine pattern - Google Patents

Working method of fine pattern

Info

Publication number
JPS5990806A
JPS5990806A JP20091482A JP20091482A JPS5990806A JP S5990806 A JPS5990806 A JP S5990806A JP 20091482 A JP20091482 A JP 20091482A JP 20091482 A JP20091482 A JP 20091482A JP S5990806 A JPS5990806 A JP S5990806A
Authority
JP
Japan
Prior art keywords
thin film
pattern
magnetization
magnetic
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20091482A
Other languages
Japanese (ja)
Inventor
Takao Tsuji
隆男 辻
Moriyoshi Hashimoto
母理美 橋本
Makoto Shimokooriyama
下郡山 信
Tatsuya Kinoshita
達也 木下
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Canon Inc
Original Assignee
Canon Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Canon Inc filed Critical Canon Inc
Priority to JP20091482A priority Critical patent/JPS5990806A/en
Publication of JPS5990806A publication Critical patent/JPS5990806A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • C23C14/042Coating on selected surface areas, e.g. using masks using masks
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/18Diffraction gratings
    • G02B5/1847Manufacturing methods
    • G02B5/1857Manufacturing methods using exposure or etching means, e.g. holography, photolithography, exposure to electron or ion beams

Abstract

PURPOSE:To enable easy working of an ultrafine pattern by forming the magnetization of the fine pattern on a thin vertical magnetization film formed on a base plate and sticking and fixing the magnetic particles coated with a high polymer material to the thin film thereby patterning the film. CONSTITUTION:A thin film 2 having high magnetic permeability is laminated on a base plate 1 and further a thin vertical magnetization film 3 is laminated by a method, such as sputtering, on the film 2, thereby forming a medium 6. Magnetization of a grating pattern is formed at a micro pitch P, for example, 0.5mum, on the thin film 3. Magnetic writing by a vertical magnetic head is used for forming the grating pattern. The magnetic pattern formed of the magnetic particles coated with a thermoplastic material 12 is developed. For example, iron powder and thermoplastic, etc. are used for the particles and the material. The material is then heated to melt and the particles are fixed on the film 3 thereby forming a mask 4. The parts of the thin film 3' and the thin film 2' covered by the mask 4 are allowed to remain and the remaining parts are dissolved away by etching, whereby the diffraction grating having the fine pattern is produced.

Description

【発明の詳細な説明】 本発明は、回折格子等の微細パターンの加工方法に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for processing fine patterns such as diffraction gratings.

従来、例えば、回折格子等の作製の際には、一般にフオ
) Uソ法ど呼ばれる加工方法が用いられてきた。この
方法は、まず被加工物上にフォトレジストヲ薄<ぬυ、
ネガのマスクをのせて紫外線テ密5B 焼付し、光の当
った部分のフォトレジストだけを重合させる。次にこれ
を現像液に入れ、光の当らなかった部分のフォトレジス
トを溶解除去する。更に、これをエツチング液に浸し、
フォトレジストの除去された被加工物の露出部分をエツ
チングする。この後、フォトレジストを取シ除けば、前
記マスクに描かれた通りのパターンで物体を加工するこ
とができる。
Conventionally, for example, when producing a diffraction grating, etc., a processing method generally referred to as a photo-optic method has been used. This method first involves applying a thin layer of photoresist on the workpiece.
Place a negative mask on the mask and bake with 5B ultraviolet light, polymerizing only the photoresist in the exposed areas. Next, this is placed in a developer to dissolve and remove the photoresist in the areas not exposed to light. Furthermore, soak this in etching solution,
Etch the exposed portion of the workpiece from which the photoresist has been removed. Thereafter, by removing the photoresist, the object can be processed with the pattern drawn on the mask.

しかし、上記の加工方法において、微細なパターンの加
工を行なおうとすると、前記マスクを製作する為に大型
で高価な装置が必要となる。また露光の際のマスクの解
像限界等から、極端に微細なパターン(例えば1μm以
下)の加工は困難であった。
However, in the above-mentioned processing method, if a fine pattern is to be processed, a large and expensive device is required to manufacture the mask. Furthermore, it has been difficult to process extremely fine patterns (for example, 1 μm or less) due to the resolution limit of the mask during exposure.

本発明は、上記事実に鑑み、極微なパターンの加工を容
易に行ない得る微細パターンの加工方法を提供すること
を目的とする。
SUMMARY OF THE INVENTION In view of the above-mentioned facts, an object of the present invention is to provide a method for processing a fine pattern that can easily process a very fine pattern.

本発明は基盤上に垂直磁化薄膜を形成する過程と、該垂
直磁化薄膜に微細パターンの磁化を形成する過程と、該
微細パターンに従って前記垂直磁化薄膜上に高分子材料
で被覆された磁性粒子を付着し定着させる過程と、該磁
性粒子の付着定着したパターンに従って、前記垂直磁化
薄膜をパターン化する過程とから成る微細パターンの加
工方法によって上記目的を達成するものである。
The present invention includes a process of forming a perpendicularly magnetized thin film on a substrate, a process of forming a fine pattern of magnetization on the perpendicularly magnetized thin film, and a process of forming magnetic particles coated with a polymeric material on the perpendicularly magnetized thin film according to the fine pattern. The above object is achieved by a fine pattern processing method comprising the steps of adhering and fixing the magnetic particles and patterning the perpendicularly magnetized thin film according to the adhering and fixing pattern of the magnetic particles.

以下、本発明の実施例を図面を用いて説明する。Embodiments of the present invention will be described below with reference to the drawings.

第1図(N〜(0は、本発明に基づく加工方法で回折格
子を作製する過程を説明する略断面図である。
FIG. 1 (N~(0) is a schematic cross-sectional view illustrating the process of producing a diffraction grating by the processing method based on the present invention.

まず第1図(A)の如く、基板1上に高透磁率薄膜2を
、更にその上に垂直磁化薄膜6を例えばスパッタリング
等の方法で積層し媒体6を形成する。ここで高透磁率薄
膜2は、後述の磁化パターンの形成の際に、磁束を垂直
磁化ヘッドの主磁極に当接する部分に集中させ、微細な
パターンの形成を助けるものであるが、必ずしも必要で
はなく、省略は公知のものである。
First, as shown in FIG. 1A, a medium 6 is formed by laminating a high magnetic permeability thin film 2 on a substrate 1 and a perpendicular magnetization thin film 6 thereon by, for example, sputtering. Here, the high magnetic permeability thin film 2 helps form a fine pattern by concentrating the magnetic flux on the part that comes into contact with the main pole of the perpendicular magnetization head when forming a magnetization pattern, which will be described later. However, it is not necessarily necessary. The omission is well known.

次に垂直磁化薄膜6に、第1図(E9に示すように微小
なピッチP(例えば0.5μff1)で、格子パターン
の磁化を形成する。格子パターンの形成には、例えば一
般に垂直磁気記録法として知られた、垂直磁化ヘッド圧
よる磁気書き込みを用いる。この様子を第2図に示す。
Next, as shown in FIG. 1 (E9), a lattice pattern of magnetization is formed on the perpendicularly magnetized thin film 6 at a minute pitch P (for example, 0.5 μff1). Magnetic writing using perpendicular magnetic head pressure is used, known as .This process is shown in FIG.

第2図において、7は高透磁率材料の薄板から成る主磁
極で、その先端は媒体6に当接している。また、8はや
はシ高透磁率材料から成る補助磁極、9は補助磁極に巻
かれた信号巻線で、主磁極7と合わせて垂直磁化ヘッド
を構成している。ここで媒体6を矢印Aの方向に定速度
で移動させながら、巻線9にパルス電圧を印加し、主磁
極7と補助磁極8間に垂直方向の磁界を励磁して、図中
10に示すように格子パターンの磁化を形成する。この
場合、・<ルス電圧の繰υ返し周期は、媒体乙の移動速
度と、求める回折格子の格子ピッチの設定値により決ま
る。
In FIG. 2, 7 is a main magnetic pole made of a thin plate of high magnetic permeability material, the tip of which is in contact with the medium 6. Further, 8 is an auxiliary magnetic pole made of a material with high magnetic permeability, and 9 is a signal winding wound around the auxiliary magnetic pole, which together with the main magnetic pole 7 constitutes a perpendicular magnetization head. While moving the medium 6 at a constant speed in the direction of arrow A, a pulse voltage is applied to the winding 9 to excite a vertical magnetic field between the main magnetic pole 7 and the auxiliary magnetic pole 8, as shown in 10 in the figure. To form a grid pattern of magnetization. In this case, the repetition period of the .<Russ voltage is determined by the moving speed of the medium B and the set value of the grating pitch of the diffraction grating to be sought.

次に前述のように形成された格子パターンに従って、第
1図(qの如く垂直磁化薄膜6上にマスク4を形成する
。このマスク4が形成される様子を第5図(I%L(1
3Iで詳しく説明する。まず、第6図(への如く、熱可
塑性材料12で被覆された磁性粒子11で形成された磁
化I(ターンを現像する。このとき磁性粒子11は硼化
によって生ずる磁界に従い、磁化の境界部分に集中して
付着する。ここで用いる磁性粒子11及び熱可塑性材料
12は例えば夫々鉄粉及び熱可塑性プラスチック等を用
いることができる。磁性粒子11を付着させる方法は、
具体的には、磁性粒子を含んだ溶液中に垂直磁化薄膜6
を浸す。或いはこの溶液を垂直磁化薄膜6上に流す等の
方法が考えられる。次に、第6図(Blの如く、熱可塑
性材料12を可熱して溶解せしめ、磁性粒子11を垂直
磁化薄膜6上に定着させマスク4を形成する。
Next, according to the lattice pattern formed as described above, a mask 4 is formed on the perpendicular magnetization thin film 6 as shown in FIG.
This will be explained in detail in 3I. First, as shown in Figure 6, the magnetization I (turn) formed by the magnetic particles 11 coated with the thermoplastic material 12 is developed. At this time, the magnetic particles 11 follow the magnetic field generated by the boriding, and The magnetic particles 11 and the thermoplastic material 12 used here can be, for example, iron powder and thermoplastic plastic, respectively.The method for attaching the magnetic particles 11 is as follows:
Specifically, a perpendicularly magnetized thin film 6 is placed in a solution containing magnetic particles.
Soak. Alternatively, a method such as flowing this solution onto the perpendicularly magnetized thin film 6 may be considered. Next, as shown in FIG. 6 (Bl), the thermoplastic material 12 is heated and melted, and the magnetic particles 11 are fixed on the perpendicularly magnetized thin film 6 to form the mask 4.

最後に、第1図tqの如くマスク4でカッ(−された垂
直磁化薄膜6′、高透磁率薄膜2′の部分を残してのこ
りをエツチングによって溶解除去し、微細パターンの回
折格子を作製する。
Finally, as shown in FIG. 1 tq, the remaining portions of the perpendicular magnetization thin film 6' and high magnetic permeability thin film 2' cut off by the mask 4 are dissolved and removed by etching to produce a fine pattern of diffraction gratings. .

第4図は、本発明に基づいて形成された他の微細パター
ンの例を示す略断面図である。この微細パターンは、前
述の第1図(9の過臀から更にマスク4を熱可塑性材料
を溶解する溶剤などに浸すことによって除去し形成され
る。このように基板1上に形成された垂直磁化薄膜6′
と高透磁率薄膜2′から成る微細パターンは、回折格子
だけでなく、例えば垂直磁化薄膜3′を磁化することに
よって、マグネスケールのスケール板として用いること
もできる。
FIG. 4 is a schematic cross-sectional view showing another example of a fine pattern formed based on the present invention. This fine pattern is formed by further removing the mask 4 from the upper part of FIG. Thin film 6'
The fine pattern consisting of the high magnetic permeability thin film 2' can be used not only as a diffraction grating but also as a scale plate of Magnescale, for example, by magnetizing the perpendicularly magnetized thin film 3'.

また、第5図(A)のように、第1図中の過程の後、基
板1もエツチングし、そこから1スク4.垂直磁化薄膜
6′、高透磁率薄膜2′を除去することによって、第5
1司山の如く、基板1自体に微細・くターンを刻むこと
もできる。
Further, as shown in FIG. 5(A), after the process shown in FIG. 1, the substrate 1 is also etched, and from there one screen 4. By removing the perpendicular magnetization thin film 6' and the high magnetic permeability thin film 2', the fifth
It is also possible to carve fine turns on the substrate 1 itself, such as in the case of 1st ridge.

前述の実施例の回折格子を作製する際に、格子ピッへ誤
差は、磁化パターンの形成過程における、パルス電圧の
4!!シ返し周期の・(ラツキと、媒体の送り速度のパ
ラツキによυ決まる。そこで第2図の如き系において、
媒体6の送υ量を例えばマグネスケール等の位置センサ
ーで検出し、この位置情報によυ、信号巻線9への・(
ルス電圧の印加を制御する事により、精度の高い回折格
子の作製が可能となる。また、ここで主磁極7を、前述
の高透磁率材料の薄板の代わりに、平面性の良好なガラ
ス基板上に高透磁率薄膜を蒸着或いはスパッタリング等
で作成したものを用いることによシ、回折格子の直線性
を改善する事もできる。
When producing the diffraction grating of the above-mentioned example, the grating pitch error was 4! of the pulse voltage in the process of forming the magnetization pattern. ! It is determined by the fluctuation of the return period and the fluctuation of the feeding speed of the medium. Therefore, in the system shown in Fig. 2,
The amount of feed υ of the medium 6 is detected by a position sensor such as a magnescale, and based on this position information, υ is sent to the signal winding 9.
By controlling the application of the pulse voltage, it is possible to fabricate a highly accurate diffraction grating. In addition, the main magnetic pole 7 can be made by using a thin film of high magnetic permeability formed by vapor deposition or sputtering on a glass substrate with good flatness instead of the thin plate of the high magnetic permeability material described above. It is also possible to improve the linearity of the diffraction grating.

本発明に基づく微細パターンの形成方法におい変 では、前述の実施例に限らず、種々の戸威が可能である
。例えば、垂直磁化ヘッドを用いる代わシに、光学的に
磁化パターンを書き込むこともできる。この方法は、一
般に光磁気記録法として知られておシ、簡単に説明する
と、垂直磁化薄膜は、予め一方向(上向き或いは下向き
)に磁化され、該垂直磁化薄膜上をレーザビーム等の光
ビームで走査する。光ビームの当った部分はキューリ一
点以上に湿度が上昇し、磁化方向が無秩序となυ、光ビ
ームが通り過ぎると、冷却の過程で、周囲の磁界の影響
で、光ビームの当っていない部分とは磁化方向を逆にし
て磁化される。この原理を利用して、光ビームによって
磁化パターンを書き込むものである。
The method for forming a fine pattern according to the present invention is not limited to the above-mentioned embodiments, and various variations are possible. For example, instead of using a perpendicular magnetization head, the magnetization pattern can be written optically. This method is generally known as magneto-optical recording method. To put it simply, a perpendicularly magnetized thin film is magnetized in one direction (upward or downward) in advance, and a light beam such as a laser beam is passed over the perpendicularly magnetized thin film. Scan with . In the area hit by the light beam, the humidity increases to more than a Curie point, and the magnetization direction becomes disordered. is magnetized with the direction of magnetization reversed. This principle is used to write a magnetization pattern using a light beam.

また、実施例においては直線状に磁化パターンを記録す
る例を示したが、主磁極の形状、数を種々に変化させる
、或いは前述の光磁気記録法を用いることによシ、曲線
等を含んだ更に複雑な微小パターンの形成も可能である
In addition, although the example shows an example in which a magnetization pattern is recorded in a straight line, it is possible to record a magnetization pattern including a curved line by variously changing the shape and number of the main magnetic poles, or by using the above-mentioned magneto-optical recording method. However, it is also possible to form even more complex micropatterns.

更に、本発明に基づいて、前述の回折格子、スケール板
に限らず、対物電クロメータ、フレネルレンズ等を作製
することもできる。
Furthermore, based on the present invention, not only the above-mentioned diffraction grating and scale plate but also objective electrochromators, Fresnel lenses, etc. can be manufactured.

以上説明したように、本発明は従来の微細パターンの形
成方法において、垂直磁気記録法を応用することによっ
て、更に極微なパターンの形成を容易(・テする等の効
果を有するものである。
As described above, the present invention has the effect of facilitating the formation of even finer patterns by applying the perpendicular magnetic recording method to the conventional fine pattern forming method.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(八〜(巻は夫々本発明に基づく微細パターンの
形成方法の過程を示す略断面図、第2図は垂直磁化ヘッ
ドを用いて微細パターンの磁化を書き込む過程を説明す
る概略図、第6図fA)、fBlは夫々本発明において
マスクを形成する過程を説明する略断面図、第4図は本
発明に基づいて形成された他の微細パターンの例を説明
する略断面図、第5図(A)、(Qは夫々本発明に基づ
く更に他の微細パターンの形成過程を説明する略断面図
である。 ・・・主磁極、8・・・補助(1°趨極、9・・・信号
巻線、10・・・格子パターンの磁化、11−・拳磁性
粒子、12・−・熱可塑性材料 手続補正書(自発) 昭和58年2月4日 特許庁長官 若 杉和 夫  殿 事件の表示 昭和57年 特許願  第 200914   +−す
発明の名称 微細パターンの加工方法 補正をする者 11+1とθ)門(才       特r「出ign人
(1ノリi   !J!足部人Ill K F #、 
I’−3−30−2名ゼ(・ (+00)キャノン株式
会社キャノン株式会ン1内(I:1、話758−211
1)5、補正の対象 明細書 6、補正の内容 1)明細書第4頁1行目から2行目にかけて「垂直磁化
ヘッド」を1垂直磁気ヘツド」と訂正する。 2)同第4頁7行目の「垂直磁化ヘット」を「垂直磁気
ヘッド」吉訂正する。 ろ)同第7頁6行目の「垂直磁化ヘッド」を「垂直磁気
ヘット」と訂正する。 4)同第8頁16行目から14行目にかけて「垂直磁化
ヘット」を1垂直磁気ヘツド」と訂正する。 39−
FIG. 1 (volumes 8 to 8) are schematic cross-sectional views showing the process of the method of forming a fine pattern based on the present invention, and FIG. 2 is a schematic diagram explaining the process of writing the magnetization of a fine pattern using a perpendicular magnetization head. 6 fA) and fBl are schematic cross-sectional views illustrating the process of forming a mask in the present invention, respectively. FIG. 5 (A) and (Q are schematic cross-sectional views illustrating the formation process of still other fine patterns based on the present invention, respectively. Main magnetic pole, 8... Auxiliary (1° trending pole, 9... ... Signal winding, 10... Magnetization of lattice pattern, 11-- Fist magnetic particles, 12-- Thermoplastic material procedural amendment (voluntary) February 4, 1980 Mr. Kazuo Wakasugi, Commissioner of the Patent Office Display of the case 1982 Patent application No. 200914 F#,
I'-3-30-2 people (+00) Canon Co., Ltd. Canon Co., Ltd. 1 (I:1, talk 758-211
1) 5. Specification subject to correction 6, Contents of correction 1) From the 1st line to the 2nd line of page 4 of the specification, "perpendicular magnetic head" is corrected to 1 perpendicular magnetic head. 2) Correct "perpendicular magnetization head" in line 7 of page 4 to "perpendicular magnetic head". (b) On page 7, line 6, "perpendicular magnetic head" is corrected to "perpendicular magnetic head." 4) On page 8, lines 16 to 14, ``perpendicular magnetic head'' is corrected to ``1 perpendicular magnetic head''. 39-

Claims (1)

【特許請求の範囲】[Claims] (1)基盤上に垂直磁化薄膜を形成する過程と、該垂直
磁化薄膜に微細パターンの磁化を形成する過程と、該微
細パターンに従って前記垂直磁化薄膜上に高分子材料で
被覆された磁性粒子を付着し定着させる過程と、該磁性
粒子の付着定着したパターンに従って、前記垂直磁化薄
膜をパターン化する過程とから成る微細パターンの加工
方法。
(1) A process of forming a perpendicularly magnetized thin film on a substrate, a process of forming a fine pattern of magnetization on the perpendicularly magnetized thin film, and a process of forming magnetic particles coated with a polymeric material on the perpendicularly magnetized thin film according to the fine pattern. A method for processing a fine pattern, comprising the steps of adhering and fixing the magnetic particles, and patterning the perpendicularly magnetized thin film according to the adhering and fixing pattern of the magnetic particles.
JP20091482A 1982-11-16 1982-11-16 Working method of fine pattern Pending JPS5990806A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20091482A JPS5990806A (en) 1982-11-16 1982-11-16 Working method of fine pattern

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20091482A JPS5990806A (en) 1982-11-16 1982-11-16 Working method of fine pattern

Publications (1)

Publication Number Publication Date
JPS5990806A true JPS5990806A (en) 1984-05-25

Family

ID=16432369

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20091482A Pending JPS5990806A (en) 1982-11-16 1982-11-16 Working method of fine pattern

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0777605A (en) * 1993-09-09 1995-03-20 Agency Of Ind Science & Technol Production of optical spot array element
EP1267396A2 (en) * 2001-04-26 2002-12-18 Hewlett-Packard Company Magnetically patterning conductors

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0777605A (en) * 1993-09-09 1995-03-20 Agency Of Ind Science & Technol Production of optical spot array element
EP1267396A2 (en) * 2001-04-26 2002-12-18 Hewlett-Packard Company Magnetically patterning conductors
EP1267396A3 (en) * 2001-04-26 2003-11-12 Hewlett-Packard Company Magnetically patterning conductors

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