JPS59204525A - Preparation of synthetic resin coated pipe - Google Patents

Preparation of synthetic resin coated pipe

Info

Publication number
JPS59204525A
JPS59204525A JP58079836A JP7983683A JPS59204525A JP S59204525 A JPS59204525 A JP S59204525A JP 58079836 A JP58079836 A JP 58079836A JP 7983683 A JP7983683 A JP 7983683A JP S59204525 A JPS59204525 A JP S59204525A
Authority
JP
Japan
Prior art keywords
synthetic resin
coated
metal
pipe
spacer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58079836A
Other languages
Japanese (ja)
Inventor
Takemi Ishihara
石原 武美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takiron Co Ltd
Original Assignee
Takiron Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takiron Co Ltd filed Critical Takiron Co Ltd
Priority to JP58079836A priority Critical patent/JPS59204525A/en
Publication of JPS59204525A publication Critical patent/JPS59204525A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • B29C48/151Coating hollow articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To contrive the enhancement of productivity, by coating the outer peripheral surfaces of metal pipes with a synthetic resin in such a state that spacers are interposed between adjacent end parts of said metal pipes. CONSTITUTION:Metal pipes 5 each cut into a predetermined dimension are sent in a longitudinally arranged state so as to leave small gaps (l) and spacers 6 are interposed between the metal pipes 5 prior to entering the crosshead die 9 of an extrusion molding machine 8. In this crosshead die 9, the outer peripheries of the metal pipes 5, 5 are coated with a synthetic resin in such a state that the mutually adjacent metal pipes 5, 5 pinch the spacers 6 and, after cooling, the central part of each spacer 6 is cut to obtain a synthetic resin coated pipes. By this method, the synthetic resin coated pipe can be mass-produced by using the metal pipe having an outer diameter of about 10-30mm..

Description

【発明の詳細な説明】 この発明は、芯材に金属管を用いた合成樹脂被覆パイプ
の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method of manufacturing a synthetic resin-coated pipe using a metal pipe as a core material.

本出願人は、金属線材の外周面に合成樹脂を被覆し、両
端に腐食防止用の管端キャップを接着剤などで被着した
従来の合成樹脂被覆支柱に代わって、製造コストが低く
、生産性が良(、しかも管端キャップの脱落の虞のない
という点で優れた合成樹脂被覆支柱を提供するために、
先に特願昭57−188791号の中で、管端キャップ
の被着を要しない農園芸支柱及びその製造法について開
示したが、このものは長尺の金属線材を所定の長さに切
断し、この切断された金属線材を小間隙をあけて縦列状
態に保持して次々と押出成形機のクロスへソドダイに供
給して、各金属線材の外周面と前後に隣合う各金属線材
の端面間に合成樹脂を充填被覆し、しかる後に各合成樹
脂充填部分を中央で切断するものであった。
The applicant has developed a new method that reduces manufacturing costs and improves productivity in place of the conventional synthetic resin-coated struts, in which the outer circumferential surface of a metal wire is coated with synthetic resin, and tube end caps for preventing corrosion are attached to both ends with adhesive. In order to provide a synthetic resin-coated support that has good properties (and there is no risk of the tube end cap falling off),
Previously, in Japanese Patent Application No. 57-188791, we disclosed an agricultural and horticultural support that does not require the attachment of tube end caps, and a method for manufacturing the same. The cut metal wires are held in a vertical line with a small gap between them, and are fed one after another to the cross of the extrusion molding machine, so that the distance between the outer circumferential surface of each metal wire and the end surface of each adjacent metal wire The parts were filled with synthetic resin and then each part filled with synthetic resin was cut at the center.

つまり、この方法は、直径が7〜8mよりも小さい鉄や
アルミなどの線材を用いて農園芸用支柱などに使用され
る合成樹脂被覆パイプを製造する方法を開示したもので
、このような方法を直径が7〜8fiよりも大きい金属
管に通用する場合には、隣接する端部間に多量の合成樹
脂を流入充填しなければならず、しかもその充填時には
金属管の内部に合成樹脂が多量に入り込んで隣接する両
端部を十分に被覆出来ないなどの問題があった。
In other words, this method discloses a method for manufacturing synthetic resin-coated pipes used for agricultural and horticultural supports, etc., using wire rods such as iron and aluminum with a diameter smaller than 7 to 8 m. If this is applied to a metal tube with a diameter larger than 7 to 8 fi, a large amount of synthetic resin must be injected and filled between the adjacent ends, and when filling, a large amount of synthetic resin will be inside the metal tube. There was a problem that it could not sufficiently cover both ends of the adjoining ends.

また、特願昭57−188791号には、予め所定の長
さに切断された金属管を芯材として用い、その各々の金
属管の対向する開口部に突部を両端に有した合成樹脂の
栓体を挿嵌させて、金属管同士を縦列状態に接続させ、
押出成形機のクロスへラドダイに供給してこれら金属管
に栓体を挿嵌させたままの状態でその外周面より合成樹
脂を被覆し、しかる後に、栓体の中央部を切断して同様
な合成樹脂支柱を製造する方法が提案されている。
Furthermore, Japanese Patent Application No. 57-188791 discloses that a metal tube cut into a predetermined length in advance is used as a core material, and each of the metal tubes is made of synthetic resin having protrusions at both ends at opposing openings. Insert the stopper and connect the metal pipes in tandem,
The cloth of the extrusion molding machine is fed to the RAD die, and with the plugs still inserted into these metal tubes, synthetic resin is coated from the outer peripheral surface of the metal tubes, and then the center part of the plugs is cut and the same process is carried out. A method of manufacturing synthetic resin struts has been proposed.

しかしながら、この提案された方法は、合成樹脂の栓体
にある程度の精度を要し、このため金属管に応じた径の
栓体をあらかじめ別工程で製造して用意しなければなら
ず、やはり生産性の面からいって改善の余地があった。
However, this proposed method requires a certain degree of precision for the synthetic resin stopper, and for this reason, the stopper with a diameter that corresponds to the metal tube must be prepared in advance in a separate process, which also results in production From a gender perspective, there was room for improvement.

そこで、この発明は、このような従来の方法の有する問
題を解決するためなされたもので、金属管を芯材とした
合成樹脂被覆パイプの改善された製造方法を提供するも
ので、一層化産性に優れ、かつ−N製造コストの安価な
合成樹脂被覆パイプを製造する方法を提供するものであ
る。
Therefore, this invention was made to solve the problems of the conventional methods, and provides an improved manufacturing method for synthetic resin-coated pipes using metal pipes as the core material, thereby further promoting industrialization. The object of the present invention is to provide a method for manufacturing a synthetic resin-coated pipe that has excellent properties and is inexpensive in -N manufacturing cost.

以下、その製造方法を第1図〜第3図を参照しながら説
明する。
Hereinafter, the manufacturing method will be explained with reference to FIGS. 1 to 3.

第1図は、この発明方法に用いる連続製造装置の概略構
成を示すもので、1は平板から管を形成するための造管
装置、2は金属管の外表面に付着した錆や油等を除去す
るための処理機、3は後の工程において被覆する合成樹
脂の種類に応じて種々な接着剤を塗布するための接着剤
塗布機であり、これらは良く知られた方法で使用されて
金属管にいわゆる前処理を施す。
Figure 1 shows the schematic configuration of the continuous manufacturing equipment used in the method of this invention. 1 is a pipe making equipment for forming pipes from flat plates; 2 is a pipe making equipment for removing rust, oil, etc. attached to the outer surface of metal pipes; 3 is an adhesive applicator for applying various adhesives depending on the type of synthetic resin to be coated in the subsequent process, and these are used in a well-known manner to remove metals. The tube is subjected to a so-called pretreatment.

前処理の施された鉄、アルミニウムなどより成る長尺の
金属管5は、次いでカッター4によって所定寸法に切断
され、さらにその切断部の端縁5aは先革状に圧潰され
る。ここで、この圧潰処理は次の工程で使用される合成
樹脂スペーサ6の介挿時に該スペーサ6の両端部が金属
管5の内空部5bに入り込んでしまわないようにするた
めなされるもので、したがってカッター4による切断時
に金属管5の切断部の端縁5aが先革状の粗面になるよ
うな場合にはあえて施す必要がない。
The pretreated long metal tube 5 made of iron, aluminum, or the like is then cut into a predetermined size by a cutter 4, and the end edge 5a of the cut portion is crushed into a leather-like shape. Here, this crushing treatment is performed to prevent both ends of the synthetic resin spacer 6 from entering the inner cavity 5b of the metal tube 5 when the synthetic resin spacer 6 is inserted in the next step. Therefore, if the end edge 5a of the cut portion of the metal tube 5 becomes a leather-like rough surface when cut by the cutter 4, it is not necessary to perform the cutting.

かくして、所定寸法に切断された金属管5は、第2図に
示すように、小間隙lをあけて縦列状態のまま送りロー
ラ7に送られて押出成形機8のクロスヘッドダイ9に入
る前にスペーサ6が介挿される。ここで、スペーサ6は
次の工程において外皮層7を形成するため被覆される合
成樹脂と相溶性の良いものが用いられ、たとえばこの合
成樹脂と同じような軟質もしくは半硬質のポリ塩化ビニ
ル、低密度ポリエチレン、ABS樹脂その他の一般的な
熱可塑性合成樹脂によって適当な大きさに形成される。
As shown in FIG. 2, the metal tubes 5 cut to a predetermined size are sent to the feed rollers 7 in tandem with a small gap 1 between them before entering the crosshead die 9 of the extrusion molding machine 8. A spacer 6 is inserted between. Here, the spacer 6 is made of a material that is compatible with the synthetic resin that will be coated to form the outer skin layer 7 in the next step, such as soft or semi-hard polyvinyl chloride similar to this synthetic resin, It is formed into an appropriate size from density polyethylene, ABS resin, or other general thermoplastic synthetic resin.

また、隣接する金属管5.5同士の間に形成される小間
隙 は、隣接する金属管5.5の両切断部がスペーサ6
を挟持する程度の大きさに設定される。
In addition, the small gap formed between the adjacent metal tubes 5.5 is such that both cut portions of the adjacent metal tubes 5.5 are connected to the spacer 6.
The size is set to the extent that it can be held between the two.

金属管5が供給されるクロスへラドダイ9は、第2図に
示すように、押出成形機8の先部にブレーカプレート1
0を介して取付けられたものであって、ダイボディー1
1内にインナーダイ12を設けることによりダイボディ
ー11の内周とインナーダイ12の外周との間に樹脂通
路13を形成し、インナーダイ12の軸心を貫通して設
けたバイブ挿通路14に後端より金属管5を導入してダ
イボディ11の押出口15から金属管5を導出する構造
となっている。しかして、このクロスヘッドダイ9に、
金属管5の隣接する端部間に生じた小間隙 にスペーサ
6を介挿させたままの状態を保持して縦列状態で送りロ
ーラフにより次々と供給すると、各金属管5−・はその
外周が合成樹脂で被覆されるとともに、その端部間に介
挿されたスペーサ6と各金属管同士の間及びスペーサ6
の外     ゛周面にも合成樹脂が被覆され、隣接す
る金属管5.5同士が第3図に示すようにスペーサ6を
挟持した状態でその外周に合成樹脂が被覆され、この合
成樹脂外皮16によって一体化された状態でクロスヘッ
ドダイ9より導出される。
As shown in FIG.
0, and the die body 1
By providing the inner die 12 in the inner die 1, a resin passage 13 is formed between the inner periphery of the die body 11 and the outer periphery of the inner die 12, and a resin passage 13 is formed between the inner periphery of the die body 11 and the outer periphery of the inner die 12. The structure is such that the metal tube 5 is introduced from the rear end and is led out from the extrusion port 15 of the die body 11. However, in this crosshead die 9,
By keeping the spacer 6 inserted in the small gap created between the adjacent ends of the metal tubes 5 and supplying them one after another by the feed roller ruff in tandem, each metal tube 5 has its outer periphery A spacer 6 coated with synthetic resin and inserted between the ends of the spacer 6 and between each metal pipe and the spacer 6
The outer peripheral surface of the metal tube 5.5 is also coated with a synthetic resin, and the outer periphery of the adjacent metal tubes 5.5 is coated with a synthetic resin with the spacer 6 sandwiched between them as shown in FIG. is led out from the crosshead die 9 in an integrated state.

かくして、各々の金属管5は合成樹脂外皮16を纏った
押出成形物となって、冷却機17を通って冷却された後
、カッター4によりスペーサ6の中央部分を切断されて
第4図に示すような合成樹脂被覆パイプとなる。
In this way, each metal tube 5 becomes an extrusion molded product covered with a synthetic resin jacket 16, and after being cooled through a cooler 17, the center portion of the spacer 6 is cut by a cutter 4, as shown in FIG. This is a synthetic resin-coated pipe.

このような方法によって製造される合成樹脂被覆パイプ
はその外径がlQm〜30酊程度の金属管を用いて量産
され、農園芸支柱、テント支柱。
The synthetic resin coated pipes manufactured by this method are mass-produced using metal pipes with an outer diameter of 1Qm to 30cm, and are used as agricultural and horticultural supports and tent supports.

その他の簡易家具などのフレーム材として使用される。Used as frame material for other simple furniture.

なお、既述の実施例では芯材として通常の円形の金属管
を用いたものを示したがこの発明はこのような金属管を
用いるものに限定されず第5図に示すような突状リブの
形設された金属管を用いてもよい。
In addition, although the above-mentioned embodiments used ordinary circular metal tubes as the core material, the present invention is not limited to the use of such metal tubes; A shaped metal tube may also be used.

すなわち、第5図に示す金属管5は、薄肉金属管の造管
時にその外周面を長手方向に沿って内方に折込んで襞状
のリプ51−を形設したものであるが、このような金属
管5を芯材に用いる時は軽量で、曲げ方向の外力に対し
て特に強い構造の合成樹脂被覆パイプを得ることができ
るはかりでなく、その製造工程においても突状リブ51
−がスペーサ6の入り込みを阻止するので切断端縁をわ
ずかに先革状に形成するだけでよく生産性も一層改善さ
れるなどの利点がある。
That is, the metal tube 5 shown in FIG. 5 has pleated lips 51- formed by folding the outer peripheral surface inward along the longitudinal direction during manufacturing of the thin-walled metal tube. When using the metal tube 5 as the core material, it is possible to obtain a synthetic resin-coated pipe that is lightweight and has a structure that is particularly strong against external forces in the bending direction.
Since - prevents the spacer 6 from entering, there is an advantage that the cut edge only needs to be formed into a slight serpentine shape, and productivity is further improved.

また、既述の実施例では、合成樹脂被覆パイプの合成樹
脂外皮層の表面を平坦面に形成しているが、外皮層の形
成時に第6図に示す突起17・−や第7図に示すような
節状鍔18・−を形成したり、或いは縦条溝を全周に刻
設する(不図示)などしてもよい。特に突起17・・−
や節状鍔18・・−は合成樹脂パイプの外観を体裁良く
する他、縛り付けた紐や針金などが抜けるのを防止する
のに効果的である。
Furthermore, in the embodiments described above, the surface of the synthetic resin outer skin layer of the synthetic resin coated pipe is formed into a flat surface, but when the outer skin layer is formed, the protrusions 17 shown in FIG. 6 and the projections 17 shown in FIG. It is also possible to form knot-like flanges 18.-, or to carve vertical grooves around the entire circumference (not shown). Especially protrusion 17...-
The knotted flanges 18, etc. not only improve the appearance of the synthetic resin pipe, but also are effective in preventing tied strings, wires, etc. from slipping out.

更に、スペーサ6としては、熱可塑性樹脂の中でも耐衝
撃に強いゴム系の樹脂などをポリ塩化ビニル樹脂にブレ
ンドしたものなどを用いることは望ましく、このような
ものを用いた合成樹脂被覆パイプを例えば農園芸用支柱
などとして使用する時には該支柱を木槌で打ち込むよう
な時に壊れに(いという利点がある。 また、スペーサ
の中央部を切断する際に、第8図に示すように下側のス
ペーサ部分を斜めに切断すれば、土中への打込みや差し
込みを容易にする効果がある。
Furthermore, as the spacer 6, it is desirable to use a thermoplastic resin, such as a rubber-based resin that has strong impact resistance, blended with polyvinyl chloride resin, and a synthetic resin-coated pipe using such a material may be used, for example. When using the spacer as a support for agriculture and gardening, it has the advantage that it will not break when driven in with a mallet.Also, when cutting the center part of the spacer, as shown in Figure 8, Cutting the spacer portion diagonally has the effect of making it easier to drive and insert into the soil.

以上詳述したように、この発明方法によれば、金属管の
隣接する端部間にスペーサを介挿させた状態でその外周
面より合成樹脂を被覆して管端キャップの被着の不要な
合成樹脂被覆パイプを連続した工程によって能率良く大
量に生産でき、したかって製造コストの安価な合成樹脂
被覆パイプを得ることができる。
As described in detail above, according to the method of the present invention, a spacer is inserted between adjacent ends of a metal tube, and synthetic resin is coated from the outer peripheral surface of the metal tube, thereby eliminating the need for attaching a tube end cap. Synthetic resin-coated pipes can be efficiently produced in large quantities through a continuous process, and thus synthetic resin-coated pipes can be obtained at low manufacturing costs.

また、スペーサは被覆される合成樹脂と溶着一体化して
しまうので射出成形によるなどの高い精度の成形加工は
必要でなく、金属管よりわずかに小径のものであれば形
は多少変形していても使用できるなどの利点がある。
In addition, since the spacer is welded and integrated with the synthetic resin it is coated with, there is no need for high-precision molding such as injection molding, and if the spacer is slightly smaller in diameter than the metal tube, the shape may be slightly deformed. It has the advantage of being usable.

更に、製造される合成樹脂被覆パイプは、合成樹脂が被
覆され金属管と一体となったスペーサが管端キャップと
同様な役目をなすので、端部が十分に保護され錆等を生
じる虞がない。
Furthermore, in the manufactured synthetic resin coated pipe, the spacer, which is coated with synthetic resin and integrated with the metal pipe, plays the same role as a pipe end cap, so the end is sufficiently protected and there is no risk of rust etc. .

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、この発明方法を実施するために用いる製造装
置の概略説明図、第2図はクロスへラドダイの縦断面図
、第3図はこの発明によって製造される押出成形物(中
間製造物)の端部間の縦断面図、第4図はこの発明によ
って製造される合成樹脂被覆パイプの一部破断縦断面図
、第5図は金属管の他の実施例図、第6図、第7図、第
8図はいずれも合成樹脂被覆パイプの別の実施例を示す
図である。 (符号の説明) 5は金属管、5aはその切断端縁、6は合成樹脂スペー
サである。 特許出願人   タキロン株式会社 代表者   へ木隆太部 0
FIG. 1 is a schematic explanatory diagram of a manufacturing apparatus used to carry out the method of the present invention, FIG. 2 is a longitudinal cross-sectional view of a cross-toward radial die, and FIG. 3 is an extrusion molded product (intermediate product) manufactured by the present invention. ), FIG. 4 is a partially cutaway longitudinal sectional view of a synthetic resin-coated pipe manufactured by the present invention, FIG. 5 is a diagram of another embodiment of a metal pipe, FIGS. 7 and 8 are views showing other embodiments of the synthetic resin-coated pipe. (Explanation of symbols) 5 is a metal tube, 5a is a cut edge thereof, and 6 is a synthetic resin spacer. Patent applicant Takiron Co., Ltd. Representative Ryuta Heki 0

Claims (1)

【特許請求の範囲】[Claims] 11)  所定の長さに切断され、その各々の切断□端
縁が先窄状に圧潰された金属管を、その隣接する   
゛端部間に合成樹脂スペーサを介挿させて縦列状態に保
持しながら次々と押出成形機のクロスヘッドに供給して
、その各々の隣接し合う金属管同士をその外周面より上
記スペーサを挟持した状態で合成樹脂を被覆させ、しか
る後に合成樹脂の被覆されたスペーサをその中央部より
切断することを特徴とする合成樹脂被覆パイプの製造方
法。
11) A metal tube that has been cut to a predetermined length and whose cut edge has been crushed into a tapered shape is connected to the adjacent metal tube.
゛Synthetic resin spacers are inserted between the ends, and the metal tubes are held in tandem and fed one after another to the crosshead of an extrusion molding machine, and the spacers are sandwiched from the outer peripheral surface of each adjacent metal tube. 1. A method for manufacturing a synthetic resin-coated pipe, which comprises coating the pipe with a synthetic resin in such a state, and then cutting the spacer coated with the synthetic resin from its center.
JP58079836A 1983-05-06 1983-05-06 Preparation of synthetic resin coated pipe Pending JPS59204525A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58079836A JPS59204525A (en) 1983-05-06 1983-05-06 Preparation of synthetic resin coated pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58079836A JPS59204525A (en) 1983-05-06 1983-05-06 Preparation of synthetic resin coated pipe

Publications (1)

Publication Number Publication Date
JPS59204525A true JPS59204525A (en) 1984-11-19

Family

ID=13701292

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58079836A Pending JPS59204525A (en) 1983-05-06 1983-05-06 Preparation of synthetic resin coated pipe

Country Status (1)

Country Link
JP (1) JPS59204525A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6186535A (en) * 1984-09-29 1986-05-02 久保山 信義 Decompression heating heat-generating method
EP3508321A4 (en) * 2016-09-01 2020-03-11 Sekisui Jushi Kabushiki Kaisha Extrusion molded article

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4935817A (en) * 1972-08-07 1974-04-03
JPS597029A (en) * 1982-07-05 1984-01-14 Zeon Kasei Kk Preparation of synthetic resin rod reinforced by metal tube

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4935817A (en) * 1972-08-07 1974-04-03
JPS597029A (en) * 1982-07-05 1984-01-14 Zeon Kasei Kk Preparation of synthetic resin rod reinforced by metal tube

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6186535A (en) * 1984-09-29 1986-05-02 久保山 信義 Decompression heating heat-generating method
EP3508321A4 (en) * 2016-09-01 2020-03-11 Sekisui Jushi Kabushiki Kaisha Extrusion molded article

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