JPS5934350B2 - Seaweed "a" - Google Patents
Seaweed "a"Info
- Publication number
- JPS5934350B2 JPS5934350B2 JP56167960A JP16796081A JPS5934350B2 JP S5934350 B2 JPS5934350 B2 JP S5934350B2 JP 56167960 A JP56167960 A JP 56167960A JP 16796081 A JP16796081 A JP 16796081A JP S5934350 B2 JPS5934350 B2 JP S5934350B2
- Authority
- JP
- Japan
- Prior art keywords
- seaweed
- cage
- affinity
- synthetic resins
- seaweed cage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Landscapes
- Edible Seaweed (AREA)
Description
【発明の詳細な説明】
本発明は海苔簀に関し、詳しくは海苔に対して親和性の
良好な合成樹脂と親和性に乏しい合成樹脂を用いて海苔
簀を構成する箸休もしくはヒゴ体の表面に前記2種以上
の合成樹脂をダイ内もしくはダイ外共押出しで一体成形
により混在配夕Iルで形成せしめた海苔簀に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a seaweed cage, and more specifically, a synthetic resin with good affinity for seaweed and a synthetic resin with poor affinity are used to form a seaweed cage on the surface of a seaweed cage or seaweed body. The present invention relates to a seaweed cage formed by integrally molding the above two or more synthetic resins by co-extrusion inside a die or outside a die.
海苔簀は板状の箸休より、もしくは棒状のヒゴ体を編織
することにより形成されるものであり、これらヒゴ体の
素材としてアシ、ヨシ、竹などの天然物から合成樹脂に
代替されるようになってきている。A seaweed cage is formed from a plate-shaped chopstick or by weaving a stick-shaped rod, and synthetic resin is replacing natural materials such as reed, reed, and bamboo as the material for these rod-shaped rods. It is becoming.
しかし、合成樹脂製素材は天然物と異なり、そのま\使
用することには種々問題があり、実用に供せなかった。However, unlike natural materials, synthetic resin materials have various problems when used as is, and have not been put to practical use.
たとえばナイロン、ポリエステル、ポリアクリロニトリ
ル等の海苔との親和性の強い樹脂(以下、親和性樹脂と
いう。For example, resins that have a strong affinity with seaweed (hereinafter referred to as affinity resins) such as nylon, polyester, and polyacrylonitrile.
)からなるものは腰が弱く、実用に供し難く、また他の
樹脂を該親和性樹脂で積層したものや、親和性樹脂の溶
液中に海苔簀用素材を浸漬したものあるいは該親和性樹
脂の溶液を該素材の表面にスプレー塗布(特開昭49−
124270号)もしくは刷毛塗り(特公昭51−14
596号)したもの等は種々の性質の海苔に適応する親
和性があるけれども、このものはぐず海苔等で汚れ易く
、また使用回数が増すにつれて海苔に対する付着性が強
固になり、乾燥した海苔をはがす際に破れや端欠けを生
じ、しかもぐず海苔等の汚れが落ち難く、この汚れが次
回の板海苔製造の際、製品に悪影響を与えるという欠点
があった。) is weak and difficult to put to practical use, and it is difficult to put it into practical use, and it is difficult to use it in practical applications. Spraying the solution onto the surface of the material (Japanese Patent Application Laid-open No. 1987-
124270) or brush painting (Special Publication No. 51-14
No. 596) has an affinity for adapting to seaweed of various properties, but it is easily soiled by dried seaweed, and as the number of times it is used increases, its adhesion to seaweed becomes stronger, making it difficult to remove dried seaweed. It has the disadvantage that it causes tears and chips when peeled off, and it is difficult to remove stains such as Guzu nori, and this stain adversely affects the product when the next time the sheet nori is manufactured.
また、浸漬、スプレー、刷毛塗り等は親水性樹脂溶液中
の樹脂濃度の変化や塗布量の変動等によって親和力が不
均一となり、かつ製品に品質上のバラツキができるとい
う問題点があった。In addition, dipping, spraying, brushing, etc. have the problem that the affinity becomes uneven due to changes in the resin concentration in the hydrophilic resin solution, fluctuations in the amount of coating, etc., and that the quality of the product varies.
一方、ポリスチレン、ポリプロピレン等の海苔との親和
性の弱いまたは無い樹脂(以下、非親和性樹脂という。On the other hand, resins such as polystyrene and polypropylene that have weak or no affinity with seaweed (hereinafter referred to as non-affinity resins).
)は腰が強くて実用的であるけれども、海苔との親和性
が極めて悪いため、該樹脂を素材とした海苔簀の表面に
種々の親和化処理を施す等の改良が必要とされる。) is strong and practical, but it has extremely poor affinity with seaweed, so improvements such as applying various compatibility treatments to the surface of seaweed cages made from this resin are required.
しかし、このような改良を加えても一長一短があって満
足すべきものではなかった。However, even with such improvements, there were advantages and disadvantages, and the results were not satisfactory.
すなわちコロナ放電処理や混酸接触等の酸化処理は適正
な処理条件の設定が難かしく、処理が強いと乾海苔の剥
離が困難になり、逆に処理が弱いと乾海苔が縮んで定形
状の製品が得られず、特にポリオレフィン等を素材とし
たものにコロナ放電処理した場合に、海苔簀の使用中に
海苔との親和性が衰えるという経時変化の問題が生じる
。In other words, it is difficult to set appropriate treatment conditions for oxidation treatments such as corona discharge treatment and mixed acid contact.If the treatment is too strong, it will be difficult to peel off the dried seaweed, and if the treatment is too weak, the dried seaweed will shrink and it will be difficult to obtain a product with a regular shape. In particular, when a material made of polyolefin or the like is subjected to corona discharge treatment, the problem arises that the affinity with seaweed deteriorates over time during use of the seaweed cage.
また、ヒゴ体をパーライト等の親和性付与剤槽中に浸漬
させて該親和性付与剤をヒゴ体全面に付着させる方法(
特公昭44−29391号)は、海苔簀の洗浄や乾海苔
の剥離の際に親和性付与剤が剥離したり摩耗したりして
耐久性に問題がある。Alternatively, a method (
Japanese Patent Publication No. 44-29391) has problems with durability because the affinity-imparting agent peels off or wears away when the seaweed cage is washed or the dried seaweed is peeled off.
さらに、海苔の性状の面から考えると、前記特公昭51
−14596号にも記載されているように、海苔の性質
に応じて調節された付着性と剥離性のバランスのとれた
海苔簀を使用しなければならず、現実には付着性の異な
る数種の海苔簀を使い分けている。Furthermore, considering the properties of seaweed, the
As described in No. 14596, it is necessary to use a seaweed cage that has a well-balanced adhesiveness and removability adjusted according to the properties of the seaweed, and in reality, there are several types of seaweed with different adhesiveness. We use different seaweed cages.
このため、海苔簀の生産にあたっては少量多品種の生産
が要求されている。For this reason, when producing seaweed cages, it is required to produce a wide variety of products in small quantities.
そこで本発明者らは、海苔との付着性と剥離性のバラン
スがとれ、かつ1種の海苔簀用素材で数種の親和性を持
ち、どのような性状の海苔にも適応でき、かつ耐久性の
ある海苔簀を効率よく生産する方法について検討し、本
発明を完成した。Therefore, the present inventors have developed a material that has a good balance between adhesion and removability with seaweed, has several types of compatibility with one type of seaweed cage material, is adaptable to any type of seaweed, and is durable. The present invention was completed after studying a method for efficiently producing a seaweed cage with a high quality of quality.
本発明は合成樹脂製海苔簀において、該海苔簀を構成す
る箸休もしくはヒゴ体の表面に海苔との親和性の異なる
2種以上の合成樹脂をダイ内もしくはダイ外共押し出し
で一体成形により混在配列して形成せしめた海苔簀であ
る。The present invention is a synthetic resin seaweed cage, in which two or more types of synthetic resins having different compatibility with seaweed are mixed on the surface of the chopstick rest or hugo body constituting the seaweed cage by integral molding inside a die or co-extruding outside the die. This is a seaweed cage formed by arranging them.
本発明の海苔簀の製造に用いる合成樹脂を例示すれば、
親和性樹脂としてポリアミド、アイオノマー、ポリエス
テル、ポリカーボネート、塩素化ポリオレフィン、ポリ
アクリロニトリル、エチレン・酢酸ビニル共重合体、ポ
リビニルアルコール。Examples of synthetic resins used for manufacturing the seaweed cage of the present invention include:
Compatible resins include polyamide, ionomer, polyester, polycarbonate, chlorinated polyolefin, polyacrylonitrile, ethylene/vinyl acetate copolymer, and polyvinyl alcohol.
酸変性ホリオレフイン、エチレン・ビニルアルコール共
重合体等がある。Examples include acid-modified polyolefin and ethylene/vinyl alcohol copolymer.
また、非親和性樹脂としてポリオレフィン、ポリスチレ
ン、ポリ塩化ビニル等がある。In addition, non-compatible resins include polyolefin, polystyrene, polyvinyl chloride, and the like.
これら合成樹脂には無機充填剤(炭酸カルシウム、炭酸
マグネシウム、珪藻土、ドロマイト、シリカ、軽石粉、
カオリナイト、クレー。These synthetic resins contain inorganic fillers (calcium carbonate, magnesium carbonate, diatomaceous earth, dolomite, silica, pumice powder,
Kaolinite, clay.
マイカ、モンモリロナイト、 CaSiO3等)、耐候
性付与剤、帯電防止剤、耐熱剤、補強剤、界面活性剤、
滑剤等を適宜添加することができ、その添加量、添加方
法等は常法にしたがって決定すればよい。mica, montmorillonite, CaSiO3, etc.), weather resistance agents, antistatic agents, heat resistant agents, reinforcing agents, surfactants,
A lubricant or the like can be added as appropriate, and the amount and method of addition may be determined according to a conventional method.
本発明では上記合成樹脂のうち親和性の異なる2種以上
のものを用いて箸休あるいはヒゴ体を共押出しにより一
体成形し、その表面に該樹脂が混在するように配列する
ものである。In the present invention, two or more of the above-mentioned synthetic resins having different affinities are integrally molded by co-extrusion to form a cylindrical body or cylindrical body, and the resins are arranged so as to coexist on the surface of the body.
海苔簀を形成するヒゴ体は中実もしくは中空の棒状体で
あり、その外郭断面形状は円形、楕円形。The seaweed bodies that form the seaweed cage are solid or hollow rod-shaped bodies, and their outer cross-sectional shapes are circular or oval.
多角形(三角形、四角形、五角形等)である。It is a polygon (triangle, quadrilateral, pentagon, etc.).
また、箸休は板状体であり、表面に凹凸があり、かつ水
抜き用の孔を有するものが好ましい。Further, it is preferable that the chopstick rest is a plate-shaped body with an uneven surface and holes for draining water.
海苔との親和性が異なる2種以上の合成樹脂の配列は縦
縞状2点状、短線状などがあるけれども、これらに制限
されるものではない。The arrangement of two or more synthetic resins having different affinities with seaweed may be in the form of vertical stripes, two dots, short lines, etc., but is not limited to these.
第2図a ”−’ eおよび第3図a、bはその例示で
ある。Figures 2a''-'e and 3a and 3b are examples thereof.
図面からも明らかなように、通常は非親和性樹脂部4を
マトリックスとしてその表面に親和性樹脂を適宜の形状
に配夕1ルた状態にヒゴ体は形成される。As is clear from the drawings, the rib body is usually formed by using the non-affinity resin portion 4 as a matrix and having the affinity resin arranged in an appropriate shape on the surface thereof.
第4図はシート状箸体にて形成された海苔簀を示してお
り、第5図はその部分詳細図である。FIG. 4 shows a seaweed cage formed of sheet-like chopsticks, and FIG. 5 is a partially detailed view thereof.
箸休もしくはヒゴ体の全表面に占める親和性樹脂部分の
面積比率は5〜70係であることが望ましい。It is desirable that the area ratio of the affinity resin portion to the entire surface of the chopstick rest or higo body is 5 to 70.
この比率が5%未満では海苔との付着性が十分でなく、
70係を超えると全面被覆の場合と同様に海苔簀が汚れ
易くなる。If this ratio is less than 5%, the adhesion to seaweed is insufficient,
When the number exceeds 70, the seaweed basin becomes easily soiled as in the case of full-coverage.
また、縦縞状に配列する場合は条数が3〜8本となるよ
うにすべきである。Moreover, when arranging in vertical stripes, the number of stripes should be 3 to 8.
なお、本発明の海苔簀は箸休もしくはヒゴ体の表面を酸
化処理等の活性化処理を施したものを用いて形成するこ
ともできる。In addition, the seaweed cage of the present invention can also be formed using a material whose surface has been subjected to activation treatment such as oxidation treatment.
本発明の海苔簀は海苔との付着性と剥離性のバランスが
良好であり、しかも表面が海苔との親和1性が異なる2
種以上の合成樹脂で配列されているため、性質の異なる
各種の海苔に対して巾広く適用することができ、作業性
にすぐれている。The seaweed cage of the present invention has a good balance between adhesion and removability with seaweed, and the surface has different compatibility with seaweed (1).
Since it is composed of more than one type of synthetic resin, it can be widely applied to various types of seaweed with different properties, and has excellent workability.
しかも、箸休やヒゴ体の表面は親和性の異なる樹脂が混
在一体となって箸休もしくはヒゴ体を形成しているため
海苔加工作業中に剥離することがなく、耐久性にすぐれ
ている。Moreover, since the surface of the chopstick rest or the higo body is made up of a mixture of resins with different affinities to form the chopstick rest or the higo body, it does not peel off during nori processing work and has excellent durability.
また、海苔簀の製造時の安全性(環境)が非常に高く、
かつ極めて容易に製造できることも本発明の特色である
。In addition, the safety (environment) during the production of seaweed cages is extremely high.
Another feature of the present invention is that it can be manufactured extremely easily.
次に、本発明の実施例を示す。Next, examples of the present invention will be shown.
;実施例 1〜5
親和性樹脂としてアイオノマー樹脂(三井ポリケミカル
(株)製、商品名:ハイミラン1652)あるいはエチ
レン−酢酸ビニル共重合体(東洋曹達工業(株)製、商
品名:ウルトラセンUE630)と非親和性樹脂として
タルク20重量係を含有するメルトインデックスMIが
3.5g/10分のポリプロピレン(出光石油化学(株
)製、商品名:出光ポリプロY−400G)とを第1表
に示す割合でダイ内接着による共押出しで断面六角形の
中空体(外径2−1 mm )のヒゴ体を成形した。Examples 1 to 5 As the affinity resin, an ionomer resin (manufactured by Mitsui Polychemical Co., Ltd., trade name: Himilan 1652) or an ethylene-vinyl acetate copolymer (manufactured by Toyo Soda Kogyo Co., Ltd., trade name: Ultrasen UE630) was used. ) and polypropylene with a melt index MI of 3.5 g/10 min (manufactured by Idemitsu Petrochemical Co., Ltd., trade name: Idemitsu Polypro Y-400G) containing talc 20% by weight as an incompatible resin are shown in Table 1. A hollow body (outer diameter 2-1 mm) with a hexagonal cross section was formed by coextrusion using adhesion within a die at the ratio shown.
なお、アイオノマー樹脂は、断面六角形の各頂点部に長
さ方向にそって縦縞状に配列ルー°体化した。The ionomer resin was arranged in a vertical stripe pattern along the length at each vertex of the hexagonal cross section.
このヒゴ体を定尺切断し、縦29CrrL×横27ぼの
海苔簀を作り、千葉系の海苔漁家で秋芽一番摘みから漁
期終了まで使用し、得られた乾海苔について次の基準で
乾海苔の良否、剥離の難易性、ぐず海苔等による海苔簀
の汚れ等を評価した。This seaweed body was cut to a specified length, and a seaweed cage of 29 CrrL x 27cm was made, which was used by seaweed fishing families in Chiba from the first picking of autumn buds until the end of the fishing season. Quality, difficulty in peeling, staining of the seaweed cage due to guzu seaweed, etc. were evaluated.
その結果を第1表に示す。The results are shown in Table 1.
なお、海苔簀の使用回数は漁期終了まで150回であり
、1回毎に1000枚の海苔簀を用いた。The number of times the seaweed cage was used was 150 times until the end of the fishing season, and 1000 seaweed cages were used each time.
実施例 6
実施例1と同じ原料を用いて共押出後断面六角形のヒゴ
体の全面をコロナ放電処理した。Example 6 After coextrusion using the same raw materials as in Example 1, the entire surface of a hexagonal cross-section was subjected to corona discharge treatment.
次いで、実施例1と同様の海苔簀を作り、同様にして評
価をした。Next, seaweed cages similar to those in Example 1 were made and evaluated in the same manner.
その結果を第1表に示す。比較例 1
実施例1で使用したタルク20重量係を含有するMIが
3.5,9710分のポリプロピレン(出光石油化学(
株)製、商品名:出光ポリプロ¥−400G)を断面六
角形の中空体(外径2.1 mm )のヒゴ体に成形し
、このヒゴ体を定尺切断後縦29crIL×横27Cr
rLの海苔簀を作り、実施例1と同様に評価した。The results are shown in Table 1. Comparative Example 1 Polypropylene (Idemitsu Petrochemical Co., Ltd.
Co., Ltd., product name: Idemitsu Polypro ¥-400G) is molded into a hollow body (outer diameter 2.1 mm) with a hexagonal cross section, and after cutting this frame to a specified length, it is 29 cr IL x 27 cr horizontal.
An rL seaweed cage was made and evaluated in the same manner as in Example 1.
その結果を第1表に示す。比較例 2
実施例1で使用したタルク20重量係を含有するMIが
3.5g/10分のポリプロピレン(出光石油化学(株
)製、商品名:出光ポリプロY −400G)を用い断
面六角形の中空体(外径2.1闘)のヒゴ体を成形し、
このヒゴ体を塩素化ポリプロピレン(山陽国策パルプ(
株)製、商品名ニス−パークロン773H)と酢酸エチ
ル混合した溶液(粘度100cps、25℃)中に通過
させた後風乾してヒゴ体表面に塩素化ポリプロピレン薄
膜を形成せしめた。The results are shown in Table 1. Comparative Example 2 Using polypropylene (manufactured by Idemitsu Petrochemical Co., Ltd., trade name: Idemitsu Polypro Y-400G) containing 20% of talc used in Example 1 and having an MI of 3.5 g/10 minutes, a hexagonal cross-section was used. Molding a hollow body (outer diameter 2.1 mm),
This polypropylene is converted into chlorinated polypropylene (Sanyo Kokusaku Pulp)
After passing through a solution (viscosity: 100 cps, 25° C.) containing a mixture of Nis-Perclone 773H (trade name, manufactured by Co., Ltd.) and ethyl acetate, the sample was air-dried to form a chlorinated polypropylene thin film on the surface of the polypropylene body.
以下、実施例1と同様にして海苔簀を作り、評価した。Hereinafter, seaweed cages were made and evaluated in the same manner as in Example 1.
その結果を第1表に示す。The results are shown in Table 1.
比較例 3
比較例1および2で得られたヒゴ体を交互に編織し、実
施例1と同様にして海苔簀を作り、評価した。Comparative Example 3 The bamboo bodies obtained in Comparative Examples 1 and 2 were alternately knitted and woven to make a seaweed cage in the same manner as in Example 1, and evaluated.
その結果を第1表に示す。The results are shown in Table 1.
第1図は海苔簀の概略説明図、第2図a ”’−eはヒ
ゴ体の断面図、第3図a、bはヒゴ体の外表面の部分的
見取図、第4図は箸休の概略説明図、第5図は第4図の
部分詳細図である。
1・・・・・・ヒゴ体、2・・・・・・編織糸、3・・
・・・・端物、4・・・・・・非親和性樹脂部、5・・
・・・・親和性樹脂部、6・・・・・・水抜き千1Figure 1 is a schematic explanatory diagram of a seaweed cage, Figure 2 a''-e is a cross-sectional view of the higo body, Figure 3 a and b are partial sketches of the outer surface of the higo body, and Figure 4 is a chopstick rest. A schematic explanatory drawing, Fig. 5 is a partial detailed view of Fig. 4. 1... Thread body, 2... Knitting yarn, 3...
...Fundamentals, 4...Non-affinity resin part, 5...
...Affinity resin part, 6...Water removal 1,1
Claims (1)
休もしくはヒゴ体の表面に海苔との親和性の異なる2種
以上の合成樹脂をダイ内もしくはダイ外共押出しで一体
成形により混在配夕1ルで形成せしめたものである海苔
簀。 2 海苔簀表面に酸化処理等の活性化処理を施したもの
である特許請求の範囲第1項記載の海苔簀。 3 海苔との親和性の異なる2種以上の合成樹脂の配列
が縦縞状である特許請求の範囲第1項記載の海苔簀。 4 海苔との親和性の異なる2種以上の合成樹脂の配列
が点もしくは短線状である特許請求の範囲第1項記載の
海苔簀。 5 箸休もしくはヒゴ体の表面に占める親和性樹肪部分
が5〜70係である特許請求の範囲第1〜4項のいずれ
かに記載の海苔簀。[Scope of Claims] 1. In a synthetic resin material cage, two or more types of synthetic resins having different compatibility with seaweed are extruded inside or outside the die on the surface of the chopsticks or hugo bodies constituting the nori cage. A seaweed cage made of a single piece of mixed material by integral molding. 2. The seaweed cage according to claim 1, wherein the surface of the seaweed cage has been subjected to activation treatment such as oxidation treatment. 3. The seaweed cage according to claim 1, wherein the two or more types of synthetic resins having different affinities for seaweed are arranged in a vertical stripe pattern. 4. The seaweed cage according to claim 1, wherein the two or more types of synthetic resins having different affinities for seaweed are arranged in the form of dots or short lines. 5. The seaweed cage according to any one of claims 1 to 4, wherein the number of affinity resin portions on the surface of the chopsticks or lizard bodies is 5 to 70.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56167960A JPS5934350B2 (en) | 1981-10-22 | 1981-10-22 | Seaweed "a" |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56167960A JPS5934350B2 (en) | 1981-10-22 | 1981-10-22 | Seaweed "a" |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5871875A JPS5871875A (en) | 1983-04-28 |
JPS5934350B2 true JPS5934350B2 (en) | 1984-08-22 |
Family
ID=15859226
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56167960A Expired JPS5934350B2 (en) | 1981-10-22 | 1981-10-22 | Seaweed "a" |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5934350B2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2522697B2 (en) * | 1989-03-17 | 1996-08-07 | 博俊 樋口 | Seaweed |
JPH0595292U (en) * | 1991-02-28 | 1993-12-27 | 全国海苔貝類漁業協同組合連合会 | Seaweed |
JP6295109B2 (en) * | 2014-03-12 | 2018-03-14 | 有限会社金子商会 | Nori seaweed and method for drying nori using it |
JP7112781B1 (en) * | 2021-07-15 | 2022-08-04 | 株式会社イツワ工業 | Dried seaweed conveying method and dried seaweed conveying spacer |
-
1981
- 1981-10-22 JP JP56167960A patent/JPS5934350B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS5871875A (en) | 1983-04-28 |
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