JPS5974557A - Method for bleaching color photographic sensitive material - Google Patents

Abstract

PURPOSE:To bleach a color photosensitive material efficiently even when the material contains a colloidal silver layer, without producing offensive odor, by bleaching the color photographic silver halide material contg. a specified org. compd. with a processing soln. contg. persulfate after exposure and color development. CONSTITUTION:The color photographic sensitive silver halide material cotg. a compd. having formula I [R<1>, R<2> are each H or an aliphatic residue, and both may form a ring; R<3> is -R<4>- or -R<4>-S-(R<4> is a divalent aliphatic residue); X is a divalent heterocyclic residue contg. at least one of N, O, and S; and M is H, alkali metal, alkaline earth metal, quaternary ammonium salt, or quaternary phosphonium salt] or its strong acid salt, such as a compd. of formulae II or IIIis bleached with a processing soln. contg. persulfate, such as sodium persulfate, after the photographic material has beed exposed and color developed. A color photosensitive material even having a colloidal silver layer contg. a high content of silver can be bleached efficiently without producing offensive odor.

Description

[Detailed description of the invention]

The present invention relates to an egg white method for silver halide color photographic paper (hereinafter referred to as color material), and particularly to a bleaching method using persulfate for color material which is an improved version of the albumen method. In general, the basic processing steps for color photosensitive materials are the color development step and the desilvering step. In other words, the electrophotographic color photosensitive material is
In the color development process, the halogenated compound is reduced by the color image forming material to form a rut, and the oxidized color development process reacts with the coloring agent to give a pigment residue. The feed enters the desilvering process, where the silver produced in step 1 is oxidized by the action of an oxidizing agent (commonly known as a bleaching agent), and then it is desilvered by a 1-silver complexing agent, commonly known as a bleaching agent. The color photosensitive material is excluded from the photosensitive materials.Actually, only a dye image is produced on the color photosensitive material.In addition to the two foundation processes of color development and desilvering mentioned above, the actual development process is , Il!Il involves auxiliary steps to maintain the four-membered, physical quality of the image or to impair the preservation of the image. For example, softening of the photosensitive layer during processing for a few weeks. Examples include a hardening bath to prevent this, a stopping bath to effectively stop the development reaction, an image fixing bath to femaleize the N image, and a film removal bath to remove the backing 1- of the support. In addition, the desilvering process described above can be carried out in one step using a bleaching and fixing bath in which the white side and the fixing bath coexist, or in two separate baths, each consisting of bleaching and fixing baths. In general, the bleaching agents used in bleach solutions include red blood salt, dichromated potassium, '54JJ2 iron ion complex salt, and persulfate. Although the bleaching solution has an excellent raw material effect, it still causes overflow during processing and ferricyanion ions that are discharged when brought into the water tank after milling. It is known that cyanide ions undergo photochemical oxidation to completely generate cyanide compounds, but these cyanide compounds are highly toxic and cause great harm.Therefore, the development of a bleaching agent to replace red blood salt is desired. Ionic complex salts are sometimes used as whitening agents in color photographic papers (German Patent Nos. RTT, T
o! Specification box No. 744, 4'/θ Specification loose, British Specialty No. 7≠6. Specification No. t7, same No. y33. otr specification, 94/, 0/II. 326 statement). However, since the ferric ion complex salt containing ferric ion complex salts, such as hard powder or Xiebai Dingnan, have weak oxidizing power, it should be noted that
When used in a color photosensitive lamp for photography that uses silver iodobromide containing silver halide of a degree A, it takes a long time to process. In any case, the V Hakuju method, which uses high gold j ion such as red blood salt or ferric ion complex salt, is a method that does not use gold j^ ion because the pollution purchase price of @ liquid is large, specifically, the average price l! I!
Rakuhakuho is very promising. However, supersulfur I! 1l1
The disadvantage of the 2-layer bath is that the bleaching blade is weaker than that of the diferric ion mackerel acid, and it takes a long time to bleach. Therefore, it is important to avoid using too much copper halide, especially for color impressions that use a large amount of copper halide.
New techniques are needed to promote the closure of shells. Conventional methods for accelerating persulfate bleaching are described in US Pat. rri 3.1 evening r issue and research
This is a method for removing the amine compounds listed in Disclosure A/Tough 0 Kenato in a process (egg white bath, bleach-fixing bath, or a tower thereof). However, this method requires a long period of time to achieve sufficient bleaching, and many of the amine compounds mentioned above have a bad odor.
L-CJ4] It's not clever to be there. 14, this cuff remover has a layer of yellow filter and anti...
Cos such as Ration Ha・1

[Co-f-do silver ha<'c;
214s of 214s -h ler feeling j' (L l', j busy enough 6 distortion and one stone stone -0 (IL in book j Q Ming's l' target is condolence/ niyi+ 111
The matter has been improved/Color feeling due to the acid salt)'e M
The second step is to provide hard extrusion method for I-1.
(Egg white t'1 without the risk of generation of ingredients: improved egg white (1, 1i + post Q) (depending on color (1 each bi←)) Color feeling)
3jQ+l can be whitened by VC (lambda - white is to be provided with 1 husband, tth colloid 81ik! 2 layers of gold 41'□il 1) The purpose of this clarification is to serve the purpose of this clarification. At least one of the compound represented by the general formula (1) or a strong acid salt thereof is treated with a treatment solution containing salt removal. It is characterized by color 1t & round t4 material - 1 is combined with 1. -・General formula (1) In the formula 1self, 1(・2+t, j each 4 elemental element f or C old 1
1 → Rib, j Noge Residue. As the j111 cost family game body, r, j, , Haii/~/)'s Alkyl Sarashi, Alkunirnoyo, and Alkinil Hiroshi f1 respectively) Jf? It is okay to have a straight 1-inch hole with a reasonable Q. Alkyl/l(ast'', 1γ)]er'' methyl leather,
Azole ^(, propyl, methyl pattern, hekinru, -
, Hiroshi Tesil, J□6 Inopropyl, sec
Use the butyl method, cyclohexyl method, etc.゛Alkenyl as C゛Example &-1' allyl, 2~butenyl)
j', 1.2-hexyl J, 1.1.2-ocdenyl etc. Alkynylno i (tojite)'l, N
E(・' pro-grugyl group, 2-- < nthinyl 4(, etc.). , (, carphogycyl scraps, sulfo-like alkylamino J, 1., amide nails, etc. 1 and 1 form a base J@ base, carbon or 14;;4 J'- and carbon number/~3 alkyl aki-c
1 Historically preferred (7 is 4 (Irana E, methyl handle and ethyl 8). 1 (, 3 represents -164- or -1 also represents 48-. 2 (as 4 water, carbon number / ~ 6 saturation 11th and Furanwa Matoshu or (・'yo branched 1
lif rib group carbide No. 1 Kusuhiro, for example iJ', -CH2-
+-CH2CH2-+-(C112)3-,-(cH2
)4, -(CH□)6-2-0 month 2cII=cJ(C
H12-, -CH2CECCII2-. 113-UH2C11CI-12-, etc. As a number, it is 1t4 good charcoal! -C112C112- and -C)-1 as 1 mo4 for ~t
2GHzC142-. ■ Tojikoha 1t
-δ- is preferable for lees. X is a mere bond, or
It does not represent a j and a 6-membered heterozygous mass. This hetero mass may be complemented by a pentagon. Hetero-j: iI′t is a strange and aromatic compound, such as tetrazole, triazole, thiadiazole, oxazazole, imidazole, thiazole,
These include oxazole, benzimidazole, benzothiazole, penzogisazole, etc. Of these, 4','
? Nikoto 1-< are tetrazole and thiadiazole. 84 is yJ< elemental atom, alkali metal (Na+, ni+
. Alkaline earth metals (Ca, Mg, etc.), quaternary ammonium [carbon number -
゛ ~ 30 power, +/11 eha (CI-13)
4N. (C21-]s) 4N+, (C4),,L(1
) 4N+, C61-15CI-1zN' (CH3)
3゜0Ct6)133N(CH3)3 etc.], tAv′J,
Phosphonium deca salt ((C4H9)4J), C16H33P (CHa
)3. C6H3CH2P (C,L,+3)3, etc.] or amidinodisease. Examples of strong acid salts of the general formula (1) include hydrochloride, ester salt NpF luenesulfone vigilance salt, and methanesulfone lV+* salt. Examples of useful co-V compounds are listed below. (1)-(2) (1)-(5) 1l C1)-(to) 5l-1(1
) - (13) In the case of -1+, '-, the hetero levee is It can be synthesized by a ring-closing reaction. Synthesis Example-1) Synthesis of Compounds (1)-(1) to (5) Commercially available 2. 30
11-Butanol (7
5m11. ) After stirring at 8'00C, add pyridine (7,?9.0./7). , the anti-1-core lf was cooled with water, and the precipitated crystals were collected.
(+-I↓tlCo(22, Otsu?, Yi>+S77%) m, +1, / l / ~ /
Otsu 3 °C 4 members of the same class have arrived G', and the same 4
(2) with a yield of ↑. (1, (4) + (5) ♀ia+/ko. (1) - (2) m, p, /l4I-~/J'A
'C(1) -(3) 'Ill, I), /
t/-7~/evening, 2 °C (1) - (4) m
, p , /7 no~/7j 0C(1) −(s
) m, l), 22 g -222'C (Synthesis Example-2> Synthesis of compounds (1)-(9) to (12)! - Dimebu-aminocochinylamine (g?, 1 mol), triethylamine ( 10/?, 7mol) Existing 'J'
1-I J,' (l/-00Iblind+Q) mixed in a -/l honey 1'' flask, ice/! [j 2, 2111
Carbon monoride, A (g 3 , , < 1i?, /, 74'nyl)? Do'H1to did it. I box charge is about 311 t'c
/? ] W stirring'tc +l+l'i: VJ Daibutsu Diisochlorohequinle'11 Rufodiimide (, 2/7f, i,
otmol) k・Add to IL for 1 hour] rL stirring 1~p. Benzene (lloomc) was added to the reaction solution and Nonuma 11i hΔ
1. ．． 2N-Hc7! Water bath solution and 7J (
1) 1-4 crystals were collected from the awns, and λ-dimethylamine ethyl isothiocyanide -1. Ol↓/11
`` 1 container M (T.Heavy t Mountain-like 4 Tsutomu Isha Small ν /l Three Shiso 1-j Classco Medium 7JK (+00
mU), 1 min in ethanol (/3; Oml')
11, in a hot water bath, 1131 F at 700-7!0C
ζj! ~忰('4-zui). The reaction solution was cooled to about io 0C and 1.2N1. Iα゛(g00 m12) add purple,
The precipitated rbi'r crystallizes and is filtered. 11↓Mother crystal from crystal keisopro・ξnor, (hi@
proboscis (9) to contradict; (riI/-2,4/-ta%)' m,
p,, 2/f~ノ/ta 0C Same 1. ! le fx i, by v4 (10), (1
1), (12): i= is (Iri/kuji, a monk at Godoji Temple. (1) -(lo) m, p, /3i ~i3.2
°C(1)-(11) m, p, /riλ~/ri3°
C(1) -(12) ■, I), /ri0-/
The compound of the general formula (I) of the present invention was incubated at 2 °C for 2 hours. 9 for 1 heart Kakai
Is there no limit to 6, in general / per m2 / IX /
0 ”Mo/L, ~/ ) (/ 0-3-E-le 4
1” 1 Iroku・Yamashi, especially /x10 '7ru～/
Me/l) 4 mol of 1/l river is UJ-dou. A' of the present invention! Carano used in 1j・hi 1tF! ＆Emokuryo is the use of the gods [For example, for color positive, for color paper, for color power, color sentence middle 1, river (there are mi names including couplers, including 6v ko Jl+,, combine)
Of these, one night's worth of stables, ducks, and 3θ〃l.
ノ/100 (1112su, top,) (4t0〃tsuk for the child/
100 heads 2 or more, B4. Since it is used for silver color feeling), it is used for each 'If JJ: according to the meaning of the gods, but the effect of 7 TriC Ming is especially enhanced. As for U1Lri 4・^ formation, from the support L1111 order, Colloid-1・J Halley Fuco 2m stopper, (middle layer,) Red 111\), l, (Intermediate layer,) Green 1 (3\8゛/1, colloidal silver yellow filter 11・j, +Ar !jj'A Ii￥i, good, I1j and 7 halo configuration that governs the i layer...・γa・1 in () , it's good to fall into L.
& ribs, 11 different u, i$? i；・、L'l小i'
1jlH% layer ke'', 1 sense JIS 1 and quotient 11 & 1 current 1
It may be divided into 1 and 7 parts respectively.゛Mada Tokuko Sho I
- Redness 1 (upper edge layer, T
'At least 7 of the 1-sensitivity layer were divided into 3 sublayers] Zeng (
Composition, 11"L with commercial value 1 current emulsion layer and low-sensitivity emulsion layer, as seen in Japanese Kaishoyu/-geta 0.27.
Composition arrangement V Ko West German public collection, 1, 2.1, ri,! λ−
No., same), Otsu 2.2. Tano 3, same, A22, 7.2
No. 1I, same! , 70 Hiromu, 8! , No. 24 and the same λ, 70≠
, No. 777, the layer (j'4 formation, etc. is suspended. This defense's Isshu) formula (the compound of No. 1 is the upper hole; the color feeling) Y-, vU advantageous 1v) stratification. Among them, Kano 1, d no, silver milk + 'l li', protection, 'jLl so, lower, ≧1 so, middle layer, yellow filter halation!
The 9-core IJII is placed in the Soj stop layer. Among these, it is preferable that the constituent layers containing colloidal silver have at least 1 plus r. In particular, Shintsu is the most difficult to open colloid, ration 1≦r,i'L, Iψ-'
i l', 2 ill; If you sword, you will have 8 sad layers (Elephant 1-J1
The effect is that ``)λ has one advantage as a woman. ) lr'l 'IAr l'l'j Jy, N IIC
According to iQ, (1, ', ', , l is history Nika 1 rate, 1:
＜ d+l'ia Vcz xli: Ming) fi,
'I-Ji to L (/, 1-hc Formula (1) +
With Sugi 1 - [・Ki no - 1:l! NJ+, (II)
A compound of the general formula C'A is preferably used in combination with
) compound, which temporarily retains the 4i of the color impression W7 rJ material 11,1 1; 11] Another stable compound called anti-fogging agent or anti-fogging agent is carefully put on the plane.5
・Compound d of general formula (II) does not inhibit de-ibl, so it is a non-explosion 1 (11 It is a compound of the general formula (1) and the compound of the general formula (II). ^ Represents an atom or a group, nium. Yfyo-Nl(, I(, still -
011,'Xun expression, 几5.1 and 6.1 are 7 and R8
are hydrogen, substituted or unsubstituted alkyl, respectively.
(Also, it is easy to freeze 11.
Alternatively, a 6-membered 3M may be formed. To describe the compound of the present invention in detail, in the general formula (11), Q is an alkali fluorophore D41 and C is Li, Na, and Φ, etc., and j-class ammonium is 1 and 11. For example, H4N■, (
CH, 3)4N, (C4H9)4N■, nC12H2
s (C1-1a)aN■, 11c l 6H33(
CH3)3N and PhC)12 (CHa)a
Examples include N(ll!l). The aliphatic groups of R, R, R and R are preferably alkyl groups or alkenyl groups having up to the number of carbon atoms/g, such as butyl group, ethyl^, ll-propyl &,
There are n-butyl group, t-butyl group, n-pentyl group, n-hexyl group, cyclohexyl & n-octyl pattern, n-dodecyl method, n-octadecyl group, and allyl-like. As the aromatic group J& of R, )l, , R and R, an aryl pattern having t to 20 carbon atoms is preferable, such as phenyl threads and naphthyl koji. The ring formed by R and 1 is a ring with 2 to 10 carbon atoms and may contain CI, N or S in the first ring member. For example, +CH24, +Cl-I25, There are +CH2→6, -CH2CH20CH2CHz-1H3 -CH2C, H2N CH2CH2-, etc. R, Jt, R and ordinary political exchange groups include acyloxy group (Shio Rie has methki 7 patterns, ethoxy Hiroshi), haloken (e.g. chloro, bromo), alkyl & (for example, methyl ice, ethyl pattern, etc.), phenyl eight, alkoxycarbonyl camellia (e.g. ethoxycarbonyl group), acyl group (
(e.g., acetyl group), acyloxy group (e.g., acetyloxy group), cyanogen, nitro group, alkylthio group (e.g., methylthio Nr), amide group (e.g., acetamide group)
and sulfonamide paper (for example, methanesulfonamide paper). Particularly preferable R5 is a hydrogen atom and a carbon number l.
-3 alkyl groups and phenyl groups, preferably hydrogen atoms and methyl groups. Particularly preferred as R and R are a hydrogen atom j-, an alkyl group having a carbon number of 1 to 2, and a phenyl thread, and k is preferably a hydrogen atom, methyl, ethyl, and n-propyl. Particularly preferable as 几8 are alkyl groups and phenyl groups having a carbon number of 1 to 2, with methyl groups, ethyl and n-propyl groups, and phenyl groups being particularly preferable. Specific useful compounds (l!l't: are shown below. (n) -(z) Sl(1 (11)-(4) H (11) -(9) ) 1-1 (II)-(11) H (If)-(12) 11 (11)-(13) S11(■)-(1
5) 5HCHaO-CNH1(II)-(16)1(n)-(17)SH(II)
-(18) 11 CH3 (II) -(+9) SiJ () (II) -(21) SH These compounds are generally classified as U.S. 1-), l Vessel Total No. 3,275
．． No. 776, No. 3.37t, 3104+ J
The amide directly (φ and 1H/-phenyl-j-mercabutotetrazole) is hydrolyzed with a strong l:1 (such as hydrochloric acid), and the 7mino-substituted /-phenyl-j- Mercaptotetrazole and isocyanine Ht=
-Isocyanate esters, N-equipment (1,1l carboxylic acid esters, or halocarbonyl esters, etc.) under the right conditions of an organic salt solution (e.g., triethylamine, pyridine) These compounds can be easily synthesized by reaction.
3) (!Although it has been mentioned, 113 ingredients salary old synthesis example rv
ζnin]\zu. <Inquiry example 1. ), , t-mercapto-/-(3-ureidonoenyl)-/ , 2.3.4'-tetrazole ((
11)-(1)) /-(3-aminophenyl)-4-mercaptotetrazole hydrochloride 4+-ta, Irt was added to 71 (3♂θn11.) and stirred in room r: 17t'f' for 1Y17. To this add 11-.2 m9 of triethylamine (1 J1 of acetic acid/and OmO) and dissolve it with fire/Antrenda 26P grape water/IOmν.
The mixture was stirred at room temperature (lζ for an hour'nJ).
-After that, υ1 crystals were collected by filtration and washed with water. The obtained crystals are dissolved in methanol and triethylamine, filtered, and then acidified with hydrochloric acid. Filter the precipitated crystals IIX
and washed with methanol to obtain the title compound 33.7? (IIX
A ratio of 71.3 cm) was obtained. +n, p, , 22 A~2300 <Synthesis Example 2>Termercapto-/-[3-(j-methylureido)phenyl)'+ 2.3. Hiro-tetrazole ((1) /-(3-aminophenyl)-j-mercaptotetrazole salt) ↓g salt not, tata and triethylamine i3.
Disperse in acetonitrile/Oml, and add methyl isocyanate♂, 39 to this. Sono=to. I throw 4V stirring for volita time under 11■λ, water 7
00 mt+ was added. Salt (take out the crystals that have been acidified & L with '8' l, and l with lr) ()
. Ishut et al. are talented ho+'j Jf+ 'fNumagawa'1 with methanol triethylamine, filter it, and make it acidic with hydrochloric acid. 411 crystals) r Collect by filtration (7. Clean thoroughly with methanol +L゛,: notation ↑1! I・4/&, 4'f
(yield: 6 min) was obtained. +n, p, 2/
Evening~2/l 0C similar 1j)j ('):, other alkyl position 1''llA (II)-(3)~(5)
can stand there. <n>-C3) ro1, p
, ,! 0 2 ~. 204t 0(2(I
I) (4) m, p, /77~/ri♂
0C(II)-(5) River, p, /7/~/72°
Synthesis Example 3/-CJ-(3-diethylureido)phenylcotermercapto/. Su, 3. Hiro-tetrazole ((n) -(12)) / -(3-aminophenyl)-J--mercaptotetrazole family 3? and viridin3. ! ? 1z acetonitrile, 220 + + + 0 J)'r, N,N-ethylcarb7yl chloride/, 4f car 1 - 7'ζ. i, s time addition; 941, t□ evening flow I1z ho, 2
00 mu gold was added and extracted with one drop of ethyl acid. Acetonitrile after Shokin, 2 evenings. Recrystallize with ml+ l-me 'J monomado / 9 (yield jichi), lock point /glI-~/rj 0
C (component force f〆) was obtained. <Synthesis Example 4> Termercapto-/-(3-noenoxycarphonamidophenyl)-/. ! , 3. Gutetrazole ((II) -C15,)) /-(3-7minophenyl)-J--mernonozototetrazole Jiif, Shiohiro Shionohiro, Ri 2 in acetonitrile, 1 portion in 200 ml +, Torie f Ruamiy 2
Add g mu 31. Chlorocarbonic acid phenyl ester/restored at firm temperature. Improve Otsu 2 1. / , :+:; 7: lA Otsu time (W stirred I, Hono, λl were added, and the crystals taken out in step 4 were collected. From acetonitrile, 10 P crystals were produced. 72 (Collection s, Section 5l17) Ke Samurai. m, p, /20°~/ri70C''Other urethane compounds 1>1 is based on the synthesis method listed in (Total amount - Example 4>)! JOtij of the compound of general formula (II) of the present invention is a value that should be adjusted individually depending on the size of the compound and lj≧addition. Although it is difficult to determine, generally between 10-2 mol and 102 mol per mol of silver (ji:
Kawa: If no, the performance of the samurai during storage over time will be affected... 1, especially if the generation of Capri is suppressed. More preferable Ig+− of 1 small addition i・i! The compound of formula (11) is generally i: (the same group as the compound of (1), 71 has γr). x
) is extremely effective in preventing an increase in lag fog in the adjacent layer due to colloidal silver diffusing into the I·-+p l'Q layer and acting as a physical nucleus. ! 9 (yellow filter ribs or halation layer 1) is advantageous. Used in invention in 4] Color! +t, % ) 'C fee!
-i(''↓ Emulsion I Zeng has 1 silver nitride, silver iodobromide 1 iodobromide + 1; IJ s salt 11.l: oxidation,
j・l,! 71
It's okay to use . 1. ') Member Rei 111] Inside No.1 cogen comparison cry 1-'s flat J, J particle S.R. , the particle size of the rhomboid grain horse 8 is the particle size, and the particle size (expressed as <$1'-J based on the masonry) is not particularly limited, but it is preferably 3μ or less.゛ν'' is wide or thick or wide. 1-j: 1, ↓! It may be a more regular crystalline substance,
Also, spherical, non-shaped, etc.
(gular) crystals, or those with the m combination 1a of these 1i τ15 crystal forms are also good. It may consist of an amalgamation of particles of various crystal forms.
,/). The silver halide grains may have different phases inside and on the surface, or may consist of a uniform phase. Further, the particles may be such that 1m IW is mainly formed in Table 1IIIV, or may be particles that are mainly formed inside y, -J'-. Honkomei e use l,'JLru7-j:member a'L jl
l is j', UlafkidesJChimie et
Yen ty s i Q IJ c Yen + otog
rapl+iq++e(Paul f+1onte
l J 1su, /9' Otsu 74t),
(-1, F. J)uffinJPbotographic Em
ulsionCI+emistry ('ll”bc
Published by Focal l'ress, 1993), V, L, Zelikman
et al author 1~1 making a
nd Coating Pbotographic
Emulsion ('I'he J'ocal
It can be prepared once a month using the l'ζ method, which is described in ``L'ress, 2013, 2013''. So acidic
Either the neutral method or the ammonia method can be used, and the goal is to use exactly soluble silver salt! Zet halogen 1^, ・1 to anti-1.
As for the stirrup type, one side mixed YL1 same rib mixed /
Using any of those demonstrations II-Soup etc.'C-
L. , rI′L child f i, (1,1 ion 1i+Jzz,
It is also possible to use a method of forming under Ilj and Ilj (so-called 1-sho method). As one of the simultaneous mixing methods, it is also possible to use a method of keeping I) A g in the liquid phase in which silver halide is produced constant, that is, the so-called Chondrald double jet method. According to 7k, the crystal le is given by the rule Lllj ll'J, and t-Q-j' = Reis ゛ or JLq-((: halogenated milk;:ill. y'c 21-11 or more 1/, 1 High IJ silver genide 1' 1 uon] 14 go (
- May be used with -. Halokonization Station I) 1.4-J: The murderous truth;
J2; 41, 14 culms of ν formation, cadmium salts, zinc salts, lead salts, thallium J crystals, iridium salts V.
That W old! n',% rhodium salt or (/:l: (
A complex salt of -, an iron salt or an iron complex t, -7, etc. may be combined with 41-. Is there a surface on the unexploded IJ14? θ image jF; #+! Even if it is a negative hole agent with 5 or IC114 inverted type milk i%ll,
I can make a river. V, as a lullaby for those who hate you, plant trees inside 5+
There are milk 1111 and pre-curved direct 11 sir type I L preparations. Internal 5 inspections 1 Song type halogenation 9'' that can be used for 0 Ming 14) 1! An example of an emulsion is US special silicon lambda! octopus,
No. 250, 3.2o6, 3/3++, 3. Conversion type emulsions, core/shell type emulsions, and non-magical metals described in Gugu 7゜Turf No., JU13.7t/, No. 274, and 3゜3j, θ/4' No. Blue. Rain in January...27 guns. The lr 1. of this emulsion 1'J. i i'r11 and I, -1? ;;l:, US 4Qr#l゛213gFf
, 7g, 2 to 'j, same, 2. 11: l” in the hydrazide described in Talo 3.7gj@] J j + 2−
27 + Tata λ No. 1 was written on Hydrazide Junior High School and Hitra No. 1 "; Takashi and Kokusai ηd1" /, 213.
- 3 and /Otsu'7-'-; 1 US l; t1%y 5
'l-3,73'I, 7 j g xy, same 3゜'
7/ri, 4/ri≠-number, same 3. Otsu 15. Otsu/j keni 1,
Self'b・(Sugared 4th class Boutique sentry; Sue J) x)! l'-
2 cut 3,77 and <1L*-1 Kaburaze 11 described in issue 170], F) ru(nu c I e at
i n g) it': l+/+ bracket i c color poison" 1 in 1 / 0 increase 1G color: Book: United States) I, 1-1I
-, 030, 9, 2I issue, Mukai≠, 03/, /, 27 issue (
6 811, a) Kabukoanruhydrazinonoenylbu 1urinaryl'r (1-, the compound is a generational zoc thing. Halokun ratio eil J emulsion is chemically enhanced J 41 (0 lines)
Don't do that, Iwa t4J noru 1'r imi (1'r imi
t i ve) Emulsion//) It can be used as is, but it is not suitable for general I4-directed chemistry ji? ,I J,,,X(Sa)L. For the chemical jY1 feeling, the fJ I a f k
i d e s or ZeIikman et al.'s spring e, mouth! , J+'ri eser copper (/~k
adcmiscl+e vcrl;B4sgcscl
lscl+;jft. / 9 A g) i'ko1. Self 11 Power C″ left?
・If there is a j-th monkey, it is a monkey. 3. 4. Tonoimeno and j also 1 heart and 1 (Iru (+j
Self (Compound 1 diagram that includes 1, Sei 1, □ (Se) 7 chin?, Use Ill: i u'L shield ° feeling l, suburban 11A''V)
All the houses have 1 use piece 1 ゛ 1 cut off, 〈恍yaq) Other Y cover metal 11 parts combined (・zu constant pressure 1 - (kai 1 #! 1'''
1゛1ha evil Vλ and 1 month insect extermination ξ (can be used in combination.・Hot A11 Chif Sol G
l, rhodanine 1.11, the transformation of 'a'a AA
Is it possible to use k, that ←)'s specific meaning is 'oh, US IFJ (1', o('/, -+7<l, ha → shizu, 2,
'I10. Ag9+4.1. ．． 271.911'7,
-, 7! 3.
Otsu 3 Otsu, 9 Ta j 吋G'Kopaki 1ij/,
has been done. ] ~J Jau'' ip ~ 11 as Vyod - Tin salt, amino, 11, hydrazine m$ 1 bottle, pollemamidine sulfinic acid, with siphonization! By using +Δ etc. 11, home I:) c) Concrete 1 n
T, USA! I (1 total), Hirof7, 8th evening O, Ko, 47/
Ri, Ri 7V- No., 2. Evening ig, t2 issue, λ, 7f3,
607 No. 1.2, 911: 3, 1r107 2;, a, 1
94/, t37 No. Φ is also written. For the prize money 1d hair 1 helmet 11j7 t<t21i 1.
In addition to 11, Mortar, Iridium, Nogradium No. 1
1□, I Jv1 Ritsuno, ■1 group's introduction of <e+ can be used, and its J (example
゜3 Tata, No. 06'3-! , Guguza, No. 060, 9 British cows total, 0 Otsu/Riki, etc. are ranked 5 times 1, \, 1. Spectral enhancement may be achieved by photochromic dyes, methine dyes, etc. II Irere 2) In Zekuito,
7 anine f2. Elements, merocyanine pigments, low-61 cyanine pigments, complex melonanine pigments, 1-polar cyanine pigments, hemicyanine pigments, styryl pigments, and hemitarcinol-1. Ru. ! The eye-catching pigment is cyanine pigment, merocyanine t1. The base and bedside merocyanine 1 pigments are l), i-i pigments are 6° + i river jr +, 'a4! +;); ['v
So rL, 'll, f-Q-l' Germany #J,, forgive me! Published by Ogo, USA 1. □l', :p' +)3
/, Otoyu g issue, same! . ≠23,7 VlI issue, episode! 03, 77/, issue, same, siri, 007, same λ, ri/2,327, same, 3
,1. J-! , 3rd issue, l, BJ3. Aj7. rijri issue, same J, 672, 1rty7'-y, 1. +-
13, t tough, λ77 Shirokuka to", I '4 ShiE'
+λl/-ノ, Rito g, 'P to I〉ShoK +'-/
'l No. 030 6 myself, Iν1 Sano L7 here) so (
Five. −, lj:, ii own fil 1・1 color) “enough −”
41-Jl,) Hello Keni Shikan J Milk 1111 1.1 1 ton Q Kool Go'i 1 Song D'C+Il, j11~
)□shi4'l (・) ding M1 "j, f゛ha "]
Gen 1 Shisemi's' (, jilt layer 4f1\γ1
．． For the purpose of 1; ′(1)′J to Jl-1u:
4) lc'tlノ12? (hJ1'i'L V+'
! IM kJ Koka Jf, 1, 4. :, /S D Genka Chon 141i11 li'iυ)" - Ru sweat Puko (j1
Silver halide hole with sensitivity 1ilI A! 6C can be inserted between -11T color filter and ehalation 1). 7+i invention sense)'(, H separate 1'i'-&'', sense!2 shi upper Kay-, contrast=(211, map j IrJ,
3 views 1 view ``Ruzu) iJuri, 1 calligraphy, 1 poly~
/N oxide 1 ζ is its ether, ester amine 22 1,1 ζ #T1.4, thioether fls combination 1 □, Nao Morno' Lin River, quaternary ammonium compound 'i '*l % Urethane I11'et al.'
Good too. For example, ゛ni 1]・1 (11th Saturday, 71.2. I
I Olo, No. 432, Same Yu, ≠ Ko 3. jt ri issue, same), 7/Otsu, 062 inches, same 3. Otsu/7゜2 g O”
rl';, 3,772. tノ -2/-
ey, times 3. I can go. Gelatin is used as a pore-forming agent B・j-i or other +r′4 stratification agent. Colloids can also be used./Colloids include gelatin ajf'!%, graft polymers of gelatin and other IMJ molecules, protein properties such as albumin and casein: hydroxyethyl cell I',
I-su, calhogin methyl → cellulose, cellulose l
+il' M Taester j4 Temple<Dμm1 x cellulose piece, I≠ body, algin 1-stage noda, j7sj 'nh'nh ``J body: borihinyl alcohol, polyvinyl alcohol partial ahital, poly-N- Vinylpyrrolidone, Polyacrylic
Ru, polyhinylvirazole exclusive tri -;
It is possible to use Sumitomo Corporation's FA purchase. Gelatin includes Q, lime-treated gelatin, acid-treated DL gelatin, Hull, Soc, Sci, Pbot,
Japan. A/A, 30th (/9A l) iiY□y＞. Treated ceratin may be used once a month, and gelatin's ]j,l/J (decomposition →, ・) or enzyme ur+)/r(figure) may also be used. For example, add acid to gelatin (shu, isocyanate).
Bromo i! i'll iy5,', TlucanzaltonjM, hinylsulfonamit'fib Maleimide compounds, polyalkylene quinodna [1, epoxy compounds, etc.] It can be used. The specific 1.11 is rice 1:hl
'Nr l￥12. A/p, No. 924, 3, 13
, l, No. 9u3, same 3. Ir1s, gilt issue, same 3
゜3ノ2,! ;33 μ, English 1st grade -
1 in total g 6 ノ, Hiro / ≠ issue, same 1,033. /
If2, 1ril/, 00k, 7g '1
Hiro 4'-'? )>1liJ 4' It is written in 2-26 Agency Ut number etc. The gelatin graft polymers mentioned include seratin, acrylic acid, 1 methacrylic acid, 1% acrylonide such as esters, amides, etc., styrene, etc.
-r-(Dta-(S)-Mo) or eutectic gold-grafted '(=ill).In particular, gelatin and a certain focal phase f('110 some polymer l Hitoe QJ゛Acrylic acid, methacrylic 11c
Graft polymers with polymers such as acrylamide, methacrylamide, and hydroxyalkyl methacrylate! 11. Examples of these are US ribs, ii-, 2, 7
63, Otsu 2 evening issue, same λ. 13/, 7A7 issue, same 2. It is mentioned in the Rij Otsu, Toza≠ issues, etc. Typical Br@@NarikusuiSonobun]-Monogat', / Speaking of West Germany 'l'-: r permission! IH ((J JJ S ) 2
, 3/, 2, No. 701, Iceberg Patent 3. A-2
0, 7J / □-7, same 3. g79. ．． No. 20, hour and minute 1f (-111-3-7j l / issue. The compounds expressed are also used as VC turnip inhibitors or (kyu 51'') as a middle-of-the-road compound.
4.1 It is possible to contain. Benzothiazolium salt for Zunawara Anru, 21 Heroin Da Sol, Trianol, Benz I/Ryazole Ha 1, Benzimidazoles (especially Nitro-1, Haloken direct) truncated body); heterophobic mercury, f) compounds such as mercabutothiazole j, lI, mernonozotobenzothiazole 41'A, mercabutothiazinol j, '4
'l, mercaptode], lazoles (especially phenyl router merkanototetranyl), for mercanotovirimidine: 71＼Possessing a high solubility with carpoquinol and sulfone, hetero 1j - Meru h site compound 4.11; Naoketo compound/Kotoe is oxazolinthion: Azaindene analogy is te[・raari roadenden+
u ('4#+ to t-hydrogishi~, exchange (/, 3゜3
a + 7) tetonoazainten river): benzenethiosulpone ['1t12 +'l: benzenesulfine reed; The compound can be reduced by 1 Jil. Q. Regarding these historically significant crosspieces 1911 and its convenient method, for example, in the United States, rl->I+, 3g
F tag, ≠74/, issue, same No. 3. ? Do 2. No. 47, open channel, 0)/, No. 24#, 1st floor of each Meiri or Ushi'f Kimiaki
λ−λg. You can refer to the description in the 660 Gazette. The adhesive material of the present invention may contain a converting agent of chromium 4't (chromium 4't) in one layer and other constituent layers. Q
”: Hmm, 11v r=dichlor), aldehyde D+
(+4 lumaldehyde, gliogisano geltal albucht, etc.), he-methylol 7-soup (7-methylol urea, methyl hydantoin, etc.), dioxane dioxane (2,3 -dihydro-1-//oxin, etc.), l-occupied hnylated intermediates (/, 3. tert-triacryloyl-hexahydro-8-1-IJ azine, /, 3-vinylsulfonyl-2-proa3 /-Luna), l heavy ``''
cation+3A';If!'i
can be used in combination. 1 side γ(, 1'' material l''J, shell hole piece l-l I
73 for the song jir1sei j11j
1. Auxiliary agent; 1 example 3. 15) J stop, improved slipperiness, emulsifying property 11y, 1st grade 1()Jll-co-''
= Hiichi 13L-1-44 Seikai J-J, (For example, Kuumizuka 311j % l1j14 H+7j, Masu 1 Takashi)
For the purposes of the gods, the 4, 4, etc. realms + Inviscous iIJ may be carried away. For example, zahonin (steroid lead), alkylene oxide n)"+ '! 1 body (eg.
” ') Enolen Krikor Algiru L-Furukawa J, 7゛ζi, t :+: Reeff-Rengelikol Algiru, ゛1 Ruarylnee 1-Ru 1..ti, ;j
', lyethylene glycol n-snol +, j I N
:I! 'J Enalene Glycol Norbitano S 1
l, jl, polyalkylene glycol alkyl-amine 1+, J” amide 131% silicone,
1 Te IJ Aburen Oharu - Tide 1・] Force 11 (, Itrf), Crisidor 1 White υIJ- (fc and par are -r Lu/) 2, Ilz Co/% Ri l:, +; l:
”) f IJ se') t,'alkylphenol holiguri・(ζlido Ls + song Al: J-Lunoli: J j
ilIi%NS'f /L/J"'l, 17.i
i +7) Alkyl 1.1 7;
l+-Q, 1 koku +1, -f Le'S), - SuJshi7 Oni/ l'l'F II'+, /-) I/:l
゛/l/ Hensensulfon i'f<y', IN
, alkyl nanotales sulfur A7 (+lj J.l:A
, alkyl') 7 (:D ester +, Us N -
-fsil-N--f/lekyltaurinel'l'j
% sulfosuccinic acid TP, ester ratio 7''
Royal holimegishiethylene al#/L-phenylny)-l, cy4, 7j, lyoki/ethylene alkyl phosphorus 1,..., Nissal 1t:natoC)':su7 to 1
Calfoxyzuke, Sur:! = 7+k, phosphorus, (p'
+: Anionic field UU activity, including shell ester release, and branching properties such as ester shell, etc. l Niamino Setsukawa, aminoalkyl sulfone i jzt+, aminoano 1/kyl (plx acid-"! 7r- FL 9s4 1M.'
) i ester! , 14, Alki/L/Bequin JU. Aminokijido, 14, etc., exploded in the unevenness of the bisexual world 1;
Alkylamine salts, )] For H rib or sword class ammonium salts, heterocycles such as pyridinium and imidazolium ≠ I and A/7nium! A:: i. ++ ,
It is also possible to use a cationic compound such as phosphonium or sulfonium SH containing phosphonium or sulfonium SH as a main agent. “L1 fee jj I J-rei i111 layer t1
Color-forming couplers, Zunawaratsugo color ring lk processing, Z7 test results / grade amines, 1 and 1 ((, 11), phenylenediamine ItAj, phenylene diamine ItAj, amine phenol derivatives, etc. ) produces a compound that emits light color by oxidative coupling with a magenta coupler.
-Virazolone cazolar, virazolobenzimixol kablar, cyanoacetyl tamarone cazolar, open-cy L1 acylacetonitrile coupler blue, E-r-low kabcy and 1, C1 a/ly acetamidocapsi-(1ge1
1 is Benz 1 Ruacetanilide River, Viva IJ Ilyase (・anilide +, 1.'l), Temple... Dust, cyan couplers include naphthol-kabucy, and noenol coupler 1, It. This 11. ballast in one molecule, i, 1. Toyo it, 1'reru Il
l! Mizuno, it is undesirable that there is a non-1 wide one that does (grape). The coupler is 6th! Ion and V) 411 raw or! It may be 1.4% or so. A colored coupler with the effect 1r of Ushitairo Sensho, along with Flui vJ current IW i(,! image use 111i1 rll order-11(
Coupler to output (so-called l+ I tt coupler)
It may be.・Fta J) I) In addition to t couplers, the products of the coupling reaction are silent, and JSJ
I'Q 11 rlill agent k Extracted A: 11 Color development 1) I II. Coupling compound meat and 1) I H, may also contain a redox compound. Mazenota Color Coupler Specification 11V” 1, US Special Q
]: 2゜boo, ygg issue, times, 2.9+! '3. tO
No. r, No. 3.06, /, No. 53, No. 3. /27. λt
No. 3. Go//, Gua wo issue, same 3. tl/ri, 3ri/u711jlj', ri/9. <1.2? No. 3. evening! ♂, 3/ri issue, same 3. ! rg2,322 → bar 3,6
/3". Evening 0 otsu, same 3. and 3≠, 90g x, same 3. dori/
, 46 ≠ Kor - Bow, West Umushi/Xun - 41/
, to 10,1ily/74), left West Germany Wf;
Territory (su L8) 2. '7011, tAj issue, same! ,1
%/7. I7.5, same! , 'A/I, Tatata, same 2. ≠24t, 4tt7+-5, bond (public 111A≠0-
Otsu 03/No., Tokukai Showyu/--7,0g) No. 6, same as left 0-
/30g/issue, direction t, 2-. t-dori λ no, same t-turf, 2! 733g 'im Dokota 7g 0.27 bow, Dota O-/,! '2336, same, t 2- </-
, 2/2/ issue, 4t turf 4/-0, 2r issue, KO-4/, 1233 issue, j/-, 24st, i month, 53-r j/2.2 issue, ij :l Tata/
/do (J 3 l/L- etc. It is a self-centered y thing. Specific example of IIT color corpse 1L coupler C, US line total 1. and 7
3.0! ;No. 7, 3,2t, No. 06, 3゜hirotheta
8°, / basket'', l, iJ 3.5j/, /, tj 吋, same 3.5), No. 322, same 3,7 no 3゛, 07! issue,
same,? , f 9 / , 41. </, number, j3. δ! 7 Hiro, ♂7j issue, same 4/, / tough, ri/ tar issue, fourro! +l special W1/, t gua, Itg issue, Nishizumushi deuta I; song, 2/ri, ri/7shi six days 9.2 otsu/, 3/
,/issue, same, 2. F/G, OO Otsu-shiha history 1kl q
1j total/, 4t26, 0.20, equity 1163/-1
3shi7 in 07, JP11ij 4' 7-2 Otsu/No.33, samege g-73/11.7, sameta 1-io, 2t3t
- issue, I, 1fj 0-63g/issue, same! ;0-/23
3V2 issue, same jθ-/30'1112 issue, jtil evening/
-, 2jg27, same evening 0-g7 Otsuyo O, l52-.
l', 24'! , l:+, l j , 2- / /
In the evening, 2/Risawa, 1r11J' 3-, 1331, etc. are the ones I1lV Nere/Komono. A specific example of the /-i coupler is the US Special Price 2 or 3. the law of nature! ri吋, same λ, ≠341. +27.2, same λ, g7
G, 293 Geo, λ, 32/, RI0g, λ. Krij, za,, No. 7, 1ijJ, 03j9gri2
No. 3.3//, ≠ No. 76, No. 3. Hiro! Do, 3// issue, 1iIJ, 4' 7 Otsu, I43 issue, same 31 evening 13
．． Ri7! No. 3. Jri/, 3g3 No. 3,767,
≠ // issue, same p, oo≠, octopus 7, same g, /2 g. 3ri t-〉bu, Western raccoon special W1-out hunting (ULS) z, l/-
/p. No. 1130, same No. 2.11411, No. 329, JP-A-Sho<a'-t 9 J' 31 Q, 1rjl! /
-2603'I, same <zr-30 getu, same 3/-/
ll-6g2g issue, same evening no 2ri Otsu J], times j2-ta O
3.2 sand, same j Otsu-Otsu j/3t1. ÷ Evening, same tx - λ
235A'', the same Ta-Otsu-Tata 31A/issue was irred with a pirate car. Assuming Kashid/Katana puller, the first row is the American shot [δi・
3゜47.7 otsu, evening I! lO>6 times 2,327. riOdosjl same 3.03ge, r! 72+-'FX holder ≠
-λ0/l, 1rd3g -2233! Yl, direction 4
1λ-//30 Hiroman, II-Ij≠4L-3,2t/-
1,/su,';”+,i Kaishoj/-260311”71
(1j nl'l i'r % same"-4/, 2/
,! / , h 11,114i:I N, =', West 3!
It 4・"Measurement condyle (<) JJS) 2,1//do,ys
It ends with "for all the services of ri + ha (-description q)". ],) I, 11. Kabunotoshi (Ij:, 191
1e (5[, 1-3゜iti-g to U.S. lees, otsu, 0-aminoazo to F in No. 2, jlp, l)] I also Kabunow, U.S. 11, ¥3. J,,,17. Written on the Tatag code +
IBV, thionidel type IJ t 1. T Tsuno Shino, tree Lklζ1 my itgo. t/7, 2nd/No. Q, 1st/II Island's λ-be 7th Triangle. le type 1 no ■ 1 (, Kabu no, Nishi, I insect! 1.'J,'i
'1 out+! AIj (OIJS) 2. 'I/' 1,00 Otsu +5, ! l! l open 11d
Evening 2-If, 2 4', 2'
l@Qhidojko//-benzo described in 7t27)
l) Anolyl type 1) Jl is also kabji, '(:j 13i
1tl+ke0-303 Taha bow) Eno・'1 Kano group 111i
'! J So 1.2' No. 123 has 4 gold coins - ;'
r' −, terror J, f1:is+', l'l f'1
l-rl* ” Sude/l/ 41'4. January 1 (Kabji, Shidoku 'L'+Siride 111:t'l (+-) J
JS), 2, 3", 27, 43', 2-9,
In+! 31i1:j J ,2-? L) 93
No. 2 antihikin Kaishoj/-/Hiroto, /r No. (lζ+:l-
,”(',',:'s!this[d-type January 1 modian coupler,'l',:1liillf:i!,2-191
+ 2'l number rbyt, ) -7o On By/-
No'mito power, month 11) also coupler US cost meter, 21
/, 1゜5' A, No. 7 and Rich Tis Closure magazine, 27.22g, 4j of 1 mink i1
7 + (fkl) j less 11, 1 less 1 (11
There is a '11ζ2 Kazoler sunny. Co・I′□Upper (!=, D J, J also has coupling compound and 1-teke, 4pH poor, tJ:, Yukokutoku+il'
/ , <' -23,511, West Germany'+h A'
tlj nl, ++((-1L IJ) -'! +
Rio! + μ'j"j-'7.1, 11 no, evening J
, 3, 70 Tashiba same 2. ．． 4', 2, 3! Ofj
,same! . 4411', 0l) No. 3, Paddy 'D total 3.23za,
Thioether-type cone-shaped illumination described in Tata No. 131> 1. I type: 'n WM-+
N';1. −j;ll='+'R'l' j
, A J 2, 3 4' Evening 49 Tomo 0-3,22g, θ41- Thioairal ν (Riko 1 person, Precious IH-Coloring J) l) (Chemical Zeng Things, regulations ■) jl customs! 0- / li 77 / Otsuke, if, '1M・]] 1'13/-10 tag, and he same evening d-Otsu 7 Otsu no do Ichiyumi ni 2. Self I1. s i3 , n
-C benzotriazolyl type Noah..., Saitomoe I
J, 11 is also converted to Lj-threshold, JP-A-1i1j J/-'
IH. Cup linking 'I'l' ()j % 'ill ga ai. 1) l Ii, Redsonization <4”lΔ as 1・1
．． 1.11 For example, home country, □rM'f 3, Otsu
3 9, 11/7 ta), Shi・No. 1'+! 'i-1-1-out, :+1 (OLS)
,2,guA0,202. ``S-tree 1・l 'j=,
F, fI3 +λ Schiff, 4th note in the text] No. 11 - 1 Doro A'non, Ekiku I11'33-. 2-57g
, No. 2g- has 11 of its own 1) [1 is also a redox-type bunozonin-, 1) is b. i, j for light,, % n Y; togl (+: j, 1) and) K main < deception 4: including -1'' 1. U':j OJ, 'l+'
+I family E (,, lj Toshiko, Relieve Teisnoroger, +; 4p/7 otsushi; l', 2 tarari
1l) cvelop+ng agents''<v
J to Nokai, V to self, I go to cram school on Saturday/,) Things are 4 months a month)
The first ruru. Little Uko 11! ] Shiku-J Nili Tsukura 11-ru 1...s
+'1'; mouth i, [(ko(・'1,;jI; 4 hole agent c
lzono (1140) ++Henariha・1 filter 91
And, as 1:1, or Q↓・rshinny 7'-1 藺 halti 1 old II 1'' old-gu, 1 i! Fees included.”
"(〜'(Good. This", Una'-I:I: 4th Toshi C1 Research Disclosure, Condolences/7 Volume 2 P, 2
3 “～-2 Otsu no [8 bso+i]ing and
filter dyesj's lj, J to h11・V
, is used.・1.91November's 1,1'i nail [''book] il, again, Koyama, IXh, u-i 1[, 11J Sosai 1 Hamanoto? +ll N +1141 it'thIJ, ultraviolet:
1. kl l, i aggregation,! , Ka91v 11], Togo (Nonofrit 11r14 etc. 4-nai Ishitsuru. Halogen u:, l::, I4j'L 1111 layer o, 1
H/or other configurations are crossed 4Sr (,4; -1- to do I'll. 1Y) I1' method is Research Zois Closure, Note/7&I 1st page P27-2 which 11
:Written during oating proceduresJ:
7 no 2 can be used for those who are iik and C. J-statement/ζノ1, 日１しのから(t, &iY:
+JJ fee (color positive film, color positive film, color bar)? -If τ1 month, then 11 rivers 1XVW each)'C after, llI4
帛、 (1) U1) σi brother 1'& → stop 1-→4 (1 凭 → Labor White promotion J country l valley → necessary) Sen 11 Go no 1:, i! by(
Soβto-1-→tJ<δL→Teikan→Water let, -→Woman Tei-→Shinbeigsao, (i-Ji% wood and place J111・How to do it.(1)'s work 4♂ is υ Moreover, HIC (Ijijifu, dura mater, etc. can be added to the elephant f urine excretion, etc.) This 1.
L-, L stop, 84 moss promotion shop bath, QY! (Flf U 'J < 7 + ij after bleaching with U salt (r, j mountain lu,
'i can also be done. It is also possible to abbreviate the line ``white promotion'' and ``stop.'' On the other hand, as a color text, it should be used as a color text.
1. Processing process illusion, rule, (21 black)'-1 no. 1 elephant → A, → Stop → Holo L → Ding Bai Zheng J1 Fatty → Water 1 → UH by J Shōkai Ichishio → Boro L → Fixed blindness → /J Subtract 9.(2) upper 4.Y, I/ko is history tα, +1'J ++, lμj prefecture, neutralization 16
You can also set it in purple. 1, stop, Kaflav, Ranpaku Yun JL
! ：The water of each bath 75'：、It
yo'r:;'ll'is t, but that's fine. Kaflav 7
(It's possible to attend il + 11 club and K11-,
Coupler/agent light color 1 cheap. By adding 1 family to 1 valley, it is possible to clear 1 white. It is also a good idea to briefly describe u4 VC Koishaku J Hifu. ``Color'' complete image l (Yu Q, l1, - crotch 11L rule 1 landlord medicine included alkaline matter yJ < iii liquid from IJ, 'Zru. Original color' Shiyama 2 King Chestnut, 1 public knowledge 1 I and aromatic amine l, I family?11'', it II e Qj phenylene diamine angle (e.g. V, l:ll-amino-to, IN-diethylaniline, 3-methyl-guamino-IN, N-diethylaniline , Hiro-amino-he-ethyl-N-β-hibi-1-cogyphethylaniline, 3-methyl-p-amino-he-ethyl-N-, &-hydroxyethylaniline,
3-Methyl-Hiro-amino-N-ethyl-1”, I-β-
Methanesulf* -f)"ethylaniline, ≠Niaminor 3-methyl-N-ethyl-N-β-methoxyenalaniline) can be used. In addition, F", A, Mason wearing circle totograph
hicProcessing Cbemistry
(Le ``oca11'ressi-ri, /9'')
, 22J-227 [1, US time ♂■・λ, /ri 3,0
/! No., λ, jri2゜36, JP-A-11 ('yl
4I-,! '-4 Ko 733, etc. ・1tt( may be used, color current 11U, its(・Skaalkali-related Kabutsaba fsui jflA % charcoal 1kafun, boric vinegar salt and 0-phosphorus) Inhibitors or antifoggants such as acid salts, ppH sulfur agents, bromides, iodides, and anti-fogging agents can be used. softening ax 1,
Preservatives such as hydroxylamine, organic compounds such as benzyl alcohol, diethylene glycol, polyethylene glycol, 41. ! i4 Ammonium salts, amine development accelerators, dye-forming compounds, competitive couplers, sodium holhydride moieties ([1, 7
〜Phenyl-3-pyrazolidone's 11-kikusuke''it(
I line A store, no 61'1' attachment, no 1 (tt! clock t
T. And 3.723- issue, the pirate's polycarphone crystal thread chelate Qi 11, West J Mushiko 1 City (Su Lδ) 2,62! , No. 250, ``+'P prevention explosion'' may also be included. Ui, Tangen IXi IX, the addition to the emulsion + kj, 1)
νii t:JQ ”:ni:1 ('Koyori Noyama processing Zuzu)
Shie). Is it true that the self-processing is positive and the light is on from 11j to 1 o'clock? It's okay to be 1, piece y! I'm glad that I fell by 11. Kou 11 Ming's doorway ifl + Toshi - C used 1 liter τ
Eyelid, Jl・^41: Potassium acid, 911 kalkali gold) of sodium acid, ][νrihakut
nix + butt or / import + IIIj D ammonium etc.). 11. i1j・(・maff1j white line/l
It takes about 20 to 2 moles of O2 per day. A few songs 11 in the evening, Hanawa i1. S: 1 Jyosugi - 11 Ehashi Ehashi is caused by eating potassium chloride, sodium chloride, ammonium chloride, and bromides such as 1lium, sodium bromide, and ammonium bromide. (lA, l, folded compounds are difficult to use practically because they raise/-U the oxidizing gas.) The preferred amount of halides is θ per liter of blood (liquid/l). / to 2 moles.In addition, within the wall there is a cape + 1QW, <tit sand, meta(llill 14
sodium chloride, vinegar 1 length, sodium acetate, +4'9 I
'll sodium, potassium carbonate, 1 pot of phosphorus, phosphorus
'lJ, phosphorus thorium, citric acid, citrate r1 linorium, l Shiraishi h! i: such as p Ll Hime! li
J fit shiwo/I￥suru/ ;i! i! Above ;I
j + ζ machine acid 1,1 i machine smoothness and increase. 7 can be fed-batch. -f (lift) You can also add 1115 salts such as potassium natodisodium acid to tune irC+ to 1f in bamboo J white liquor. An imide compound to prevent the generation of halogen gas as described in Tatag No. 1 may be added within the range of lx/θ''2 moles. It's a bit complicated. Also, although it is not essential for the mortar liquid or its tower of the present invention, it is possible to use occasional pieces of nickel silver. 37'
No. 1, 3°77, (No. 120, 3,193.g!
No. I, special public Sho tough-2g22 ladle, size "open) J rota 3-
Tagta 2d i s c I o S Ll r e
y-shi/! 7θ! Mercapto butter 11 hi 5 'IA nato's ζζ mortar 4jυipii written in (/9, 1977)
From l to i. Fixed liquid and 17 te 1. i Ii↑″q]
1j1You can use your father's. In addition to thioanthate, thioanthate, and thione+rf
Results as a Mll／)・Knowing small pillars ψ匍CJ′+1・Kan 1 Regular accommodation 7shio d. 7J (may contain 1 raw aluminum resin 1 attack as ll history i glare piece I. Example purple 4f, % kemoto λIN light can history, plan 1 and curse 1 clear. Real 7IN+if) re 1 A multilayer color photosensitive feed consisting of a cellulose triacetate film carrier (one film each having the composition as shown below) was prepared; Blackened silver per 9/!?
Gelatin 10O? (Including) / For this reason, Dofu agent! ]-Dodecylbenzene sulfone soda polyhydric solution vO
Add cβ and heat the firefly FIT to a thickness of 2μ.
I, ta. Layer-2 Gelatin intermediate layer (rolled film thickness i, oμ) 1--3
Red-sensitive, low-sensitivity halogenated emulsion containing iodine 41 (average grain nice 0.3μ, emulsion/
kf adari) Rogen, 'se 10 op, gelatin 70
? ) were prepared in a conventional manner. This hole rabbit 1/ノη
red sensitivity component)゛C sensitizer and tear 7 high)”o -
j, j-cyclorotaethyl-3,3' .-di(3-sulfoprobyl)thiacarbocyanine ha. / Methanol adds 210Cn to 11, then! -Methyl-7-hydrology λ, 3. Hiro - Triazaindolizine! Commercial aqueous solution 2 oct: * and cyan coupler emulsion 111i according to the following formulation! OOV, emulsion (2) was added in 2009. Next, I used colored cyan coupler (CC-/)'s λ00ct and gelatin 1st history 11y.
Kishi J as 2-hydroxy-≠, 6-cycloltria/
A red-sensitive, low-sensitivity silver halide emulsion was prepared by adding 30α of a 1L% aqueous solution of sodium salt. This bold dry film thickness is 3°! It was applied so that it became μ. CC-/ Emulsion (1) ■ IO Higashiwa Chigelatin Water Aqueous Solution 10009 ■ liter
Compound 7] After dissolving at 0C in a l-j oven, the mixture was added to (2) previously heated to rz'c and emulsified in a colloid mill. Emulsion (2) ■ Gelatin aqueous solution on IO vehicle A mixture of 10009■ <rr After dissolving at 0c, it was added to ■ previously heated to tj'c and emulsified in a colloid mill. IJ-/Layer-Hiroshi Red-sensitive Commercial-Sensitive Wave Halogen Silver Emulsion Layer) The halogen string hole agent solution of Kazu-3 was used at the following meeting. The silver halide solution prepared in this way has a dry film thickness of 2.2 μm.
It's a 6th color so that it looks like this. Layer-! Gelatin intermediate 1-(dry film thickness O1rμ) Mon-6
Edge-sensitivity, low-sensitivity silver halide emulsion layer - 3,3'-di(2-sulfoethyl)-terethylbenzoxacarbocyanine emulsion used in layer-3 Zinium salt 0.
/% methanol treatment/zaOα, 1-methyl-7-hydroxy-λ, J,! −) of riazaindolizine! A proper amount of aqueous solution Oα was added sequentially, and then magenta coupler emulsion (3) according to the following formulation was added at 320? , emulsion (4) at 1
roy added. Cohydroxy≠ 2% aqueous solution of 6-cyclotriazine sodium salt as a gelatin hardening agent in history! oct2 was added to form a green-sensitive, low-sensitivity FF halogen silver emulsion. This solution was applied so that the line thickness was 3.2 μm. (--7 Green Sensitivity Commercial Sensitivity Halogen Silver Emulsion The following changes were made to the halogen silver emulsion 1 cod of I-B. (Emulsion L4) 30 f
Dry the silver melt made in this way,
I gave the god that becomes 2 μ. Emulsion (3) ■ 70 Toko Chizelatin/J (@liquid 1ooo9■
After the mixture was heated at rr'c *4'lJW, r r
It was added to ■ heated to 'C' and emulsified in a colloid mill. Emulsion (4) ■ 70 direct songs gelatin bath/& 1000? After the mixture of ■ is dissolved at 50C in the evening, in advance! It was heated to 0C and emulsified in a colloid mill. ll 9 1
11]! :isl')llIti, %ha, (hello care
jllJ milk ji1411W1+ 141 i'Qko'-
Resize is 0. Is it written in μ?k l';)? Ite 6
↓l, ゛/i Same as the one used in -3 (Hishi・(
[Masari Kishi] / Therefore 5 = Methyl-7-Hydroxy / -2,3,
Hiro-Triari'indolizine jH day d%71<1~liquid20cβfu・yohi1・,; self/normata V due to yellow force plaiolation 1 person (51f/, tθ0?)
L eye f:. To the song, Piratin (1 History 11!i! As a drug! - Hido 17 Gi/-11.6-Cycloltriazine Natriuno, "Fukuno") Higashi 11i Section 4 (solution 50 ct containing added ladle sensitivity low 1 + & river Halogen silver milk size 07hei and buhi. This 7"r seke dry J・f1 rotjψ3,0μ.
It was planted. t(1 oxidation 'I'4 t5+ ■ / 0 !'J3', 'Li-related zegitin water fi-
47 (27/ 000 ri (■) After extinguishing the power at ``c'', add it to s s 'C in advance M L / (-(
1) Force 11 e, near + j: l Iji ζ le V trowel emulsification saw. )'-/ layer-/ 0 'i'j'li & business sense 1 and no logeno, 1ze-a i'rll Iku111i-9 no\logen silver emulsion II /l ni horn lS ：Tetsugi σ no ogashi no j
That's one. Jin (1. halogen 1lllltl 7g on ice)
Liquid? °Nakagakirai month 411″d, so that it becomes 5μ l ■ I (
lshi1'c. Harl-//Gelatin 1st grade (ψOtsujishuj'narration/・5μ) Can be made by straining like this/ξTest 1'l? r film/What should I do? Eve Kuni Iguichi/(・kojlbuttoI(ruυn<, film/o)AntihalenoJun1soehihonjamei's combination'+
vA(l>-(1)(N-(2),(1)-(3),(
1) - (5) (1) - (7), (+) - (9), CI)
-(12)(1)-(1:(N O, 1 person IJ% water 1
ET liquid? :By turning 4' into water/Jll, ゛Ctill: りふino【・mu!】 ~/7 Kinsaku tpi Jshi〕(
. The above jl (1 (preparation of 'ζ film sample/~/7 using C wedge/?, gi 5't; The residual value after the treatment was shaved.The resulting values were summarized in Table 1.
Intermediate ＾ color current press lI/0C3 minutes (-?, +3 g
0 < Wash with water for 30 seconds
304. ′υ between Shiroi Ashi Shindatsu]
30 sho sei
Mouth 7
Wash with water for 3 minutes and 3 minutes Set for 7 minutes Set with water for 2 minutes 3g 0 (2 minutes)
2 minutes, female fixed 7 (-i
/ 0 (Small, the treatment used <it lacks V, the 4:11 life is dead., color development Δ sphere number sodium hydroxide 29 scolding 1゛υ
1 Sodium chloride, 29 Potassium bromide /, 2 Sodium chloride / 9 Hoiidon
l ≦-) Hydroxylamine (D1f free salt) Sodium 22V-amino 3-methyl-N-diyl-N-(β-hydroxyethyl)aniline heptanosulfate 4t9 Add water 1/ Stop liquid water Doomr Glacial acetic acid 30ml 1" Caustic powder 1. Add 5g water
Combines total amount/l of Xuhaku promotion and withdrawal! IIu Sodium Kayate (Anhydrous) Ta,oy
λ-N,N-dimethylaminoethylisothiourea dihydrochloride 2.52 acetic acid sodium r,ot glacial acetic acid
λ, Jmfl add water
All fingers/l Bleach solution Sodium pervalent 6θ2 Sodium chloride -〇2 Sodium dihydrogen phosphate/R? Sodium tetrapolyphosphate 22β-alanine
Co-diphosphoric acid (?!)
x, add 2mg water and transfer all the fixing solution sodium thiosulfate /Yop sub-value is sodium (Kumaho) /If hor sand
/29hydroacetic acid
/jmu water sword, get it
Total fit/7 Stable bath Formaldehyde (37%) Add 10 ml of water Total amount/table - As is clear from the table, the compound of general formula (1) according to the present inventor was decomposed by applying pressure to the antihalation layer. Silver production was significantly promoted, and it became possible to grow multiple rice plants in the whitening time. Furthermore, even when the compound of general formula (1) was added to layers other than the antihalation layer, an increase in the rate of boron removal was obtained. Example 2 Colloid 41 in one layer of the yellow filter of the sample of Example 1
A film sample containing 2.1 mol/mol of Compound (II) as shown in Table 2 was added, of course, and a known antifoggant, /-phenyl-1t-mercaptotetrazole. At the same time as the film sample
The following film forced aging test was carried out for the purpose of f+lJM in a short period of time. Forced aging test storage conditions ■ Room temperature storage 3 days ■ 0°C, tO%, 3-1 ■ ≠ evening"c, rθchi, 3 days After this, wedge stroke was applied, and then the same as shown in Example 1 The development process of (T Natsu/He) was carried out by measuring the diary strength of the sample for 3 minutes of cleaning time to determine the characteristic IJ and il lines of the green feeling that come into instant contact with the P1 yellow filter. The layer's low potency Dmin and the relative logarithmic sensitivity of 80.2 (Measured with #Fushimi 5 of Capri+02) were determined.The changes due to the storage conditions of each building obtained are shown in Table 2. In addition, in order to compare the removal rate of yellow colloid Q in these samples, the lowest yellow coloring degree at 3 minutes and 7 minutes was measured. It was found that there was a large amount of yellow colloidal silver remaining in the bad phase of the seed-treated plants with a large difference in foundation between 1 and 7 minutes.The obtained results are shown in Table 3. 2. Table-j Nibosu Like, Anti-halation 1m
By adding the compound represented by the general formula (1) according to the present invention to the yellow filter and removing the compound 1 in the general formula (n), the green feeling 1 (up to) can be obtained. Time (
It was found that the occurrence of fogging (particularly over time under wet conditions) was significantly suppressed, and the desilvering promoting effect of the compound of the present invention represented by general formula (1) was not inhibited. Example 3 On a cellulose acetate film coated with a conventional undercoat, each of the breasts described below was sequentially placed on the support side to prepare an inner fabric sample. Layer-7 Antihalation layer Same as layer-7 in Example 1 j-1λ Intermediate layer Same as layer-2 in Example 1 HA-3 Red-sensitive low-sensitivity silver emulsion layer Example/1
Same layer as So-3 - Red-sensitive medium-sensitivity halogen silver emulsion 10 The following changes were made to the halogen silver emulsion liquid of So-3. The thus obtained halogen film was rubbed on the palm of the hand so that the dry film thickness was i and rμ. Ball! Examples of red-sensitive toning halogen punching agents
Same layer as ≠-t Gelatin intermediate layer '45 Example/same as 1--5 15-7 Low sensitivity to green female Rogen milk 11J It
→Same as Layer-6 of Example 1 Ifi-♂ Green-sensitivity Medium-sensitivity No. Rogen Station Emulsion Breast 14-♂
The halogen plane's breasts are contained in one stomach. The dry film thickness of the halogen I bath solution prepared in this way was 3
I tried to be like μ. Layer-2 Green-sensitive, commercial-sensitivity silver halogen emulsion layer Same as layer-7 of Example/1 BiH-io Yellow colloidal silver layer Same layer as the layer-r of Example 1-/ Blue-sensitive, low-sensitivity silver halogen emulsion layer The following changes were made to the silver halogen emulsion in layer 72, blue-sensitive medium-sensitivity halogen emulsion layer, which was the same as that in Example 1. The halogen-limited solution thus prepared was applied to a dry film thickness of 1 μm and 1 μm. 1 m-/3 Sensitive Sieve Sensitivity Halogen Emulsion Layer Example/Layer - Same as IO Layer 7≠ Gelatin Protective Layer Example/Layer - Same as /// The sample thus produced is designated as 30. As in Example 1, antihalation 1- of film sample 30 was added with 0. / Added water and water as shown in Table -≠, and examined film sample 3/~g≠ (7). The wedge was shaped into a circular shape, and subjected to the same development process as in Example 1, and the residual silver and copper after the process was measured.As is clear from the table, the desilvering accelerator according to the present invention is added to the care antihalation layer. By this,) Kyokai J.
(Include) iL is accelerated significantly, and the double wheel of Mukuhaku time becomes cIJ function.

Claims (1)

[Claims] tl+ A silver halide color photographic light-sensitive material containing at least seven compounds represented by the following general formula (1) or its strong acid salt is subjected to electrophotographic and color development and then processed with peroxide. A line whitening method for color photographic H materials, which is characterized by bleaching. General formula (1) However, ■ and R each represent a hydrogen atom or a costal aliphatic residue, and R1 and 112 may form a lump. ■Mo 3 represents one liter - or -I (-8- (here -
1 and - do not represent divalent aliphatic residues). X represents a nitrogen atom, and the acid ligation atom represents a divalent heterocyclic residue & containing at least seven marrow atoms. M is a hydrogen atom/alkali metal,
Represents an alkaline earth metal, quaternary ammonium salt, quaternary phosphonium salt, or amidino number. (2. i of general formula (1) in claim 1)
A nickel silver method for producing a color photographic material, characterized in that t3 represents -1 or -8- (wherein -R- represents a covalent aliphatic residue paper). (3) The first aspect of the patent claim characterized in that the silver halide color photosensitive material is a silver halide color photographic light-sensitive material containing a compound represented by the following general formula (Il). Is the color photographic shell photosensitive toy fee for the battle? ! p-mortar method. However, Q represents a hydrogen atom, an alkali metal atom, or μ-class ammonium. Y is -N 几 R1 or 10R
R5, R6, R7 and R are each a hydrogen atom, and 111! ! Or represents an unsubstituted alkyl group or a substituted or unsubstituted aryl group.几6 and R7 may be the same or different! It may form a membered or t-membered ring. (4) In claim 3, R in general formula (1) represents -14-8-, and Y in general formula (II) represents -N
Color photographic feeling y characterized by expressing l()L
c. Bleaching method for materials. (5) In claim 3, 3 in general formula (1) represents -R'-8-, and Y in general formula i) is -OR
Egg white method of color photographic impression 9H material characterized by representing 8.