JPS5947374A - Manufacture of decoration - Google Patents

Manufacture of decoration

Info

Publication number
JPS5947374A
JPS5947374A JP15834682A JP15834682A JPS5947374A JP S5947374 A JPS5947374 A JP S5947374A JP 15834682 A JP15834682 A JP 15834682A JP 15834682 A JP15834682 A JP 15834682A JP S5947374 A JPS5947374 A JP S5947374A
Authority
JP
Japan
Prior art keywords
plating
manufacturing
decoration
item
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15834682A
Other languages
Japanese (ja)
Inventor
Takeshi Chikura
千倉 健
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mansei Kogyo KK
Original Assignee
Mansei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mansei Kogyo KK filed Critical Mansei Kogyo KK
Priority to JP15834682A priority Critical patent/JPS5947374A/en
Publication of JPS5947374A publication Critical patent/JPS5947374A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

PURPOSE:To obtain a decoration retaining its appearance and color tone similar to those of a sintered hard alloy and having superior wear resistance, hardness and corrosion resistance, by forming thin Cr plating on a Cu alloy material worked to the required surface and shape before carrying out ionic plating. CONSTITUTION:A Cu alloy material such as brass is worked to a shape necessary for a decoration, and the required faces of the worked product are made specular. Cr plating of about 5mum thickness is then formed while retaining the edge between the specular faces, and the Cr plating is plated with Ti or a Ti alloy. Thus, a decoration which resembles a sintered hard alloy in appearance and has superior wear resistance, hardness, etc. is obtd.

Description

【発明の詳細な説明】 本発明は、腕時計側、腕輪、詩語バンド又シ」机上品、
ltl吻などの装飾品の製造ノj法Cτ関」ろ。
[Detailed Description of the Invention] The present invention is applicable to wristwatches, bracelets, poetry bands, desk items,
The manufacturing method for ornaments such as proboscises and other accessories.

従来の装飾品、1lfVl腕時泪側などには、耐色1′
1:、硬度、耐Jψ耗性に優れ、(7かも表面の呻面什
1げによる光沢が良いことで、WC1゛r+cなどの超
(+dj質炭化炭化物’rtlJ s ZrNなどの超
硬質窒化物を粉末冶金した、所謂超硬合金による製品が
提供さ11ている。しかしこの超硬合金製品あるいけ部
品Q」、商品価値は高いが、低い耐衝撃性、悪い加、1
−件が量産化に対する致命点な欠点であり、コスト高の
原因となっていた。
Conventional ornaments, 1lf Vl arms, etc.
1: Excellent hardness, Jψ abrasion resistance, and good gloss due to the surface roughening of the surface (7). There are products made of so-called cemented carbide made by powder metallurgy.However, these cemented carbide products have a high commercial value, but have low impact resistance, poor damage, and
This was a critical drawback to mass production and caused high costs.

そこで本発明は、加工性が良く、安価な銅基合金を用い
ながら、上記超硬合金の製品あるいυ部品と同様の外観
、色調を持ら、1.かも従来の銅基合金のメッキより大
巾に硬度、耐食性、面1摩耗1イ1゜に優れる装飾品の
製造方法を提供−1″ろことを目的とする。
Therefore, the present invention uses a copper-based alloy that has good workability and is inexpensive, while having the same appearance and color tone as the above-mentioned cemented carbide products or υ parts. Another object of the present invention is to provide a method for manufacturing a decorative article that is far superior in hardness, corrosion resistance, and surface wear to 1° compared to conventional copper-based alloy plating.

以下、本発明の好適なる実施例を説明する。Hereinafter, preferred embodiments of the present invention will be described.

装飾品の母材としては、加工性が良く、比1咬的安価な
銅基合金lを使用するが、腕時計、時HE:ンドなどに
は、それらの素材として一般的に用いられろ黄銅材を採
用寸ろことか、安価であり、加工性、メッキ処理性が良
好であり、又イオンフレーディングの処理温度に十分耐
えるなどの条件から望捷(2い。この黄銅材を、装飾品
と12で必要な形状に加工し、この加工物の公費な面に
ダイーVカット加工によって鏡面加工をする。この鏡面
加工にて、鏡面加工を施した面と而との陵線にシャープ
なエツジを持たせ、優シ]、た鏡面状纏にすることは容
易である。
Copper-based alloys, which have good workability and are comparatively cheap, are used as the base material for decorative items, but brass materials, which are commonly used for watches, watches, etc., are used as base materials for decorative items. This brass material is suitable for use in decorative items due to its low cost, good workability and plating properties, and its ability to withstand the processing temperature of ion fretting. Processed into the required shape in Step 12, the publicly funded surface of the workpiece is mirror-finished using die V-cut processing.This mirror-finishing process creates sharp edges on the ridge lines between the mirror-finished surface and the other. It is easy to make a mirror-like robe.

この後、研摩機Vこて、前記陵線のシーV−ブさと、鏡
面状1tすをぐず芒ないように、軽くノクフ研摩して、
洗浄装置にて、溶剤による脱脂と研j早にて生じた滓の
除去を行う。
After that, use the V-trowel of the polishing machine to lightly polish the sheave V-button of the ridge line and the mirror-like 1t, being careful not to scratch them.
A cleaning device is used to degrease using a solvent and remove slag generated during sanding.

千1−て、−1−記の成型品Vtメッキな施−Jのであ
るが、このメッキは、前処理の活性化に工夫をこらし、
メッキの密層力を向上させろことにより後述するイメン
プレーテインダ処理によって発生しゃすいメッキ層Tの
フクレを防ぐためのものであり、一般的なりロムメッキ
を採用17た。またメ・ツヤ層Tの総厚を厚くとも5 
tt程度ノ=シ、一般的なりロムメッキに比較して薄く
し7ている。例えば、銅ストライクメッキ2は0.2〜
0.3μ、ニツウルメッキ3は35μ以十、クロノ・メ
ッキ4は0.2 IIσ)範囲内で、このクロムメッキ
層Tの紗シ19が5μ44.1度になるようにすると良
い。従つ−(、この稈+ifσ)メッキ層Tであれば、
成型品の陵線しでメッキが1;1き過ぎて、陵線のシャ
ープな感じのテリ゛インを1j1うことかない。
The molded product described in -1-1 is Vt-plated, but this plating is done by devising the activation of the pre-treatment.
This is to improve the plating strength and prevent blistering of the plating layer T, which is caused by the image plate binder treatment described later, and a general ROM plating was used17. Also, the total thickness of the glossy layer T should be increased by at least 5
It is about tt, and is thinner than general chrome plating. For example, copper strike plating 2 is 0.2~
It is preferable that the gauze 19 of this chrome plating layer T be 5μ44.1 degrees within the range of 0.3μ, 35μ or more for nickel plating 3, and 0.2 IIσ for chrono plating 4. Therefore, if −(, this culm + ifσ) plating layer T, then
The plating is too thick on the ridge lines of the molded product, and the ridge lines look sharp.

このクロムメッキ処理の後、前処理洗浄をしてイオンブ
レーティング処理を行うのであるが、このイオングレー
ティング処理t」1、成型品の母相たる負鋼材に熱的悪
影響ケJシえず、かつル−テづング層の布屑性が十分に
得ら1)ろ温IW設定をする必便があるが、このイオン
ブレーティング処理によって、前記メッキ層Tの上に被
膜Sを形成する。。
After this chromium plating treatment, pretreatment cleaning is performed and ion brating treatment is performed, but this ion grating treatment does not cause any adverse thermal effects to the negative steel material that is the matrix of the molded product, and In order to obtain sufficient dust-free property of the routing layer, 1) it is necessary to set the filtration temperature IW, and a film S is formed on the plating layer T by this ion blating treatment. .

層性を得る足がかりとなるTI層5を(=i L、この
’rI層5の上に耐食性、硬度、強度を付すためのTi
N6層を付し、さらにこのTiN6層の上に最終的に装
飾目的となる色調を得るためのTiN + TIC7)
qを付している。従って、この色調調整によって・従来
の超硬合金が示す色調と同様のものを出すことができる
The TI layer 5, which serves as a foothold for obtaining layered properties, is formed on the TI layer 5 (=i L, and the Ti layer 5 is added to provide corrosion resistance, hardness, and strength.
Apply a N6 layer, and then add TiN + TIC7 on top of this TiN6 layer to finally obtain a decorative color tone.
A q is added. Therefore, by this color tone adjustment, it is possible to produce a color tone similar to that exhibited by conventional cemented carbide.

−F述の処理の結果、イオンブレーティング処理によっ
て形成された硬質のチタニウム層の被膜Sと、比較的軟
らかい母相1との間に、前述のメッキ層Tが介在するこ
とになゆ、硬度が段階的に硬くなゆ、各層間の密2n性
、耐摩耗性などの!時性が良好になる0−また上述のイ
オンブレーティング処理の除、一般的に母材に直接イオ
ンプレーディング処理をすると、母材からのガスの発生
により、上述したフクレなどを生じて外観が悪くなると
共に耐食性、硬1現、耐摩耗性の低F fzどの問題が
生じるが、−1−5己のm着性の良いクロムメッキを施
して、しくことによって解消できる。
As a result of the treatment described above, the plating layer T is interposed between the hard titanium layer coating S formed by the ion blating treatment and the relatively soft matrix 1. gradually hardens, the density between each layer is 2n, wear resistance, etc.! In addition to the above-mentioned ion blating treatment, when ion plating treatment is performed directly on the base material, the above-mentioned blistering occurs due to the generation of gas from the base material, resulting in poor appearance. As it deteriorates, problems such as low fz of corrosion resistance, hardness, and wear resistance occur, but these problems can be solved by applying chrome plating with -1-5 self-adhesiveness.

丼た、手記実施例にて、チタニウム又はヂタニウム台金
ル−ディングを施して金色に近い色調を出せるが、イオ
ンプレーディングを一4″ろ金属を適宜選択することに
より、金色に限定さJするこノ・なく広い色調範囲のも
のが得らJする。
In the notes example, a color tone close to gold can be obtained by applying titanium or ditanium base metal ruding, but it can be limited to a gold color by appropriately selecting the ion plating metal. You can get a wide range of tones.

このように、鏡面仕上りが良く、陵線のジードブさを出
せると云う従来の超硬合金が持つ外観)−の特性を有す
と共に硬度、4食性、而」摩耗性に、i <t’r来の
銅基合金に対するクロムメ、ツキ、金メッキより一段と
信頼性あるもので商品1曲値も高い4、のである。
In this way, it has the appearance characteristics of conventional cemented carbide, such as a good mirror finish and the ability to express the sharpness of the ridge lines, but also has the characteristics of hardness, tetracorrosion, and abrasion resistance. It is much more reliable than conventional copper-based alloys such as chrome, gloss, and gold plating, and the product price is also higher4.

本発明の装飾品の製造方法によJl、げ、銅基全金利の
必要な而に鏡面加工をし7、装置1品、I−1,,で公
費な形状に形成した後、前記鏡面加−1−0を施(、た
而と面との陵線をくずさない程度の比較的薄いメッキ処
理性 してなるため、加工性が良く、安1曲な銅基合金をイサ
材と1ろことVCより、任意の形状しく6易に成型でき
、その成型品の形状をくずすことなく、9jL埋後の被
膜の硬度、耐食性、耐摩耗性が優−7またイオングレー
ティング処理を、メッキ処理を1υ祠の加工面上に施す
ことによりa実かつ奇麗に施すことができ、従来の超硬
合金の製品あるいは部品と同様の高級感ある外観、色調
を壱(17,17かも従来の銅基合金のメッキより太[
1]に優度、耐食性、耐摩耗性の優れた装飾品を安価に
提供できイ)。
According to the method for manufacturing ornaments of the present invention, mirror finishing is applied to the necessary parts of the Jl, ridge and copper base 7, and after forming it into a publicly expended shape using one piece of equipment, I-1,. -1-0 is applied (but it has a relatively thin plating process that does not destroy the ridge line between the surface and the surface, so it is easy to work and is made of a cheap copper-based alloy. In particular, VC can be easily molded into any shape without changing the shape of the molded product, and the hardness, corrosion resistance, and abrasion resistance of the coating after 9JL burial are excellent. By applying it to the machined surface of 1υ, it can be applied neatly and neatly, giving it the same luxurious appearance and color tone as conventional cemented carbide products or parts. thicker than the plating [
1) It is possible to provide decorative products with excellent corrosion resistance and wear resistance at low cost.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例を示す断面図、第2図e;(
同実施例の工程を示す説明図である。 1・―銅)((合金相、T拳・メッキ層、5・・イオ/
フレーディノグによる被膜。 l(¥訂11冒頗人 〆1\11)土渠株式会社第1図 第2図 −36;
FIG. 1 is a sectional view showing one embodiment of the present invention, and FIG. 2 e;
It is an explanatory diagram showing the process of the same example. 1.-copper) ((alloy phase, T fist/plating layer, 5..io/
Coating with Fredinog. l (¥11 Adventurer 〆1\11) Doyu Co., Ltd. Figure 1 Figure 2-36;

Claims (1)

【特許請求の範囲】 1 銅基合金材の必要な面に鏡面加工をし、装飾品とし
て必・メメな形状に形成した後、前ML煉而面工を施U
7た而と面との陵線をぐずさないイ呈度の比較的薄いメ
ッキ処理を施し、その後イオンブレ−ティング処理をし
てなる装飾品の製造方法。 2、 前記銅基台金材を黄銅とした特許請求の範囲第1
項KL載の装飾品の製造方法。 3、 前記メッキ処理をクロムメッキとし、そのメッキ
層の総厚を厚くとも5μ程度にした特許請求の範囲第1
項又は第2項記載の装飾品の製造方法。 4、 前記イオンブレーティング処理として、チタニウ
ム又はチタニウム合金グレーティンクをした!hf許d
〜求の範囲第1項又は第2項又は第3項記載の装飾品の
製造方法。
[Claims] 1. After mirror-finishing the necessary surfaces of the copper-based alloy material and forming it into the desired shape as a decorative item, the pre-ML metal surface treatment is applied.
7. A method for manufacturing an ornament by applying a relatively thin plating process that does not disturb the ridge lines between the base and the surface, and then applying an ion blasting process. 2. Claim 1 in which the copper base metal material is brass
Method for manufacturing ornaments listed in Section KL. 3. Claim 1, wherein the plating treatment is chrome plating, and the total thickness of the plating layer is approximately 5 μm at most.
2. A method for manufacturing a decorative article according to paragraph 2 or paragraph 2. 4. Titanium or titanium alloy grating was applied as the ion brating treatment! hf permission
. . . A method for manufacturing a decorative article according to item 1, item 2, or item 3.
JP15834682A 1982-09-10 1982-09-10 Manufacture of decoration Pending JPS5947374A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15834682A JPS5947374A (en) 1982-09-10 1982-09-10 Manufacture of decoration

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15834682A JPS5947374A (en) 1982-09-10 1982-09-10 Manufacture of decoration

Publications (1)

Publication Number Publication Date
JPS5947374A true JPS5947374A (en) 1984-03-17

Family

ID=15669631

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15834682A Pending JPS5947374A (en) 1982-09-10 1982-09-10 Manufacture of decoration

Country Status (1)

Country Link
JP (1) JPS5947374A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6189036A (en) * 1984-10-08 1986-05-07 ヤマハ株式会社 Decorative material and manufacture thereof
JPS6428360A (en) * 1987-06-30 1989-01-30 Inco Ltd Production of golden color coin

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51151277A (en) * 1975-06-20 1976-12-25 Sumitomo Electric Ind Ltd A coated super hard alloy
JPS52149279A (en) * 1976-06-07 1977-12-12 Tsuneo Nishida Golden colored decorative casing parts
JPS5379577A (en) * 1976-12-24 1978-07-14 Tsuneo Nishida Case elements for timepiece
JPS5382672A (en) * 1976-12-28 1978-07-21 Sumitomo Electric Ind Ltd Coated high speed steel and its manufacture
JPS53138989A (en) * 1977-05-10 1978-12-04 Koyo Seiko Co Ion plating method
JPS5633475A (en) * 1979-08-24 1981-04-03 Seiko Instr & Electronics Ltd Manufacture of exterior ornamental parts
JPS5693875A (en) * 1979-12-27 1981-07-29 Hamasawa Kogyo:Kk Display member
JPS5811783A (en) * 1981-07-13 1983-01-22 Seiko Epson Corp Armor parts for decoration
JPS5896870A (en) * 1981-12-07 1983-06-09 Seiko Instr & Electronics Ltd External part

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51151277A (en) * 1975-06-20 1976-12-25 Sumitomo Electric Ind Ltd A coated super hard alloy
JPS52149279A (en) * 1976-06-07 1977-12-12 Tsuneo Nishida Golden colored decorative casing parts
JPS5379577A (en) * 1976-12-24 1978-07-14 Tsuneo Nishida Case elements for timepiece
JPS5382672A (en) * 1976-12-28 1978-07-21 Sumitomo Electric Ind Ltd Coated high speed steel and its manufacture
JPS53138989A (en) * 1977-05-10 1978-12-04 Koyo Seiko Co Ion plating method
JPS5633475A (en) * 1979-08-24 1981-04-03 Seiko Instr & Electronics Ltd Manufacture of exterior ornamental parts
JPS5693875A (en) * 1979-12-27 1981-07-29 Hamasawa Kogyo:Kk Display member
JPS5811783A (en) * 1981-07-13 1983-01-22 Seiko Epson Corp Armor parts for decoration
JPS5896870A (en) * 1981-12-07 1983-06-09 Seiko Instr & Electronics Ltd External part

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6189036A (en) * 1984-10-08 1986-05-07 ヤマハ株式会社 Decorative material and manufacture thereof
JPS6312784B2 (en) * 1984-10-08 1988-03-22 Yamaha Kk
JPS6428360A (en) * 1987-06-30 1989-01-30 Inco Ltd Production of golden color coin

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