JPS59201847A - Blank for printed label - Google Patents
Blank for printed labelInfo
- Publication number
- JPS59201847A JPS59201847A JP7488083A JP7488083A JPS59201847A JP S59201847 A JPS59201847 A JP S59201847A JP 7488083 A JP7488083 A JP 7488083A JP 7488083 A JP7488083 A JP 7488083A JP S59201847 A JPS59201847 A JP S59201847A
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- polyamide resin
- nylon
- layer
- printed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
本発明は感熱性プリントラベル用素材、くわしくは優れ
た印刷適性、ペン書き適性、油性インキ適性、耐はつれ
性、耐洗たく性、耐ドライクIJ−二ング性を有する感
熱性プリントラベル用素材に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention is a material for heat-sensitive printed labels, specifically having excellent printability, pen-writing suitability, oil-based ink suitability, fading resistance, washing resistance, and dry IJ-printing resistance. Regarding materials for heat-sensitive printed labels.
従来よりプリントラベル用素材としてアセテートサテン
、ナイロンタフタ、7I?リエステルタフタ。Acetate satin, nylon taffeta, and 7I? have traditionally been used as materials for printed labels. Lyester taffeta.
レーヨンサテン等が使用されている。又最近ではポリア
マイド多孔質層を有する布帛が多く使われるようになり
、その技術は実用新案公報S、)−’l:l’177に
開示されている。Rayon satin etc. are used. Recently, fabrics having a polyamide porous layer have come into widespread use, and the technology thereof is disclosed in Utility Model Publication S, )-'l:l'177.
これ等のプリントラベル用素材は印刷後所望の大きさに
裁断されミンン縫いにより取りつけられているがミシン
による取り付けは人手にたよらざるを州ないため時間と
コストががかり改良を要望する声が多い。After printing, these materials for printed labels are cut to the desired size and attached by mincing stitches, but attachment using a sewing machine requires manual labor, which is time-consuming and costly, and there are many requests for improvements.
前記要望に応えるものとしてアセテートサテン。Acetate satin meets the above requirements.
ナイロンタフタ、ポリエステルタフタ、レーヨンザテン
等の布帛の片面にエチレン・ビニルアセテート共重合物
層を設は印刷 裁1新の後熱プレス機アイロン等で所望
の基体に接着する方法が一部実姉されている。Some methods have been developed in which an ethylene-vinyl acetate copolymer layer is printed on one side of a fabric such as nylon taffeta, polyester taffeta, or rayon zaten, and then bonded to the desired substrate using a hot press machine or iron. .
しかし、前II己布帛−七にエチレン・ビニルアセテー
ト共重合体から成る感熱性接着剤層を設けたプリントラ
ベル用素相は印刷適性か不十分な上、はつれ防止」−ヒ
ートカッ1が必要である。又、1′ライクリーニングに
耐えられず家庭における洗たくにも弱いという欠点があ
るだめ用1余が限られており、一般に普及するという状
態にはなっていない。However, the base material for printed labels, which has a heat-sensitive adhesive layer made of ethylene-vinyl acetate copolymer on the self-fabric (Section II), has insufficient printability and requires a heat cutter to prevent peeling. be. In addition, there are only a limited number of dry cleaners, which have the drawback of not being able to withstand 1' dry cleaning and being weak when washed at home, and are not widely available.
又、前記布帛」−に低融点ポリアマイド層を設ける試み
も成されでいるが、而」ドライクリーニング件、面1畠
メこく性においては満足できるものの印刷適性が不十分
、ヒートカットが必−要という点が解決されていな(・
。又、布帛と低融点ポリアマイド層の接着強度が弱い、
熱圧着貼溶融した接着剤が布帛を逆浸透する等の諸問題
も発生してくる。Attempts have also been made to provide the above-mentioned fabric with a low-melting point polyamide layer, but although it is satisfactory in terms of dry cleaning and one-sided texture, the printability is insufficient and heat cutting is required. That point has not been resolved (・
. In addition, the adhesive strength between the fabric and the low melting point polyamide layer is weak.
Various problems arise, such as reverse osmosis of the melted adhesive during thermocompression bonding into the fabric.
一方、i11記要望に応える別の手段として前記布帛の
片面にアクリル酸エステル、合成ゴム、天然ゴム等を主
体とする感圧性の接着剤を塗布したものもあるが接着強
度が低くドライクリーニング。On the other hand, as another means to meet the request in item 11, there is a method in which one side of the fabric is coated with a pressure-sensitive adhesive mainly made of acrylic acid ester, synthetic rubber, natural rubber, etc., but the adhesive strength is low and dry cleaning is possible.
家庭洗たくにも耐えられない。It can't even withstand washing at home.
本発明者等は前記要望に応えるべく欽意研究を続けた結
果、ポリアマイド樹脂多孔質層を有する基体の片面に低
融点ボリアマイ1゛樹脂層を設けることにより前記諸問
題が一挙に解決することを見出し本発明を完成させるに
至った。As a result of continuing research in order to meet the above-mentioned needs, the present inventors have found that the above-mentioned problems can be solved at once by providing a low-melting point polyamide resin layer on one side of a substrate having a porous polyamide resin layer. Heading: The present invention has been completed.
即ち本発明はポリアマイド樹脂多孔質層を有する基体の
片面に融点g0°C〜/gO°C1厚さ30μ〜750
μのポリアマイド樹脂接着剤層を設けてなることを特徴
とする熱圧着像プリントラベル用累月を提供するもので
ある。That is, in the present invention, one side of a substrate having a polyamide resin porous layer has a melting point of g0°C~/gO°C1 thickness of 30μ~750.
The object of the present invention is to provide a thermocompression bonded image print label, characterized in that it is provided with a polyamide resin adhesive layer of μ.
本発明に使用する基体の形態は織布1編布、不紗布のい
づれでもよい。又使用する繊維は、15 リアミド(ナ
イロン乙、ナイロン6乙、ナイロン乙10等)−アセテ
ート、 、]?リエステル、アクリロニトリル。The form of the substrate used in the present invention may be either a single-knit woven fabric or a non-woven fabric. The fibers used are 15 lyamide (nylon Otsu, nylon 6 Otsu, nylon Otsu 10, etc.) - acetate, ]? Lyester, acrylonitrile.
レーヨン、綿等及びその混紡品、混繊品、混合品か使用
できるが、繊維が長繊維である場合ミ・基体とポリアマ
イド樹脂多孔′721層間の接着節用の点て刀?リアミ
]ゞ糸繊維を主体とすることが望しい。又使用する繊維
か短繊維である場合、繊イ4[の種類に11111IJ
a 1:J、’ if: イ。Rayon, cotton, etc. and their blends, mixed fibers, and mixtures can be used, but if the fibers are long fibers, do you need a pointer for bonding between the substrate and the porous polyamide resin layer? It is desirable that the main material is yarn fiber. Also, if the fiber or short fiber to be used is 11111IJ for the type of fiber
a 1: J,' if: I.
本発明に使用されるポリアミド多孔質層(づ]ナナイフ
ろ2ナイロン品等を堵化カルンウムのメタノール溶液え
溶解し、ドクターナイフコーティング。The polyamide porous layer used in the present invention is dissolved in a methanol solution of carunium chloride and coated with a doctor knife.
ロールコーティング等公知の方法により基体」二に塗布
し水洗、乾燥等の工程を経て1月られる。前記ポリアマ
イド樹脂の塩1ヒカル/ウムメタノール溶液には柔軟性
イ」力剤、各樺安定剤を混入することもできる。又前記
基体がボリアマイ1:′繊糸11を主体としたものの場
合、j塩1ヒカル/ウムメタノール溶液のみをマンゲル
コーティング等公知の方法て適用し水洗、乾燥すること
により繊維の表面を多孔atヒすることもでき、実用新
案公報SJ−’IAJg/に開示されている。It is applied onto a substrate by a known method such as roll coating, washed with water, dried, etc., and then dried for a month. A flexibility strength agent and various birch stabilizers may be mixed into the polyamide resin salt solution in methanol. In addition, when the substrate is mainly composed of boriamy 1:' fibers 11, the surface of the fibers is made porous by applying only a solution of j salt 1 hical/um methanol using a known method such as mangel coating, washing with water, and drying. It is also disclosed in Utility Model Publication SJ-'IAJg/.
本発明に使用するボリアマイl゛樹脂多孔質層の伺着喰
の内印刷面IF]、ljについて口!侍に制限はないが
感熱接着剤層側のポリアマイド樹脂多孔質層の重量は基
体重量の0.2.!i重計倍以下、好捷しくは0.70
重量倍以下か望ましい。この理由はボリアマイト゛樹脂
多孔實層の重量が基体itの0.25重縦倍以上になっ
た場合その塗膜表面と内部間に発生する歪が大きくなる
ためその塗膜強度が低下しプリントラベルとその被接着
体間に必要な接着強度以下になりポリアマイド樹脂多孔
質部分から破壊されてプリントネームラベルが被接着体
から剥離される危険性かてでくるからである。前記塗膜
内歪の発生理由の理論的解明は未だされていないが、塗
膜表面と塗膜内部間の凝固速度、凝固形態の差に起因す
ると考えられる。Regarding the printed surface IF of the polyamide resin porous layer used in the present invention, lj! There is no limit to the weight of the polyamide resin porous layer on the heat-sensitive adhesive layer side, but the weight of the polyamide resin porous layer on the heat-sensitive adhesive layer side is 0.2 of the base weight. ! i weight scale times or less, preferably 0.70
Preferably less than double the weight. The reason for this is that when the weight of the porous real layer of boriamite resin exceeds 0.25 times the weight and height of the base IT, the strain that occurs between the surface and the interior of the coating film increases, resulting in a decrease in the strength of the coating film, which makes it difficult to print labels. This is because there is a risk that the adhesive strength between the objects to be adhered will be lower than the required level and the printed name label will be broken from the porous portion of the polyamide resin and peeled off from the objects to be adhered. The reason for the occurrence of the strain within the coating film has not yet been theoretically elucidated, but it is thought to be caused by the difference in solidification rate and solidification form between the surface of the coating film and the interior of the coating film.
本発明に使用するポリアマイド樹脂接着剤層に1更用す
る槓」旨はナイロン乙、ナイロン乙乙、ナイロン乙10
.ナイロン72等の共重合物やダイマー酸系ポリアマイ
ド等が挙げられる。"Last layer used in the polyamide resin adhesive layer used in the present invention" refers to nylon Otsu, nylon Otsutsu, and nylon Otsu 10.
.. Examples include copolymers such as nylon 72 and dimer acid polyamides.
又、該ポリアマイド樹脂接着剤層に使用される樹脂の融
点は接着強度、4洗たく性、面Jクリーニング性等の点
からgθ′C以上でなければならずボリアマイl?多孔
質層に影響を与えないという点がら/gO°C以下てな
げれはならない。In addition, the melting point of the resin used for the polyamide resin adhesive layer must be higher than gθ'C from the viewpoints of adhesive strength, washability, surface J cleanability, etc. In order not to affect the porous layer, the temperature should not exceed /gO°C.
又、該ポリアマイド樹脂接着層に使用される樹脂の塗布
厚はプリントネームラベルと被接着体間の最低限度の接
着強度を保つため、?0μ以」二でなければならず、風
合い、接着剤の(はみ出し等の諸問題を抑えるため/!
iθμ以下でなげればならない。Also, what is the coating thickness of the resin used for the polyamide resin adhesive layer in order to maintain the minimum adhesive strength between the printed name label and the adhered object? It must be less than 0μ to prevent problems such as texture, adhesive extrusion, etc.
It must be thrown below iθμ.
実施例
ナイロンタフタ(経70デニールIOg本/インチ2緯
70デニール?θ本/インチ、重@bs7矛7z2)の
両面に配合/のナイロン樹脂をI5クターコーティング
法を用いて傾面し温水(rio’c)中に浸a後水洗乾
燥し、片面の付a量か各5.07.An2のプリントラ
ベル素材の中間体を得だ。次に融点/15’Cのナイロ
ン/、2糸コボ゛リマーをエクストルーノヨンコーター
て゛70μフィルムに押出し前記中間体の片面にラミネ
ートして熱圧着付のプリントラベル累月を得だ。Example: A nylon taffeta (warp 70 denier IO g pieces/inch 2 weft 70 denier ? θ pieces/inch, heavy @bs7 7z2) was coated with nylon resin on both sides using the I5 ctor coating method and coated with hot water (rio 'c) After soaking in a, wash with water and dry, the amount of a applied on one side is 5.07. Obtained intermediate material for printed label material of An2. Next, a 2-thread copolymer of nylon with a melting point of 15'C was extruded onto a 70μ film using an extrusion coater and laminated on one side of the intermediate to obtain a printed label with thermocompression bonding.
以」−のごとくして得られた熱圧着性プリントラベル累
月の多孔′拵ナイロン樹脂面に文字、絵柄をオフセット
印刷し裁bJ[の後ウール地(トロピカル)に圧力0.
21ψ飼、温度/20°C1時間S秒の条件で明細書の
浄摺(内容に変更なし))
熱圧着しqg待時間放置後濯試験及びドライクリーニン
グ試験に供したところ、第1表、第2表に示すように面
]洗濯性1mlドライクリーニング性、印刷適性、耐は
つれ性、耐浸み出し性が極めて優秀であった他ペン引き
マジックインキ書きにおけるにじみもなかった。The thermocompression-adhesive printed label obtained as described above was offset printed with letters and designs on the perforated nylon resin surface, then printed on wool fabric (tropical) with 0.0 pressure.
The specifications were cleaned under the conditions of 21ψ feed, temperature: 20°C, 1 hour and S seconds (no change in content)), and were subjected to a rinsing test and a dry cleaning test after being left for qg waiting time. As shown in Table 2] Washing property (1 ml) Dry cleaning properties, printability, peeling resistance, and bleed-out resistance were extremely excellent, and there was no bleeding when writing with marker ink.
配合/
ナイロンA M)部
メチルアルコール 左g部
塩化カルシウム コク部
炭酸カルシウム 7部
比較例
実施例記載のナイロンタフタに前記ナイロンコポリマー
の70μフイルムを圧着し熱圧矯性のナイロンタフタを
得たのち、実施例と同様の試験を行った・
第2表
注/ 試験方法JTSL/θヶ、2F−/法注2 試験
機 新6に法ドライ機(秋田洋服溝たく機(株)製)Blend/Nylon A M) part Methyl alcohol Left g part Calcium chloride Body part Calcium carbonate 7 parts Comparative Examples After pressing a 70μ film of the nylon copolymer onto the nylon taffeta described in the example to obtain hot-pressable nylon taffeta, Tests similar to those in Examples were conducted.Table 2 Note/Test method JTSL/θ, 2F-/Method Note 2 Testing machine New 6-method drying machine (manufactured by Akita Clothing Groove Tucker Co., Ltd.)
図は本発明プリントラベル用素利の断面模式図である。
図中/及びJはポリアマイド多孔質層、2は基体、弘は
感熱性ボリアマイF接着剤である。
手続補正書(方式)
昭和58年 8月16日
特許庁長官 若杉 和夫殿
1、事件の表示 昭和58年特許願第74880号2
、発明の名称 プリントラベル用素材3、補正をする
者 事件との関係 特許出願人京都府京都市右京区西
京極大門町26番地4、補正命令の日付
昭和58年 7月26日
5、補正の対象
明細書の発明の詳細な説明の欄
6、補正の内容The figure is a schematic cross-sectional view of the printed label element of the present invention. In the figure, / and J are polyamide porous layers, 2 is a substrate, and Hiroshi is a heat-sensitive Boriamy F adhesive. Procedural amendment (formality) August 16, 1980 Kazuo Wakasugi, Commissioner of the Patent Office 1, Indication of case Patent Application No. 74880, 1988 2
, Title of the invention Material for printed labels 3, Person making the amendment Relationship to the case Patent applicant 26-4 Nishikyogoku Daimon-cho, Ukyo-ku, Kyoto-shi, Kyoto Prefecture Date of amendment order July 26, 1980 5 Subject of amendment Column 6 of detailed explanation of the invention in the specification, contents of amendment
Claims (2)
融点g0°C〜/gO°C1厚さ30μ〜/30μのポ
リアマイド樹脂接着剤層を設けてなることを特徴とする
熱圧着性プリントラベル用素材。(1) For a thermocompression print label characterized by providing a polyamide resin adhesive layer with a melting point of g0°C to /gO°C1 and a thickness of 30μ to /30μ on one side of a substrate having a porous polyamide resin layer. material.
アマイド樹脂多孔質層の重量が基体重量の0.2S倍以
下であることを特徴とする特許請求の範囲第(1)項記
載の熱圧着性プリントラベル用素拐・ (J)基体がポリアマイド系繊維から成る長繊維織物で
あることを特徴とする特許請求の範囲第(1)項ないし
第(2)項記載の熱圧着性プリントラベル用素材。 (/I)基体が短繊維織物から成ることを特徴とする特
許請求の範囲第(1)項ないし第(2)項記載の熱圧着
性プリントラベル用素材。(2) The heat according to claim (1), characterized in that the weight of the porous polyamide resin layer sandwiched between the substrate and the polyamide resin adhesive layer is 0.2S times or less the weight of the substrate. (J) A thermocompression adhesive print label according to claims (1) and (2), characterized in that the substrate is a long fiber fabric made of polyamide fibers. Material for use. (/I) The thermocompression-adhesive printed label material according to claims (1) and (2), characterized in that the substrate is made of short fiber fabric.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7488083A JPS59201847A (en) | 1983-04-30 | 1983-04-30 | Blank for printed label |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7488083A JPS59201847A (en) | 1983-04-30 | 1983-04-30 | Blank for printed label |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59201847A true JPS59201847A (en) | 1984-11-15 |
JPH0324335B2 JPH0324335B2 (en) | 1991-04-03 |
Family
ID=13560105
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7488083A Granted JPS59201847A (en) | 1983-04-30 | 1983-04-30 | Blank for printed label |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59201847A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015517125A (en) * | 2012-04-23 | 2015-06-18 | メディレックス システムズ インコーポレイテッド | Foam with removable wristband |
-
1983
- 1983-04-30 JP JP7488083A patent/JPS59201847A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015517125A (en) * | 2012-04-23 | 2015-06-18 | メディレックス システムズ インコーポレイテッド | Foam with removable wristband |
Also Published As
Publication number | Publication date |
---|---|
JPH0324335B2 (en) | 1991-04-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ES2304951T3 (en) | SUBSTRATE COATINGS, SUBSTRATE TREATMENT METHODS FOR PRINTING BY INK JETS AND ITEMS PRODUCED THROUGH THE SAME. | |
US4515849A (en) | Transfer printing sheet, printing method and printed article | |
US5153064A (en) | Hot-melt adhesive substance for the raster-pattern coating of fabrics, especially of lining materials | |
US20040170799A1 (en) | Heat-insulating material and method of making the same | |
JPH0796745B2 (en) | Non-woven laminated material | |
JPS59201847A (en) | Blank for printed label | |
US4101359A (en) | Composite material for use in covering walls, and a method of manufacturing same | |
JPS6164447A (en) | Laminate | |
JPS6312796A (en) | Air permeable wallpaper | |
CN101370978A (en) | Shape-changeable cloth | |
JP2997251B1 (en) | Printing sheet | |
CN212636841U (en) | Warm-keeping printed fabric | |
JPH0337977Y2 (en) | ||
JPS6141372A (en) | Printing sheet | |
JPS60183139A (en) | Composite nonwoven fabric | |
EP1037541A1 (en) | Adhesive bonding | |
JPH02154074A (en) | Sheet material for printing | |
JPH0625626A (en) | Cloth with adhesive | |
JPS62212487A (en) | Fused core material | |
JPH0311275Y2 (en) | ||
JPH06103424B2 (en) | Labels for clothing with good durability such as displayed characters, pictures, symbols | |
Thomsen | An old adhesive–starch paste. A new technique–the suction table offers new horizons in the treatment of brittle textiles | |
JPS59192768A (en) | Base cloth for tarpaulin | |
JPH09143886A (en) | Adhering interlining cloth | |
JPS58166036A (en) | Novel waterproof, moisture-permeable pasting cloth |