JPS5989755A - One side hot dipping method of steel strip - Google Patents

One side hot dipping method of steel strip

Info

Publication number
JPS5989755A
JPS5989755A JP57198485A JP19848582A JPS5989755A JP S5989755 A JPS5989755 A JP S5989755A JP 57198485 A JP57198485 A JP 57198485A JP 19848582 A JP19848582 A JP 19848582A JP S5989755 A JPS5989755 A JP S5989755A
Authority
JP
Japan
Prior art keywords
plating
stop
roll
agent
steel strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57198485A
Other languages
Japanese (ja)
Inventor
Yoshinori Fujita
藤田 芳則
Takao Shimizu
孝雄 清水
Hisao Yasunaga
安永 久雄
Katsunori Akiyoshi
秋吉 勝則
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP57198485A priority Critical patent/JPS5989755A/en
Publication of JPS5989755A publication Critical patent/JPS5989755A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0035Means for continuously moving substrate through, into or out of the bath
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0038Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
    • C23C2/004Snouts
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Abstract

PURPOSE:To prevent the generation of a recessed flaw on a stop-off surface in the stage of plating a steel strip formed with a layer of a plating stop-off agent on one surface by removing the metallic balls sticking on the stop-off surface before the stop-off agent surface contacts with a roll. CONSTITUTION:A steel strip 1 is coated with a plating stop-off agent on one surface A thereof with a coater 2 and is then subjected to calcination of the stop-off agent,that is, the formation of a stop-off agent layer together with annealing in a continuous annealing furnace 3. The strip 1 is thereafter dipped in a molten metal pot 4, and is subjected to hot dipping on one side, and is guided by rolls 5-8 so as to be transferred to the succeeding stage. A brushing device 9 is provided in a desired position in the section after the passage of the port 4 and before the contact of the surface A with the roll 8, for example, in the position between the rolls 5 and 6, to brush the surface A and to remove the fine metallic balls sticking on the surface A. The formation of a recessed flaw on the surface A owing to the contact of said surface having such balls sticking thereon with the roll 8 is thus prevented.

Description

【発明の詳細な説明】 本発明は銅帯の片面溶融めっき方法に関し、特に、めっ
き後めっき阻止剤面がロールに接する前に該めっき阻止
剤面上に付着した金属上を除去することによシ、該めつ
睡阻止剤面の凹疵の発生を防止する銅帯の片面溶融めっ
き方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for single-sided hot-dip plating of copper strips, and in particular, by removing the metal deposited on the plating inhibitor surface after plating and before the plating inhibitor surface contacts the roll. B. A method for single-sided hot-dip plating of a copper strip that prevents the occurrence of dents on the surface of the anti-nausea agent.

−帯の片面のみを溶融めっきする場合hv14帯のめつ
き阻止面にめっき阻止剤の被覆層を形成した後これを溶
融金属ポットに通して片面に金属を付着する方法が採用
されている。
- When hot-dipping only one side of the strip, a method is adopted in which a coating layer of a plating inhibitor is formed on the plating-inhibiting surface of the HV14 strip and then passed through a molten metal pot to deposit metal on one side.

このような連続式片面溶融めっき方法に用いるめっき阻
止剤として種々のものが提案されて込るが、一般的には
、溶融金属と反応しない安定した酸化物が用いられる。
Various types of plating inhibitors have been proposed for use in such continuous single-sided hot-dip plating methods, but generally stable oxides that do not react with molten metal are used.

このようなめつき阻止剤は溶融金属に対するはじき性に
すぐれたものである。
Such a plating inhibitor has excellent repellency against molten metal.

しかし、溶融金属ポットを通してめっきする時には、溶
融金属の微細な金属上(例えば直径t)、 5 fi程
度の金属上)がめつき阻止剤の表面に付着することは避
けえない。
However, when plating is carried out through a molten metal pot, it is inevitable that fine particles of the molten metal (for example, metals with a diameter of t or about 5 fi) adhere to the surface of the plating inhibitor.

従来の溶融めっき方法では、めつき後そのま\冷却装置
や後処理装置などへ搬送していたので、′めつき阻止剤
面上に微細な金属上が付着した状態で該めっき阻止剤面
がロールに接触することに力υ、このためめっき阻止面
に凹状の疵が生じるという欠点があった。
In the conventional hot-dip plating method, after plating, the plating is directly transported to a cooling device or post-processing device. There was a drawback that the contact with the roll caused a force υ, which caused concave scratches on the plating blocking surface.

本発明の目的は、このような従来技術の欠点を解消し、
めっき後めっき阻止剤面がロールに接する前に該めっき
阻止剤面上の金属上を除去することによシ、門流が少な
く平滑な非めっき面が得られる銅帯の片面溶融めっき方
法を提供することである。
The purpose of the present invention is to eliminate such drawbacks of the prior art,
To provide a single-sided hot-dip plating method for a copper strip in which a smooth non-plated surface with less gate current is obtained by removing the metal on the plating inhibitor surface before the plating inhibitor surface comes into contact with a roll after plating. That's true.

すなわち、本発明によれば、銅帯の一面にめっき阻止剤
の層を形成した後該銅帯を溶融金属ボットに連続的に挿
通して片面をめっきする銅帯の片面溶融めっき方法にお
いて、溶融金属ボットを通過した後めっき阻止剤面がロ
ールに接する前に、このめっき阻止剤面をブラッシング
して該めっき阻止剤面上に付着した金属玉を除去するこ
とを特徴とする銅帯の片面溶融めっき方法が提供される
That is, according to the present invention, in a method for single-sided hot-dip plating of a copper strip, in which a layer of a plating inhibitor is formed on one side of the copper strip, the copper strip is continuously passed through a molten metal pot to plate one side. Single-sided melting of a copper strip, characterized in that after passing through a metal bot and before the plating inhibitor surface contacts the roll, the plating inhibitor surface is brushed to remove metal balls adhering to the plating inhibitor surface. A plating method is provided.

以下図面を参照して本発明の詳細な説明する。The present invention will be described in detail below with reference to the drawings.

第1図において、片面溶融めっきすべき鋼帯lは、先ず
コーター2でその一面(非めっき面)Aにめっき阻止剤
を塗布され、次いで、連続焼鈍炉3で銅帯の焼鈍ととも
にめっき阻止剤の焼成すなわちめっき阻止剤の層の形成
が行なわれ、その後溶融金属ボット4内へ連続的に浸漬
させて片面溶融めっきを行なう。
In FIG. 1, a steel strip l to be single-sided hot-dipped is first coated with a plating inhibitor on one side (non-plated surface) A in a coater 2, and then coated with a plating inhibitor while annealing the copper strip in a continuous annealing furnace 3. , that is, the formation of a layer of a plating inhibitor, is performed, and then continuously immersed into a molten metal pot 4 to perform single-sided hot-dip plating.

溶融金属ボット4を通過した鋼帯lはターンロール5,
6,7.8によって案内されて次の工程へ搬送される。
The steel strip l passed through the molten metal bot 4 is passed through a turn roll 5,
6, 7.8, and transported to the next process.

しかして、図示の例では、上流側に位置する3個のター
ンロール5,6.7はいずれも鋼帯1のめっき面Bに接
するロールであ夛、最後のターンロール8はめつき阻止
剤面(非めっき面)Aに接するロールになっている。
Therefore, in the illustrated example, the three turn rolls 5, 6.7 located on the upstream side are all rolls in contact with the plating surface B of the steel strip 1, and the last turn roll 8 is a roll with a plating inhibitor surface. (Non-plated surface) The roll is in contact with A.

溶融金属ボット4を通過した後めっき阻止剤面Aがロー
ル(ターンロール8)に接する前の区間の所望位置、す
なわち図示の例ではターンロール5.60間の位置に、
めっき阻止剤面Aをブラッシングするブラシノ装置9が
設置されている。
At a desired position in the section before the plating inhibitor surface A contacts the roll (turn roll 8) after passing through the molten metal pot 4, that is, at a position between the turn rolls 5 and 60 in the illustrated example,
A brushless device 9 for brushing the plating inhibitor surface A is installed.

このブラシノ装置9は、溶融金属ボット4を通過する間
にめっき阻止剤面A上に付着した微細な(例えば約0.
5 wa粗粒径金属玉を除去するためのものである。ブ
ラシノ装置9としては、例えば、回転ドラム周面姉ワイ
ヤを植立した回転式ブラシ装置が使用される。
This Brassino device 9 has fine particles (for example, about 0.0 mm) deposited on the plating inhibitor surface A while passing through the molten metal pot 4.
This is for removing 5 wa coarse grain size metal beads. As the brush brush device 9, for example, a rotary brush device in which wires are planted on the circumferential surface of a rotating drum is used.

図示の例ではブラシノ装置9はめっき面Bに接するロー
ラ5,60間に設けたが、この設置場所は溶融金属ボッ
ト4とめつき阻止剤面AK接するロール8との間の他の
適当な位置に選定することができる。例えば、第1図中
の点Xと点Yとの間の任意の位置に選定することができ
る。
In the illustrated example, the Brassino device 9 is installed between the rollers 5 and 60 that are in contact with the plating surface B, but this installation location is at another suitable location between the molten metal bot 4 and the roll 8 that is in contact with the plating inhibitor surface AK. can be selected. For example, it can be selected at any position between point X and point Y in FIG.

また、図示の例では、1個のブラシノ装置9七設置した
が、設置個数は2個以上の適当な数にするととも可能で
ある。
Further, in the illustrated example, one Brassino device 97 is installed, but it is also possible to install an appropriate number of two or more.

溶融めっき後の高温状態の銅帯10表面に付着している
金属玉を除去するブラシノ装置9のプラツシ材としては
腰の強いブラッシングワイヤを使用することが好ましく
、ナイロン系よりスチール系のブラッシングを使用する
ことが好ましい。スチール系でも、耐熱性の観点からス
テンレススチールを使用することが好“ましい。
It is preferable to use a strong brushing wire as the plastic material of the brushless device 9 that removes metal balls adhering to the surface of the hot copper strip 10 after hot-dip plating, and use steel-based brushing rather than nylon-based brushing. It is preferable to do so. Among steel-based materials, it is preferable to use stainless steel from the viewpoint of heat resistance.

また、ナイロン系のワイヤブラシノでは焼付けが生じや
すいが、これを防止するために水スプレーを併用するこ
とが行なわれる。
In addition, nylon-based wire brushes tend to seize, but in order to prevent this, water spray is also used.

さらに、残存金属玉の数を最小限にし、凹疵の数を安定
的に最小限に抑えるためには、プラシンの本数は1本よ
りも複数本使用する方が好ましい。
Furthermore, in order to minimize the number of remaining metal balls and to stably minimize the number of dents, it is preferable to use a plurality of plasticine pieces rather than one.

次に、本発明の方法の実施例を具体的データに基いて説
明する。
Next, examples of the method of the present invention will be described based on specific data.

N aI OS i Os  B鵞Os  、Mg O
−T 1Otr  Altos系のめつき阻止剤を洗浄
剤銅帯の片面に塗布し、連続焼鈍炉中で銅帯の焼鈍とと
もにめっき阻止剤の焼成を行ない、次いで、溶融znボ
ット中を通してznめっきを行なった。
N aI OS i Os B鵞Os , Mg O
-T 1Otr An Altos-based plating inhibitor is applied to one side of the cleaning copper strip, and the copper strip is annealed and the plating inhibitor is fired in a continuous annealing furnace, and then passed through a molten ZN bot to perform ZN plating. Ta.

ポット通過直後の垂直立上がシ部では、通祁の気体絞り
装置によυめつき面のzn付着量を制御しめつき阻止剤
面には火災を当て\Znの付着防止を行なった。ワイヤ
ブラシノによるプラ、ツシング効果はめつき阻止剤剥離
後の銅帯非めっき面の門流の個数で評価した。
Immediately after passing through the pot, at the vertical rise point, a gas throttling device was used to control the amount of Zn adhering to the plating surface, and fire was applied to the plating inhibitor surface to prevent Zn from adhering. The plastic and tushing effect of the wire brass was evaluated by the number of gates on the non-plated surface of the copper strip after the anti-plating agent was removed.

第1表は、本発明の実施例である試験1−5とブラッシ
ングを行なわない従来例とのデータを示す表である。
Table 1 is a table showing data for Tests 1-5, which are examples of the present invention, and a conventional example in which brushing was not performed.

各実施例1〜5ともブラシノとしては、材質がSUS 
304で線径0.3 mのワイヤブラシノを使用した。
In each of Examples 1 to 5, the material of Brassino is SUS.
304 and a wire diameter of 0.3 m was used.

実施例1のごと<、11000rpの回転数で逆転(銅
帯進行方向と逆方向の接線速度)させたところ、プラシ
ン本数が1本でも1mmクシ門流は35個であり、プラ
シンなしの従来例の場合の195個に比べ大巾な門流の
低減を達成することができた。
As in Example 1, when the rotation was reversed at a rotation speed of 11,000 rpm (tangential speed in the opposite direction to the copper band advancing direction), even with one plasticine, the 1 mm comb flow was 35, compared to the conventional example without plasticine. We were able to achieve a significant reduction in the number of gates compared to the 195 gates in the case.

プラシン本数を2本にすると、実施例2〜5に示すごと
く、各ブラッシング条件(正転または逆転1回転速度な
ど)下でも1mmクシ門流の数を5個以下にすることが
でき、疵の発生を最小限に抑えることができた。
When the number of plastic brushes is set to two, as shown in Examples 2 to 5, the number of 1 mm combs can be reduced to 5 or less even under various brushing conditions (forward rotation or reverse rotation speed, etc.), which prevents the occurrence of scratches. was able to be minimized.

第  1  表 以上の説明から明らかなごとく、本発明によれば、門流
が少なく平滑な非めっき面を形成しうる鋼帯の溶融片面
めっき方法が得られる。
As is clear from the explanations in Table 1 and above, the present invention provides a single-sided hot-dip plating method for steel strips that can form a smooth non-plated surface with less gate flow.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明による鋼帯の溶融片面めっき方法を実施
する装置の概略説明因である。 ■・・・鋼帯、  2・・・めつ唇阻止剤を塗布するコ
ーター、  3・・・連続焼鈍炉、  4・・・溶融全
島ポット。 5.6,7.8・・・ロール(ターン口・−ル)。 A・・・めつき1泪止剤面、  B・・・めっき面。 代理人  鵜 沼 辰 之 (ほか2名)
FIG. 1 is a schematic illustration of an apparatus for carrying out the single-sided hot-dip plating method for steel strip according to the present invention. ■...Steel strip, 2...Coater for applying eyelash inhibitor, 3...Continuous annealing furnace, 4...Melting whole island pot. 5.6, 7.8...Roll (turn mouth/role). A: Plating 1 adhesive side, B: Plating side. Agent Tatsuyuki Unuma (and 2 others)

Claims (1)

【特許請求の範囲】[Claims] (1)銅帯の一面にめっき阻止剤の層を形成した後該銅
帯を溶融金属ポットに連続的に浸漬して片面をめっきす
る銅帯の片面溶融めっき方法において、溶融金属ポット
を通過した後めっき阻止剤面がロールに接する前に、こ
のめっき阻止剤面をブラッシングして該めっき阻止剤面
上に付着した金属上を除去することを特徴とする銅帯の
片面溶融めっき方法。
(1) In the single-sided hot-dip plating method for copper strips, in which a layer of plating inhibitor is formed on one side of the copper strip and then the copper strip is continuously immersed in a molten metal pot to plate one side, the copper strip passed through the molten metal pot. 1. A method for single-sided hot-dip plating of a copper strip, which comprises brushing the plating inhibitor surface to remove metal deposited on the plating inhibitor surface before the plating inhibitor surface comes into contact with a roll.
JP57198485A 1982-11-12 1982-11-12 One side hot dipping method of steel strip Pending JPS5989755A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57198485A JPS5989755A (en) 1982-11-12 1982-11-12 One side hot dipping method of steel strip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57198485A JPS5989755A (en) 1982-11-12 1982-11-12 One side hot dipping method of steel strip

Publications (1)

Publication Number Publication Date
JPS5989755A true JPS5989755A (en) 1984-05-24

Family

ID=16391894

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57198485A Pending JPS5989755A (en) 1982-11-12 1982-11-12 One side hot dipping method of steel strip

Country Status (1)

Country Link
JP (1) JPS5989755A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5827969A (en) * 1981-08-14 1983-02-18 Hitachi Ltd Plating method on one side

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5827969A (en) * 1981-08-14 1983-02-18 Hitachi Ltd Plating method on one side

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