JPS5941716A - Burner having ceramic refractory wall structure - Google Patents

Burner having ceramic refractory wall structure

Info

Publication number
JPS5941716A
JPS5941716A JP15007882A JP15007882A JPS5941716A JP S5941716 A JPS5941716 A JP S5941716A JP 15007882 A JP15007882 A JP 15007882A JP 15007882 A JP15007882 A JP 15007882A JP S5941716 A JPS5941716 A JP S5941716A
Authority
JP
Japan
Prior art keywords
ceramic
ceramic piece
cover
cooling air
combustor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP15007882A
Other languages
Japanese (ja)
Other versions
JPS6242213B2 (en
Inventor
Minoru Muto
武藤 実
Norio Tsuta
蔦 紀夫
Kenji Mori
建二 森
Yoshiki Tozaki
遠崎 良樹
Toshiyuki Kuyama
久山 利之
Toshinori Nakamura
中村 敏則
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP15007882A priority Critical patent/JPS5941716A/en
Publication of JPS5941716A publication Critical patent/JPS5941716A/en
Publication of JPS6242213B2 publication Critical patent/JPS6242213B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23RGENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/007Continuous combustion chambers using liquid or gaseous fuel constructed mainly of ceramic components

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Gas Burners (AREA)
  • Pre-Mixing And Non-Premixing Gas Burner (AREA)

Abstract

PURPOSE:To provide the burner of the ceramic refractory wall structure allowing high temperature combustion to be made and having a high degree of mechanical strength. CONSTITUTION:The inner surface 2a of an inner cylinder of the combustor of a gas turbine is attached with a refractory wall 27 consisting of a number of segments 28. The segment 28 is formed of a plate-like ceramic piece 29, a cover 30 for holding the ceramic piece 29 and a cushion 31 made of a material having elastic and ventilating properties and interposed between the cover 30 and the ceramic piece 29. As the ceramic piece 29 has an excellent heat resistant propperty, the inner cylinder 12 is prevented from being heated to high temperature, high temperature combustion in a combustion chamber 11 is made possible. Further, the ceramic piece 29 which has a low degree of strength is held by the cover 30 through the cushion 31 so that it is possible to improve the strength of the ceramic piece 29 against vibrations and to keep the mechanical strength of the entire combustor at a high level.

Description

【発明の詳細な説明】 この発明は、主としてガスタービンに用いられ、燃焼室
壁の内面にセラミックの耐火壁を設けて、高温燃焼を可
能にしたセラミック耐火壁構造の燃焼器に関するもので
ある。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a combustor that is mainly used in gas turbines and has a ceramic refractory wall structure that enables high-temperature combustion by providing a ceramic refractory wall on the inner surface of the combustion chamber wall.

ガスタービンの燃焼器は、省エネルギー化のために、高
温燃焼が要求される。これは、ガスタービンにおいては
、周知のように、タービン入口のガス温度を高くするの
に伴なって熱効率が向上するので、上記ガス温度を高く
するために、燃焼器での燃焼温度を高める必要が生じる
からである。
Gas turbine combustors are required to perform high-temperature combustion in order to save energy. This is because, as is well known, in gas turbines, thermal efficiency improves as the gas temperature at the turbine inlet increases, so in order to increase the gas temperature, it is necessary to increase the combustion temperature in the combustor. This is because

ととろで、燃焼温度を高めるには、燃焼器の燃坤室壁を
、高温に耐えて機械的強度を保持し得る一モのにしなけ
ればならない。そこで従来のガスタービンの燃焼器では
、第1図に示すように、燃焼室Uを形成する燃焼室壁で
ある内筒νの外周に、外筒13を設け、その間に冷却空
気14を流して上記内筒νを外側から冷却すると同時に
、上記冷却空気14の一部を、内筒校に設けられた冷却
空気導入(い5から上記内f;Jr’ 12の内面]凪
に導入して、この内面厖に冷却空気14のフィルムを形
成し、上記内面皿を高温の燃焼ガスから熱遮断すること
により、内f;!1J12の高温化による機械的強度の
低下を防止している。なお、第1図において、17は燃
料噴射ノズル、18は7ワーブである。
In order to increase the combustion temperature, the combustion chamber wall of the combustor must be made of a material that can withstand high temperatures and maintain mechanical strength. Therefore, in a conventional gas turbine combustor, as shown in FIG. 1, an outer cylinder 13 is provided around the outer periphery of an inner cylinder ν, which is the combustion chamber wall forming the combustion chamber U, and cooling air 14 is allowed to flow between the outer cylinders 13 and 13. At the same time as cooling the inner cylinder ν from the outside, a part of the cooling air 14 is introduced into the cooling air introduction (from 5 to the inner surface of Jr' 12) provided in the inner cylinder, By forming a film of cooling air 14 on this inner surface and thermally insulating the inner surface from high-temperature combustion gas, a decrease in mechanical strength due to the rise in temperature of the inner surface is prevented. In FIG. 1, 17 is a fuel injection nozzle, and 18 is a 7-warb.

ところが、力゛ヌク−ビンにおいては、コンプレッサ(
図示せずンからの圧縮空気19を燃焼用空気すと上記冷
却空気14とに分けて使用しているので、燃焼温度を高
めるには、上記圧縮空気19の総量に対し、燃料を多量
に燃やすために多)tの燃焼用空気孔が必要となシ、そ
れだけ冷却空気14の量が少なくなる。その結果、燃焼
ガスの高温化と相まって、内筒認がより高温にさらされ
、機械的強度の低下が避けられなくなシ、燃焼温度の十
分な高温化が達成できない欠点がある。
However, the compressor (
Compressed air 19 from a tank (not shown) is used separately for combustion air and cooling air 14, so in order to increase the combustion temperature, a large amount of fuel must be burned relative to the total amount of compressed air 19. Therefore, the number of combustion air holes is required, and the amount of cooling air 14 is reduced accordingly. As a result, together with the increase in the temperature of the combustion gas, the inner cylinder is exposed to higher temperatures, which inevitably leads to a decrease in mechanical strength, and there are disadvantages in that a sufficiently high combustion temperature cannot be achieved.

この発明は上記従来の欠点を解消するためにな1れたも
ので、高温燃焼が可能で、かつ、高い機−惨的強度を有
するセフミック耐火壁構造の燃焼器を提供することを目
的とする。
The present invention was made in order to eliminate the above-mentioned conventional drawbacks, and an object of the present invention is to provide a combustor with a cefmic firewall structure that is capable of high-temperature combustion and has high mechanical strength. .

以下、この発明の実施例を図面にしたがって説Hする。Embodiments of the present invention will be described below with reference to the drawings.

第2図において、12はガスタービンの燃焼器の内筒で
、内部に燃焼室11を形成する燃焼室壁そのものである
。17は燃料噴射ノズル、田はヌワーラ、怒は燃焼用空
気孔、希は希釈用空気孔である。
In FIG. 2, reference numeral 12 denotes an inner cylinder of a combustor of a gas turbine, and is the combustion chamber wall itself that forms a combustion chamber 11 inside. 17 is a fuel injection nozzle, 1 is a nuwara, 3 is a combustion air hole, and 1 is a dilution air hole.

上記内筒稔の内面飄には耐火壁nが装着されておシ、こ
の耐火壁Iは、第3図に示すように、多数のセグメン)
28を隣接配置して形成されている。
A fireproof wall (I) is attached to the inner surface of the inner cylinder (as shown in Fig. 3).
28 are arranged adjacent to each other.

上記セグメン)28は、第4図に明示するように、板状
のセラミックピース四ト、このセラミックピース固を保
持するカバー(至)と、このカバー30トセラミツクピ
ーヌ宛との間に介装された弾力性および通気性のある材
料からなるクッション体31とで構成されておシ、その
セラミック表面劾が下側、すなわぢ、内筒ルの内側おに
向くように設定されている。また、上記カバー初にはね
じ体調がろう付けされておシ、このねじ体勢を内@ルか
ら外方へ突出させ、ナラ)35でカバー(資)を、すな
わちセグメン)28を内筒νに取シ付けている。
As clearly shown in FIG. 4, the above segment 28 includes four plate-shaped ceramic pieces, a cover for holding the ceramic pieces, and a cover 30 interposed between the ceramic piece and the cover. The cushion body 31 is made of a resilient and breathable material, and its ceramic surface faces downward, ie, toward the inside of the inner cylinder. In addition, the screw body is brazed at the beginning of the cover, and this screw body is made to protrude outward from the inner cylinder, and the cover (material), that is, the segment) 28, is attached to the inner cylinder ν with the hollow (2) 35. It is installed.

上記セラミックピース固の材料は、アルミナ、ジルコニ
ア、窒化ケい緊、コージライト、炭化けい素、ムライト
等のうちの1種または2種以上の申合物であシ、クッシ
ョン体31は500°以上の高公トに耐え、しかも弾力
性および通気性を有する材]ト、たとえば、ニッケル・
クロム合金からなる耐熱発泡金属、ハニカム状もしくは
繊維状の金属またはセラミック等で形成され、さらに、
カバー(資)秋数百度Cに耐える2テンレス系のような
金属材料で形成される。
The material of the ceramic piece is a combination of one or more of alumina, zirconia, silicon nitride, cordierite, silicon carbide, mullite, etc., and the cushion body 31 has an angle of 500° or more. [Materials that can withstand high temperatures and have elasticity and air permeability], for example, nickel, etc.
It is made of heat-resistant foamed metal made of chromium alloy, honeycomb-shaped or fibrous metal, ceramic, etc., and
The cover (material) is made of a metal material such as stainless steel that can withstand temperatures of several hundred degrees Celsius.

内筒ルには、フィルム冷却用の冷却空気導入孔15が設
けられておシ、冷却空気14を内PiIJ12の外側か
ら上記冷却空気導入孔15を通ってセグメン)28の内
側のセラミック表面羽に導入し、このセラミック表面羽
に冷却空気14のフィルムを形成するようになっている
。さらに、内812およびカバー(資)には、空気孔3
7,38.39からなる冷却空気導入路40が設けられ
、内筒セの外側から冷却空気14を通気性のあるクッシ
ョン体31へ導入している。
The inner cylinder is provided with a cooling air introduction hole 15 for film cooling, and the cooling air 14 is passed from the outside of the inner PiIJ 12 through the cooling air introduction hole 15 to the ceramic surface blade inside the segment 28. The cooling air 14 is introduced to form a film of cooling air 14 on the ceramic surface vanes. Furthermore, there are air holes 3 in the inner part 812 and the cover (material).
A cooling air introduction path 40 consisting of 7, 38, and 39 is provided to introduce cooling air 14 from the outside of the inner cylinder section into the breathable cushion body 31.

セグメン)2Bの組立手順を第5図に、組立後のセグメ
ン)28を第6図にそれぞれ示す。第5図のセグメン)
28は、第2図に示すように、内筒認の軸心■に対して
後ろ下がりに傾いて取シ付けられているので、その前縁
先の曲率半径aが後縁28bの曲率半径すよシも大きく
なシ、その結果、第5図に示すように、必然的にカバー
Jの前縁島の長さLが後縁の長さMよシ大きくなシ、平
面テーパ状となる。セラミックピース固およびクッショ
ン体31も同様に平面テーパ状となる。また、カバー(
至)の側部aOCは内側おに向かって末すほまジ状に形
成されており、やは杉、セラミックピース四および4ツ
ション体31の各側部290 、310もカバーJの側
部eに合わせたテーバ状に形成されている。したがうて
、セラミックピース固とクッション体31を接合したも
のを、カバー(資)にその前緑薫側から挿入し、この前
緑薫に抜止板6を接合することによシ、セラミックピー
ス9とクッション体31とが、抜止板部によって抜は止
めされた状態でカバー(資)に強固に保持される。
The assembly procedure for the segment 2B is shown in FIG. 5, and the segment 28 after assembly is shown in FIG. 6. Segment in Figure 5)
28, as shown in Fig. 2, is installed so that it is tilted backwards with respect to the axis 2 of the inner cylinder, so that the radius of curvature a of its leading edge is equal to the radius of curvature of the trailing edge 28b. As a result, as shown in FIG. 5, the length L of the leading edge island of the cover J is inevitably larger than the length M of the trailing edge, resulting in a tapered shape in plane. The ceramic piece and the cushion body 31 also have a planar tapered shape. In addition, the cover (
The side part aOC of the cover J is formed in a serpentine shape that tapers toward the inside. It is formed in a tabular shape that matches the . Therefore, the ceramic piece 9 and the cushion body 31 bonded to each other are inserted into the cover from the front side of the cover, and the retaining plate 6 is bonded to the front side of the cover. The cushion body 31 is firmly held by the cover in a state where it is prevented from being removed by the removal prevention plate part.

上記接合の手段としては、溶接、ろう付け、耐熱性接着
剤による接着、拡散接合、a械的結合などがある。なお
、クツショ吟体31トカバー30との間は接合してもよ
いし、接合しなくても牛、Vに不荀1合はない。
Examples of the above-mentioned joining means include welding, brazing, adhesion using a heat-resistant adhesive, diffusion joining, and mechanical joining. In addition, the shoe body 31 and the cover 30 may be joined together, or even if they are not joined, there is no problem with the cow and V.

第7図はセグメン)28の内筒稔への取付手段の変形例
を示し、−レラミツクピース四、クッション体31およ
びカバー(資)を貫ぬく挿通孔45を設け、ボルト46
およびナツト47によりセグメント路を内筒毘に取り付
けている。
FIG. 7 shows a modification of the means for attaching the segment 28 to the inner cylinder rim, in which an insertion hole 45 is provided that penetrates the reramik piece 4, the cushion body 31, and the cover (material), and a bolt 46 is provided.
A nut 47 attaches the segment passageway to the inner cylinder.

第8図のセグメン)28は、第2図の燃焼用空気孔部を
後部に有するものを示し、第9図のセグメン)28は第
2図の希釈用空気孔別を前部に有するものを示す。これ
らセグメント路のを気孔δ、26は完全な円孔ではなく
、1/4孔であるから、セラミックピース茨の強度を低
下させるおそれがない。
Segment 28 in Fig. 8 indicates the one having the combustion air hole in Fig. 2 at the rear, and segment) 28 in Fig. 9 indicates the one having the dilution air hole in the front as shown in Fig. 2. show. Since the pores δ and 26 of these segment paths are not completely circular holes but 1/4 holes, there is no risk of reducing the strength of the ceramic piece.

上記構成において、第4図に示したように、内筒νの内
面12aには、多数のセグメン)28からなる耐火壁I
が取シ付けられておシ、セグメン)28のセラミックピ
ース茨は耐熱性に優れていて遮熱効果が大きいから、内
向νの高温化が防止され、第2図の燃焼室11において
高温燃焼が可能になる。
In the above configuration, as shown in FIG.
Ceramic piece thorn (segment) 28 has excellent heat resistance and has a large heat shielding effect, so it prevents the temperature of the inward direction ν from increasing and prevents high-temperature combustion in the combustion chamber 11 in Fig. 2. It becomes possible.

ここで、第4図のカバー恥も高温化が防止されるから、
このカバーJと内筒認を比較的耐熱性に劣る低級な金属
材料で形成できるので経済的である。
Here, the cover shown in Figure 4 is also prevented from becoming hot, so
This is economical because the cover J and the inner sleeve can be made of a low-grade metal material with relatively poor heat resistance.

また、強度の低いセラミックピース9はクッション体3
1を介してカバー加に保持されているから、セラミック
ピース四の耐振強度が向上し、燃焼器全体の機械的強度
が高く維持される。
In addition, the ceramic piece 9 with low strength is used as the cushion body 3.
Since the ceramic piece 4 is held in place through the cover 1, the vibration resistance of the ceramic piece 4 is improved, and the mechanical strength of the entire combustor is maintained at a high level.

が破損しても、他のセグメン)28には影響がないので
、燃焼器全体の重大破損に至ることがなく、接セヲミッ
ク表面澄に触れなくなるので、火炎と− わ接触によるホットスポットがセラミック表面32に発
生してセラミックピース茨を割れ易くする不具合は生じ
ない。また、クッション体31を通気性のものとして、
このクッション体31に冷却空気14を導入すれば、ク
ッション体31自身およびセラミックビーフ9の冷却が
有効になされるので、よシーJΔの高温燃焼が可能にな
る。
Even if the combustor is damaged, other segments (28) are not affected, so the entire combustor will not be seriously damaged, and since it will not come into contact with the ceramic surface, hot spots caused by contact with the flame will not reach the ceramic surface. The problem that occurs in 32 and makes the ceramic piece thorns more likely to break does not occur. Moreover, the cushion body 31 is made of a breathable material,
By introducing the cooling air 14 into the cushion body 31, the cushion body 31 itself and the ceramic beef 9 are effectively cooled, so that high-temperature combustion of Yoshi JΔ becomes possible.

上記実施例ではガスタービンの燃焼器について蝉、明し
たが、この発明は他の燃焼器についても適用できるもの
である。
In the above embodiment, the combustor of a gas turbine has been described, but the present invention can also be applied to other combustors.

以上説明したように、この発明によれば、高温燃焼が可
能で、かつ、P械的強度の高い燃焼器が得られる効果が
ある。
As explained above, according to the present invention, there is an effect that a combustor that is capable of high-temperature combustion and has high P mechanical strength can be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は従来の燃焼器の一例を示す縦断面図、第2図は
この発明の一実施例を示す縦断面図、第3図は第2図の
3−3線に沿った断面図、第4図は第3図の要部を示す
縦断面図、第5図はセグメントの組立手順を示す分解斜
視図、第6図は組み立てられたセグメントを示す側面図
、第7図はセAメンFの内筒への取付手段の変形例を示
す側面図、@8図および第9図はセグメントの変形例を
示す斜視図である。 11・・・燃焼室、臣・・・燃焼室壁(内筒)、14・
・・冷却空気、15・・・冷却空気導入孔、I・・・耐
火壁、列・・・セグメント、四・・・セラミックピース
、J・・・カバー、31・・・クッション体、32・・
・セラミック表面、の・・・冷1J空気導入路。 特許出願人  工業技術院長 第3図 第4図 82− 第6図 )グ 第7図 第8図 第9図
FIG. 1 is a longitudinal sectional view showing an example of a conventional combustor, FIG. 2 is a longitudinal sectional view showing an embodiment of the present invention, and FIG. 3 is a sectional view taken along line 3-3 in FIG. Fig. 4 is a vertical sectional view showing the main parts of Fig. 3, Fig. 5 is an exploded perspective view showing the assembly procedure of the segments, Fig. 6 is a side view showing the assembled segments, and Fig. 7 is a cement assembly. A side view showing a modified example of the means for attaching F to the inner cylinder, and FIGS. 8 and 9 are perspective views showing modified examples of the segment. 11... Combustion chamber, Minister... Combustion chamber wall (inner cylinder), 14.
...Cooling air, 15...Cooling air introduction hole, I...Fireproof wall, row...Segment, 4...Ceramic piece, J...Cover, 31...Cushion body, 32...
- Ceramic surface, cold 1J air introduction path. Patent applicant: Director of the Agency of Industrial Science and Technology (Figure 3, Figure 4, 82-Figure 6)

Claims (1)

【特許請求の範囲】 (1)板状のセラミックピースと、このセラミックピー
スを保持するカバーと、このカバーとセラミックピース
との間に介装された弾力性のある材料からなるクッショ
ン体とでセグメントを構成し、多数の上記セグメントを
、そのセラミック表面を内側にして、燃焼室壁の内面に
取り付け、これらセグメントによシ耐火壁を形成したこ
とを特徴とするセラミック耐火壁構造の燃焼器。 (支))燃°焼室壁に、冷却空気を燃焼室壁の外側から
セグメントの内側のセラミック表面に導入して、このセ
ラミック表面に冷却空気のフィルムを形成する冷却空気
導入孔が設けられた特許請求の範囲第1項記載のセラミ
ック耐火壁構造の燃焼器。 (3)クッション体は通気性を有し、熱焼室壁の外側か
ら上記クッション体へ冷却空気を導入する冷却空気導入
路が設けられた特許請求の範囲第1項またけ第2項記載
のセラミック耐火壁構造の燃焼器。
[Claims] (1) A segment consisting of a plate-shaped ceramic piece, a cover that holds the ceramic piece, and a cushion body made of an elastic material interposed between the cover and the ceramic piece. A combustor having a ceramic fireproof wall structure, characterized in that a large number of the above-mentioned segments are attached to the inner surface of a combustion chamber wall with their ceramic surfaces facing inside, and these segments form a fireproof wall. (support)) Cooling air inlet holes are provided in the combustion chamber wall to introduce cooling air from the outside of the combustion chamber wall to the ceramic surface inside the segment, forming a film of cooling air on this ceramic surface. A combustor having a ceramic refractory wall structure according to claim 1. (3) The cushion body has air permeability and is provided with a cooling air introduction path for introducing cooling air into the cushion body from the outside of the heat-burning chamber wall. Combustor with ceramic firewall structure.
JP15007882A 1982-08-31 1982-08-31 Burner having ceramic refractory wall structure Granted JPS5941716A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15007882A JPS5941716A (en) 1982-08-31 1982-08-31 Burner having ceramic refractory wall structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15007882A JPS5941716A (en) 1982-08-31 1982-08-31 Burner having ceramic refractory wall structure

Publications (2)

Publication Number Publication Date
JPS5941716A true JPS5941716A (en) 1984-03-08
JPS6242213B2 JPS6242213B2 (en) 1987-09-07

Family

ID=15489031

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15007882A Granted JPS5941716A (en) 1982-08-31 1982-08-31 Burner having ceramic refractory wall structure

Country Status (1)

Country Link
JP (1) JPS5941716A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05507333A (en) * 1990-07-17 1993-10-21 シーメンス アクチエンゲゼルシヤフト Tubing, especially flame tubes, with an inner area for hot gas induction
EP1126221A1 (en) * 2000-02-17 2001-08-22 Siemens Aktiengesellschaft Padded refactory tile as liner for a gas turbine combustor
CN106247400A (en) * 2015-06-08 2016-12-21 A.S.En.安萨尔多开发能源有限责任公司 The fixing device of adiabatic brick and tile for the combustor of gas turbine

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05507333A (en) * 1990-07-17 1993-10-21 シーメンス アクチエンゲゼルシヤフト Tubing, especially flame tubes, with an inner area for hot gas induction
EP1126221A1 (en) * 2000-02-17 2001-08-22 Siemens Aktiengesellschaft Padded refactory tile as liner for a gas turbine combustor
WO2001061250A1 (en) * 2000-02-17 2001-08-23 Siemens Aktiengesellschaft Thermal shield stone and device for lining a combustion chamber, and gas turbine
CN106247400A (en) * 2015-06-08 2016-12-21 A.S.En.安萨尔多开发能源有限责任公司 The fixing device of adiabatic brick and tile for the combustor of gas turbine

Also Published As

Publication number Publication date
JPS6242213B2 (en) 1987-09-07

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