JPS59204003A - Plastic clad glass fiber for optical transmission - Google Patents
Plastic clad glass fiber for optical transmissionInfo
- Publication number
- JPS59204003A JPS59204003A JP58079808A JP7980883A JPS59204003A JP S59204003 A JPS59204003 A JP S59204003A JP 58079808 A JP58079808 A JP 58079808A JP 7980883 A JP7980883 A JP 7980883A JP S59204003 A JPS59204003 A JP S59204003A
- Authority
- JP
- Japan
- Prior art keywords
- optical transmission
- core
- fiber
- glass fiber
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/104—Coating to obtain optical fibres
- C03C25/105—Organic claddings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は光伝送用プラスチッククラッドガラスファイ・
くに係り、特に耐油性、耐溶剤性に優れた光伝送用プラ
スチッククラッドガラスファイ・ぐに関するものである
。[Detailed description of the invention] The present invention is a plastic clad glass fiber for optical transmission.
In particular, the present invention relates to a plastic clad glass fiber for optical transmission which has excellent oil resistance and solvent resistance.
石英ガラスもしくは光学ガラスのファイバをコアとし、
シリコーン樹脂をクラッド層とするプラスチッククラツ
ド光ファイバは、比較的短距離の光伝送用として実用化
されている。With a core of quartz glass or optical glass fiber,
Plastic clad optical fibers whose cladding layer is made of silicone resin have been put into practical use for relatively short-distance optical transmission.
しかし、シリコーン樹脂は、トランス油、ケーブル油、
潤滑油等の炭化水素油や炭化水素系の溶剤に浸漬すると
膨潤するという欠点がある。そのブ辷め、従来のシリコ
ーン樹脂クラツド光ファイバは、これらの油や溶剤と接
触した場合、コアとクラット層間の接着が著しく低下し
、場合によっては剥離してしまうことがある。捷だ、こ
れらの油や溶剤は、屈折率が１４５を越えるものが多い
ので、浸漬後のクラッド層の屈折率が上昇してしまう。However, silicone resin can be used for transformer oil, cable oil,
It has the disadvantage that it swells when immersed in hydrocarbon oils such as lubricating oils or hydrocarbon solvents. When a conventional silicone resin-clad optical fiber comes into contact with these oils or solvents, the adhesion between the core and the clad layer decreases significantly, and in some cases, the optical fiber may peel off. Unfortunately, many of these oils and solvents have refractive indexes exceeding 145, so the refractive index of the cladding layer after immersion increases.
これらによって、光ファイバの伝送損失が大きくなり、
また、光ファーｆパが破断しやすくなることが容易に想
定される。These increase the transmission loss of the optical fiber,
Furthermore, it is easily assumed that the optical fiber becomes more likely to break.
ｊ〜たかつて、炭化水素系の油や溶剤に浸漬しても伝送
１ｉ（失が増大したり、破断することがない光伝送用）
′□ラスナッククラッドガラスファイバの開発か星９ノ
さノ１ている。j ~ Once upon a time, transmission 1i (for optical transmission that does not increase loss or break) even when immersed in hydrocarbon oil or solvent
'□The development of Rusnac clad glass fiber is 9 stars, 1 star.
不発明６寸上記に鑑みてなされたもので、その目的とす
るところは、炭化水素系の油や溶剤に対する酬油性、面
］溶剤性に優れた光伝送用プラスチッククラフトガラス
ファイバを提供することにある。This invention was made in view of the above-mentioned problems, and its purpose is to provide a plastic kraft glass fiber for optical transmission that has excellent oil resistance and solvent resistance against hydrocarbon oils and solvents. be.
本グ１−明の４１１１徴は、石英ガラスもしくは光学ガ
ラスのノつ′イパをコアとし、このコアの表面に、不飽
和結合を有し７ていない炭化水素基もしくは（：１１２
ｒ：１１２Ｃｕ１′Ｉパ２ｍ′月で示されるツ１（をＪ
正の整ズタを１・・、）・・′、・・とし７だときに、
次の一般式％式％
で衣わさλしるものと水素含不ボリ／ロキザンと白金化
ｒ： Ｉ：’！４とからなる付加重合型ボリノロギサン
糾ＩｊＳ’、杓からなるクラッド層を被覆Ｌ〜、その後
、このクラッド層を加熱硬化させＣ，なる光伝送用プラ
スチンククランドガラスファイノぞとしだ点にある。The 4111 characteristic of this group 1-Mei has a core made of quartz glass or optical glass, and on the surface of this core, a hydrocarbon group or (:112
r: 112Cu1′IP2m′ month
If the positive regularization factor is 1..., )...',... and it is 7, then
The following general formula % formula % shows coating λ, hydrogen-containing non-boly/roxane, and platinized r: I:'! A cladding layer consisting of an addition-polymerized borinologisane paste IjS' consisting of 4 and a ladle is coated with a cladding layer L~, and then this cladding layer is heated and hardened to form a plastic clad glass fin for optical transmission.
ここに、Ｒは不飽和結合を有していない炭化水素基もし
くは−０１（２０Ｈ２Ｃｍ’ Ｆ２ｍ′＋１で示される
基であるが、炭化水素基としては、メチル、エチル、プ
ロピル、イソプロピル、ブチル、ター・／ヤリブチル等
が該当し、特にメチル基からなるものが好適である。そ
してｎｌとｍ′は同じであっても異なっていてもよい。Here, R is a hydrocarbon group having no unsaturated bond or a group represented by -01(20H2Cm'F2m'+1), but examples of the hydrocarbon group include methyl, ethyl, propyl, isopropyl, butyl, tertiary . / Yabutyl etc., and those consisting of a methyl group are particularly preferred. nl and m' may be the same or different.
水素含有ポリシロキサンとは、分子中にＳｉ −１−Ｉ
を含むポリシロキサン（例えば、特公昭５７−２０３４
０に開示されている。）で、このうち、分子中にフルオ
ロアルキル基、例えば、
ＣＨ２Ｃｌ１２ＣＦ３． ＣＨ２０ｌ−１ｚ０２Ｆ５
． Ｃｌｌ２ＣＴ−Ｉ２Ｃ３Ｆ”ｓといつだ基を含むも
のが好ましい。これらの２リマ捷たはコポリマは単独で
使用してもよく、２種以上組み合せて使用してもよい。Hydrogen-containing polysiloxane is Si-1-I in the molecule.
(e.g., Japanese Patent Publication No. 57-2034)
0. ), among which a fluoroalkyl group, for example, CH2Cl12CF3. CH20l-1z02F5
．． Those containing Cll2CT-I2C3F"s and an Isuda group are preferred. These two polymers or copolymers may be used alone or in combination of two or more.
白金化合物は、上記の一般式で表わされるものと水素含
有ポリシロキサンとを付加反応させるだめの触媒となる
もので、一般にシリコーン化合物の反応１呻媒として公
知のものである。The platinum compound serves as a catalyst for the addition reaction between the compound represented by the above general formula and the hydrogen-containing polysiloxane, and is generally known as a reaction medium for silicone compounds.
ＪＪ、下実施例と比・殴例について説明する。JJ, the following examples and examples of comparison and punching will be explained.
実施例
イー１英ガラスフアイバコア（外径１５０μ）に、両末
、ｌｌ；ｉ、ｉがツメチルビニル／リル基で封鎖された
。Ｉ？＋） ）−１−ルー ３ 、 ：（、３−トｌ
）フルオロゾロビル７０ーザン１００重１１１部に水素
含イ；ｒポリ／ロキサンとしてボ″リノチルノ・イドロ
／ロキサン１０手量部ど白金０１１１冒−１：部とを加
えてなる付加重合型７Ｉ９ ｌ）ノ１１キ”リン組成物
をクラッド層として被覆し、：３ ５１） ’０の加熱
炉を通過させることによって上記クシノＩ！ Ｉ（”ｉ
／（一完全に硬化させて光伝送１月プラスチンククラ
ンドガラスファイノぐとしノー。Example E1 An English glass fiber core (outer diameter 150 μm) was capped at both ends, ll;i, and i with trimethylvinyl/lyl groups. I? +))-1-ru 3, :(,3-tl
) Addition polymerization type 7I9 prepared by adding 100 parts by weight of fluorozolobil 70-zan and 111 parts by weight of hydrogen-containing atom; The above-mentioned Kushino I! I(”i
/ (1) Completely harden the light transmission plastic tinkland glass fiber.
この）’Ｃ：ファイバを７０′Ｃのトランスン山に１ケ
月侵／山さ」書、−ところ、外観上何ら変化の徴候が認
め１′−）八す、、１、／こ、伝送損失の増大が殆んど
なかった。This )'C: The fiber was exposed to a transponder at 70'C for one month.However, no signs of change were observed in its appearance. There was almost no increase in
実ｈ：Ｄ １列２
石英がラスファイバコア（外径１５０μ）に、両１シＩ
Ｉ゛１１末かツメデルビニルノリル基で封鎖されたポリ
メチル−１ 、１，２．２−デトラヒＰロノξーフル
オロオクチルンロキサン１００重＠ｇｉ５に水素含有ポ
リノロキサンとしてポリメチルレノ１イド０（４０〜６
０％）メチルトリフルオロゾロピルンロキサンコボリマ
５０重量部と白金触媒ｏ１市ｉ，４部とを加えてなる付
加重合型ポリシロキサン組成物をクラッド層として被覆
し、３５０′ｃの加熱炉をｉ（１過させることによって
上記クラッド層を完全に（−１化させて光伝送用プラス
チッククララＶ 〕ｆラスファイバとしだ。Actual h: D 1 row 2 quartz is attached to the lath fiber core (outer diameter 150μ), both 1 row I
Polymethyl lenoide 0 (40-6
0%) An addition polymerizable polysiloxane composition prepared by adding 50 parts by weight of methyltrifluorozolopyrunoxane cobolimer and 4 parts of a platinum catalyst was coated as a cladding layer, and heated in a 350'c heating furnace. The above cladding layer is completely changed to (-1) by passing the fiber through the fibers to form a plastic Clara V for optical transmission.
この光ファイ・ぐを７０Ｃのトランス油に１ケ月浸漬さ
せたところ、実施例１と同様の結果■１１られた。When this optical fiber was immersed in 70C transformer oil for one month, the same results as in Example 1 were obtained.
比較例
実施例１のクラッド層として、付加重合型Ｌ’ｌ”Ｖシ
リコーン樹脂（ジオルガノポリシロキサンとオルガノ・
・イ１５０ポリシロキサンと白金触媒と力・らなる組成
物で、分子中にフッ素原子を含まないもの）を用い、他
は実施例１と同様の光伝送用プラスチッククララ１ガラ
スフアイ・ぐとしだ。Comparative Example As the cladding layer of Example 1, addition polymerization type L'l''V silicone resin (diorganopolysiloxane and organo-
・A composition consisting of A-150 polysiloxane, a platinum catalyst, and no fluorine atoms in the molecule) was used, except that the same plastic Clara 1 glass fiber for optical transmission as in Example 1 was used.
この光ファイバを７０℃のトランス油に１ケ月浸漬した
場合は、クラッド層が膨潤し、ところどころにクランド
層の剥離が認められ、伝送損失は１゛ランス油に浸漬す
る前に比べて１桁り、−ヒ増大していた。When this optical fiber was immersed in transformer oil at 70°C for one month, the cladding layer swelled, peeling of the cladding layer was observed in some places, and the transmission loss was 1 digit compared to before being immersed in transformer oil. ,-Hi was increasing.
以上説明したように、本発明によれば、炭化水素系の油
や溶剤に対して抵抗性があり、耐油性、耐溶剤性に優れ
ており、油中ライトガイドのように油に授ｍして用いる
用途にも使用できるという効果がある。As explained above, according to the present invention, it is resistant to hydrocarbon oils and solvents, has excellent oil resistance and solvent resistance, and does not impregnate oil like an in-oil light guide. It has the advantage that it can also be used in applications where it is used.
Claims (1)
をコアとし、該コアの表面に、不飽和結合を有していな
い炭化水素基もしくは （ｉ ｌ−］ ２ Ｃ）Ｉ２ Ｃ＋ｎ’ Ｆ ２１ｎ’
＋ １で示される基をＲ１正の整数をＩ＋１．…′、１
１としたときに、次の一般式％式％ ） で表わされるものと水素含有ポリシロキサンと白金化合
物とからなる付加ψ金型ボリア０キーリーンに、１１成
物からなるクラッド層を被覆し、その後、該クラッド層
を加熱硬化させてなることを特徴とする光伝送用プラス
チッククラッドガラスファイバ。(1) Fiber ζ of quartz glass or optical glass
as a core, and on the surface of the core, a hydrocarbon group having no unsaturated bond or (i l-] 2 C) I2 C+n' F 21n'
The group represented by +1 is represented by R1, and the positive integer is represented by I+1. ...', 1
1, a cladding layer consisting of 11 components is coated on an addition ψ mold boria 0 key lean consisting of a hydrogen-containing polysiloxane and a platinum compound represented by the following general formula % formula %), and then A plastic clad glass fiber for optical transmission, characterized in that the cladding layer is cured by heating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58079808A JPS59204003A (en) | 1983-05-07 | 1983-05-07 | Plastic clad glass fiber for optical transmission |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58079808A JPS59204003A (en) | 1983-05-07 | 1983-05-07 | Plastic clad glass fiber for optical transmission |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS59204003A true JPS59204003A (en) | 1984-11-19 |
Family
ID=13700507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58079808A Pending JPS59204003A (en) | 1983-05-07 | 1983-05-07 | Plastic clad glass fiber for optical transmission |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59204003A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS627006A (en) * | 1985-07-04 | 1987-01-14 | Asahi Glass Co Ltd | Optical transmission fiber having plastic clad |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5447667A (en) * | 1977-09-21 | 1979-04-14 | Sumitomo Electric Ind Ltd | Silicone resin clad optical communication fiber |
| JPS5662206A (en) * | 1979-10-09 | 1981-05-28 | Raychem Corp | Optical wave guide |
| JPS57172302A (en) * | 1981-04-17 | 1982-10-23 | Shin Etsu Chem Co Ltd | Coating material for optical communication fiber |
-
1983
- 1983-05-07 JP JP58079808A patent/JPS59204003A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5447667A (en) * | 1977-09-21 | 1979-04-14 | Sumitomo Electric Ind Ltd | Silicone resin clad optical communication fiber |
| JPS5662206A (en) * | 1979-10-09 | 1981-05-28 | Raychem Corp | Optical wave guide |
| JPS57172302A (en) * | 1981-04-17 | 1982-10-23 | Shin Etsu Chem Co Ltd | Coating material for optical communication fiber |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS627006A (en) * | 1985-07-04 | 1987-01-14 | Asahi Glass Co Ltd | Optical transmission fiber having plastic clad |
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