JPS5959746A - Production of temperature-sensitive electrically conductive polymer composition - Google Patents
Production of temperature-sensitive electrically conductive polymer compositionInfo
- Publication number
- JPS5959746A JPS5959746A JP17275182A JP17275182A JPS5959746A JP S5959746 A JPS5959746 A JP S5959746A JP 17275182 A JP17275182 A JP 17275182A JP 17275182 A JP17275182 A JP 17275182A JP S5959746 A JPS5959746 A JP S5959746A
- Authority
- JP
- Japan
- Prior art keywords
- cesium
- carbon
- temperature
- mixture
- conductive polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 229920001940 conductive polymer Polymers 0.000 title claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229920000642 polymer Polymers 0.000 claims abstract description 10
- 230000002687 intercalation Effects 0.000 claims abstract description 9
- 238000009830 intercalation Methods 0.000 claims abstract description 9
- 238000004132 cross linking Methods 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000010382 chemical cross-linking Methods 0.000 claims description 3
- 229910052792 caesium Inorganic materials 0.000 abstract description 9
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 abstract description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052799 carbon Inorganic materials 0.000 abstract description 7
- 239000011575 calcium Substances 0.000 abstract description 4
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 abstract description 3
- 239000006229 carbon black Substances 0.000 abstract description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052791 calcium Inorganic materials 0.000 abstract description 2
- 238000010894 electron beam technology Methods 0.000 abstract description 2
- 229920001903 high density polyethylene Polymers 0.000 abstract 1
- 239000004700 high-density polyethylene Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- JVWLOLRJWFXRLM-UHFFFAOYSA-N [C].[Cs] Chemical compound [C].[Cs] JVWLOLRJWFXRLM-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（発明の技（（・１分野）
本発明は導電性重合体組成物、特にその抵抗率がある特
定の濡１σ領域に達す−ると、急激に増加し、正の温Ｉ
Ｕ係数（以−１・Ｉ） Ｉ Ｃと称する）ｂ増大する性
質を示１温度Ｗｌ感１’ｌ導電１イ１重合体組成物の’
Ｍ造万ン人に関りる。DETAILED DESCRIPTION OF THE INVENTION (Techniques of the Invention (1) Field of the Invention The present invention relates to a conductive polymer composition, in particular, the resistivity of which increases rapidly when it reaches a certain 1σ region, and The temperature of
The U coefficient (hereinafter referred to as I C) shows the property of increasing 1 temperature Wl feeling 1'l conductivity 1i1 polymer composition'
Concerning M-Zouman people.
＜発明の技１「トｉ的背■ｄ３よび問題点）従来、ポリ
ｌ ’Ｔ Ｉノンあるいはポリプロピレンなとの結晶１
１１手合体に、たどえば金属微粉末あるいはカーボンブ
ラック＜アどを分散させたＰ Ｔ’ Ｃ特性を右する導
電性重合体組成物（以−Ｆ Ｐ Ｔ Ｃ重合体と称する
）が知られているが、前者は室ｉ１Ｍ （２０℃）にお
りる抵抗率は１０２ Ｑ・Ｃｌ１ｌど大きい−１、＾）
合成（１８０’Ｃ）でも１０３Ω・ｃａｎ稈度であり抵
抗率の温度依ひ性が１分で４丁いツＩｔ ｓ：、ｉを・
右し、一方後者においては一応満足できるＰ１’Ｃ特１
１をポリ−が、室温にＪ３ける抵抗率が１０〜１０２Ω
・（、Ｉｎと高いため、さらに人容最の電流を流すため
には素子の形を大きくｕざるを得ず小型化の要求、ある
いは月利コスｌ〜の低域の要求を満足するに（，１０ら
なかった。<Inventive Technique 1 "Background ■d3 and Problems" Conventionally, crystals of polyl'Tinon or polypropylene 1
A conductive polymer composition (hereinafter referred to as F PTC polymer) which has PTC characteristics and has fine metal powder or carbon black dispersed therein is known. However, in the former case, the resistivity in the chamber i1M (20℃) is 102 Q・Cl1l -1, ^)
Even in synthesis (180'C), the culmability is 103Ω・can, and the temperature dependence of resistivity is 4 times in 1 minute.
On the other hand, in the latter case, P1'C characteristic 1 is somewhat satisfactory.
1 is poly, and the resistivity at room temperature is 10~102Ω
・(Because of the high In, the shape of the element must be made larger in order to flow the most human-sized current, and in order to satisfy the demand for miniaturization, or the demand for low frequency range of monthly cost l~) ,10 wasn't there.
（発明の目的）
本発明の目的とづ−るところは、改良された［〕［Ｃ特
性、とくに常温での抵抗率がイルく、入電流を流１場合
でも素子の小型化が１＋１能な湿度敏感１１導電性重合
体組成物の製造方法を提供覆ることである。(Objective of the Invention) The object of the present invention is to improve the C characteristics, especially the resistivity at room temperature, and to reduce the size of the device by 1+1 even when the input current is 1. It is an object of the present invention to provide a method for preparing a humidity sensitive conductive polymer composition.
（発明の概要）
本発明はカーボン−セシウム層ｔ、１．ｉｊ化合物を混
入した結晶性重合体に、化学架橋あるいは照射架橋を廁
りことにＪ、り前記結晶性重合１本を架Ｉ臭さけること
を１：ｒ徴どりる）晶度敏感性導電性小合体組成物の！
Ｊ、Ｒ；ｌｌｒ万ン人１こ関りるしのである。(Summary of the Invention) The present invention provides a carbon-cesium layer t, 1. When the crystalline polymer mixed with the ij compound is subjected to chemical crosslinking or irradiation crosslinking, the above-mentioned crystalline polymer is exposed to a 1:r) crystallinity-sensitive conductivity. Small combined composition!
J.
ここて゛カー小シーヒシウム層間化合物どはカニボンの
！１、）定１１′＋品面間にセシウムが入り込んだもの
をさ４が、完全（（，１なく部分的に層間化合物が形Ｊ
戊さ４１．たｂのを含Ｃむ５．カーボンどセシウムは′
１：５の割合てパ反応づる。Here, the small Sihissium intercalation compound is from Kanibon! 1, ) constant 11' + cesium has entered between the surfaces of the product.
41. 5. Carbon and cesium are
The ratio is 1:5.
木北明に使用りるカーボン−セシウム層間化合物の製造
方法としては、例えば真空ポンプにより真空系をＩ Ｘ
１０ ” ｌ１ｌｌｌ ＋−１（Ｊの真空に保ちつつ
、前記真望系中にカーボンブラックおにび塩化セシウム
とカルシラｌ＼の混合物を分離して配置し、次に塩化セ
シウムとカルシウムの混合物をヒーター等により１１１
１熱りる／ｊ法をとる。。As a method for producing the carbon-cesium intercalation compound used in Akira Kikita, for example, the vacuum system is
A mixture of carbon black, cesium chloride, and calcium chloride was separated and placed in the vacuum system while maintaining a vacuum of 10" l1llll +-1 (J), and then a mixture of cesium chloride and calcium was placed in a heater. 111 by etc.
1 Heat up / Take the j method. .
口の加熱により次の反応がおこりセシウムの蒸気が光／
１．シ、
２Ｃ３Ｃｆｌ ）Ｃａ −＞Ｃａ Ｃａ２ ２ ＋
２Ｃ８↑上記セシウムの蒸気をカーボンに吸着する。The following reaction occurs due to the heating of the mouth, and the cesium vapor becomes light/
1. , 2C3Cfl ) Ca −>Ca Ca2 2 +
2C8↑The above cesium vapor is adsorbed on carbon.
この状態（・カーホンを約／Ｉ ００″Ｇに加熱りると
カーボンーレシウ１ＸＩｉｖ間化合物が生成Ｃさる。／
Ｊ−ボン−セシウム層間化合物の配合量として【、１ベ
ースポリマー１００可［！ｈ）部あたり３〜・Ｅｉ Ｉ
ｆＴ！郡の範囲で添加するのが好ましい。ここで３千
０１部より添加量が少ないと常温にお（プる抵抗率がト
がらず５０小間部をこえると分１１に不良のため（本成
的４【・持性か低下り−るためである。In this state (・When carbon is heated to about /I 00″G, a carbon-residue 1XIiv compound is formed./
The blending amount of the J-bon-cesium intercalation compound is [, 1 base polymer 100 [!] h) 3~・Ei I per part
fT! It is preferable to add within a certain range. If the amount added is less than 3,001 parts, the resistivity will not rise at room temperature, and if it exceeds 50 parts, the resistance will decrease. It's for a reason.
なお、結晶性重合体を架橋する方法どじで【よ有機過酸
化物による化学架橋による方法と、電子線、ガンマ−線
などの電離性放１＝Ｉ線にＪ、る照Ｏｉｌ架橋による方
法とがあるが、このいづれし＋） １ Ｃ狛性の改善に
対しては同様な効果を示づことか認められる。There are two methods for crosslinking crystalline polymers: chemical crosslinking using organic peroxides, and oil crosslinking using ionizing radiation such as electron beams and gamma rays. However, this combination +) 1 It can be seen that it shows a similar effect on improving C.
（発明の実施例）
次に本発明の実施例について説明する１゜実施例
結晶性重合体どして高密瓜ポリ１ブレン１ハイＵツクス
１３００ＪＪ （三井ボリクーミカル社製商品名）１
００重量部と前記製造法によりｊ！、ＩたＶＵしＣΔＮ
ＸＣ−７２（Ｃａｂｏ＋４Ｊ商品名＋ ’、／ ｔ
’−ネス吸油１．３ ）とレシウｌ＼よりなるカーボン
−セシウム層間化合物／Ｉ Ｃ’）Φω部をゴム）ム１
練用ロールで１ ！３０ ℃、１０ブン間ｉ１Ｊ Ｉ東
後厚さ１市川のシート４人（こ１］−力 １００ Ｋす
／ ｃｎｆの条件で押出しｌ、。次に前記シートに電ｊ
′−線を照射した後２０ ｍ１ＩＸ ２０ ｍＩＩに切
断し、両面に一ツクル電極をつ（Ｊ試料しＩこ。(Embodiments of the Invention) Next, embodiments of the present invention will be explained.
00 parts by weight and the above manufacturing method j! , I and VU and CΔN
XC-72 (Cabo+4J product name + ', /t
Carbon-cesium intercalation compound consisting of '-ness oil absorption 1.3) and resin l\/I C') Φω part rubber) Mu1
1 with a practice roll! A sheet of Ichikawa with a thickness of 1 J I Togo thickness 1 was extruded by 4 people at 30 °C for 10 hours with a force of 100 K/cnf.Then, the sheet was
After irradiating the specimen with 20 ml x 20 ml, one electrode was attached to both sides (J sample).
ｔ”Ｉ’ ＣＩ’＋ １４１の測定（よ、電気炉中で室
温から２０”Ｃ／分の）＊世ｃ”ｊｒ （晶し、温度と
抵抗率の関係を測定した。Measurement of t"I'CI'+ 141 (20"C/min from room temperature in an electric furnace)
従来例どじではカーボンーレシウム層間化合物ヲカーホ
＞ （Ｖ （Ｊ ｌ−ＣＡ Ｎ Ｘ Ｃ−７２） Ｃ
，、、変え他（３１実加例どＩｉ’ｉｌじしのを用い、
同様に測定した１゜図にこの測定結果を示づ。In the conventional example, the carbon-resium intercalation compound was removed (V (J l-CA N X C-72) C
,,, change etc. (31 actual examples using Ii'il original,
The measurement results are shown in the 1° diagram, which was measured in the same way.
図にＪ３い（従来例は点線、実施例は実線ぐ承り。J3 is shown in the figure (the conventional example is shown by the dotted line, the embodiment shown by the solid line).
（発明の効果）
以」ムＴ述した如く本発明の温度敏感性導電士１重合体
組成物の製造方法ににれば良９．ｒなＰＴＣ特性を保ら
ながら室温にお（）る抵抗率は従来品に比へ１／１０ど
なり、大電流でかつ小型の製品を可能でさる。(Effects of the Invention) As described below, the method for producing the temperature-sensitive conductive polymer composition of the present invention has nine advantages. While maintaining excellent PTC characteristics, the resistivity at room temperature is 1/10 that of conventional products, allowing for large current and small size products.
図は従来品Ｊ３よび本発明の方法にＪ、っ（１，１られ
た温度敏＠１１導電１（Ｉ：重合体組成物の１ｌｉｌＡ
度ど比抵抗の関係の一実施例を示づ図である。
／ｌ〕で。
代理人弁理士 山 １）明 （ｎ４・、・。
′−The figure shows the temperature sensitivity @ 11 conductivity 1 (I: 1 lil A of the polymer composition) of the conventional product J3 and the method of the present invention.
It is a figure which shows one example of the relationship of degree specific resistance. /l]. Representative Patent Attorney Yama 1) Akira (n4・,・. ′-
Claims (1)
重合体に、化学架橋あるいは照射架橋を施すことにＪ：
り前記結晶性重合体を架橋さＵることを特徴どＪるン！
ｉ＋ロ燵敏感性導電性重合体組成物の製造り法。11 J: Chemical crosslinking or irradiation crosslinking of a crystalline polymer mixed with a carbon-resium intercalation compound:
The feature is that the crystalline polymer is cross-linked!
A method for producing an i+rotation-sensitive conductive polymer composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17275182A JPS5959746A (en) | 1982-09-30 | 1982-09-30 | Production of temperature-sensitive electrically conductive polymer composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17275182A JPS5959746A (en) | 1982-09-30 | 1982-09-30 | Production of temperature-sensitive electrically conductive polymer composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5959746A true JPS5959746A (en) | 1984-04-05 |
Family
ID=15947643
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17275182A Pending JPS5959746A (en) | 1982-09-30 | 1982-09-30 | Production of temperature-sensitive electrically conductive polymer composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5959746A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009203441A (en) * | 2008-02-29 | 2009-09-10 | Denso Corp | Composite material, manufacturing method therefor, and composite structure |
-
1982
- 1982-09-30 JP JP17275182A patent/JPS5959746A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009203441A (en) * | 2008-02-29 | 2009-09-10 | Denso Corp | Composite material, manufacturing method therefor, and composite structure |
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