JPS59186688A - Production of water by electrolysis - Google Patents

Production of water by electrolysis

Info

Publication number
JPS59186688A
JPS59186688A JP6199383A JP6199383A JPS59186688A JP S59186688 A JPS59186688 A JP S59186688A JP 6199383 A JP6199383 A JP 6199383A JP 6199383 A JP6199383 A JP 6199383A JP S59186688 A JPS59186688 A JP S59186688A
Authority
JP
Japan
Prior art keywords
water
level
anode chamber
chamber
cathode chamber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6199383A
Other languages
Japanese (ja)
Other versions
JPS638832B2 (en
Inventor
Tatsuo Okazaki
龍夫 岡崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP6199383A priority Critical patent/JPS59186688A/en
Publication of JPS59186688A publication Critical patent/JPS59186688A/en
Publication of JPS638832B2 publication Critical patent/JPS638832B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/4618Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water
    • C02F2001/4619Devices therefor; Their operating or servicing for producing "ionised" acidic or basic water only cathodic or alkaline water, e.g. for reducing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level

Abstract

PURPOSE:To prevent degradation of taste of generated water by performing stopping of feeding of water by providing a level sensor at a high position than the top opening of an overflow passage and discharging water to keep the water level of a cathode chamber above the water level of an anode chamber. CONSTITUTION:When the water level in a storage tank 14 attains below the specified level, a level sensor detects it and operates a control system to open a feed water valve 11. When the water level in the cathode chamber 3 exceeds the top opening of the overflow passage 12, water begins to enter the anode chamber 4 through the passage 12. When the water level of the anode chamber exceeds the top opening of the passage 12, the levels of both electrode chambers 3, 4 are elevated up to the same level, and the level sensor 13 operates to close the feed water valve 11. A DC voltage is impressed to the electrodes 5, 6, and electrolysis is performed during the time set by a timer, etc.

Description

【発明の詳細な説明】 不発明は、アルカリイオン水を生成する電解水の製造装
置に関するものであシ、とくに、パージ式に電解水を連
続製造するための構成を持った電解水の製造装置に関す
るものである。
[Detailed Description of the Invention] The invention relates to an electrolyzed water manufacturing device that generates alkaline ionized water, and in particular, an electrolyzed water manufacturing device that has a configuration for continuously manufacturing electrolyzed water using a purge method. It is related to.

どの種の製造装置としては、本発明者によって、既に、
第1図およ゛び第2図に示すような方式が採用されてい
た。第1図にみられるものは、陰極室aと陽極室すとを
素焼などの隔壁Cで仕切り、そhぞれ両極室a、b内に
電id、eを配す涙し、こヌに直流電圧を印加し、水の
電気分解および電気滲透作用を行なうようにすると共に
、各極室はそれぞれ底部に排水弁f、gを配置している
もので、給水は陰極室aに対して行なわわ5、陽極室b
Kはレベルセンサhを配置し、陰極室aから隔壁Cを越
えて水を陽極室すに供給する形式になっていて、レベル
センサhの働きで自動給水停止を行なうようにガってい
る。この製造装置では、陰極室aから排水弁fi介して
供給されたアルカリイオン水を貯蔵するタンクiかあシ
、こXにはレベルセンサjが設けてあって、レベルセン
サJがJFiiタンクiの水が使用されであるレベル以
下になった時、これを信号として制御系(図示せず)に
伝え、給水、電解、排水のシーケンス作業を行なうよう
になっている。こ\で問題になる点は、陰極室aの上部
の水がその電解過程で隔壁Cを越えて陽極室すに流入す
る点である。この問題点を理解するには、次のよう々実
際の状況を知らなければならない。電気分解を行なうと
、よく知らn−るように、陰極室a内では電気滲透作用
で水レベルが上昇すると共に、水酸基イオン濃度が高く
なるか、この水酸基イオンの分布は、上方に片寄シ、上
方で濃度が高く、下方で低いという状況が実現する。一
方、陽極室す内では、電気滲透作用で水レベルが下降す
ると共に、酸性度が上方で高く、下方で低いという分布
状況を実現する。したがって、電解中、電気滲透作用で
陰極室aのレベルが上昇すると、最も水酸基イオン濃度
の高い水の部分が、隔壁Cを越えて陽極室すに入シ、中
和作用を起すため、陰極室a内の水の平均的水酸基イオ
ン@度を所定値にあけるまでに相当の時間を要し、電力
ロスも大きいという性能上のデメリットが発生する。
What kind of manufacturing equipment has already been developed by the inventor of the present invention?
The system shown in Figures 1 and 2 was adopted. What can be seen in Figure 1 is that the cathode chamber a and the anode chamber are separated by a partition wall C made of unglazed ceramic, etc., and the electrodes id and e are placed in the bipolar chambers a and b, respectively, and a direct current is applied to the cathode chamber a and the anode chamber. A voltage is applied to cause water electrolysis and electroosmosis, and drain valves f and g are arranged at the bottom of each electrode chamber, and water is supplied to the cathode chamber a. 5. Anode chamber b
K is provided with a level sensor h, and is configured to supply water from the cathode chamber a over the partition wall C to the anode chamber, and the water supply is automatically stopped by the action of the level sensor h. In this manufacturing equipment, a level sensor j is installed in a tank i and a tank When the water used drops below a certain level, this signal is transmitted to a control system (not shown), which performs the sequence of water supply, electrolysis, and drainage. The problem here is that water in the upper part of the cathode chamber a flows over the partition wall C into the anode chamber during the electrolysis process. To understand this problem, we must know the actual situation as follows. As is well known, when electrolysis is carried out, the water level in the cathode chamber a rises due to electroosmosis, and the concentration of hydroxyl ions increases, or the distribution of hydroxyl ions shifts upward. A situation is realized in which the concentration is high at the top and low at the bottom. On the other hand, inside the anode chamber, the water level decreases due to electroosmosis, and a distribution situation in which acidity is high at the top and low at the bottom is realized. Therefore, during electrolysis, when the level in the cathode chamber a rises due to electroosmosis, the part of the water with the highest hydroxyl ion concentration crosses the partition wall C and enters the anode chamber, causing a neutralizing effect. It takes a considerable amount of time to bring the average hydroxyl ion concentration of water within a to a predetermined value, and there are performance disadvantages such as large power loss.

また、第2図にみもれるように、陽極室す側に水を供給
し、レベルセンサhは陰極室a側に配置する方式も採用
された。こ\では、初期給水段階において、オーバフロ
ーにより陰極室a側に給水される関係で、酸性水側に残
されたスケール(ABS樹脂々どの樹脂系、電気分解残
留物、電極溶出物、サルファーなど)が陰極室a側に人
見また、残留酸性水が入る可能性がある、このため、陰
極室aで飲料に供する食味のアルカリイオン水を生成し
ても、先きに入ったスケール、残留酸性水などで味の質
を著しく低下するという欠点がある。
Furthermore, as shown in FIG. 2, a method was adopted in which water was supplied to the anode chamber side and the level sensor h was placed on the cathode chamber a side. In this case, during the initial water supply stage, water is supplied to the cathode chamber a side due to overflow, so scales left on the acidic water side (ABS resin and other resin systems, electrolysis residue, electrode eluate, sulfur, etc.) However, there is a possibility that residual acidic water may enter the cathode chamber A side. Therefore, even if alkaline ionized water with a flavor suitable for drinking is produced in cathode chamber A, the scale that has entered earlier and the residual acidic water may enter the cathode chamber A side. The drawback is that the quality of the taste is significantly reduced by water, etc.

不発明は、上記事情にもとづいてなさねたもので、陰極
室から陽極室へのオーバフロー形式ではあるが、水酸基
イオン濃度をあげる効率は低下させず、しかも、生成さ
れたアルカリイオン水の味覚を低下させることがないよ
うにした電解水の製造装置を提供しようとするものであ
る。
The non-invention was made based on the above circumstances, and although it is an overflow type from the cathode chamber to the anode chamber, it does not reduce the efficiency of increasing the hydroxyl group ion concentration, and moreover, it does not change the taste of the generated alkaline ion water. It is an object of the present invention to provide an apparatus for producing electrolyzed water that does not cause deterioration.

以下、本発明の一実施例を第3図を参照して具体的に貌
、明する。図において、符号1は、パージ式に飲料水を
生成する電解槽であシ、例えば、円筒状の素焼などのポ
ーラスな隔壁2で内外2室に仕切シ、外側を陰極室3、
内側を陽極室4としたものである。そして、各極室3.
4にはそtぞれ*、極5.6が配置されていて、スイッ
チ・オンによって直流電圧が印加されるようになってい
る。
Hereinafter, one embodiment of the present invention will be explained in detail with reference to FIG. In the figure, reference numeral 1 denotes an electrolytic cell that generates drinking water in a purging manner. For example, it is partitioned into two internal and external chambers by a porous partition wall 2 made of cylindrical bisque, and the outside is a cathode chamber 3.
The inner side is an anode chamber 4. And each pole chamber 3.
4 are provided with poles 5 and 6, respectively, and a DC voltage is applied when the switch is turned on.

丑/C1各極室3.4の底部には、排水芹・7.8が設
けてあわ、そこにはンレノイド式の制水弁9.10が設
けである。また、陰極室3に標゛維水弁11を介して水
が供給さhるようになっておシ、オた、陰極室3の底部
から陽杯・室4内の頂部にオーバフロー通路12が設け
らtでいる。この実が一1例では、上記」−バフロー通
路12は管状体で構成さjている。一方、陰極室3内に
はレペルセ:/ザ13が設けてあシ、その水との接触レ
ベルは上記オーバ70−通路12の頂部よシ罵りなって
いる。
A drainage valve 7.8 is provided at the bottom of each electrode chamber 3.4 of OX/C1, and a water control valve 9.10 of a water-reinoid type is provided there. In addition, water is supplied to the cathode chamber 3 via the fiber water valve 11, and an overflow passage 12 is formed from the bottom of the cathode chamber 3 to the top of the positive cup chamber 4. It's set up. In this case, the buff flow passage 12 is formed of a tubular body. On the other hand, in the cathode chamber 3, there is provided a repercussion 13 whose contact level with water is higher than that of the top of the overpass 70 and the passage 12.

なお、図中、符号14は排水路7に通じる貯蔵タンクで
アシ、これには供給用カラン15が設けら力、また、V
ベルセンサ16が設けらj−ている。
In the figure, reference numeral 14 denotes a storage tank connected to the drainage channel 7, and a supply column 15 is installed in this tank.
A bell sensor 16 is provided.

次に、この装置縦のンーケンシャルな11作を説明する
。貯蔵タンク14内の水が所定レベル以下になると、レ
ベルセンサ16がこれを検知して、図示しない制御系′
(i7動作し、給水弁11を開放させる。陰極室3内の
水レベルかオーバ70−通路12の頂部開口を越えると
、±sb通路12を介して陽極室4内に水が入シはじめ
る。陽極室4の水レベルが上記ヤーバフロー通路12の
頂部開口を越えると1両樅室3および4は同レベルで水
位をあげ、第3図のような水位にいたって、レベルセン
サ13が伎1き、給水弁11を閉じ、電極5.6にjα
流電圧を印加し、タイマーなどで設定された時間、電気
分触を行々う。
Next, I will explain the 11 sequential works of this device. When the water in the storage tank 14 falls below a predetermined level, the level sensor 16 detects this and a control system (not shown) is activated.
(i7 operates to open the water supply valve 11. When the water level in the cathode chamber 3 exceeds the top opening of the over 70 passage 12, water begins to enter the anode chamber 4 through the ±sb passage 12. When the water level in the anode chamber 4 exceeds the top opening of the Yerba flow passage 12, the water level in the two fir chambers 3 and 4 rises to the same level, and the level sensor 13 reaches the level shown in FIG. , close the water supply valve 11, and apply jα to the electrode 5.6.
A current voltage is applied, and electricity is distributed for a set time using a timer or the like.

この電気分解の過程で、霜、父滲透作用により、陽極室
4から陰イ企室3への水の移動があるが、オーバフロー
通路12を介して陰極室3から陽@j室4への還流によ
シ、陽極室3.4間で水レベルの差は生U、ない。しか
も、オーバフロー通路から陽極室4への水の海流は、陰
イψJ室3の底部から行なわt7ているから、一番イオ
ン濃度の低い水が還流さt]るのであり、陰極室3の上
部のイオン濃度の高い水の部分は陰極室3に保持される
。しかも、電解中は、オーバフロー通路12からの水の
流わけ一方的であυ、陽極室4の水は電体滲透作用によ
ってしか、陰極室3には入り存力いのである。
During this electrolysis process, water moves from the anode chamber 4 to the anode chamber 3 due to frost and permeation, but water refluxes from the cathode chamber 3 to the anode chamber 4 via the overflow passage 12. Unfortunately, there is no difference in water level between anode chambers 3 and 4. Furthermore, since the ocean current of water from the overflow passage to the anode chamber 4 is carried out from the bottom of the anode chamber 3, the water with the lowest ion concentration is refluxed, and the water with the lowest ion concentration is refluxed from the top of the cathode chamber 3. The water portion with a high ion concentration is retained in the cathode chamber 3. Moreover, during electrolysis, the flow of water from the overflow passage 12 is unidirectional, and the water in the anode chamber 4 can only enter the cathode chamber 3 by the action of electric permeation.

電解作用が完了すると、タイマー橙どの働きで電極5.
6への電圧印加が解除さカー、各排水弁9.10が開放
され、陰4M室3のアルカリイオン水は貯蔵タンク14
に入り、陽極室4側の酸性水け、この実施夕11では、
排水弁10を介して排出される。
When the electrolytic action is completed, the timer (orange) activates the electrode 5.
When the voltage application to the car 6 is released, each drain valve 9.10 is opened, and the alkaline ionized water in the negative 4M chamber 3 is drained into the storage tank 14.
In this implementation evening 11, the acid water on the anode chamber 4 side was
It is discharged via the drain valve 10.

なお、この実施例では、vト水弁10がさきに開放され
て、オーバフロー通路12の頂部開ロレペル以下1で陽
極室4のレベルが下る才で、排水弁9の開放を遅らせる
とよい。このために、陰柩室3には別のレベルセンサ1
7を設けるとよい。この間、陰極室3の底部の水は、オ
ー・々フロー通路12を介して、陽椋室4偶に流れるの
で、オーバフロー通路12を介して、酸性水が陰極室3
側ももたらされる量は完全にlくなる。なお、排水弁9
.10を同時開放しても、陽極室4の水レベルが陰極室
3のそtlよ勺も下になるようにレベル降下速度か大き
ければ、実質的にオーバフロー油路12を介して陰41
訳室3から陽極室4へ水があふわ、逆に陽極室4の水が
陰極♀3 (1!lに流入されるおそれはない。
In this embodiment, it is preferable to open the water valve 10 first and delay the opening of the drain valve 9 so that the level of the anode chamber 4 decreases by 1 below the opening of the top of the overflow passage 12. For this purpose, another level sensor 1 is installed in the shade room 3.
It is good to provide 7. During this time, the water at the bottom of the cathode chamber 3 flows through the overflow passage 12 to the positive chamber 4, so that acidic water flows through the overflow passage 12 into the cathode chamber 3.
The amount brought on the side will also be completely l. In addition, the drain valve 9
.. Even if 10 are simultaneously opened, if the water level in the anode chamber 4 is lower than that of the cathode chamber 3 at a high level drop rate, the water level in the anode chamber 4 will be substantially lower than that of the cathode chamber 3 through the overflow oil passage 12.
Water flows from the translation chamber 3 to the anode chamber 4, and conversely, there is no risk that water from the anode chamber 4 will flow into the cathode ♀3 (1!l).

実際にはオーバフロー通路12の底部開口(ri、排水
路7の開口とできるだけ離して、排水の1川」、オーバ
フロー通路12に対して、吸引作用が働かないように工
夫するのがよい。このために、図示のようにオーバフロ
ー通路n路12の底部開口は、排水路7のそれとは正反
対側に位置さ力、る。
In reality, it is best to devise measures to prevent suction from acting on the bottom opening (ri) of the overflow passage 12, as far as possible from the opening of the drainage channel 7, so that no suction action is applied to the overflow passage 12. As shown, the bottom opening of the overflow passage 12 is located on the opposite side of the drain passage 7.

本発明は、以上詳述したように、陰極室と陽極室とをポ
ーラスな隔壁で仕切シ、両極室に電極を配置して、直流
直圧を印加し、水の電気分解および電気滲透をヤ)なう
ものにおいて、給水を陰8!家に対、−c6ない1.4
□(1) ag部から陽極室山頂うに連通ずるオーバフ
ロー通路を設け、両浴室はそれぞれ底部よ多排水弁を介
して排水する構成にすると共に、レベルセンサを上記オ
ーバフロー通路の頂部開口よ’) Kh <配置しでに
給水停止を行なうようにし、捷だ、排水弁を開いて排水
する時には少なくとも上記オーバフロー通路の頂部開口
よシ下まで陽極室の水レベルが降下のに対して、陰極室
の水レベルは陽極室の水レベルより十にあるように排水
するように構成したので、陰極室から陽’tgti4へ
のオーバフロー形式ではあるが、水酸基イオンmk K
をあける効率は低下させず、しかも、酸性水がアルカリ
イオン水側に入るおそわがないのでアルカリイオン水の
味覚を低下させないという効果が祷られる。
As described in detail above, the present invention partitions a cathode chamber and an anode chamber with a porous partition, arranges electrodes in both electrode chambers, applies direct current pressure, and controls water electrolysis and electroosmosis. ) In what is now, water supply is 8! vs. house, -c6 not 1.4
□(1) An overflow passage is provided that connects the ag part to the top of the anode chamber, and both bathrooms are configured to drain water from the bottom through multiple drain valves, and a level sensor is installed at the top opening of the overflow passage. <Be sure to stop the water supply before starting the installation, and when you open the drain valve to drain water, the water level in the anode chamber will drop to at least below the top opening of the overflow passage, whereas the water level in the cathode chamber will drop to below the top opening of the overflow passage. Since the water level was set to be 10 times higher than the water level in the anode chamber, the hydroxyl ions mk K
It is hoped that the efficiency of opening the bottle will not be reduced, and since there is no possibility that acidic water will enter the alkaline ionized water side, the taste of the alkaline ionized water will not be impaired.

4、し、1面の留j牢な説明 第1図および第2図は従来方式を示す図面、第3図は不
発明の一実施例を示すし1面である。
4. DETAILED DESCRIPTION OF PAGE 1 FIGS. 1 and 2 are drawings showing the conventional system, and FIG. 3 is the first page showing an embodiment of the invention.

1・・・・・・蜜釉槽、2・・・・・・隔壁、3・・・
・・・陰極室、4・・・・・・陽極室、5.6・・・・
・・型合、7.8・・・・・・排水路、9.10・・・
・・・排水弁、11・・・・・・給水弁、12・−・・
オーバ70−通路、13・・・・・・レベルセンサ、1
4・・・・・・貯蔵タンク、15・・・・・・供給用カ
ラン、16.17・・・・・レベルセンサ。
1... Honey glaze tank, 2... Partition wall, 3...
...Cathode chamber, 4...Anode chamber, 5.6...
・・Type match, 7.8・・・・Drainage channel, 9.10・・
...Drain valve, 11...Water supply valve, 12...
Over 70-passage, 13...Level sensor, 1
4...Storage tank, 15...Supply tank, 16.17...Level sensor.

特許出願人9(lコ 崎 iは 夫 手続補正書(方式) 昭和58年8月(1日 1、事件の表示 昭和58年特許願第61993号 2、発明の名称 3、補正をしだ者 事件との関係     特許出願人 任 所 埼玉県上福岡市西2丁目7番18号4 補正命
令の日付 昭和58年7月26日(御発送) 5、補正の対象 (1)図 面
Patent Applicant 9 (l Kozaki I) Written amendment (method) August 1988 (1st day 1, case indication 1982 Patent Application No. 61993 2, title of the invention 3, person who made the amendment) Relationship to the case Patent applicant location 4-2-7-18 Nishi, Kamifukuoka-shi, Saitama Date of amendment order July 26, 1980 (shipped) 5. Subject of amendment (1) Drawings

Claims (1)

【特許請求の範囲】[Claims] 陰極室と陽極室とをポーラスな隔壁で仕切′シ、両極室
に電極を配置して、直流電圧を印加し、水の電気分解お
よび電気滲透を行なうものにおいて、給水を陰極室に対
して行ない、陰極室の1部から陽極室内頂部に連通ずる
オーバフロー通路を設け、両極室はそれぞれλ部よυ排
水弁を介して排水する構成にすると共に、レベルセンサ
を上記オーバフロー通路の頂部開口よシ高く配置して会
動給水停止を行なうようにし、また、排水弁を開いて排
水する時には少なくとも上記オーバフロー通路の頂部開
口より下まで陽極室の水レベルが降下のに対して、陰極
室の水レベルは陽極室の水レベルよシ上にあるように排
水するように構成したことを%徴とする電解水の製造装
置。
A cathode chamber and an anode chamber are separated by a porous partition, electrodes are placed in both electrode chambers, and a direct current voltage is applied to perform water electrolysis and electroosmosis, and water is supplied to the cathode chamber. An overflow passage communicating from one part of the cathode chamber to the top of the anode chamber is provided, and both electrode chambers are configured to drain water from the λ part through υ drain valves, and the level sensor is placed higher than the top opening of the overflow passage. Furthermore, when the drain valve is opened to drain water, the water level in the anode chamber drops to at least below the top opening of the overflow passage, while the water level in the cathode chamber drops. An electrolyzed water production device characterized by being configured to drain water so that it is above the water level in the anode chamber.
JP6199383A 1983-04-08 1983-04-08 Production of water by electrolysis Granted JPS59186688A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6199383A JPS59186688A (en) 1983-04-08 1983-04-08 Production of water by electrolysis

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6199383A JPS59186688A (en) 1983-04-08 1983-04-08 Production of water by electrolysis

Publications (2)

Publication Number Publication Date
JPS59186688A true JPS59186688A (en) 1984-10-23
JPS638832B2 JPS638832B2 (en) 1988-02-24

Family

ID=13187230

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6199383A Granted JPS59186688A (en) 1983-04-08 1983-04-08 Production of water by electrolysis

Country Status (1)

Country Link
JP (1) JPS59186688A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0530673Y2 (en) * 1988-02-09 1993-08-05
JPH0716727U (en) * 1993-09-06 1995-03-20 小川珈琲株式会社 Drip coffee cup package

Also Published As

Publication number Publication date
JPS638832B2 (en) 1988-02-24

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