JPS59177813A - Method of forming transparent conductive coating film - Google Patents
Method of forming transparent conductive coating filmInfo
- Publication number
- JPS59177813A JPS59177813A JP5208483A JP5208483A JPS59177813A JP S59177813 A JPS59177813 A JP S59177813A JP 5208483 A JP5208483 A JP 5208483A JP 5208483 A JP5208483 A JP 5208483A JP S59177813 A JPS59177813 A JP S59177813A
- Authority
- JP
- Japan
- Prior art keywords
- coating film
- film
- transparent conductive
- resin
- conductive coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Non-Insulated Conductors (AREA)
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Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
この発明は透明導電性塗膜の形成方法に関しさらに詳し
くは、熱可塑性合成樹脂板などの対象物しこ透明性に優
れた導電性塗膜を形成する方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for forming a transparent conductive coating film, and more particularly to a method for forming a conductive coating film having excellent transparency on an object such as a thermoplastic synthetic resin plate.
透明導電性塗装を施こした熱可塑性合成樹脂板は、帯電
防止性に優れていることがら、主として半導体ウェハー
保存用容器その他の電子・電気部材や、窓枠、徳利、床
材などの建築用部材に用いられている。ところで、一般
に透明導電性塗料には金属元素またはその酸化物よりな
る導電性微粉末が含まれているため、生成した塗膜は曇
りを生しがぢであり、そのため塗膜の透明性および色調
が損なわれるうらみがあった。Thermoplastic synthetic resin boards coated with transparent conductive coating have excellent antistatic properties and are used primarily for semiconductor wafer storage containers, other electronic and electrical components, and architectural applications such as window frames, sake bottles, and flooring materials. Used for parts. By the way, since transparent conductive paints generally contain conductive fine powder made of metal elements or their oxides, the resulting paint film tends to be cloudy, which reduces the transparency and color tone of the paint film. There was a feeling of resentment that this would be damaged.
またこの塗膜はその吸湿性のために基板への密着性が低
下して基板から剥離するおそれがあった。Furthermore, due to its hygroscopicity, this coating film has a risk of decreasing its adhesion to the substrate and peeling off from the substrate.
この発明は、上記のような実情に鑑みてなされたもので
あって、帯電防止性を保持したままで、透明性を向上さ
せかつ基板への密着性を改良することのできる透明導１
Ｂ性塗膜の形成方法を提供することを目的とする。The present invention was made in view of the above-mentioned circumstances, and provides a transparent conductor that can improve transparency and adhesion to a substrate while maintaining antistatic properties.
The object of the present invention is to provide a method for forming a B-type coating film.
この発明による塗膜形成方法は、熱可塑性樹脂と導電性
微粉末を主成分とする塗料を用いて透明導電性塗膜を形
成するに当り、同塗料を対象物に塗布した後、塗膜を有
する対象物を加圧下に加熱することを特徴とするもので
ある。The coating film forming method according to the present invention involves applying a transparent conductive coating film to an object using a coating material whose main components are a thermoplastic resin and a conductive fine powder, and then applying the coating film to an object. It is characterized by heating the object under pressure.
透明導電性塗膜を形成する塗料としては公知のものがそ
のまま使用できる。その代表例としては市販の「透明静
電気防止塗料」（三菱金属株式会社製）や特開昭５７−
８５８６６号公報に記載されたものが拳げられる。塗料
の構成樹脂としては、ポリエステル系、アクリロニトリ
ル系、ポリ塩化ビニル系、ポリカーボネート系などの一
般塗料用の樹脂がいずれも使用できる。As the paint for forming the transparent conductive coating, known paints can be used as they are. Typical examples include the commercially available "transparent antistatic paint" (manufactured by Mitsubishi Metals Co., Ltd.) and the
The one described in 85866 is published. As the constituent resin of the paint, any resin for general paints such as polyester, acrylonitrile, polyvinyl chloride, and polycarbonate can be used.
導電性微粉末としては、金属元素またはその酸化物より
なる微粉末であって、特に光屈折率が樹脂の光屈折率１
６〜１．７に近くかつ微粉末の粉径が０２μ以下である
白色の微粉末が好ましく用いられる。粉径が０．２μを
越えたものは、可視光の散乱が多く、＠膜の透明性がＪ
ｊ→われるので、好ましくない。The conductive fine powder is a fine powder made of a metal element or its oxide, and in particular has a light refractive index lower than that of the resin (1).
A white fine powder having a particle size close to 6 to 1.7 and a fine powder diameter of 02 μm or less is preferably used. If the powder diameter exceeds 0.2μ, visible light will be scattered more and the transparency of the film will be lower than J.
j → It is not desirable because it will be destroyed.
塗料の塗布は常法にしたがって行なわれる。Application of the paint is carried out according to conventional methods.
その代表例としてはスプレー法、ロールコータ−法、グ
ラビア印刷法、オフセット印刷法などが挙げられる。塗
膜の厚さは０５〜２０ ｔｔ程度である。Typical examples thereof include a spray method, a roll coater method, a gravure printing method, and an offset printing method. The thickness of the coating film is approximately 0.5 to 20 tt.
塗装すべき対象物は加圧加熱に耐えるものであれば特に
限定されない。特に透明熱可塑性合成樹脂よりなる板状
物、シート、フィルムなどがよく用いられる。上記樹脂
の例としては、ポリ塩化ビニル樹脂、メタアクリル樹脂
、アクリロニトリル・ブタジェン拳スチレン樹脂、ポリ
カーボネート系脂などが挙げられる。The object to be coated is not particularly limited as long as it can withstand pressure and heating. In particular, plates, sheets, films, etc. made of transparent thermoplastic synthetic resin are often used. Examples of the resin include polyvinyl chloride resin, methacrylic resin, acrylonitrile-butadiene styrene resin, polycarbonate resin, and the like.
塗布後の対象物の加圧下における加熱は、通常の熱盤プ
レス、加熱ロールプレスなどを用いて行なわれる。After coating, the object is heated under pressure using a conventional hot plate press, heated roll press, or the like.
加圧・加熱条件はつぎのとおりである。The pressurization and heating conditions are as follows.
ａ）圧力＝５堅佃以上。５陪保未満では塗膜内に混入し
た気泡が抜は切らないので、均一な平滑面が得られない
。ただし圧力を極端に高くしても、塗明性が著しく向上
することはないので、圧力は通常約１００ ＫＳＭｃＪ
以下である。a) Pressure = 5 or more. If it is less than 5 degrees, air bubbles mixed in the coating film will not be removed, and a uniform and smooth surface will not be obtained. However, even if the pressure is extremely high, coating properties will not be significantly improved, so the pressure is usually about 100 KSMcJ.
It is as follows.
ｂ）温度＝６０℃以上。６０℃未満では塗膜の１度がほ
とんど低下しない。ただし塗装対象物が熱可塑性樹脂よ
りなるものである場合には、加熱温度はその形成温度以
下である。したがって加熱温度範囲の上限は樹脂の種類
によって異なる。たとえば塗装対象物が硬質塩化ビニル
のシートであってこれを用いて積層品を作る場合には、
これを積層プレス湿度である約１７０℃以上に加熱する
と、樹脂が軟化して、均一な厚さの積層品が得られない
上に樹脂が色焼けを生じる。したがってこの場合、加熱
温度は約１７０℃以下である。b) Temperature = 60°C or higher. When the temperature is lower than 60°C, the 1 degree of the coating film hardly decreases. However, if the object to be coated is made of thermoplastic resin, the heating temperature is below its formation temperature. Therefore, the upper limit of the heating temperature range varies depending on the type of resin. For example, if the object to be painted is a hard vinyl chloride sheet and a laminate is made from it,
If this is heated to a temperature higher than about 170° C., which is the lamination press humidity, the resin will soften, making it impossible to obtain a laminate of uniform thickness, and causing discoloration of the resin. Therefore, in this case, the heating temperature is about 170°C or less.
この発明による加圧加熱処理の結果、塗膜の１度が大幅
に低下する。この理由は、確たるものではないが、つぎ
のように考えられる。すなわち塗膜は熱可塑性樹脂をベ
ースとするので、これを加熱すると、塗膜は軟化する。As a result of the pressure and heat treatment according to the present invention, the 1 degree of the coating film is significantly reduced. Although the reason for this is not certain, it is thought to be as follows. That is, since the coating film is based on a thermoplastic resin, heating it softens the coating film.
この状態で塗膜を加圧すると、塗膜表面部に存在してい
た導電性微粉末が軟化塗膜内に押込まれる。その結果塗
膜表面が全体に均一な平滑面となり、１度が低下する。When the coating film is pressurized in this state, the conductive fine powder present on the surface of the coating film is pushed into the softened coating film. As a result, the surface of the coating film becomes a uniform and smooth surface, and the temperature decreases by 1 degree.
また塗膜の密着性が改良される理由は、塗膜の加圧加熱
によって塗膜が脱湿および脱気せられるためと考えられ
る。The reason why the adhesion of the coating film is improved is thought to be that the coating film is dehumidified and degassed by pressurizing and heating the coating film.
つぎにこの発明の実施例をいくつか挙げる。Next, some examples of this invention will be listed.
たたしこれらはいずれも例示的なものであって、この発
明を限定するものではない。However, these are merely illustrative and do not limit the invention.
実施例１
透明ポリカーボネート樹脂よりなる厚さ３．０ｍｍの基
板の片面に、三菱金属株式会社製の「透明静電気防止塗
料」（商品記号ＴＥＰ−３０）をロールコータ−法で厚
さ１．０μに塗布した。Example 1 "Transparent antistatic paint" (product code: TEP-30) manufactured by Mitsubishi Metals Corporation was coated on one side of a 3.0 mm thick substrate made of transparent polycarbonate resin using a roll coater method to a thickness of 1.0 μm. Coated.
ついで塗布後の基板を常温で１時間放置して塗布層を硬
化させ、塗膜を形成した。こうして塗装製品Ａを得た。The coated substrate was then left at room temperature for 1 hour to cure the coated layer and form a coating film. In this way, a coated product A was obtained.
また、」二記と同じ手法で基板の片面に塗膜を形成し、
ついで第１図に示すように、塗膜（１１）を上にして基
板（鴎を上下一対の鏡面板（＋３）（１４）の間しこ配
し、基板（１２）と上部鏡面板（１３）の間に鏡面板保
護フィルム（１５）を９配した。この状態て塗膜（＝Ｊ
き基板（１２）を上下一対の熱盤（１６！（１７）によ
って、圧力−５０Ｋｒｄて濡度二１００℃で１０分間加
圧加熱した。In addition, a coating film was formed on one side of the substrate using the same method as in Section 2,
Next, as shown in Figure 1, with the coating film (11) facing upward, the substrate (the seaweed) is placed between the pair of upper and lower mirror plates (+3) (14), and then the substrate (12) and the upper mirror plate (13) are placed. ) were arranged with 9 specular plate protective films (15) between them.In this state, the coating film (=J
The substrate (12) was heated under pressure of -50 Krd and wetness of -100° C. for 10 minutes using a pair of upper and lower heating plates (16! (17)).
こうして塗装製品ａ′３）を得た。In this way, a coated product a'3) was obtained.
」二記塗装製品ＩＡ）（ｆ３）について、歩度、表面抵
抗値および塗膜密着性をそれぞれｆｉｌｌ定した。結果
を表１に示す。The fill rate, surface resistance value, and coating film adhesion of the coated product IA) (f3) described in Section 2 were determined. The results are shown in Table 1.
表 １
×）塗膜密着性はいわゆる基板目テストによって測定し
た。すなわち各塗装製品を６０゜Ｃの温水に５日間浸漬
した後、塗膜に１００個の格子目状のカットを入れ、塗
膜に接着テープを貼着して、同テープを製品から引き離
したときに、基板から剥離した塗膜カットの個数を数え
た。Table 1 ×) Coating film adhesion was measured by a so-called substrate grain test. That is, after each painted product is soaked in warm water at 60°C for 5 days, 100 grid-like cuts are made in the paint film, adhesive tape is applied to the paint film, and the tape is separated from the product. Next, the number of paint film cuts that had peeled off from the substrate was counted.
表１から明らかなように、塗装製品の）は帯電防止性を
保持したまま、優れた透明性および塗膜密着性を発揮し
た。As is clear from Table 1, the coated product () exhibited excellent transparency and film adhesion while maintaining antistatic properties.
実施例２
基板として透明ポリカーボネート樹脂板の代わりに透明
ポリ塩化ビニル樹脂板を用いる点を除いて、実施例１と
同じ手法で基板に塗膜を形得られた塗装製品について歩
度および表面抵抗値を測定した。結果を表２に示す。Example 2 The rate and surface resistance values were measured for a coated product in which a coating film was formed on a substrate using the same method as in Example 1, except that a transparent polyvinyl chloride resin plate was used instead of a transparent polycarbonate resin plate as the substrate. It was measured. The results are shown in Table 2.
表２から明らかなように、塗装製品は特に圧力５〜１０
０階個、温度６０〜１７０℃の範囲で加圧加熱せられた
場合、帯電防止性を保持したままで、優れた透明性を発
揮した。As is clear from Table 2, the coating products are particularly sensitive to pressures of 5 to 10
When heated under pressure at a temperature in the range of 60 to 170°C, it exhibited excellent transparency while maintaining antistatic properties.
実施例３
透明ポリ塩化ビニル樹脂よりなる厚さ０．０５ｍｍのフ
ィルムの片面に、実施例１と同じ手法によって塗膜を形
成した。ついで第２図に示すように、塗膜（２１）を上
にしてフィルムＣ２１を上下一対の鏡面板（２３＋ ０
４１の間に配し、フィルム（２２）と上部鏡面板□）の
間に鏡面保護フィルム（ハ）を配するとともに、フィル
ム（ハ）と下部鏡面板（２４）の間に透明ポリ塩化ビニ
ル樹脂よりなる厚さ０．５ ｍｍのシート（２８１６枚
を配した。この状態で、塗膜伺きフィルムを上下一対の
熱盤（イ）□□□によって、圧力＝３０に９Ａで温度＝
１７０℃で１０分間加圧加熱した。Example 3 A coating film was formed on one side of a 0.05 mm thick film made of transparent polyvinyl chloride resin by the same method as in Example 1. Next, as shown in FIG. 2, the film C21 is placed between a pair of upper and lower mirror plates (23+0
41, and a mirror protective film (c) is placed between the film (22) and the upper mirror plate □), and a transparent polyvinyl chloride resin is placed between the film (c) and the lower mirror plate (24). 0.5 mm thick sheets (2816 sheets) were arranged. In this state, the coating film was heated at a pressure of 30 and a temperature of 9 A using a pair of upper and lower heating plates (A) □□□.
The mixture was heated under pressure at 170° C. for 10 minutes.
こ）して厚さ３．０ ｍｍの塗装積層製品（Ｃ）を得た
。A coated laminated product (C) with a thickness of 3.0 mm was thus obtained.
また比較のために、上記フィルムに」１記シー１−６枚
を単に貼合せただけの県２積層製品σ〕）およびこの貼
尤積層製品０）に」１記と同し手法で塗膜を形成した塗
装貼着積層製品但）を製作した。In addition, for comparison, a coating film was applied to the above film using the same method as described in 1. A paint-bonded laminated product was produced.
これら積層製品（Ｃ） ＣＤ）但）について、１度およ
び表面抵抗値をそれぞれ測定した。結果を表３に示す。Regarding these laminated products (C), CD), and surface resistance values were measured, respectively. The results are shown in Table 3.
表 ３
表３から明らかなように、この発明にょって得られた塗
装積層製品は、帯電防止性を保持したままで、優れた透
明性を発揮した。Table 3 As is clear from Table 3, the coated laminated product obtained according to the present invention exhibited excellent transparency while maintaining antistatic properties.
実施例４
第３図において、透明ポリ塩化ビニル樹脂よすする厚さ
０．０５ ｍｍのロール状フィルム（３１）を上下一対
の塗装ロール（３２１（３３）の間に通してフィルム（
３１）の」二面に塗膜（詞を形成した。ついでフィルム
（３１）を上下一対のヒータ（ト）（ｙ３）の間に通し
、さらに上下一対の加圧ロール（３７１（３８）の間に
通して、塗膜付きフィルムを加熱加圧した。こうして塗
装製品「）を得た。Example 4 In FIG. 3, a roll-shaped film (31) made of transparent polyvinyl chloride resin and having a thickness of 0.05 mm is passed between a pair of upper and lower coating rolls (321 (33)) to coat the film (
The film (31) was then passed between a pair of upper and lower heaters (g) (y3), and then passed between a pair of upper and lower pressure rolls (371 (38)). The coated film was heated and pressurized by passing it through.A coated product ``)'' was obtained in this way.
実施例５
透明ポリ塩化ビニル樹脂よりなる厚さ０．０５調の帯状
フィルムの片面に、実施例１と同じ手法によって塗膜を
形成して、フィルムをロール状に巻取った。ついで第４
図に示すように、ロール（４１）から引出した塗膜（４
７Ｊ付きフィルム（４３）と、押出装置（４４）から押
出した加熱状態の透明ポリ塩化ビニル樹脂より、なる厚
さ０．５πｍのシート（４５）とを、フィルム（４３）
の非塗装面にシー） （４５）が来るようにして重ねて
、上中下の艶付ロール＋４６） （４η（４８）の間に
通した。こうして塗装積層製品（Ｇ）を得た。Example 5 A coating film was formed on one side of a 0.05-tone strip film made of transparent polyvinyl chloride resin by the same method as in Example 1, and the film was wound into a roll. Then the fourth
As shown in the figure, the coating film (4) pulled out from the roll (41)
A film (43) with 7J and a sheet (45) with a thickness of 0.5πm made of heated transparent polyvinyl chloride resin extruded from an extrusion device (44).
The sheets were stacked so that the sheet (45) was on the non-painted surface of the rolls, and passed between the upper, middle and lower gloss rolls +46) (4η (48). In this way, a painted laminated product (G) was obtained.
以上のとおりで、この発明の塗膜形成方法によれば、熱
可塑性樹脂と導電性微粉末を主成分とする塗料を対象物
に塗布した後、塗膜を有する対象物を加圧下に加熱する
ので、塗膜の帯電防止性を保持したままで、塗膜の１度
を低下せしめるとともに、塗膜の密着性を向上させるこ
とができる。したがってこの発明によれば、透明性およ
び色調が損われることがなく、かつ長期にわたって剥離
するおそれのない塗膜を形成することができる。As described above, according to the coating film forming method of the present invention, after applying a coating material mainly composed of a thermoplastic resin and conductive fine powder to an object, the object having the coating film is heated under pressure. Therefore, while maintaining the antistatic property of the coating film, it is possible to reduce the degree of 1 degree of the coating film and improve the adhesion of the coating film. Therefore, according to the present invention, it is possible to form a coating film that does not lose its transparency and color tone and is free from the risk of peeling off over a long period of time.
第１図から第４図はいずれもこの発明の実施例における
加圧加熱工程を示す概略図である。
（＋６） Ｑ７） ＋２６） （２７）・・・熟語、（
１１）（２旧３４）卿・・・塗膜、（１１）・・・・基
板、（２２１＋３１＋ ＋４９）・・・フィルム、■）
＋３６）・・・ヒータ、（３７） ＋３８１・・・加
圧ロール、（４４１・・・押出装置、（４６）＋４７１
＋４８）・・・艶伺ロール。
以 上
手続補正書
昭和５８イ１６４ 月−シロ
１、事件の表示 １１１１和５８年特許願第５２０８
４ 号２ 発明の名称 透明導電性塗膜の形成方法３
、補正をする者
下件との関係 特γ「出願人
４、代 理 人
５ 補正命令の日付 昭和 年 月 日６
補正（こより増加する発明の数
７、補正の対象 明細書の発明の詳細な説明の欄８、補
５１゛の内容
關！］Ｒ５９−１７７８１３（６）
補正の内容
（１）明細書２頁下から２行日「帯電間５イヒ竹三」を
「帯電防止性」に訂正する。
（２） 同３頁下から４行日「アク１ノロニド１ノ」
を「アクリ」に訂正する。
（３） 同５頁１行目「カーボネート」を「カーボネ
ート」に訂正する。
（４）同５頁１０行「塗明性」を「透明性」（こｇ１正
する０
（５）同１２頁表３中の最右欄
以 上
手続補正書（方式）
１、事件の表示 昭和５８年持重、Ｊ１願第５２０８
４ 号２、発明の名称 透明導電性塗膜の形成方法
３、補正をする者
事件との関係 特Ｉ「出願人
４、代 理 人
外 ４ 名
５、補正命令の日付 昭和５８年６ 月２８［］６
、補正により増加する発明の数
７、補正の対象 明細書の発明の詳細な説明の欄８、
補正の内容
別 添
補 正 の 内 容
１．明細書５８頁の表１を
「
」
に訂正する。
２、明細書１０頁の表２を
以下余白
に訂正する。
３、明細書１２頁の表３を
「
」
に訂正する。
以 上FIG. 1 to FIG. 4 are all schematic diagrams showing the pressurizing and heating process in an embodiment of the present invention. (+6) Q7) +26) (27)...idiom, (
11) (2 former 34) Sir...paint film, (11)...substrate, (221+31+ +49)...film, ■)
+36)... Heater, (37) +381... Pressure roll, (441... Extrusion device, (46) +471
+48)...Ashiki roll. Written amendment to the above procedure, 1982, April 1, 1973, Case No. 1111, Patent Application No. 5208, 1972
4 No. 2 Title of the invention Method for forming transparent conductive coating film 3
, Relationship between the person making the amendment and the case: Applicant 4, agent 5 Date of amendment order: Showa year, month, day, 6
Amendment (number of inventions increased by 7, subject of amendment, detailed explanation column 8 of the specification, contents of supplement 51!) R59-177813 (6) Contents of amendment (1) Bottom of page 2 of the specification From the 2nd line from the bottom, ``Charging 5 Ihi Takezo'' is corrected to ``Antistatic property''.
is corrected to "Akuri". (3) On page 5, line 1, "carbonate" is corrected to "carbonate." (4) On page 5, line 10, “paintability” should be changed to “transparency” (Kg1 Correct 0 (5) From the rightmost column of Table 3 on page 12, above. Written amendment to the procedure (method) 1. Indication of the case Mochiju, J1 Application No. 5208 in 1982
4 No. 2, Title of the invention Method for forming a transparent conductive coating film 3, Relationship with the case of the person making the amendment Special I "Applicant 4, non-representative 4 person 5, Date of amendment order June 28, 1982" []6
, the number of inventions increased by the amendment 7, the subject of the amendment Detailed explanation of the invention in the specification column 8,
Contents of attached amendments by content of amendments 1. Table 1 on page 58 of the specification is corrected to "". 2. Table 2 on page 10 of the specification is corrected in the following margin. 3. Table 3 on page 12 of the specification is corrected to "".that's all
Claims (2)
を用いて透明導電性塗膜を形成するに当り、同塗料を対
象物に塗布した後、塗膜を有する対象物を加圧下に加熱
することを特徴とする透明導電性塗膜の形成方法。(1) When forming a transparent conductive coating film using a paint whose main components are thermoplastic resin and conductive fine powder, after applying the paint to the object, the object with the coating film is placed under pressure. 1. A method for forming a transparent conductive coating film, the method comprising heating the film to a temperature of .
０℃以上である特許請求の範囲第（１）項記載の方法。(2) Pressure heating conditions are 5 katsukuta or higher and temperature -6
The method according to claim (1), wherein the temperature is 0°C or higher.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5208483A JPS59177813A (en) | 1983-03-28 | 1983-03-28 | Method of forming transparent conductive coating film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5208483A JPS59177813A (en) | 1983-03-28 | 1983-03-28 | Method of forming transparent conductive coating film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59177813A true JPS59177813A (en) | 1984-10-08 |
| JPH0372169B2 JPH0372169B2 (en) | 1991-11-15 |
Family
ID=12904957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5208483A Granted JPS59177813A (en) | 1983-03-28 | 1983-03-28 | Method of forming transparent conductive coating film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59177813A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59215326A (en) * | 1983-05-23 | 1984-12-05 | Takiron Co Ltd | Production of antistatic synthetic resin sheet |
| JP2000021387A (en) * | 1998-07-01 | 2000-01-21 | Mitsubishi Cable Ind Ltd | Sheet type battery |
| WO2001048764A1 (en) * | 1999-12-28 | 2001-07-05 | Tdk Corporation | Transparent conductive film and production method thereof |
| JP2001328195A (en) * | 2000-05-19 | 2001-11-27 | Tdk Corp | Functional film |
| JP2002127327A (en) * | 2000-10-30 | 2002-05-08 | Tsutsunaka Plast Ind Co Ltd | Polyvinyl chloride resin sheet excellent in surface property and its manufacturing method |
| EP2567811A1 (en) * | 2000-05-19 | 2013-03-13 | TDK Corporation | Functional film having functional layer and article provided with the functional layer |
| JP2014172290A (en) * | 2013-03-08 | 2014-09-22 | Nitto Denko Corp | Method for manufacturing a multilayer laminate film |
| JP2014177014A (en) * | 2013-03-14 | 2014-09-25 | Nitto Denko Corp | Method for producing multilayer laminated film |
Citations (18)
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|---|---|---|---|---|
| JPS49117571A (en) * | 1973-03-13 | 1974-11-09 | ||
| JPS5036574A (en) * | 1973-08-06 | 1975-04-05 | ||
| JPS5039510A (en) * | 1973-08-13 | 1975-04-11 | ||
| JPS5098988A (en) * | 1974-01-02 | 1975-08-06 | ||
| JPS5120270A (en) * | 1974-02-15 | 1976-02-18 | Dainippon Toryo Kk | |
| JPS5155381A (en) * | 1974-11-12 | 1976-05-15 | Kureha Chemical Ind Co Ltd | SEKISOHORIMECHIRUMETAAKURIREETOBAN |
| JPS5222380A (en) * | 1975-08-12 | 1977-02-19 | Seiichi Kato | Fabricating method of lantern |
| JPS53125469A (en) * | 1977-04-08 | 1978-11-01 | Toppan Printing Co Ltd | Manufacture of molded articles from powdered thermoplastic resin and metal powder |
| JPS541349A (en) * | 1977-06-06 | 1979-01-08 | Ota Toshuki | Coating method |
| JPS5463397A (en) * | 1977-10-31 | 1979-05-22 | Showa Electric Wire & Cable Co | Method of forming semiconductive layer onto rubber or plastic insulator |
| JPS54113640A (en) * | 1978-02-24 | 1979-09-05 | Mitsubishi Chem Ind Ltd | Preparation of electrically-conductive synthetic resin composition |
| JPS54117573A (en) * | 1978-03-06 | 1979-09-12 | Honshu Paper Co Ltd | Method of making antistatic and biaxially oriented polypropyrene composite film |
| JPS5785866A (en) * | 1980-11-18 | 1982-05-28 | Mitsubishi Metal Corp | Antistatic transparent paint |
| JPS57101302A (en) * | 1980-12-15 | 1982-06-23 | Mitsubishi Metal Corp | Chargeproof heat resistant plastic composition |
| JPS57158906A (en) * | 1981-03-25 | 1982-09-30 | Mitsubishi Petrochemical Co | Semiconductive resin composition |
| JPS5829658A (en) * | 1981-08-13 | 1983-02-21 | 太平化学製品株式会社 | Semi-conductive plastic structure material which can freely be colored |
| JPS5995964A (en) * | 1982-11-24 | 1984-06-02 | Tokyo Ink Kk | Method and device for applying transparent conductive film |
| JPS59149605A (en) * | 1983-02-15 | 1984-08-27 | コニカ株式会社 | Method of producing transparent conductor |
-
1983
- 1983-03-28 JP JP5208483A patent/JPS59177813A/en active Granted
Patent Citations (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49117571A (en) * | 1973-03-13 | 1974-11-09 | ||
| JPS5036574A (en) * | 1973-08-06 | 1975-04-05 | ||
| JPS5039510A (en) * | 1973-08-13 | 1975-04-11 | ||
| JPS5098988A (en) * | 1974-01-02 | 1975-08-06 | ||
| JPS5120270A (en) * | 1974-02-15 | 1976-02-18 | Dainippon Toryo Kk | |
| JPS5155381A (en) * | 1974-11-12 | 1976-05-15 | Kureha Chemical Ind Co Ltd | SEKISOHORIMECHIRUMETAAKURIREETOBAN |
| JPS5222380A (en) * | 1975-08-12 | 1977-02-19 | Seiichi Kato | Fabricating method of lantern |
| JPS53125469A (en) * | 1977-04-08 | 1978-11-01 | Toppan Printing Co Ltd | Manufacture of molded articles from powdered thermoplastic resin and metal powder |
| JPS541349A (en) * | 1977-06-06 | 1979-01-08 | Ota Toshuki | Coating method |
| JPS5463397A (en) * | 1977-10-31 | 1979-05-22 | Showa Electric Wire & Cable Co | Method of forming semiconductive layer onto rubber or plastic insulator |
| JPS54113640A (en) * | 1978-02-24 | 1979-09-05 | Mitsubishi Chem Ind Ltd | Preparation of electrically-conductive synthetic resin composition |
| JPS54117573A (en) * | 1978-03-06 | 1979-09-12 | Honshu Paper Co Ltd | Method of making antistatic and biaxially oriented polypropyrene composite film |
| JPS5785866A (en) * | 1980-11-18 | 1982-05-28 | Mitsubishi Metal Corp | Antistatic transparent paint |
| JPS57101302A (en) * | 1980-12-15 | 1982-06-23 | Mitsubishi Metal Corp | Chargeproof heat resistant plastic composition |
| JPS57158906A (en) * | 1981-03-25 | 1982-09-30 | Mitsubishi Petrochemical Co | Semiconductive resin composition |
| JPS5829658A (en) * | 1981-08-13 | 1983-02-21 | 太平化学製品株式会社 | Semi-conductive plastic structure material which can freely be colored |
| JPS5995964A (en) * | 1982-11-24 | 1984-06-02 | Tokyo Ink Kk | Method and device for applying transparent conductive film |
| JPS59149605A (en) * | 1983-02-15 | 1984-08-27 | コニカ株式会社 | Method of producing transparent conductor |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59215326A (en) * | 1983-05-23 | 1984-12-05 | Takiron Co Ltd | Production of antistatic synthetic resin sheet |
| JPS6333779B2 (en) * | 1983-05-23 | 1988-07-06 | Takiron Co | |
| JP2000021387A (en) * | 1998-07-01 | 2000-01-21 | Mitsubishi Cable Ind Ltd | Sheet type battery |
| WO2001048764A1 (en) * | 1999-12-28 | 2001-07-05 | Tdk Corporation | Transparent conductive film and production method thereof |
| JP2001328195A (en) * | 2000-05-19 | 2001-11-27 | Tdk Corp | Functional film |
| EP2567811A1 (en) * | 2000-05-19 | 2013-03-13 | TDK Corporation | Functional film having functional layer and article provided with the functional layer |
| JP2002127327A (en) * | 2000-10-30 | 2002-05-08 | Tsutsunaka Plast Ind Co Ltd | Polyvinyl chloride resin sheet excellent in surface property and its manufacturing method |
| JP2014172290A (en) * | 2013-03-08 | 2014-09-22 | Nitto Denko Corp | Method for manufacturing a multilayer laminate film |
| JP2014177014A (en) * | 2013-03-14 | 2014-09-25 | Nitto Denko Corp | Method for producing multilayer laminated film |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0372169B2 (en) | 1991-11-15 |
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