JPS5945755B2 - Coated carbide throw-away tip - Google Patents

Coated carbide throw-away tip

Info

Publication number
JPS5945755B2
JPS5945755B2 JP890679A JP890679A JPS5945755B2 JP S5945755 B2 JPS5945755 B2 JP S5945755B2 JP 890679 A JP890679 A JP 890679A JP 890679 A JP890679 A JP 890679A JP S5945755 B2 JPS5945755 B2 JP S5945755B2
Authority
JP
Japan
Prior art keywords
layer
coated carbide
cutting
coated
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP890679A
Other languages
Japanese (ja)
Other versions
JPS55100978A (en
Inventor
泰次郎 大西
健 板羽
紹太郎 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP890679A priority Critical patent/JPS5945755B2/en
Publication of JPS55100978A publication Critical patent/JPS55100978A/en
Publication of JPS5945755B2 publication Critical patent/JPS5945755B2/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates

Description

【発明の詳細な説明】 この発明は、切刃の使用・未使用を色別することができ
る被覆超硬スローアウエイチツプに関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a coated carbide throw-away tip whose cutting edge can be color-coded to indicate whether it is used or not.

従来、超硬質合金で製造された切削用超硬スローアウエ
イチツプは公知であり、また前記超硬スローアウエイチ
ツプの表面に、周期律表の4a)5a、および6a族の
金属の炭化物、窒化物、および酸化物のうちの1種、お
よびこれらの2種以上の固溶体からなる群から選んだ層
厚工〜20μmの単層あるいは2種以上の多重層を被覆
して耐摩耗性の向上をはかり、よつて切削寿命の延命化
をはかつた被覆超硬スローアウエイチツプも知られてお
り、さらに前記被覆超硬スローアウエイチツプの被覆層
上に、層厚0.2〜5μmのα−アルミナからなる被覆
層をさらに形成して、特にチップの耐熱性および耐酸化
性を改善し、鋼と鋳物の両方の切削を可能とした工業上
有用な被覆超硬スローアウエイチツプもよく知られると
ころである。
Conventionally, a carbide throw-away tip for cutting made of a super-hard alloy is known, and the surface of the carbide throw-away tip is coated with carbides and nitrides of metals from groups 4a, 5a, and 6a of the periodic table. , one type of oxide, and a solid solution of two or more of these types, and coated with a single layer or multiple layers of two or more types with a thickness of up to 20 μm to improve wear resistance. Therefore, a coated carbide throw-away chip that has a longer cutting life is also known, and furthermore, on the coating layer of the coated carbide throw-away chip, a layer of α-alumina with a thickness of 0.2 to 5 μm is coated. Industrially useful coated carbide throw-away tips are also well-known, which are further coated with a coating layer to improve the heat resistance and oxidation resistance of the tips, thereby making it possible to cut both steel and cast metals.

特に、上記後者の被覆超硬スローアウエイチツプにおけ
るα−アルミナからなる被覆層(上層)は、化学蒸着法
によつて形成され、半透明の黒色を呈し、しかも1〜2
μmの表面粗さをもつものであるため、前記被覆超硬ス
ローアウエイチツプにおいては、外観上、下地の色をわ
ずかに見ることができるものの、ほとんど黒色に近い色
調を呈し、さらに切削使用後においても、切刃の摩耗が
少ない場合には明確なる変色の発生がないことも良く知
られるところである。
In particular, the coating layer (upper layer) made of α-alumina in the latter coated carbide throw-away chip is formed by chemical vapor deposition, exhibits a translucent black color, and
Because the coated carbide throw-away tip has a surface roughness of micrometers, although the underlying color is slightly visible in appearance, it exhibits an almost black tone, and furthermore, after cutting, It is also well known that no obvious discoloration occurs when the cutting edge has little wear.

このため、上記被覆超硬スローアウエイチツプにおける
複数の切刃のうち使用・未使用を確実に色別することは
、特に照明の不十分な工作機械内部での短時間な切刃交
換作業においては、ほとんど不可能である。
For this reason, it is important to reliably distinguish between used and unused cutting edges of the coated carbide indexable insert by color, especially when changing cutting edges in a short period of time inside a machine tool with insufficient lighting. , almost impossible.

そこで、α−アルミナからなる被覆層のもつすぐれた切
削特性を生かし、かつ使用・未使用切刃の判別を容易に
行なえる被覆超硬スローアウエイチツプとして、前記α
−アルミナ被覆層の上に、化学蒸着法によつて層厚0.
5〜5μmの明るい黄色を呈した窒化チタン層を被覆し
たものが提案されたが、上記窒化チタン被覆層の化学蒸
着法による形成には1000℃近い高温を必要とするた
め、上記α−アルミナ被覆層のもつ切削特性が前記の高
温によつてそこなわれ、この結果として切削寿命の短か
いもの.となつてしまうという問題点がある。
Therefore, we developed a coated carbide throw-away tip that takes advantage of the excellent cutting properties of the coating layer made of α-alumina and allows easy discrimination between used and unused cutting edges.
- on the alumina coating layer by chemical vapor deposition with a layer thickness of 0.
A coating with a bright yellow titanium nitride layer of 5 to 5 μm was proposed, but since forming the titanium nitride coating layer by chemical vapor deposition requires a high temperature of nearly 1000°C, the α-alumina coating described above was proposed. The cutting properties of the layer are damaged by the high temperatures mentioned above, resulting in a short cutting life. The problem is that it becomes .

本発明者等は、上述のような観点から、上記従来被覆超
硬スローアウエイチツプ、すなわち、超硬質合金基体の
表面に、上記として周期律表の4a,5a1および6a
族の金属の炭化物、窒化物、および酸化物のうちの1種
、およびこれらの2種以上の固溶体からなる群から選ん
だ層厚1〜20μmの単層あるいは2種以上の多重層を
被覆し、さらに上層として層厚0.2〜5μmのα−ア
ルミナ層を被覆したものからなる被覆超硬スローアウエ
イチツプにおける使用切刃と未使用切刃の判別を、被覆
層形成によつて行なうべく、特に、(a)使用前と使用
後の変色が大きい。
From the above-mentioned viewpoint, the present inventors have proposed that the conventional coated carbide throw-away chip, that is, the surface of the cemented carbide substrate, be coated with 4a, 5a1, and 6a of the periodic table as described above.
Coated with a single layer or a multilayer of two or more of metals with a thickness of 1 to 20 μm selected from the group consisting of carbides, nitrides, and oxides of group metals, and solid solutions of two or more of these metals. In order to distinguish between a used cutting edge and an unused cutting edge in a coated carbide throw-away tip which is further coated with an α-alumina layer having a layer thickness of 0.2 to 5 μm as an upper layer, by forming a coating layer, In particular, (a) the discoloration before and after use is large;

(b)使用前は明るく美麗な色調を有する。(b) It has a bright and beautiful color tone before use.

(c)防錆作用がある。(d)油、特に切削油による大
きな見掛け上の変色がなぃ。
(c) It has a rust-preventing effect. (d) There is no significant apparent discoloration due to oil, especially cutting oil.

(e)被覆超硬スローアウエイチツプの特性をそこなわ
ない。
(e) The properties of the coated carbide throw-away tip are not impaired.

(f)コストが安い。(f) Low cost.

以上(a)〜(f)の要件を満足して備えた被覆層を見
出すべく研究を行なつた結果、TiCxNyOz(ただ
し、0.01≦X≦0.3、0.6≦y≦0.98、0
.01≦z≦0.1、x+y+z≦1.0)からなる組
成を有する厚み0.01〜0.5μmの被覆層は、上記
の要件をすべて満足する特性を有するという知見を得た
のである。
As a result of conducting research to find a coating layer that satisfies the requirements (a) to (f) above, we found that TiCxNyOz (0.01≦X≦0.3, 0.6≦y≦0. 98, 0
.. It has been found that a coating layer having a thickness of 0.01 to 0.5 μm and having a composition of 01≦z≦0.1, x+y+z≦1.0 has characteristics that satisfy all of the above requirements.

すなわち、上記従来被覆超硬スローアウエイチツプの切
刃の一部または近傍、あるいは切刃全体を0.01〜0
.5μmの厚みのTiCxNyOz層(ただし、0.0
1≦x≦0.3、0.6≦y≦0.98、0.01≦z
≦0.1、x+y+z≦1.0)で被覆すると、その被
覆部分は、使用前においては、明るく美麗な黄色〜橙色
の色調を有し、しかも耐食性が良好で保存中に錆発生が
なく、かつ切削油によつて汚れても大きな見掛け上の変
色がなく、一方使用後においては、切削時に発生する高
温によつて黒色に変色し、この結果未使用切刃のもつ明
るい黄色〜橙色と、使用済切刃のもつ黒色とを暗所にお
いてもきわめて容易に色別できるという知見を得たので
ある。
That is, a part of or the vicinity of the cutting edge of the conventional coated carbide throw-away tip, or the entire cutting edge, is coated with a coating of 0.01 to 0.
.. TiCxNyOz layer with a thickness of 5 μm (however, 0.0
1≦x≦0.3, 0.6≦y≦0.98, 0.01≦z
≦0.1, x+y+z≦1.0), the coated part has a bright and beautiful yellow to orange color tone before use, and has good corrosion resistance and does not rust during storage. In addition, there is no apparent discoloration even when contaminated with cutting oil; on the other hand, after use, the color changes to black due to the high temperatures generated during cutting, resulting in the bright yellow to orange color of an unused cutting edge. They discovered that it is very easy to distinguish the black color of a used cutting blade even in a dark place.

この発明は、上記知見にもとづいてなされたものであり
、以下にTiCxNyOz被覆層の組成および厚みを上
記の通り限定した理由を説明する。
This invention has been made based on the above findings, and the reason why the composition and thickness of the TiCxNyOz coating layer are limited as described above will be explained below.

(a) TiCxNyOz被覆層の組成TiCxNyO
z被覆層におけるX,.ylおよびzの相対割合は経験
的に定められたものであつて、0.01≦Z≦0.3、
0.6≦y≦0.98、0.01≦z≦0.1、および
x+y+z≦1.0)の条件を満足した場合に、鮮明な
黄色〜橙色を有し、しかもこの黄色〜橙色が切削時の高
温にさらされると、色別容易な黒色に変色するのである
(a) Composition of TiCxNyOz coating layer TiCxNyO
X in the z coating layer, . The relative proportions of yl and z are determined empirically, and are 0.01≦Z≦0.3,
0.6≦y≦0.98, 0.01≦z≦0.1, and x+y+z≦1.0), it has a clear yellow to orange color, and this yellow to orange color When exposed to high temperatures during cutting, it changes color to black, which is easy to distinguish.

すなわち、前記の条件から外れると、その色調が暗赤色
に変わるようになると共に、反射率も低下し暗くなるの
で、使用・未使用の判別が困難となるのである。(b)
TiCxNyOzの厚みその厚みが0.01μm未満
では、容易な色別が可能な黄色〜橙色を付与することが
できないと共に、切削使用後における黒色変化が明確で
なく、一方0.5μmを越えた厚みにすると、α−アル
ミナ被覆層のもつすぐれた耐熱性、耐酸化性、および耐
摩耗性がそこなわれるようになつて、切削寿命を低下さ
せることから、その厚みを0.01〜0.5μmと定め
た。
That is, if the above conditions are not met, the color tone changes to dark red and the reflectance decreases, making it dark, making it difficult to distinguish between used and unused. (b)
Thickness of TiCxNyOz If the thickness is less than 0.01 μm, yellow to orange colors that can be easily distinguished cannot be imparted, and the black change after cutting is not clear. If this happens, the excellent heat resistance, oxidation resistance, and wear resistance of the α-alumina coating layer will be impaired, reducing the cutting life, so the thickness is set to 0.01 to 0.5 μm. Established.

また、この発明の被覆超硬スローアウエイチツプにおけ
るTiCxNyOz被覆層は、スパツタリング法を適用
することによつてコスト安く形成することができ、しか
も蒸着速度は遅いが、非常に緻密で、かつα−アルミナ
被覆層の表面粗さが1〜2μmであるために実用上十分
な付着強度をもつものである。
Further, the TiCxNyOz coating layer in the coated carbide throw-away chip of the present invention can be formed at low cost by applying the sputtering method, and although the deposition rate is slow, it is very dense and is made of α-alumina. Since the surface roughness of the coating layer is 1 to 2 μm, it has practically sufficient adhesion strength.

また、TiCzNyOz被覆層の形成は、窒素を含有し
た雰囲気中で、陰極としてTiを使用し、700゜C以
下の温度で行なうのが望ましい。すなわち、700℃を
越えた反応温度にすると、α−アルミナ被覆層の特性が
そこなわれるようになつて、切削寿命の低下をきたすよ
うになるからである。ついで、この発明の被覆超硬スロ
ーアウエイチツプを実施例により説明する。
Further, the TiCzNyOz coating layer is preferably formed in an atmosphere containing nitrogen, using Ti as a cathode, and at a temperature of 700° C. or lower. That is, if the reaction temperature exceeds 700°C, the properties of the α-alumina coating layer will be impaired, resulting in a reduction in cutting life. Next, the coated carbide throw-away chip of the present invention will be explained with reference to examples.

実施例 1 まず、内接円:12.7mm1厚み4.76mm1ノー
ズR:0.8mmの寸法をもつたJISP3O製の超硬
スローアウエイチツプの表面に、通常の化学蒸着法を適
用して、層厚:5μMf)TiC層と、層厚:2μmの
TiCO.5OO.5層とからなる下層、および層厚:
2μmのα−アルミナ層からなる上層を被覆することに
よつて、外観上暗赤色を呈し、一見黒色といえる色調を
有する従来被覆超硬スローアウエイチツプを製造し、つ
いでこれを真空槽の中にTiの陰極をもつスパツタリン
グ装置内に装入し、真空度:8×10−3mmHg、陰
極電圧:1.2KVの条件で、Ar:N2:H2−1:
1:1の割合で混合したガスを毎分100m1の割合で
流入させながら30分間のグロー放電を行なうことによ
つて、刃先全体が、明るく、わずかに橙色をおびた黄色
の色調を有する層厚:0.2μmのTiCO.O5NO
.,OO.O2層によつて被覆された本発明被覆超硬ス
ローアウエイチツプを製造した。
Example 1 First, a normal chemical vapor deposition method was applied to the surface of a carbide throw-away chip made of JISP3O with dimensions of inscribed circle: 12.7 mm, thickness 4.76 mm, and nose radius 0.8 mm. Thickness: 5 μMf) TiC layer, layer thickness: 2 μm TiCO. 5OO. Lower layer consisting of 5 layers and layer thickness:
A conventionally coated carbide throw-away chip with a dark red appearance and a black tone at first glance was manufactured by coating the upper layer with a 2 μm α-alumina layer, and then placed in a vacuum chamber. The Ar:N2:H2-1:
By performing glow discharge for 30 minutes while flowing a gas mixture in a 1:1 ratio at a rate of 100 ml per minute, the entire cutting edge has a bright, slightly orange-yellow color. :0.2 μm TiCO. O5NO
.. ,OO. EXAMPLE 1 A coated carbide throw-away chip according to the invention, which was covered with an O2 layer, was manufactured.

つぎに、上記本発明被覆超硬スローアウエイチツプと、
上記従来被覆超硬スローアウエイチツプを自動車部品を
切削加工する自動盤に用いたところ、共に200個の部
品切削で寿命に達し、このことは切刃の使用・未使用の
色別のために設けたTiCxNyOz被覆層によつて切
削特性が何らそこなわれるものではないことを示してい
る。また、本発明被覆超硬スローアウエイチツプにおい
ては、明るいわずかに橙色をおびた黄色の色調が、使用
後は黒色に変化するので、その使用前および使用後を明
確に、かつきわめて容易に区別することができるのに対
して、従来被覆超硬スローアウエイチツプでは、α−ア
ルミナ被覆層のもつ暗赤色(黒色に近い)の色調にほと
んど変化がないので、特に照明の不十分な工作機械内部
での短時間の色別はほとんど不可能であつた。
Next, the coated carbide throwaway tip of the present invention,
When the above-mentioned conventional coated carbide throw-away tip was used in an automatic lathe for cutting automobile parts, it reached the end of its life after cutting 200 parts. This shows that the cutting characteristics are not impaired in any way by the TiCxNyOz coating layer. In addition, in the coated carbide throw-away tip of the present invention, the bright, slightly orange-yellow color changes to black after use, making it possible to clearly and extremely easily distinguish before and after use. In contrast, with conventional coated carbide throw-away chips, there is almost no change in the dark red (almost black) color tone of the α-alumina coating layer, so it is difficult to use, especially inside machine tools with insufficient lighting. Color classification in a short period of time was almost impossible.

実施例 2 下層を層厚:5μMf)TiC層のみで構成すると共に
、真空槽内へ流入させる混合ガスの組成をAr:N2:
H2:CH4=1:1:1:0.1とする以外は、実施
例1におけると同一の条件で本発明被覆超硬スローアウ
エイチツプを製造した。
Example 2 The lower layer was composed of only a TiC layer (layer thickness: 5 μMf), and the composition of the mixed gas introduced into the vacuum chamber was Ar:N2:
A coated carbide throw-away chip of the present invention was manufactured under the same conditions as in Example 1 except that H2:CH4 = 1:1:1:0.1.

この結果得られた本発明被覆超硬スローアウエイチツプ
におけるTiCxNyOz層は、橙色を有し、組成Ti
CO.l5NO.83OO.。2、厚み:0.3μmを
有するものであつた。
The TiCxNyOz layer in the coated carbide throwaway chip of the present invention obtained as a result has an orange color and a composition of Ti.
C.O. l5NO. 83OO. . 2. Thickness: 0.3 μm.

つぎに、上記本発明被覆超硬スローアウエイチツプと、
切刃の使用・未使用を色別するためのTiCxNyOz
被覆層を形成しない従来被覆超硬スローアウエイチツプ
について、被削材:JIS:SNCM−8の丸棒、 切削速度:180m/Mi!t、 切込み:0.5mm、 送り:0.1mm/Revl 切削条件:10mm、 の条件で切削試験を行なつたところ、両チツプともに0
.3mmの逃げ面摩耗を示した。
Next, the coated carbide throwaway tip of the present invention,
TiCxNyOz for color-coding used/unused cutting blades
Regarding the conventional coated carbide throw-away tip that does not form a coating layer, workpiece material: JIS: SNCM-8 round bar, cutting speed: 180 m/Mi! t, depth of cut: 0.5mm, feed: 0.1mm/Revl, cutting conditions: 10mm, When cutting tests were conducted under the following conditions, both chips were 0.
.. It showed flank wear of 3 mm.

しかし、本発明被覆超硬スローアウエイチツプでは、使
用前の明るい橙色から使用後は黒色へ変色するので色別
がきわめて容易であつたのに対して、従来被覆超硬スロ
ーアウエイチツプにおいては、使用前も使用後も変らず
黒色を呈するため判別はきわめて困難であつた。上述の
ように、通常のスパツタリング法によつて700′C以
下の低温を適用してコスト安く形成したTiCxNyO
z被覆層を有する本発明被覆超硬スローアウエイチツプ
によれば、使用前の明るい黄色〜橙色の色調が使用後に
黒色に変化するので、照明の不十分な工作機械内部にお
いても使用・未使用の切刃の色別を明確に、かつ容易に
行なうことができるのである。
However, with the coated carbide throw-away tip of the present invention, the color changes from bright orange before use to black after use, making it very easy to distinguish by color, whereas with the conventional coated carbide throw-away tip, It was extremely difficult to distinguish because it remained black both before and after use. As mentioned above, TiCxNyO is formed at a low cost by applying a low temperature of 700'C or less by a normal sputtering method.
According to the coated carbide throw-away chip of the present invention having the Z coating layer, the bright yellow to orange color tone before use changes to black after use, so it is possible to distinguish between used and unused chips even inside a machine tool with insufficient lighting. This allows the cutting edges to be clearly and easily distinguished by color.

Claims (1)

【特許請求の範囲】[Claims] 1 超硬質合金基体の表面に、周期律表の4a、5a、
および6a族の金属の炭化物、窒化物、および酸化物の
うちの1種、およびこれらの2種以上の固溶体からなる
群から選んだ層厚1〜20μmの単層あるいは2種以上
の多重層からなる下層を介して、層厚0.2〜5μmの
α−アルミナからなる上層を被覆したものからなる被覆
超硬スローアウエイチツプにおいて、その切刃の一部ま
たは近傍、あるいは切刃全体に、切刃の使用・未使用を
色別するための厚み0.01〜0.5μmを有する黄色
〜橙色のTiCxNyOz層(ただし、0.01≦x≦
0.3、0.6≦y≦0.98、0.01≦z≦0.1
、z+y+z≦1.0)を被覆したことを特徴とする被
覆超硬スローアウエイチツプ。
1. On the surface of the super hard alloy substrate, 4a, 5a,
and one type of carbide, nitride, and oxide of group 6a metal, and a single layer or a multilayer of two or more types with a layer thickness of 1 to 20 μm selected from the group consisting of a solid solution of two or more types of these metals. In a coated carbide throw-away tip that is coated with an upper layer of α-alumina with a layer thickness of 0.2 to 5 μm through a lower layer of A yellow to orange TiCxNyOz layer with a thickness of 0.01 to 0.5 μm to distinguish between used and unused blades (0.01≦x≦
0.3, 0.6≦y≦0.98, 0.01≦z≦0.1
, z+y+z≦1.0).
JP890679A 1979-01-29 1979-01-29 Coated carbide throw-away tip Expired JPS5945755B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP890679A JPS5945755B2 (en) 1979-01-29 1979-01-29 Coated carbide throw-away tip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP890679A JPS5945755B2 (en) 1979-01-29 1979-01-29 Coated carbide throw-away tip

Publications (2)

Publication Number Publication Date
JPS55100978A JPS55100978A (en) 1980-08-01
JPS5945755B2 true JPS5945755B2 (en) 1984-11-08

Family

ID=11705708

Family Applications (1)

Application Number Title Priority Date Filing Date
JP890679A Expired JPS5945755B2 (en) 1979-01-29 1979-01-29 Coated carbide throw-away tip

Country Status (1)

Country Link
JP (1) JPS5945755B2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE509201C2 (en) * 1994-07-20 1998-12-14 Sandvik Ab Aluminum oxide coated tool
JP2000042806A (en) * 1998-07-31 2000-02-15 Toshiba Tungaloy Co Ltd Laminated coated body for cutting tool
SE525581C2 (en) 2002-05-08 2005-03-15 Seco Tools Ab Cutting coated with alumina made with CVD
EP1477581A1 (en) * 2003-05-10 2004-11-17 Seco Tools Ab Enhanced alumina layer produced by CVD
JP4653450B2 (en) * 2004-10-05 2011-03-16 住友電工ハードメタル株式会社 Cutting edge replaceable cutting tip and manufacturing method thereof
JP4739234B2 (en) * 2004-12-03 2011-08-03 住友電工ハードメタル株式会社 Cutting edge replaceable cutting tip and manufacturing method thereof
US7553113B2 (en) 2005-01-26 2009-06-30 Sumitomo Electric Industries, Ltd Indexable insert and method of manufacturing the same

Also Published As

Publication number Publication date
JPS55100978A (en) 1980-08-01

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