JPS59187100A - Ornament detergent composition - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed description of the invention] The present invention relates to personal accessories 9 such as glasses and necklaces.

This invention relates to a composition for cleaning dirt from watch bands and other accessories. More specifically, the present invention relates to a composition for easily removing stains caused by the use of personal accessories as described above.

In daily life, mirrors, necklaces, watch bands, etc. gradually become dirty with use, and especially the dirt that accumulates in their slits cannot be easily removed.

For example, dirt accumulates in the small gaps between the lenses and frames of glasses, the bent parts of the frames, and sometimes lines appear on the metal parts. Depending on the situation, it may not be easy to remove it. In addition, dirt accumulates in narrow gaps or invisible parts of connecting parts and bent parts of necklaces, watch bands, etc., and is similarly difficult to remove.

Although these personal accessories can be removed by simply wiping the dirt off, they are extremely small and have small pores.
Invisible parts and bends are covered with fat, protein and sweat from the human body, and dust from the air.

÷(＃ Bacteria, Q, etc. are reeded, and these act appropriately to form different stains. These stains are not only unhealthy in themselves, but also unhealthy. Gives pleasure.

These stains cannot be easily removed with water, dilution, or regular detergent, and even if a brush is used, stains in the crevices that cannot be reached by the tip of the brush cannot be removed.

Conventional 1. There is a method using ultrasonic vibration as a means for removing dirt from these personal accessories, especially eyeglasses. This method attempts to physically remove dirt by applying ultrasonic vibrations to the instrument underwater and photographing it, and it is possible to remove a considerable amount of dirt. However, since this cleaning method uses vibration in principle, it has the disadvantage that the plating may peel off, the coating on the lens may peel off, and sometimes the equipment may even malfunction.Additionally, this cleaning device is expensive. Therefore, it has the disadvantage that it is not suitable for general household use.

Therefore, the present inventor conducted research on a method for cleaning personal accessories that does not have the above-mentioned drawbacks and can be easily cleaned not only at home but also from any place, and even dirt in any crevices. The inventors have discovered that stains can be removed extremely easily by simply dissolving a composition containing the above ingredients in water or hot water and immersing the soiled personal accessories in this aqueous solution, thereby achieving the present invention.

That is, the first invention of the present invention is (=1.l protein 5
1 degradation (inmine and/or lipolysis [IY element and (bl
A personal accessory cleaning composition containing a surfactant,
Furthermore, the second present invention provides (at protease and/or
Alternatively, it is a composition for cleaning portable equipment comprising a lipolytic enzyme, (b) a surfactant, and (cl foaming agent).

According to the present invention, by simply dissolving the above composition in water and soaking the dirty personal accessories to be cleaned in the resulting aqueous solution, not only ordinary surface stains but also surface stains can be removed. The dirt in the crevices is easily removed by the action of enzymes and surfactants. In particular, by adding KL foaming agent, air bubbles are generated in the processing liquid, and the action of the air bubbles shortens the cleaning time due to the cleaning effect of the air bubbles on the surface of personal accessories and the stirring effect of the entire processing liquid. Not only that, but also the cleaning effect is extremely high. Surprisingly, with the composition of the present invention, the regeneration caused by gold (such as brass) is
It was generated within the crevice and can now be easily removed.

In the present invention, the objects to be cleaned are those worn on the body such as eyeglasses, Nenkoresu 2 watch bands, fRm, etc., such as special metals, plastics, etc. Alternatively, it is appropriate to use a combination thereof as the main material.

As mentioned above, the object of the present invention can be more effectively achieved by a shaver that has a narrow part or a bent part, or a shaver that has fine workmanship. (Similarly, the cleaning of the present invention can also be applied to the cleaning of the present invention.In particular, for eyeglasses, the surface of the lens can be cleaned at the same time, and the dirt around the lens and frame, as well as the dirt at the kumquat joint, can be cleaned in four places.) Since it can be easily and completely removed by cleaning, it is effective as an object to be cleaned in the present invention.

As the protease, commonly known ones can be used, such as papain.

Zolomeline, Chymotrypsin, Trypsin, Chymotrypsin, etc.! ! ! ll plant origin, Aspergill
-us Fi + R4zopus Fi, B
Examples include proteolytic oxygen derived from microorganisms such as P. acillus (i), and mucoproteases such as hyaluronidase, duronase, and fundroitin degrading enzyme.

Also, commonly known fat WI enzymes are used, such as A8pergillus fi, Mn
co-rgenus fA, Riy, opus
Examples include lipolytic enzymes originating from m.

These proteolytic enzymes ζ It is more effective to use them in combination.

These (al components (enzymes) are 1 to 20% by weight per composition.
It is preferable that the number of particles is 2 to 5, preferably 2 to 5. Special (C tanobaku'iQ minute 111I? accumulation and fat content j4
When using 7 n de vermilion in combination, the former is 1 to 10%, preferably 2. to 8%, and the latter is 0.1 to 10%, preferably 0.
．． It is 11 (11) that contains 2.-8.

On the other hand, (1)) any commonly known surfactant may be used, but it must be one that does not alter or damage plastics, such as a non-ionic surfactant. Among the surfactants, fatty acid-based surfactants are not so preferred; for example, polyoxyethylene furkyl ether, polyoxyethylene boron, and lyoxybrobylene alkyl ether are preferable, and among anionic surfactants, alkyl sulfates are preferable.

Polyoxyethylene alkyl ether li! iER3N
+N-acyl amino acid salt, polyoxyethylene/alkyl ether acetate, alkyl sulfophosphate, a-
Olefin sulfone i! l! IfX and the like are preferred, and particularly preferred are polyoxyethylene alkyl ether, polyoxyethylene poly-V pyrenefurkyl ether, alkyl sulfate, and polyoxyalkyl ether sulfate. These surfactants may range from 3 to 30% by weight per composition.
20%.

It is advantageous to use preferably a range of 5 to 15 strokes.

In addition, (e) the foaming agent may be one that reacts in water to generate gas such as carbon dioxide, such as carbonates such as sodium hydrogen carbonate, potassium hydrogen carbonate, sodium percarbonate, and industrial water phosphorus. Preferred examples include combinations of acidic substances such as dibasic acid and potassium citrate.

These fc) foaming agents are 20 to 60 inches by weight per composition;
It is preferably used in an amount of about 25 to 50%.

In addition, the composition of the present invention includes perfume and A coloring agent.

Even if dispersants, binders, (PEG, etc.), moisture proofing agents (silica gel, etc.), pH adjusters, etc. are mixed with the alloy in the evening (・
. The composition of the present invention may be in powder form, but it is convenient to use it in solid form. Its shape may be tablet, pellet, disc, 9 spheres, or the like.

To clean the personal accessories described above using the composition of the present invention, pour water or hot water (preferably between room temperature and 50°C) into a container, add the composition to the container, and wash (- The personal item may be soaked for a period of about 1 hour or more, preferably 2 hours or more. - It may be soaked day and night.

After washing, take out your personal accessories, wash them with water, dry them, and the dirt will be completely removed, leaving you clean. Therefore, the composition of the present invention is extremely convenient because it can be easily used at home or at any time. Moreover, the cleaning power is excellent down to the smallest detail, and there are no drawbacks that can be found with the use of ultrasonic vibrations.

Below are 4 examples? The present invention will now be described in detail.

Example compositions 1, 2.3 were prepared and compared with commercially available neutral kitchen detergents in terms of cleaning efficacy and effects on eyeglass frames.

Composition 1゜Lipolytic enzyme produced by Aspergillus (15,000u/g)
, 2 Proteolytic tVj elements derived from Aspergillus (so, 000u, 7g)
Monophosphate disodium
7 Sodium lauryl sulfate 8 Citric acid 18 Sodium hydrogen carbonate 19 Sodium percarbonate 45100 Heavy Tsumebe Group Acid 2 Lipolytic enzyme produced from Mucorg@nugI'@ (ts, ooou/g) 2Rizop
Proteolytic enzyme (eo, ooou/g) produced from the genus Us
Disodium phosphate 8 polyoxyethylene polyoxypropylene cetyl ether (P
OE:20 pop:s) 8 citric acid
1B Sodium hydrogen carbonate
19 Sodium percarbonate
44100 parts by weight Composition 3゜Lipolytic enzyme produced from Asp@rgillusM (10?000 u/g) 2Proteolytic enzyme papain (6o, ooou/g) 1Disodium phosphate 8Diethylhexylsulfoconomonolyphosphate 8 Sodium citric acid 18 Sodium hydrogen carbonate 19 Sodium percarbonate 44,100 parts by weight The above compositions 1, 2 and 3 were mixed uniformly, respectively, and then molded to obtain a tablet-shaped product of the present invention.

Each composition contains 0.1-1.5% when used, preferably 0.
．． 4-: Used as an aqueous solution of o, 7Llj. Washing temperature is 10°C to 55°0. Preferably 30°C to 45°C
The cleaning (soaking) time is 1 hour to 24 hours, preferably 1 hour and 30 minutes to 4 hours.

The cleaning power and degree of damage to eyeglass frames (especially plastic parts) were compared between compositions 1 and 2.3 of the present invention and a commercially available neutral kitchen detergent (containing 32qb of higher alcohol-based and fatty acid-based surfactants). We investigated the effectiveness.

First, the artificial contaminants used in the test were prepared.

Dirt on glasses is originally caused by fatty sweat, waste products from broken skin, etc., and is formed by a combination of foreign matter in the air such as dust. Therefore, the inventor prepared a model stain using the following formulation.

Ranid 4g Collagen (cow skin) 3 Albumin (egg white) 1 Sodium chloride 0.07 Urea 0.01 Sodium fluorescein 0.005 Water
To adjust the 1occ above model stain, add 0.07g of sodium chloride to 100c of water.
Urea 0.01 g, fluorescein sodium 0.0
05 g was dissolved, and 1 g of albumin (egg white) + 3 g of collagen (cow skin) were added, heated to dissolve and swell, and 4 g of lard was added and allowed to cool while stirring to prepare a uniform slightly yellowish-orange artificial contaminant.

The reason why sodium fluorescein was used here was because it was judged that the fluorescent property of sodium fluorescein would make it easier to judge the degree of stain removal.

3 g of artificial contaminants were applied to the lenses and the gap between the frames and lenses of four glasses with the same frame and glass lenses of the same power, and air-dried indoors for 4 hours to obtain contaminated glasses for use in the test.

Next, 1.8 g each of compositions 1 and 2.3 was applied to each side at 35°C.
was added to a container containing 300 cc of water, and the contaminated glasses were immersed one by one in the container for 4 hours.

As a control, a commercially available neutral kitchen detergent containing a fatty acid surfactant and a higher alcohol surfactant (containing 32%)
0.45 CC was similarly added to 35°C water and one contaminated goggle was immersed for 4 hours.

After soaking, the glasses were washed with running tap water, and the degree of dirt removal from each group was observed under an ultraviolet lamp.

Next, in order to observe the degree of damage to eyeglass frames in each district,
After thoroughly washing the frame with water and wiping off the water with a soft cloth, it was observed with the naked eye.

The results are shown in the table below.

Composition i, +++ ten++/1
2. +++,
++ Composition 3. +++
+++ Control group - (Commercial kitchen detergent) +→10 Completely removed → 10 Almost removed Significantly removed - Effect on remaining frame Glossiness of metal parts Cloudy composition of plastic parts l
Good No ν 2 Good
Nothing!・3. good
Non-contrast area - VI Yes (commercial kitchen detergent) Patent applicant: Oftex Co., Ltd.

Claims (1)

[Scope of Claims] 1. A personal accessory cleaning composition comprising (al protein fraction M enzyme and/or lipolytic enzyme and (bl surfactant). 2. (a) proteolytic enzyme and/or A personal accessory cleaning composition comprising a lipolytic enzyme, (b) a surfactant, and (el foaming agent).