JPS5920479A - Acidic detergent composition - Google Patents
Acidic detergent compositionInfo
- Publication number
- JPS5920479A JPS5920479A JP12788682A JP12788682A JPS5920479A JP S5920479 A JPS5920479 A JP S5920479A JP 12788682 A JP12788682 A JP 12788682A JP 12788682 A JP12788682 A JP 12788682A JP S5920479 A JPS5920479 A JP S5920479A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- cleaning
- detergent composition
- weight
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 8
- 239000003599 detergent Substances 0.000 title claims abstract 5
- 239000002253 acid Substances 0.000 claims abstract description 26
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000007522 mineralic acids Chemical class 0.000 claims description 8
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- -1 sulfamic acid Chemical compound 0.000 abstract description 6
- 235000015165 citric acid Nutrition 0.000 abstract description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010775 animal oil Substances 0.000 abstract description 2
- 239000003945 anionic surfactant Substances 0.000 abstract description 2
- 239000003093 cationic surfactant Substances 0.000 abstract description 2
- 239000004519 grease Substances 0.000 abstract description 2
- 239000007769 metal material Substances 0.000 abstract description 2
- 239000002480 mineral oil Substances 0.000 abstract description 2
- 235000010446 mineral oil Nutrition 0.000 abstract description 2
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002736 nonionic surfactant Substances 0.000 abstract description 2
- 239000011975 tartaric acid Substances 0.000 abstract description 2
- 235000002906 tartaric acid Nutrition 0.000 abstract description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 2
- 239000008158 vegetable oil Substances 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 3
- 239000002689 soil Substances 0.000 abstract 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 abstract 1
- 239000012164 animal wax Substances 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 33
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000010960 cold rolled steel Substances 0.000 description 2
- 239000013066 combination product Substances 0.000 description 2
- 229940127555 combination product Drugs 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- FCKYPQBAHLOOJQ-UHFFFAOYSA-N Cyclohexane-1,2-diaminetetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)C1CCCCC1N(CC(O)=O)CC(O)=O FCKYPQBAHLOOJQ-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- SQVRNKJHWKZAKO-UHFFFAOYSA-N beta-N-Acetyl-D-neuraminic acid Natural products CC(=O)NC1C(O)CC(O)(C(O)=O)OC1C(O)C(O)CO SQVRNKJHWKZAKO-UHFFFAOYSA-N 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- SQVRNKJHWKZAKO-OQPLDHBCSA-N sialic acid Chemical compound CC(=O)N[C@@H]1[C@@H](O)C[C@@](O)(C(O)=O)OC1[C@H](O)[C@H](O)CO SQVRNKJHWKZAKO-OQPLDHBCSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Abstract
Description
【発明の詳細な説明】 本発明は酸性洗浄剤組成物に関する。[Detailed description of the invention] The present invention relates to acidic cleaning compositions.
従来から、酸性洗浄には、
（イ） 金属材料の高温加工や焼鈍を行うと生ずるスケ
ールの除去を目的としたピックリング、ｔｏ＋ スケ
ールを除去した後も生成する錆ヤ酸化膜を除去する酸浸
洗、
Ｐｌ ボイラー等の缶石−？錆を除去する酸洗浄があ
る。鋼材の酸性洗浄の場合、錆スケールの除去と共に、
条件により鋼材素地、そのものも浸食され酸霧の他、水
素ゼイ化、表面変色などの障害が起こる。これ等を防止
するため、分子構造内にＮ、Ｓを包む抑制剤を併用する
場合が多い。Traditionally, acid cleaning includes (a) pickling, which is used to remove scale that occurs when metal materials are processed or annealed at high temperatures; Washing, Pl Capstone for boilers, etc.? There is acid cleaning to remove rust. In the case of acid cleaning of steel materials, along with the removal of rust scale,
Depending on the conditions, the steel material itself can also be eroded, causing problems such as acid fog, hydrogen zeification, and surface discoloration. In order to prevent this, inhibitors containing N and S in the molecular structure are often used together.
酸性洗浄の対称となる汚れはスケール、錆、イ丘石等で
あるが、はとんどの場合、前工程等よりの動植物油、鉱
油グリス、ロウおよびそれ等の炭化物などの汚れと複合
されている場合が多くみかけられる。The stains targeted by acid cleaning include scale, rust, and stone, but in most cases, they are compounded with stains from previous processes such as animal and vegetable oils, mineral oil grease, wax, and their carbides. It is often seen that there are.
酸性洗浄には、硫酸、塩酸、リン酸等の無機酸が広く、
単独もしくは混合液で使用される〃；、場合により、シ
＝つ酸、クエン酸等有機酸および界面活性剤が単独系ま
たは併用で鉱酸と共に使用されている。For acidic cleaning, inorganic acids such as sulfuric acid, hydrochloric acid, and phosphoric acid are widely used.
In some cases, organic acids such as citric acid and citric acid and surfactants are used alone or in combination with mineral acids.
いずれの場合も、単独の汚れに対しては、スケ−／し除
去性、除錆性は実用に供し得る場合が多いが、複合汚れ
の場合、充分な効果を発揮することは難しい。In either case, when it comes to single stains, the scale/scale removal and rust removal properties are often practical, but when it comes to complex stains, it is difficult to achieve a sufficient effect.
木発明者は、これらの問題点を解消すべく鋭意研究の結
果、本発明に到達したものである。すなわち、無機酸ま
たは含窒素酸（０−９０重量部）、オキシカルボン酸（
５−８０重量部）、アミノカルボン酸（２−４０重量部
）および界面活性剤（０，５−１５重量部）を含有する
ことを特徴とする酸性洗浄剤組成物を提供するものであ
る。The inventor of the tree arrived at the present invention as a result of intensive research to solve these problems. That is, inorganic acids or nitrogen-containing acids (0-90 parts by weight), oxycarboxylic acids (
5-80 parts by weight), an aminocarboxylic acid (2-40 parts by weight) and a surfactant (0.5-15 parts by weight).
本発明組成物は、
（１） 複合汚れに対し有効なスケール除去、除錆お
よび洗浄性を示し、
（２） 洗浄時間の短縮
（３） 洗浄温度の低下
を可能にしたものである。The composition of the present invention (1) exhibits effective scale removal, rust removal, and cleaning properties for complex stains, (2) shortens cleaning time, and (3) makes it possible to lower cleaning temperature.
木発明において、無機酸または含窒素酸としては、硫酸
、塩酸、リン酸等の無機酸およびスルファミン酸に代表
される含窒素酸である。In the invention, the inorganic acids or nitrogen-containing acids include inorganic acids such as sulfuric acid, hydrochloric acid, and phosphoric acid, and nitrogen-containing acids typified by sulfamic acid.
オキシカルボン酸としては、シーウ酸、クエン酸、酒石
酸、グルコン酸、リンゴ酸、乳酸、グリコール酸などの
オキシカルボン酸である。Examples of the oxycarboxylic acid include sialic acid, citric acid, tartaric acid, gluconic acid, malic acid, lactic acid, and glycolic acid.
アミノカルボン酸としては、ＮＴＡにトリロ３０Ｆ酸）
、ＥＤＴＡ（エチレンジアミン４Ａ％酸）、’ＤＴＰ
Ａ（ジエチにントリアミン５酢酸） 、ＧＨＤＴＡ（グ
ライコールエーテルジアミン４バト酸）、０ＹＩ）ＴＡ
（１、２シクロヘキサンジアミン４酢酸）などのアミノ
ポリカルボン酸である。As aminocarboxylic acids, NTA and trilo-30F acid)
, EDTA (ethylenediamine 4A% acid), 'DTP
A (diethyltriaminepentaacetic acid), GHDTA (glycol etherdiaminetetrabutyric acid), 0YI)TA
(1,2 cyclohexanediaminetetraacetic acid) and other aminopolycarboxylic acids.
界面活性剤としては、ポリオキシエチレンアルキルエー
テル型、ポリオキシエチレンアルキルエールエーテル等
の非イオン界面活性剤、ポリオキシエチレンアルキ）Ｖ
またはアルキルフェニルｌ−７−／”硫酸エステル、ポ
リオキシエチレンアルキルまたはアルキルフェニルエー
テルリン酸エステル等のアニオン界面活性剤、アルキル
アンモニウム塩型、ピリジニウム塩型およびアミン型カ
チオン界面活性剤、アルキルカルボキンベタイン型、ア
ルキルアミノカルボン酸型。Examples of surfactants include nonionic surfactants such as polyoxyethylene alkyl ether type and polyoxyethylene alkyl ether, polyoxyethylene alkyl ether, etc.
or anionic surfactants such as alkylphenyl l-7-/'' sulfuric esters, polyoxyethylene alkyl or alkylphenyl ether phosphates, alkylammonium salt type, pyridinium salt type and amine type cationic surfactants, alkylcarboxine betaine type, alkylaminocarboxylic acid type.
アルキルイミダシリン型の両性界面活性剤を挙げること
ができる。Mention may be made of amphoteric surfactants of the alkylimidacillin type.
寸だ、本発明組成物に、場合により市販の抑制剤を併用
してもさしつかえない。Indeed, a commercially available inhibitor may optionally be used in combination with the composition of the present invention.
次に、本発明組成物の組成割合を説明する。Next, the composition ratio of the composition of the present invention will be explained.
無機酸または含窒素酸は０−９０重量部（単独もしくは
複数併用可能ρであり、９０重量部以上ではオキシカル
ボン酸およびアミノポリカルボン酸の量が少なくなり、
洗浄性に劣る。The inorganic acid or nitrogen-containing acid is 0 to 90 parts by weight (ρ can be used alone or in combination of two or more, and if it is 90 parts by weight or more, the amount of oxycarboxylic acid and aminopolycarboxylic acid will decrease,
Poor cleaning performance.
オキシカルボン酸ば５−８０重量部（単独もしくは複数
併用可能）であり、５重量部以下では洗浄性に劣る。The amount of oxycarboxylic acid is 5 to 80 parts by weight (can be used alone or in combination), and if it is less than 5 parts by weight, the cleaning performance is poor.
アミノポリカルボン酸１ｄ２−４０重量部（単独もしく
け複数併用可能）であり、２重量部以下では洗浄性に劣
る。The amount of aminopolycarboxylic acid is 1d2-40 parts by weight (can be used alone or in combination), and if it is less than 2 parts by weight, the cleaning performance is poor.
界面活性剤は０．５−１５ｍｍ部（単独もしくは複数併
用可能）であり、０．５重量部、以下では洗浄性に劣る
。The surfactant should be used in an amount of 0.5-15 mm (single or in combination), and if it is less than 0.5 part by weight, the detergency will be poor.
本発明組成物はその使用目的に応じ１−５０倍の希釈濃
度に調整し、酸性洗浄用途に供することにより、あらゆ
る酸性洗浄における複合汚れに対し、優れたスケール除
去性、除錆性、洗浄性を示し、かつまた、洗浄時間の短
縮、洗浄温度の低下を可能とする。The composition of the present invention can be adjusted to a diluted concentration of 1 to 50 times depending on the purpose of use and used for acidic cleaning, and has excellent scale removal properties, rust removal properties, and cleaning properties against complex stains in all types of acidic cleaning. This also makes it possible to shorten the cleaning time and lower the cleaning temperature.
次に、実施例によって木発明を詳＋ＴＩＩＩに説明する
。Next, the tree invention will be explained in detail using examples.
（部、％は重量基準を示す）
実施例１
第１表に示す各配合量（重量部）に基づき、洗浄Ｍ組成
物を調製した。(Parts and % are based on weight) Example 1 A cleaning M composition was prepared based on the amounts (parts by weight) shown in Table 1.
第１表
※ ＨＬＢ １２
効果例１
下記に示す試験方法により、洗浄ｍ１組成物のスケール
除去性能力ヌトを行い、洗浄性（％）を第２表に示した
。Table 1 * HLB 12 Effect Example 1 The scale removal ability of the cleaning m1 composition was tested using the test method shown below, and the cleaning performance (%) is shown in Table 2.
０被洗浄鈑の調製
冷間圧延鋼銀（ＪＩＳ Ｇ−３１４１） （長さ１３０
朋Ｘ幅１００朋×厚さ０．３朋）にステアリン酸カルシ
ウムをＩ ｎ？当り５０ｇ塗布し、５００℃電気炉にて
３０秒加熱し、冷却後テストに供する。0 Preparation of plate to be cleaned Cold rolled steel silver (JIS G-3141) (Length 130
Calcium stearate was added to the surface (width: 100 mm x thickness: 0.3 mm). 50g per coat was applied, heated in an electric furnace at 500°C for 30 seconds, cooled, and then tested.
０洗浄液 不発明品ハ１１比較配合品盃ｌおよび １’ａ ４の各々組成物を イ）無機酸を１０倍希釈に調製した 口）無機酸以外の成分を調製し、イ）溶液に配合した。0 cleaning liquid Uninvented product C11 Comparative combination product cup L and Each composition of 1'a 4 b) The inorganic acid was diluted 10 times. (1) Prepare components other than the inorganic acid, and (2) mix them into the solution.
０洗 浄
洗浄温度６０−８０℃に調整し、被洗浄鋼販を１０分間
浸漬洗浄した。0 Cleaning The cleaning temperature was adjusted to 60-80°C, and the steel plate to be cleaned was immersed and cleaned for 10 minutes.
０評価方法
洗浄後、被洗浄板を４０’０ ２００胃１／ｓｅａの流
水中で３０秒間水洗し、肉眼判定に供す。0 Evaluation Method After cleaning, the plate to be cleaned is washed in running water of 40'0 200 stomach 1/sea for 30 seconds and subjected to visual evaluation.
第２表
効果例２
下記試＃方法により、洗浄剤組成物の除錆性能テストを
行い、洗浄性（％）を第３表に示した。Table 2 Effect Example 2 The rust removal performance of the cleaning composition was tested using the following test method, and the cleaning performance (%) is shown in Table 3.
○被洗浄板の調整
冷間圧延鋼銀をメタケイ酸ナトリウム
３０ｇ＃Ｘ８０℃で脱脂し、充分に水洗した後、屋外に
５日間放置し、発錆せ１−７め、１ゴ当りｌｏｇの大豆
油を塗布し、洗浄テストに供する。○Adjustment of the plate to be cleaned Degrease cold rolled steel silver with 30g of sodium metasilicate at 80°C, wash thoroughly with water, and leave it outdoors for 5 days. Apply soybean oil and test for cleaning.
０洗浄液
本発明品ＩＦｚ ２、比較配合品ＩＦｚ ２ 、ＩＦｉ
、、５の各々組成物を
イ）無機酸を１０倍希釈に調整した
口）無機酸以外の成分を調整し、イ）溶液に配合した。0 Cleaning liquid Invention product IFz 2, Comparative combination product IFz 2, IFi
Each of the compositions of .
０洗 浄 常温下にて、被洗浄鋼販を５〜２０分浸漬洗浄した。0 washing The steel plate to be cleaned was immersed and cleaned for 5 to 20 minutes at room temperature.
０評価方法
洗浄後、被洗浄板を４０Ｃ２００ｇ１／ｓｅＣ；の流水
中で３０秒間水洗し、肉眼判定に供す。0 Evaluation Method After cleaning, the plate to be cleaned is washed in running water of 40C200g1/sec for 30 seconds and subjected to visual evaluation.
第３表
０水アカの洗浄性能テスト
長年使用している英験用ガラス製リービッヒ冷却管を（
サビ、無機質付着）゛本発明品１’ａ ３、比較配合品
点３各々の２０倍希釈品および水中に各々入れ、常温下
２４Ｈ劫Ｓ後の状態を観る。Table 3 0 Water scale cleaning performance test The glass Liebig cooling tube that I have been using for many years (
(Rust, inorganic adhesion) 20 times diluted products of the present invention product 1'a 3 and comparative formulation point 3 were placed in water and their condition was observed after 24 hours of cooling at room temperature.
本発明品の場合、ガラス表面に残存している物質は認め
られず、透明性を呈したが、比較配合品は残存物質が認
められ、また水中の場合は全く変らなかった。In the case of the product of the present invention, no substances remaining on the glass surface were observed and it exhibited transparency, whereas in the case of the comparative formulation, residual substances were observed, and there was no change at all when submerged in water.
以上本発明配合品は、複数の汚れに対し優れた洗浄性を
示し、かつまた、効果例１でみられる様に、洗浄液の低
温化も計れ、効果例２でみられる様に、洗浄時間の短縮
も計れることがわかる。As described above, the compounded product of the present invention exhibits excellent cleaning performance against multiple types of stains, and as seen in Effect Example 1, the cleaning solution can be lowered in temperature, and as seen in Effect Example 2, the cleaning time can be reduced. It turns out that shortening can also be measured.
出願人 第−工業製＠株式会計applicant No.-Kogyo Seisaku@Stock Accounting
Claims (1)
ボン酸（５−８０重量部）、アミノカルボン酸（２−４
０重量部）および界面活性剤（０，５−１５重量部）を
含有することを特徴とする酸性洗浄剤組成物。[Claims] ^i Inorganic acid or nitrogen-containing t (0-90 parts by weight), oxycarboxylic acid (5-80 parts by weight), aminocarboxylic acid (2-4 parts by weight)
An acidic detergent composition characterized in that it contains (0.0 parts by weight) and a surfactant (0.5-15 parts by weight).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12788682A JPS5920479A (en) | 1982-07-21 | 1982-07-21 | Acidic detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12788682A JPS5920479A (en) | 1982-07-21 | 1982-07-21 | Acidic detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS5920479A true JPS5920479A (en) | 1984-02-02 |
Family
ID=14971081
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12788682A Pending JPS5920479A (en) | 1982-07-21 | 1982-07-21 | Acidic detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5920479A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6293385A (en) * | 1985-10-17 | 1987-04-28 | Dai Ichi Kogyo Seiyaku Co Ltd | Pretreating agent composition for metallic surface |
| JPH03211292A (en) * | 1990-01-12 | 1991-09-17 | Hitachi Aic Inc | Metal surface treating solution |
| JP2000063890A (en) * | 1998-08-25 | 2000-02-29 | Takeshi Sugimoto | Detergent for artificial, tooth and drain pipe such as dental saliva-discharging ball etc. |
| EP1213343A1 (en) * | 2000-12-07 | 2002-06-12 | Heidelberger Bauchemie GmbH Marke Deitermann | Cleaning agent and use thereof |
| US6670312B2 (en) | 2000-12-08 | 2003-12-30 | Takeshi Sugimoto | Composition for removal of calcium or magnesium compounds from an article |
| JPWO2002066385A1 (en) * | 2001-02-21 | 2004-06-17 | 株式会社セイワ・プロ | Scale remover attached to titanium material |
| JPWO2003040282A1 (en) * | 2001-11-09 | 2005-03-03 | 次郎 櫻井 | Detergent for metal products |
| JP2006083376A (en) * | 2004-08-18 | 2006-03-30 | Mitsubishi Gas Chem Co Inc | Cleaning liquid and cleaning method |
| CN103422107A (en) * | 2013-08-23 | 2013-12-04 | 苏州长盛机电有限公司 | Method for processing rusty chains |
| CN106222678A (en) * | 2016-08-27 | 2016-12-14 | 合肥普庆新材料科技有限公司 | A kind of aluminium degreasing agent of suppression corrosion containing cardanol polyoxyethylene ether and preparation method thereof |
| JP2017031267A (en) * | 2015-07-30 | 2017-02-09 | 独立行政法人国立高等専門学校機構 | Scale remover for stainless steel |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4982537A (en) * | 1972-11-24 | 1974-08-08 |
-
1982
- 1982-07-21 JP JP12788682A patent/JPS5920479A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4982537A (en) * | 1972-11-24 | 1974-08-08 |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6293385A (en) * | 1985-10-17 | 1987-04-28 | Dai Ichi Kogyo Seiyaku Co Ltd | Pretreating agent composition for metallic surface |
| JPH03211292A (en) * | 1990-01-12 | 1991-09-17 | Hitachi Aic Inc | Metal surface treating solution |
| JP2000063890A (en) * | 1998-08-25 | 2000-02-29 | Takeshi Sugimoto | Detergent for artificial, tooth and drain pipe such as dental saliva-discharging ball etc. |
| EP1213343A1 (en) * | 2000-12-07 | 2002-06-12 | Heidelberger Bauchemie GmbH Marke Deitermann | Cleaning agent and use thereof |
| US6670312B2 (en) | 2000-12-08 | 2003-12-30 | Takeshi Sugimoto | Composition for removal of calcium or magnesium compounds from an article |
| JPWO2002066385A1 (en) * | 2001-02-21 | 2004-06-17 | 株式会社セイワ・プロ | Scale remover attached to titanium material |
| JPWO2003040282A1 (en) * | 2001-11-09 | 2005-03-03 | 次郎 櫻井 | Detergent for metal products |
| JP2006083376A (en) * | 2004-08-18 | 2006-03-30 | Mitsubishi Gas Chem Co Inc | Cleaning liquid and cleaning method |
| CN103422107A (en) * | 2013-08-23 | 2013-12-04 | 苏州长盛机电有限公司 | Method for processing rusty chains |
| JP2017031267A (en) * | 2015-07-30 | 2017-02-09 | 独立行政法人国立高等専門学校機構 | Scale remover for stainless steel |
| CN106222678A (en) * | 2016-08-27 | 2016-12-14 | 合肥普庆新材料科技有限公司 | A kind of aluminium degreasing agent of suppression corrosion containing cardanol polyoxyethylene ether and preparation method thereof |
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