JPS5962199A - Manufacture of ornament - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

DETAILED DESCRIPTION OF THE INVENTION This light relates to a method for producing decorative bodies with novel patterned surfaces.

Transparent dielectric lA thin JIS! Interfering colors attract the attention of many people because they are used for fortune-telling, and if you use shellfish, you can find decorations made from natural products such as C/v, pearls, and fish scale elephants11);
Although it is made with
1.Many decorative bodies have been created that utilize the interference color of transparent dielectric films, which are artificially made. , metal ii?
Vacuum deposition or sputtering of transparent dielectric material on j, ion plating, vapor phase formation I×I/j method (this J,
What kind of film is it suitable for? 'IIL L
However, it is not necessarily easy to make a transparent dielectric film by such a method, and it is difficult to make a transparent dielectric film by such a method. Secret Technique 1: It takes a lot of time compared to making a metal thin film because it requires a lot of modification.
Rub.

Iko (゛The non-applicant was able to create a deep optical interference pattern layer 1 (1 pattern layer) with a n-υ force, without requiring any precision technology, it was possible to realize it in a cylinder in 11.1 minutes. u Shumeru Technique 1・[, I heard l, and then 11I request 11j)!+6 I applied for the application as No. 177112.

Said 1・[J is 1h of gold on the glazed surface of the base coated with glaze/+iu;
A thin film is formed, and this is treated at high temperature with −C in an oxygen atmosphere to form a welding surface layer.
It is.

c(1) If J is in li rls? Wholesale (゛Shenzhen 4
``The optical interference pattern layer is used to create a sharp decorative body 19, but the interference f'l 4I; i 4.1; J (ij Ir;1
) Ni J Ni>'<: , 1° I +, 2 A strong interference color appears or weakens ■ sip 1, which is natural due to the nature of interference light There were two problems.

The present invention further degenerates from this.
Midea (accepting qi-sama's request and saying that it is 1-1 to obtain the device 1i body) (there is, 1 (j41 straw, 4\bu is '4.' + l!4 on the base)
There are 41 different colors, 41 different colors, 1 history 111 and silence, and 10 metal i'1911'l! z, to form this, in the M elementary atmosphere C high quality, accept the aesthetic pattern and form the photon 1j lj sexual human being 11° 4 tr
+ Manufacture of decorative objects (h4 Noh Umadori.

The substrate used in the present invention at 7°C is rtl, silver, silver, iron,
Metals such as steel, stainless steel and other alloys, resimic,
Ceramics, glass 4j etc. heat resistance 1 [monthly interest rate].

For glazing, there are glazes for ceramics and glazes for metals (enamel glaze,
There is L Treasure Glaze), but it matches the 44 qualities of 1"L1 body!
1. Select an appropriate glaze with different IJJ (e.g. melting point, specific heat, fluidity) and use various colored glazes from among them to create an appropriate color pattern on the substrate surface. Jru.

Such a glaze may be strained in a slightly uneven manner. To make it look like a sea urchin, all you have to do is sprinkle the glaze powder on the surface of the base. After firing, the glaze surface will be island-like or yuzu skin-like.
ζ will be able to accept slight irregularities such as rarimen shapes. Coarsely spread the glaze rJ) on the surface of the body to 11 (depending on whether you want to spread it or cover it densely, or spread it) 1 ru (J to adjust the 1t) to make the unevenness of the glaze surface after firing. 111 becomes shallow or deep<<E・), 1) Small lily 11
11, rarimen shape, 1, l, saw, f+II
1) The four-piece base rfii will be glued together to create an island-like pattern in the glaze.

;), glazed y, NrJ heat ('lli
1°! It is also possible to form a glazed surface with an uneven pattern by firing the glaze in small steps. In this case, the heat-resistant fine grains include)) Rusty beads, etc. 1 Geometric small IJi powder, metal small i ; + r ; Crushing) 1 etc. are used. these are.

The heat resistance of the culm (not completely melted) during firing (Zl must be 2-(゛).

J of 11, the base coated with sea urchin glaze produces an interference color.
Second, a bicomponent thin film is formed on the surface, and the IJ method (or any of the following methods: vacuum, sputtering, ion polishing, vapor phase growth, and plating) J, Ru. This formation is a metal thin I+!, > (A negative and - (1, 1,, Fc, Cr, Ni, CIl
, Zll, 1i, tvlll, △J2. Mo, 7
r, Si, pl+, 5u+1, l++, 3b, C
It is preferable to use metals such as O, Mo, W, I3i, steel, alloys, etc., or metals that are easily oxidized in a humid atmosphere.

1!73 of a thin metal film is J, -) (there may be some fluctuations, but the thickness of the metal thin film varies depending on the color of light reflected on the C surface) (
J30 Mili Miku Un 1- is J, I,.

The glazed base coated with the metal thin film coated with τ is subjected to high temperature treatment in an oxygen atmosphere. Electric furnaces can be heated in the air, and there is no need to introduce acid in particular.In the case of a steam furnace, an oxidation furnace is used.As for high-temperature treatment, treatment in the furnace is recommended. In addition, heating methods such as parts heating in air, infrared heating, induction heating, and dielectric heating are used. The higher the temperature is 1/1, the better.It depends on the type of metal thin film and glaze, but any temperature range from 300 to 1600°C is sufficient.

When pressed, fL genus thin] shi) is oxidized from the surface to form a thin oxide film, and an interference color appears, but as oxidation progresses, Interference colors change. This is the already known transparent dielectric 14-i9
I'), it is observed that fg is scattered according to the relationship of optical single interference color. In this case; ♀ middle row l
), the first layer is a metal oxide a9 film, and the lower layer becomes a metal thin film -C. The c1 vortex treatment may be stopped at this stage (sometimes the entire metal thin film is completely oxidized, and some parts of the metal thin film are completely oxidized, leaving some metal parts in the lower layer). In short, there is a method in which the degree of oxidation of the metal A9 film is controlled depending on the desired pattern and color.

, Lk, 1fh Temperature treatment [-1 is as described in 1, metal thin Il 1 1 is made into 1115 1↓, and the interference color is obtained, transparent metal oxide thin 11! ,! In addition to forming the glaze, semi-liquid 1
) 1, the design layer \1) Gold 1III oxide layer (cracks, wrinkles, striations, bubbles, etc.) can be used to change the pattern. In other words, -1 -How to read?F+ depending on the person
l+But(Kotaketakinhis ;'tQ II!+!Monkey(
J) CD ll3 One,
There are streaks, bubble holes, and the underlying glaze appears on the bumps. This is because the glaze is at the glass transition point)
lft is determined to occur in the relationship between the sudden increase in the integrated density of 1-1 and the (shallow area strength) of the thin film.

The metal thin film is rarely dissolved into the glaze, which has become semi-perturbative at high temperatures, but the metal oxide layer is easily dissolved into the glaze and loses its interference color.

IQ-ga (, ffnf of high temperature treatment fl,!f
Due to +A degree unevenness, thin film thickness, same thickness unevenness, etc., and the effects of J and - are intertwined with the degree of oxidation (during treatment 114), the metal thin film on the surface of the substrate is coated with gold. Cracks, wrinkles, striations, etc. occur in the RM biological layer and metal layer, and the metal oxide layer is dissolved in the glaze and disappears.
This causes bumps to appear on the ground pattern of the glaze, and bubbles to form on the surface. Interference colors are accepted, so the base color of the glaze is 11J-1 light or -1. , it is possible to obtain a light interference color surface with a beautiful overall interference color pattern.

Furthermore i! ``!I?It's time for product processing (, Metal aQ II
14).
Gap, [-114 in some J, sea urchin heru.

1 island processing ++r'1 period (, just take the multi-phase effect of the book and set it where the desired (shi) appearance appears.

1. Real/Al11911 will be explained below.

Example 1 114 fever 1! l On a remix board, 8 colors of green, yellow, red;
-). The firing temperature of these colored glazes is 750 to 850°C. This was heated in a heated electric oven J1 for 5 minutes.
(Do sputter link) Put in 4 position, low moon j' Rougon airflow (Shirataki f + 511 - [4450 seconds? I 'J, each divine color glaze surface b -,) / Koreramix temporary 1 ♀ genus J
I flapped the tan thin film, this is 7! + 0 ``C's electric furnace (air bath) (,: Put in'') I'4 Rin the wading membrane and put the Simix 41. The original interference color due to the thickness of the interference crotch, and the anti-C1l color from the color glaze on the base, are unique in the yellow, red, and white parts. i's +1jL
-Small the colors, make the whole thing- (duplicate 211', -c taste 1 runru 11 four-color pattern, Nomix temporary 11)
I'm sorry.

In addition, when sputtering is performed,
Create a pattern on the metal thin layer 1 on the glaze surface (J in 1-1)
, 5 Enoko, which has a variation of the interference pattern made by a sea urchin.

Example 2 The same glaze as in Example 1 was applied to a heat-resistant Reramix board,
A finely uneven surface was formed by applying a force of 0.2 to 0.8 mn1 and firing. This was coated with a glaze surface using the same method as in Example 1, and a titanium oxide film was applied to Lamix 4 (1'1') to create a finely uneven surface with a textured surface. From the side of A to the base color glaze 241
'J interference color is seen, and the intensity of the interference color in the viewing direction is extremely 4-fold, and the lily with various shades of aesthetic 4' JAIL 4', R's optical interference 1-1 surface 19 layers of Reramix board were produced.

As shown in 1-
c 19Nl, face! 9) - 11 songs were obtained, and this (, 1 decorative crystal, tableware, 11 pieces, 1' J゛, goods, etc.) 1'l ii'l Applicant Shinshi Ill
Pavilion Agent Buri” - Ko Song Bal Sui

Claims (2)

[Claims] (1) Apply 1411 different color glazes to the Kt body, form a metal thin film on the glaze, and treat it at 8 temperatures in an oxygen atmosphere to create an aesthetic (61-like) glaze. Indicates the method for producing a light interference +!1 surface layer by forming a surface layer. (2) Glaze is applied so that the surface has a fine unevenness.
)'R1n'l +il'i Production of the station entrance 111 body described in item 1. (:', > fill heat 1'l 1101'l 11
(Ilishi' (By firing) - (Shi1111
Surfaces t and l form fine unevenness 'lrJ, Il:
rj request range i (1 piece of equipment listed in JQ)
15 Method 1, (4) Formation of full bending i'19 film by vacuum evaporation, sputter link, ink, vapor phase growth.
> J: A method for producing a JA sieve according to claim 9 and 11, which is carried out by any of the methods listed in Item 4. (', -+) I wear a hundred crystals (the capsular membrane is oxidized, the main flow is 1!1, and the main flow is 1!
) A method for producing a sieve body using the method described in item 1 for crystallization of 'Ri8'.