JPS59196064A - Production of concentrated garlic juice - Google Patents

Production of concentrated garlic juice

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Publication number
JPS59196064A
JPS59196064A JP58071938A JP7193883A JPS59196064A JP S59196064 A JPS59196064 A JP S59196064A JP 58071938 A JP58071938 A JP 58071938A JP 7193883 A JP7193883 A JP 7193883A JP S59196064 A JPS59196064 A JP S59196064A
Authority
JP
Japan
Prior art keywords
garlic
concentrated
aroma
liquid
juice
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58071938A
Other languages
Japanese (ja)
Other versions
JPH0440980B2 (en
Inventor
Akira Sugisawa
公 杉澤
Masaru Shibuki
渋木 優
Imayoshi Imada
今田 今義
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
House Foods Corp
Original Assignee
House Food Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by House Food Industrial Co Ltd filed Critical House Food Industrial Co Ltd
Priority to JP58071938A priority Critical patent/JPS59196064A/en
Publication of JPS59196064A publication Critical patent/JPS59196064A/en
Publication of JPH0440980B2 publication Critical patent/JPH0440980B2/ja
Granted legal-status Critical Current

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  • Seasonings (AREA)

Abstract

PURPOSE:To prevent the deterioration and volatilization of gralic flavor by concentrating and heating and obtain the titled liquid having a strong garlic flavor, by heating a raw garlic, inactivating an enzyme alliinase, squeezing the juice, concentrating the juice, and adding an enzymic agent containing the enzyme alliinase thereto. CONSTITUTION:A raw garlic is heated preferably at 90-110 deg.C for 1-10min to inactivate an enzyme alliinase, and the resultant garlic is squeezed to give a juice, which is then concentrated. An enzymic agent containing an enzyme alliinase, e.g. a squeezed juice of the raw garlic, powdered garlic or garlic paste, is added thereto (in an amount of 1-20wt% based on the concentrated liquid for the raw garlic squeezed jjice of the raw garlic) to afford the aimed concentrated garlic juice. USE:Curry and stew, etc.

Description

【発明の詳細な説明】 本発明は、カレー・シチュー等の加工食品の原料に主と
して使用され、るa縮ガーリック液の製造法に関し、更
に詳しくは、特に濃縮時の加熱(でよるガーリンク香気
の変質・揮散が良好に防I卜され、強いガーリック本来
の香気を有した濃縮ガーリンク液を得ることが可能な、
濃縮ガーリック液の製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing a condensed garlic liquid, which is mainly used as a raw material for processed foods such as curry and stew. It is possible to obtain a concentrated garlic liquid that is well prevented from deterioration and volatilization, and has a strong garlic aroma.
This invention relates to a method for producing concentrated garlic liquid.

従来より、ガーリノクは栄養価値に優れ、一般的に味覚
強化剤として種々の料理に使用されている。また、ガー
リ、りの加工品、例えば粉末ガーリック、スライス、ミ
ンスド、チョツプドフレーク等も広く知られている。ガ
ーリックの濃縮液も、家庭料理ではあまり頻繁(C使用
されないが、工業的にカレーやシチュー等の加工食品を
製造する場合の、味覚強化のための原料として、欠くこ
とのできないものである。
Traditionally, Garlinok has excellent nutritional value and is commonly used as a taste enhancer in various dishes. Further, processed products of garlic, such as powdered garlic, slices, minced garlic, chopped flakes, etc., are also widely known. Garlic concentrate is also not used very often in home cooking, but it is indispensable as a flavor-enhancing ingredient in the industrial production of processed foods such as curry and stew.

一般に、ガーリ、りが特有の香気を発現するのは、ガー
リ、り中に含まれる無臭結晶性のアリーン(AIIii
+〕)が、酵素アリナーゼ(AI I 1nase )
によって加水分解し、特有臭気のあるアリシン(AI 
l 1cin )を生ずるためであるとされている。
In general, the unique aroma of gari and li is caused by the odorless crystalline Aline (AIIIi) contained in gari and li.
+]) is the enzyme allinase (AI I 1nase)
Allicin (AI), which has a characteristic odor, is hydrolyzed by
It is said that this is to generate l 1cin ).

ところが、上記のガーリンク特有の香気成分であるアリ
シンは、非常に不安定で、直ぐさ捷ジアリルジナルファ
イド等に分解されて、変質を起こす。したがって、ガー
リー、りの加工品を製造する場合は、いかに上記のアリ
シンに基づく香気の変質・揮散を起こさずに加工するか
が最大の問題であった。
However, the above-mentioned allicin, which is a unique aroma component of Garlink, is extremely unstable and is quickly decomposed into diallyldinalphide and the like, causing deterioration. Therefore, when producing processed products of girly and lily, the biggest problem was how to process them without causing deterioration or volatilization of the above-mentioned allicin-based aroma.

特に濃縮ガーリンク液を製造する場合には、どのような
濃縮法を採用する場合にも、濃縮に時間を要すると共に
、ガーリ、りにはある程度の熱がかかるため、上記のア
リシンに基づくガIJツク特有の香気は著しく変質・揮
散奮起こした。そしてこのことは、最終品として得られ
る、濃縮液の品質を著しく損なうと共に、作業中に強烈
なガーリ、り臭が発生して、作業員に生理的苦痛を与え
ることになった。
In particular, when producing concentrated garlic liquid, no matter what concentration method is used, it takes time to concentrate and a certain amount of heat is applied to garlic. The characteristic odor of tsuku was significantly altered and volatilized. This not only significantly impairs the quality of the concentrate obtained as a final product, but also generates a strong musty odor during work, causing physiological pain to the workers.

このため、実際には、上記の問題に対処するために、一
旦濃縮時に発生するガーリノク香気を含んだ蒸気を回収
し、回収した蒸気から香気成分だけを分離して、これを
濃縮液に戻す方法がとられている1、 しかし、上記の場合には、香気成分を回収するための装
置等が別途必要となり、工程的に煩雑であった。壕だ、
上記のように回収して、濃縮液に戻される香気成分は、
−fiアリシンとして発現後、加熱されて揮発したもの
であるため、生方−92ク本来の香気と比べると新鮮さ
かなく、このため、最終的に得られる濃縮液は、生ガー
リ、り本来の香気を有するものではなかった。
Therefore, in order to deal with the above problem, the method is to first collect the steam containing the Garlinok aroma generated during concentration, separate only the aroma components from the collected steam, and return it to the concentrated liquid. 1. However, in the above case, a separate device for recovering the aroma components was required, and the process was complicated. It's a trench.
The aroma components recovered as described above and returned to the concentrate are:
After being expressed as -fi allicin, it is heated and volatilized, so it is not as fresh as the original aroma of Ikukata-92, and for this reason, the final concentrate obtained is not as fresh as the original aroma of raw garlic and allicin. It had no aroma.

しかも、上記の場合には、香気成分を回収する際に、香
気成分を高い収率で回収することが困(碓である賜金が
多く、また最終品を高濃度にまで濃縮するためのハード
な濃縮条件をとると、香気が著しく揮散するため、実際
(Cは、強いガーリック香気を有し、かつ高濃度の濃縮
ガーリンク液を得ることができなかった。
Moreover, in the above case, it is difficult to recover the aroma components at a high yield (there are many cases where it is difficult to recover the aroma components), and it is difficult to recover the aroma components with a high yield. Under concentrated conditions, the aroma was significantly volatilized, so in fact (C) was unable to obtain a concentrated garlic liquid with a strong garlic aroma and high concentration.

本発明の目的は、上記のような問題のない濃縮ガーリッ
ク液の製造法を得ることにある。即ち、本発明の第1の
目的は、濃縮時の加熱によるガーリノク香気の変質・揮
散が良好に防止され、ガーリノク本来の良好な香気を有
する濃縮ガーリンク液を得ることが可能な濃縮ガーリソ
ク液の製造法を提供することにある。
An object of the present invention is to obtain a method for producing concentrated garlic liquid that does not have the above-mentioned problems. That is, the first object of the present invention is to provide a concentrated garlic liquid that can effectively prevent the deterioration and volatilization of the garlic aroma caused by heating during concentration, and that can obtain a concentrated garlic liquid that has the original good aroma of garlic. The purpose is to provide a manufacturing method.

また、本発明の第2の目的は、別途回収した香気成分を
添加する必要がなく、効率的かつ工業的に有利に強いガ
ーリック香気を有する濃縮ガーリンク液を得ることが可
能な、濃縮ガーリノク液の製造法を提供することにある
Further, the second object of the present invention is to provide a concentrated garlic liquid that can efficiently and industrially advantageously obtain a concentrated garlic liquid having a strong garlic aroma without the need to add separately recovered aroma components. The objective is to provide a manufacturing method.

また、本発明の更に他の目的は、いかなる濃縮法・濃縮
条件を採用する場合にもガーリック香気が変質・揮散せ
ず、強いガーリ、り香気を有し、しかも高濃度に捷で濃
縮された濃縮ガーリンク液を得ることが可能な、濃縮ガ
ーリ、り液の製造法を得ることにある。
Still another object of the present invention is to maintain a strong garlic aroma without deteriorating or volatilizing the garlic aroma no matter what concentration method or concentration conditions are used, and which is concentrated to a high concentration by straining. An object of the present invention is to obtain a method for producing a concentrated garlic liquid by which a concentrated garlic liquid can be obtained.

本発明者らは、上記の目的を達成すべく、練りにんにく
を製造する場合に、加熱後のガーリノクを磨砕した基体
に、別途調製した生ガーリック搾汁液又td m砕物を
添加することによって、製造時のガーリソク臭の発現及
びガーリックの変色が防止される技術(特願昭51−6
7136号)を踏甘えたトで濃縮ガーリノク液の製造法
について更に研究を進めた結果、下記するような知見を
得た。
In order to achieve the above object, the present inventors, when producing crushed garlic, add fresh garlic juice or tdm crushed material prepared separately to a substrate obtained by grinding Garlinok after heating. Technology that prevents the appearance of garlic odor and discoloration of garlic during production (Patent application 1986-6)
No. 7136), we conducted further research on the method for producing concentrated Garinoku liquid, and as a result, we obtained the following knowledge.

即ち、本発明者らは、濃縮ガーリック液を製1青する場
合に、その濃縮工程で練りにんにくの場合と比較になら
ない多量の香気が一揮散するが、生ガーリックを酵素ア
リナーゼが失活する程度に加熱した後に濃縮するととに
よって、濃縮時に於る香気の揮散をほぼ完全に防止でき
ること。
In other words, the present inventors found that when making concentrated garlic liquid, a large amount of aroma is released during the concentration process, which is incomparable to the case of crushed garlic. By heating the product to a temperature and then concentrating it, volatilization of aroma during concentration can be almost completely prevented.

贅だ、そればかりでなく、上記のように香気成分アリシ
ンの発現前に加熱したガーリンクを濃縮することによっ
て、従来ガーリ、り液を濃縮する場合に最大の問題であ
った、濃縮時の加熱によるガーリック香気の変質も非常
に良好に防止できることを知った。また、本発明者らは
、上記のように加熱濃縮後のガーリンク液に、別途に調
製した酵素アリナーゼを含んだ酵素剤を加えた場合に1
は、非常に強い生方−11ツタ本来の香気を有した濃縮
液となることを見出した。
Not only that, but as mentioned above, by concentrating the heated garlic before the aroma component allicin develops, the heating during concentration, which was the biggest problem when concentrating conventional garlic liquid, is avoided. It was also found that the deterioration of garlic aroma caused by In addition, the present inventors found that when an enzyme preparation containing the enzyme allinase prepared separately was added to Garlink liquid after heating and concentration as described above,
found that the concentrated liquid had a very strong aroma inherent to Ukata-11 ivy.

また、同1拵に本発明者らfd 、上記の方法によれば
、濃縮の際の条件が高温長時間に及ぶ厳しいものである
場合にも、ガーリノク香気の変質及び揮散が良好に防止
され、このため強いガーリノク香気を有し、しかも非常
に高濃度にまで濃縮された濃縮ガーリノク液を製造でき
ることを見出した。
In addition, according to the above-mentioned method, deterioration and volatilization of the Garlinok aroma can be effectively prevented even when the conditions for concentration are severe, such as high temperatures and long periods of time. Therefore, it has been found that it is possible to produce a concentrated Garlinok liquid that has a strong Garlinok aroma and is concentrated to an extremely high concentration.

本発明は、上記のような知見に基づいて成されたもので
、その要旨は、生ガーリックを加熱して、該生ガーリツ
ク中の酵素アリナーゼを失活させた後、加熱処理後のガ
ーリックを常法によって搾汁 濃縮し、これに酵素アリ
ナーゼを含んだ酵素剤を添加することを特徴とする、濃
縮ガーリノク液の製造法である。
The present invention was made based on the above-mentioned findings, and the gist thereof is to heat raw garlic to inactivate the enzyme allinase in the raw garlic, and then to regularly heat-treated garlic. This is a method for producing concentrated Garlinok liquid, which is characterized by squeezing and concentrating the juice by a method and adding an enzyme agent containing the enzyme allinase to the juice.

以下、本発明について詳しく説明する。The present invention will be explained in detail below.

先ず、本発明では、剥皮等の前処理を施したガーリノク
を、ガーリ、り中の酵素アリナーゼが失活する程度に加
熱する。加熱は例えは煮沸、蒸煮、マイクロ波加熱等に
よって行なわr、る3゜また、加熱の際の条件は、通常
70〜130℃で30分〜6秒、好捷しくけ、90〜1
10℃で10〜1分である。
First, in the present invention, the Garlinok, which has been pretreated such as peeling, is heated to such an extent that the enzyme allinase in the Garlin is inactivated. Heating is carried out, for example, by boiling, steaming, microwave heating, etc.The conditions for heating are usually 70 to 130°C for 30 minutes to 6 seconds, a suitable mechanism, and a temperature of 90 to 130°C.
10 to 1 minute at 10°C.

上記の加熱処理によって、前駆体アリーンの酵素による
加水分解反応は停止ト腰 このため香気成分アリシンは
、下記する酵素剤を添加する寸で1r′i発現しない。
The above heat treatment stops the enzymatic hydrolysis reaction of the precursor arene. Therefore, the aroma component allicin does not express 1r'i when the following enzyme agent is added.

尚、上記の加熱処理によれば、一部の耐熱性菌を除き、
ガーリノクを微生物的に殺菌することが可能である。
In addition, according to the above heat treatment, except for some heat-resistant bacteria,
It is possible to microbially sterilize Garlinok.

加熱後のガーリックは、例えば磨砕機等にかけておろし
た状態にし、これを布で搾汁したり、又1は遠心分離機
等にかけて、常法によって搾汁される。
After heating, the garlic is grated using a grinder, for example, and the juice is squeezed using a cloth, or the juice is squeezed using a centrifuge or the like in a conventional manner.

上記のようにして得られた搾汁液は、例えば真空低温濃
縮、真空高温濃縮、凍結による濃縮、マイクロ波による
濃縮等によって濃縮さf′12る。
The juice obtained as described above is concentrated f'12 by, for example, vacuum low-temperature concentration, vacuum high-temperature concentration, freezing concentration, microwave concentration, or the like.

この際、上記の加熱処理によって、濃縮時の加熱による
ガーリック香気の変質・揮散は未然に防止さr、るだめ
、濃縮条件は低1福〜、高温、短時間〜長時間に至る寸
で、求める濃縮液の濃度に応じて任意に設定し得る。
At this time, the above heat treatment prevents deterioration and volatilization of the garlic aroma due to heating during concentration.Concentration conditions are low, high, and short to long. It can be set arbitrarily depending on the desired concentration of the concentrated liquid.

本発明では、上記のようにして得られ、る濃縮液に、こ
れとは別に調製した酵素アリナーゼを含んだ酵素剤を加
えて最終品とする。酵素剤としては、生ガーリック搾汁
液、粉末ガーリノク、ガーリ、クペースト、アリナーゼ
の粗酵素剤等を使用することができる。この場合の酵素
剤の添加量は、少なくとも前駆体アリーンから香気成分
アリシンが50チ以上発生するだけの量、例えば、生ガ
ーリック搾汁液の場合、基本となる濃縮液に対し1〜2
0係(重璧比)添加することが好ましく、キの他の酵素
剤の添加量も、その形態に応じて適宜設定し2うる。尚
、本発明では、上記のように酵素剤の添加量を変えるこ
とによって、最r冬品の香気の強さを容易に調整するこ
とが可能である。
In the present invention, an enzyme agent containing the enzyme allinase prepared separately from this is added to the concentrate obtained as described above to obtain a final product. As the enzyme agent, fresh garlic juice, powdered garlic powder, garlic, cupaste, crude enzyme agent of allinase, etc. can be used. In this case, the amount of the enzyme agent added is at least enough to generate at least 50 units of the aroma component allicin from the precursor allene, for example, in the case of fresh garlic juice, it is 1 to 2 times the amount of the enzyme agent added to the base concentrated liquid.
It is preferable to add the other enzyme agent at a ratio of 0 (weight ratio), and the amount of the other enzyme agent added can also be set as appropriate depending on the form thereof. In addition, in the present invention, by changing the amount of the enzyme agent added as described above, it is possible to easily adjust the aroma intensity of the last winter product.

作だ、上記の酵素剤を添加する際に、適宜の調味料、着
色料、着香料等を併せて添加することも可能である。
However, when adding the enzyme agent mentioned above, it is also possible to add appropriate seasonings, coloring agents, flavoring agents, etc.

尚、上記のように濃縮液に酵素剤を添加すると、直ちに
ガーリック香気が発工Qするが、酵素の添加は、作業的
に簡略かつ単時間であるため、これを直ちに容器に充填
すj、ば、作業中のにんにく臭及び最終品の品質の劣化
(d全く間躍とならない。
In addition, when an enzyme agent is added to a concentrated liquid as described above, a garlic aroma is immediately produced, but since adding an enzyme is a simple and time-consuming process, it should be immediately filled into a container. For example, the smell of garlic during work and the deterioration of the quality of the final product (d does not occur at all).

捷だ、上記のように酵素剤を添加した濃縮液は、酵素剤
を添加後約30分〜5時間程度経過すると、その香気の
発現が最大となる。しかし酵素剤を添加後の濃縮液を、
70℃を超える高温或は15℃未満の低温で放置するこ
とは、酵素アリナーゼの酵素活性を極端に低下させるた
め、好ましくない。
However, the concentrated liquid to which the enzyme agent has been added as described above will exhibit its maximum aroma about 30 minutes to 5 hours after the addition of the enzyme agent. However, the concentrated liquid after adding the enzyme agent,
It is not preferable to leave it at a high temperature exceeding 70°C or a low temperature below 15°C, as this will extremely reduce the enzymatic activity of the enzyme allinase.

丑だ、上記のように酵素剤を添加後に容器等に充填さf
′1.た濃縮液は、殺菌効果を有するアリシンを多量に
含有するため、非常に高い保存性を有するものと4(る
Unfortunately, as mentioned above, after adding the enzyme agent, it is filled into a container etc.
'1. The concentrated solution contains a large amount of allicin, which has a bactericidal effect, so it has a very high shelf life.

以−し、本発明濃縮ガーリック液の製造法によれば、特
に濃縮時の加熱による香気の変質を招かず、十ガーIJ
 ツクと全く同様の優れた香気を有する濃縮ガーリック
液を得ることが可能である。′1′だ、同時に本発明(
てよれば、濃縮時のガIJ ツク香気の■散が防止され
、最°終品として得られる。ek縮液の香気は非常に強
く、別途回収した香気成分を添加する必要が4【<、寸
だ、作リック液を製造することが可能である。
Therefore, according to the method for producing concentrated garlic liquid of the present invention, the aroma does not change due to heating during concentration, and the
It is possible to obtain a concentrated garlic liquid with an excellent aroma exactly like that of Tsuku. '1', and at the same time the present invention (
According to this method, the dispersion of gas aroma during concentration can be prevented and the final product can be obtained. The aroma of ek condensation liquid is very strong, and it is possible to produce ek condensation liquid without adding separately recovered aroma components.

実施例1 脱皮した生ガーリックをスチーム釜によって95℃で5
分間蒸煮し、ガーリック中に含まわ。
Example 1 Fresh garlic that has been dehulled is heated to 95°C in a steam pot for 50 minutes.
Steam it for a minute and add it to the garlic.

るアリナーゼを失活させた。蒸煮後のガーリノクをミン
チャーて磨砕後、遠心分離機にかけて搾汁液を得た。こ
の搾汁iをエバポレーターによって70〜75℃で濃縮
し、水分25%の濃縮液を得た。この濃縮液10kQに
、別((調製した生ガーリンク搾汁液0.5kg全混合
して、合成樹脂製の容器(C充填し、約1時間保存した
後容器を開封して濃縮ガーリノク液を得た。上記のよう
にI〜て得ら植、た濃縮ガーリンク液は、強い生ガーリ
、り本来の香気を有する、非常に/層厚なものであった
Allinase was inactivated. After steaming, the Garlinok was minced and ground, and then centrifuged to obtain a squeezed liquid. This squeezed juice i was concentrated at 70 to 75°C using an evaporator to obtain a concentrated liquid with a moisture content of 25%. 10 kQ of this concentrated liquid was mixed with 0.5 kg of the prepared raw garlic juice, filled in a synthetic resin container (C), and stored for about 1 hour, then opened the container to obtain concentrated Garinok liquid. The concentrated garlic liquid obtained as described above was very thick with a strong raw garlic aroma.

特許出願人 ハウス食品工業株式会社Patent applicant: House Foods Industry Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 生ガーリックを加熱して、該生ガーリツク中の酵素アリ
ナーゼを失活させた後、加熱処理後のガーリックを常法
によって搾汁・濃縮し、こわ、に酵素アリナーゼを含ん
だ酵素剤を添加することを特徴とする、濃縮ガーリック
液の製造法。
After heating the raw garlic to inactivate the enzyme allinase in the raw garlic, the garlic after the heat treatment is squeezed and concentrated by a conventional method, and an enzyme agent containing the enzyme allinase is added to the crushed garlic. A method for producing concentrated garlic liquid, characterized by:
JP58071938A 1983-04-23 1983-04-23 Production of concentrated garlic juice Granted JPS59196064A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58071938A JPS59196064A (en) 1983-04-23 1983-04-23 Production of concentrated garlic juice

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58071938A JPS59196064A (en) 1983-04-23 1983-04-23 Production of concentrated garlic juice

Publications (2)

Publication Number Publication Date
JPS59196064A true JPS59196064A (en) 1984-11-07
JPH0440980B2 JPH0440980B2 (en) 1992-07-06

Family

ID=13474947

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58071938A Granted JPS59196064A (en) 1983-04-23 1983-04-23 Production of concentrated garlic juice

Country Status (1)

Country Link
JP (1) JPS59196064A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030062770A (en) * 2002-01-18 2003-07-28 전희수 Manufacturing method of yellow earth garlic sap
EP1868439A1 (en) * 2005-04-09 2007-12-26 Ecospray Limited A pesticide and repellant
CN102382020A (en) * 2010-08-31 2012-03-21 成都菊乐制药有限公司 Method for simultaneously extracting alliin and garlic enzyme from garlic
CN105309901A (en) * 2014-07-17 2016-02-10 财团法人南海蒜研究所 Garlic powder containing high concentration of alliin and preparation method therefor

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030062770A (en) * 2002-01-18 2003-07-28 전희수 Manufacturing method of yellow earth garlic sap
EP1868439A1 (en) * 2005-04-09 2007-12-26 Ecospray Limited A pesticide and repellant
GB2434313B (en) * 2005-04-09 2009-11-11 Ecospray Ltd A pesticide and repellent
US9526254B2 (en) * 2005-04-09 2016-12-27 Ecospray Limited Pesticide and repellant
EP1868439B1 (en) * 2005-04-09 2017-11-22 Ecospray Limited A pesticide and repellant
CN102382020A (en) * 2010-08-31 2012-03-21 成都菊乐制药有限公司 Method for simultaneously extracting alliin and garlic enzyme from garlic
CN105309901A (en) * 2014-07-17 2016-02-10 财团法人南海蒜研究所 Garlic powder containing high concentration of alliin and preparation method therefor

Also Published As

Publication number Publication date
JPH0440980B2 (en) 1992-07-06

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