JPS5917425A - System for automatically separating and stacking pallets - Google Patents
System for automatically separating and stacking palletsInfo
- Publication number
- JPS5917425A JPS5917425A JP12602382A JP12602382A JPS5917425A JP S5917425 A JPS5917425 A JP S5917425A JP 12602382 A JP12602382 A JP 12602382A JP 12602382 A JP12602382 A JP 12602382A JP S5917425 A JPS5917425 A JP S5917425A
- Authority
- JP
- Japan
- Prior art keywords
- pallet
- arm
- pallets
- cart
- separator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
- B65G59/00—De-stacking of articles
- B65G59/06—De-stacking from the bottom of the stack
- B65G59/061—De-stacking from the bottom of the stack articles being separated substantially along the axis of the stack
- B65G59/062—De-stacking from the bottom of the stack articles being separated substantially along the axis of the stack by means of reciprocating or oscillating escapement-like mechanisms
- B65G59/063—De-stacking from the bottom of the stack articles being separated substantially along the axis of the stack by means of reciprocating or oscillating escapement-like mechanisms comprising lifting means
Landscapes
- De-Stacking Of Articles (AREA)
- Stacking Of Articles And Auxiliary Devices (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は瓦等の成型素地を整列載置したパレットを台車
から分離せしめ、又は台単に段積みせしめる自動パレッ
ト分離システム及び積み重ねシステムに関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an automatic pallet separation system and a stacking system for separating pallets on which molded materials such as roof tiles are placed in order from a cart or stacking them on a platform.
従来屋根瓦等の成型フ゛ラントの乾燥工程において成型
素地が整列戦行されたパレットを数段積みせしめた乾燥
台車から各パレットを分離せしめるに1づ、第1図に図
1示する様にパレットを挾脱せしめるフランツ装置を昇
降自在に装備せしめたトランスカーを乾燥台車とコンベ
アとの間で往復走行させ、上段のパレy)から一段ずつ
コンベア上に分離移載せしめる様にしていた。しかしな
がらこの方式ではクランプ装置の昇降ストロークが長い
と共にトランスカーの往復走行にも時間を要し、限られ
た時間内にパレットの分離を完了せしめるにはクランプ
装置及びトランスカーを高速制御しなければ々らず1、
この場合成型素地を破損せしめる恐れがあり、又かかる
方式の装置を設置するには広いスペースを要する等の欠
点を有していた。Conventionally, in the drying process for molded materials such as roof tiles, each pallet is separated from a drying cart in which several stacks of pallets on which molded materials are aligned are stacked.1. A transcar equipped with a Franz device for lifting and lowering the drying cart was moved back and forth between the drying cart and the conveyor, and the upper pallet was separated and transferred onto the conveyor one by one. However, with this method, the lifting stroke of the clamping device is long, and the reciprocating movement of the transcar also takes time, and it is necessary to control the clamping device and transcar at high speed in order to complete the separation of pallets within a limited time. Zu1,
In this case, there is a risk of damaging the molded substrate, and there are other drawbacks such as requiring a large space to install such a device.
又逆に乾燥台車にパレットを段積みせしめる工程におい
ても固りの方式で行っているため同様に時間と空間に無
駄を生じていた。Conversely, the process of stacking pallets on a drying cart is also carried out in a solid manner, which similarly results in wasted time and space.
本発明はかかる欠点に鑑み、回動手段によりパレy)の
端部下面に係脱制御されると共に昇降手段によりパレッ
トを昇降制御せしめるアームを有する分離機、積み車ね
機と、昇降手段により昇降制御されて台車上から又は台
車上ヘパレy)を移送せしめるチ・−ンコンベアにより
パレットを自動的に分離又は積み重ねるシステムを提供
して上記欠点を解消せんとしたものにして、以下本発明
の一実施例を図面に基づいて説明すると、
(1)は台車であり、所定の軌道に敷設されたレー/l
/ (2)(2)’上をプッシャー(8)により移動制
御され、この台車(1)上には乾燥後の成型素地Wを起
立状態で整列載置せしめたパレット(4)(4)′・・
・が複数段に段積みされている。In view of such drawbacks, the present invention provides a separator and a stacking machine having an arm that is controlled to engage and disengage from the lower surface of the end of the pallet by a rotating means and that lifts and lowers the pallet by a lifting means. It is an object of the present invention to overcome the above-mentioned drawbacks by providing a system for automatically separating or stacking pallets by means of a chain conveyor that transfers pallets from or on a trolley in a controlled manner. To explain an example based on a drawing, (1) is a bogie, and a rail/l truck laid on a predetermined track.
Pallets (4) (4)' whose movement is controlled by a pusher (8) on (2) (2)', and on which the dried molded materials W are placed in an upright position on this trolley (1)・・・
- are stacked in multiple tiers.
(6)は台車(1)の走行軌道中に設置せしめた分離機
であり、搬送されて来る台車(1)を収容せしめる様に
フレーム(6)を構成し、該フレーム(6)の両側には
支持枠(γ) (7)’を上下摺動自在に取付けると共
に該支持枠(7) (7)’の前後端部にはパレット(
4)(4)′・・・を支持せしめるアーム(8) (8
1’・・・を回動自在に取付け、該アーム(81(8)
’・・・をフレーム(6)の上部に設けた適宜昇降手段
(4)により支持枠(7) (7)’を介して昇降制御
せしめると共に支持枠(γ)(γ)′に取付けた適宜回
動手段CB)によりアーム(8) (8)’・・・をパ
レット(4)(4)′・・・に干渉しない外方位置とパ
レット(4)(4)′・・・の端部下面に対向位置する
内方位置との間を係脱自在に回動制御せしめる様に成し
ている。(6) is a separator installed in the running track of the trolley (1), and has a frame (6) configured to accommodate the transported trolley (1), and has a frame (6) on both sides of the frame (6). The support frame (γ) (7)' is attached so as to be able to slide up and down, and pallets (
4) Arm (8) (8) that supports (4)'...
1'... is attached rotatably, and the arm (81 (8)
'... is controlled to rise and fall via the support frame (7) (7)' by an appropriate elevating means (4) provided on the upper part of the frame (6), and an appropriate elevating means (4) installed on the support frame (γ) (γ)' Rotating means CB) allows the arm (8) (8)'... to be positioned at an outside position where it does not interfere with the pallet (4) (4)'... and the end of the pallet (4) (4)'... It is configured to be rotatably controlled to be freely engaged and disengaged between the inner position facing the lower surface and the inner position.
m (9’l’はチーーンコンベアであり、分離機(5
)内に搬入された台車(1)の下段のパレット(4)の
両端下方に対向位置せしめると共に適宜昇降手段(0に
より昇降制御せしめて上昇時パレット(4)を持ち上げ
て後続の搬送コンベア00)へ移送せしめる様に成して
いる。m (9'l' is a chain conveyor, separator (5
) is placed opposite both ends of the lower pallet (4) of the trolley (1) carried into the carriage (1), and is appropriately controlled by a lifting means (0) to lift the pallet (4) when ascending and move the pallet (4) to the subsequent conveyor 00. It is designed so that it can be transferred to
尚α1)は分離機(6)内に搬入された台車(1)を固
定せしめるクランプ装置である。Note that α1) is a clamping device for fixing the cart (1) carried into the separator (6).
次に自動パレット分離システムの作用について説明する
と、乾燥工程完了後の成型素地Wを載置したパレット(
4)(4)′・・・が段積みされた台車(1)をプツシ
ff−+81により分離機(6)内に搬入し、定位置に
おいてクランプ装置α℃により台車(1)を固定せしめ
る。Next, to explain the function of the automatic pallet separation system, the pallet on which the molded material W after the drying process is completed (
4) The cart (1) stacked with (4)' is carried into the separator (6) by the pusher ff-+81, and the cart (1) is fixed at a fixed position by the clamp device α°C.
尚分離機(5)におけるアームf8) (8)’・・・
は最下降位置にあると共に外方に回動位置しているO
次にアーム(8) (8)’・・・を内方へ回動せしめ
て′2i’;目のパレット(4)の端部下面に対向位置
せしめた後、アーム(8j (8)’・・・を1若干上
昇せしめて2段目以上のパレツI−(4)′(4デ・・
・を持ち上げ、続いてチェーンコンベア(9)(9)′
を上昇せしめて台車(1)上に残った下1段のノ(しy
)(4)を持ち上げると共に搬送コンベア(10)へ移
送せしめて更に次のヌテーシ■ンへ移送せしめる。そし
てパレット(4)が移送された後チェーンコンベア(9
)(9)′を下降すると共にアーム(8) (8)’を
下降せしめて雑りのパレy)(4)′(4y・・・を一
旦台車(1)上に載置せしめ、続いてアーム(8) (
8)’・・・を外方へ回動せしめてノ(レット(4)′
から離胛、せしめた後アーム(8) (8)’・・・を
上昇し、再び内方へ回動せしめて2段目のノ(レット(
4デの端部下面に係合せしめると共に上昇せしめて下1
段のパレット(4)′を残して他のJりV 2 ト(4
ゲ(4Y′・・・を若干持ち上げ、再びチ・−ンコンベ
ア(9”l (9)′を上昇せしめて下1段のパレット
(4)′を移送せしめ、以上の動作をパレット(4)(
4)′・・・が々くなる迄反復せしめた後台車(1)を
入れ替えるのである。In addition, the arm f8) (8)'... in the separator (5)
is in the lowest position and rotated outward. Next, rotate the arm (8) (8)'...inward and '2i'; the end of the eye pallet (4). After placing the arm (8j (8)') in a position facing the lower surface, slightly raise the arm (8j (8)'...
・Lift up the chain conveyor (9) (9)′
The lower 1st stage remaining on the trolley (1) was raised.
)(4) is lifted and transferred to the conveyor (10), and further transferred to the next feeding scene. After the pallet (4) is transferred, the chain conveyor (9)
)(9)' is lowered, and the arm (8) (8)' is lowered to temporarily place the miscellaneous pallet y)(4)'(4y... on the trolley (1), and then Arm (8) (
8) Rotate the ``...'' outward (let (4)'
After separating and letting the arm (8) (8)'... rise, rotate it inward again and press the second stage (let).
Engage with the lower surface of the end of 4D and raise it.
Leaving the pallet (4)' on the shelf, move the other JR V 2 (4)
Slightly lift the chain conveyor (9"l (9)') to transport the lower pallet (4)', and repeat the above operation with the pallet (4) (
4)'... Replace the rear truck (1) that has been repeated until it becomes too loud.
次に第4図、第5図に図示する他一方の発明である自動
パレット積み重ねシヌテムについて説明すると、第1の
発明と同様にレール(2)(121’上をプッシャー(
1B)により搬送される台車α葡と、昇降手段囚′、回
動手段(B)′により支持枠(15) (15)’を介
してフレーム06)に昇降及び回動自在に取付けたアー
ムfi71 (17)’・・・を有する積み重ね機μs
)と、昇降手段(Q′により昇降制御されるチーーンコ
ンベアα9)α旬′と、成型後の成型素地W′を整列載
置せしめたパレット(イ)□□□′・・・を搬送する搬
送コンベア(21)と、積み重ね機Q8)内に搬入され
た台車04)を固定するクランプ装置(22)より成っ
ている。Next, the other invention, the automatic pallet stacking system, shown in FIGS. 4 and 5 will be explained. Similar to the first invention, the pusher (
The arm fi71 is attached to the frame 06) via the support frame (15) (15)' by the lifting means (B)' and the rotating means (B)' so that it can be raised, lowered, and rotated. (17) Stacking machine μs with '...
), a lifting means (a chain conveyor α9 whose elevation is controlled by Q'), and a conveyor for transporting pallets (A) □□□'... on which the molded blanks W' after molding are arranged and placed. It consists of a conveyor (21) and a clamping device (22) for fixing the cart 04) carried into the stacking machine Q8).
次に作用について説明すると、先ず空の台車04)をプ
ッシャー08)により積み重ね機(至)内に搬入すると
共に定位置にてクランプ装置面によシ固定せしめ、続い
てチーーンコンベア(19)0α′を上昇せしめて搬送
コンベア(21)から搬送されて来る成型素地W′を載
置したパレット(社)を台車0(転)の上方に移送せし
めた後チェーンコンベア酸0θ)′を下降せしめてパレ
ット(社)を台車a揚上に載置せしめる。Next, to explain the operation, first, the empty cart 04) is carried into the stacking machine (to) by the pusher 08) and fixed to the clamp device surface at a fixed position, and then the chain conveyor (19) 0α' After raising the chain conveyor (21) and transporting the pallet on which the molded material W' carried from the conveyor (21) is placed above the trolley 0 (transfer), the chain conveyor 0θ)' is lowered and the pallet is placed on the pallet. (Company) is placed on the hoisting truck a.
次にアームαη07)′・・・を内方へ回動せしめて台
車04)上のパレット@)の端部下面に対向位置せしめ
た後アーム17)o7)’・・・を若干上昇せしめてパ
レy)(財))を持ち上げ、続いてチェーンコンベアa
鋳α9)′を再び上昇せしめて次のパレy)(2))′
を台車04)の上方に移送した後下降せしめて台車04
)上にパレy)(社)′を載置せしめる。そしてアーム
07)qη′・・・を下降せしめて一番目のパレット(
社)を次のパレット(社)′上に載置せしめ、しかる後
アームロア)α7)′・・・を外方へ回動せしめてパレ
ット@)から離脱せしめた後アーム(1ηαη′・・・
を下降せしめ、再び内方へ回動せしめて2番目のバレy
)(社)′の端部下面に係合せしめ、続いてアームα吟
0η′を上昇せしめてパレット(財))(財))’t[
ち上ケ、再びチェーンコンベア69) 19)’にて次
のパレットホを台車(9)上に移送せしめ、以上の動作
を反復せしめて台車04)上に所定数のバレy)(社)
(社)′・・・を段積みせ1.めだ後台車04)を乾燥
工程へ移送し、次の台車DJと入れ替えるのでちる。Next, the arm αη07)'... is rotated inward to position it opposite the bottom surface of the end of the pallet @) on the trolley 04), and then the arm 17)o7)'... is slightly raised and the pallet y) (Foundation)), then lift the chain conveyor a
Raise the casting α9)' again and start the next pallet y)(2))'
is transferred to the upper part of the trolley 04) and then lowered to the upper part of the trolley 04).
). Then lower arm 07) qη′... and lower the first pallet (
Place the lower arm (1) on the next pallet (1), and then rotate the lower arm (1) α7)' outward to remove it from the pallet (1).
Lower it and rotate it inward again to complete the second barre.
) (corporate)' and then raise the arm αgin0η' to release the pallet (goods)) (goods))'t[
Then, the chain conveyor 69) 19)' again transfers the next pallet onto the trolley (9), and the above operation is repeated to place a predetermined number of pallets on the trolley 04).
(Company) Stack '...1. The Meda rear cart 04) is transferred to the drying process and replaced with the next cart DJ.
要するに本発明は、成型素地M’)を載置せしめたパレ
y)(4)(4)′・・・が段積みされた台車(1)の
走行軌道中に分離機(5)を設け、該分離機(5)は回
動手段の)によりパレy)(4)(4)′・・・の端部
下面に係脱制御されると共に昇降手段(A)によりパレ
ット(4)(4)′・・・を昇降制御するアーム(8)
(8)′・・・を有し、分離機(5)内に搬入された台
車(1)上の2段目のバレy)(4)′の端部下面にア
ーム(8)(8)’・・・を対向せしめると共に該アー
ム(8)(8)′・・・を上昇せしめて下1段の7(レ
フト(4)を残して2段目以上のパレット(4)′(4
ゲ・・・を持ち上げ、続いて下1段のパレット(4)の
両端下方に配設せ1〜めたチェーンコンペア (9’)
(o)’ヲ上Hせしめて下1段のパレット(4)を持
ち上げると共に移送せしめた後チェーンコンペア(9)
(9)’i下降し、続いてアーム(8> (8)’・・
・を下降して残りのパレット(4)(4)′・・・を台
車(1)上に載置せしめた後アーム(8)(8)’・・
・を2段目のパレット(4)′の端部下面に対向せしめ
てパレット(4)′(4ゲ・・・を持ち上げ、以上の動
作を反復せしめてパレット(4)(4)′・・・を分離
せしめる様にしたので、パレy1・(4)(4)′・・
・を1段分離せしめるのにアームf81 (8ビはパレ
ツ1−(4)(4)′・・・の高さに加えて50〜60
%程度のストローク昇降せしめるのみでまいため限られ
た時間内での分離工程において各動作を非常に緩やかに
作動せしめても時(lt1台9に間に合い、急激な動作
による成型素地Wの破損、変形を防止出来、スペース的
にも床面積、高さにおいて効率のよい設計が可能となシ
、又他一方の発明においても同様の効果を奏せしめるこ
とが出来る等その実用的効果甚だ大なるものである。In short, the present invention provides a separator (5) in the running track of a truck (1) on which pallets (4) (4)'... on which molded materials M') are placed are stacked, The separator (5) is controlled to engage and disengage from the bottom surface of the end of the pallet (4) (4)'... by the rotating means (), and the pallet (4) (4) is controlled by the lifting means (A). Arm (8) that controls the elevation of...
(8)'..., and an arm (8) (8) is attached to the bottom surface of the end of the second stage barre (4)' on the trolley (1) carried into the separator (5). '... and raise the arms (8) (8)'... to make the pallets (4)' (4
Lift up the gear, and then place the chain compares (9') below both ends of the lower pallet (4).
(o)' After lifting and transporting the lower pallet (4), chain compare (9)
(9)'i descends, then the arm (8>(8)'...
After lowering the ・ and placing the remaining pallets (4) (4)'... on the trolley (1), the arms (8) (8)'...
・Place it opposite the bottom surface of the end of the second pallet (4)', lift the pallet (4)' (4ge...), repeat the above operation, and lift the pallet (4)(4)'... Since we made it so that .
・In order to separate the
Since it is difficult to move up and down the stroke of about 10%, even if each operation is operated very slowly in the separation process within a limited time (it will be in time for 1 machine 9, the molded substrate W will not be damaged or deformed due to sudden movements). The practical effects of this invention are enormous, such as being able to prevent this, enabling efficient design in terms of space, floor area, and height, and being able to produce similar effects in other inventions as well. be.
(・項は本発明の一実施例を示すものにして、第1図は
従来例を示す図、第2図(、を本発明に係る自動パレッ
ト分離システムを示す図、第3図は分離機の正面図、第
4図?・づ他一方の発明に係る自称カバレット積み重ね
システムを示すl>51 、第5図は積み重ね件の正面
[ン1である。
(1)(14)台J、((+)u)’−・・(2o+(
20+’・−パレット(6)分輛機 (8B8ビ・・・
(17) (1°7)/・・・アーム(9’) (9)
’f19) flQビチェーンコンベア (18)松み
甫ね機具 上
出願人 株式会社
石川時鉄工所
第2図
A
/
第4図
A′
/
第3@l(The sections . and . indicate an embodiment of the present invention, Fig. 1 shows a conventional example, Fig. 2 shows an automatic pallet separation system according to the present invention, and Fig. 3 shows a separator. Figure 4 shows the self-proclaimed coverlet stacking system according to the other invention, and Figure 5 shows the front view of the stacking system. (+)u)'-...(2o+(
20+'・-Pallet (6) Breaker (8B8B...
(17) (1°7)/...Arm (9') (9)
'f19) flQ bichain conveyor (18) Matsumiho kneading equipment Applicant Ishikawaji Iron Works Co., Ltd. Figure 2A / Figure 4A' / Figure 3@l
Claims (2)
れた台車の走行軌道中に分離機を設け、該分離機は回動
手段によυパレットの端部下面に係脱制御されると共に
昇降手段によりパレットを昇降制御するアームを有し、
分離機内に搬入された台車上の2段目のパレットの端部
下面にアームを対向せしめると共に該アームを上昇、1
j−1,めて下1段のパレットを残して2段目以上のパ
レットを持ち上げ、続いて下1段のパレy)の両端下方
に配設せしめたチェーンコンベアを上昇せしめて下1段
のパレy)を持ち上げると共に移送せしめた後チェーン
コンベアを下降し、続いてアー・ムを下降して残りのパ
レy)を台車上に載置せしめた後アームを2段目のパレ
ットの端部下面に対向せしめてパレットを持ち上げ、以
上の動作を反復せしめてパレットを分離せし、める様に
したことを特徴とする自動パレット分離システム0(1) A separator is installed in the running track of a cart on which pallets on which molded substrates are placed are stacked, and the separator is controlled to engage and disengage from the bottom surface of the end of the υ pallet by a rotating means, and is raised and lowered. It has an arm that controls lifting and lowering of the pallet by means,
Place the arm opposite the bottom surface of the end of the second pallet on the cart carried into the separator, and raise the arm.
j-1, lift up the second and higher pallets leaving the bottom one pallet, then raise the chain conveyor placed below both ends of the bottom one pallet After lifting and transferring the pallets, the chain conveyor is lowered, and the arm is then lowered to place the remaining pallets on the cart. An automatic pallet separation system 0 characterized in that the pallet is lifted while facing the pallet, and the above operations are repeated to separate and set the pallet.
ね機は回動手段により成型素地を載置せしめたパレット
の端部下面に係脱制御されると共に昇降手段によりパレ
ットを昇降制御するアームを有し、積み重ね機内に搬入
された台車の上方にチ・−ンコンベアによりパレットを
移送すると共にチェーンコンベアを下降せしめてパレッ
トを台車上に載置せしめ、続いてパレットの端部下面に
アームを対向せしめると共に該アームを上昇せしめてパ
レットを持ち上げ、続いてチェーンコンベアにて次のパ
レットを台車上に移送載置せしめた後アームを下降せし
めて前のパレットを次のパレット上に載置せしめ、続い
てアームを下降せしめて下段のパレットの端部下面に対
向せしめると共に上昇せしめて台車上のパレットを持ち
上げ、以上の動作を反復せしめてパレットを積み重ねる
様にしたことを特徴とする自Mパレット槙み重ねシステ
ム。(2) A stacking machine is provided in the running track of the cart, and the stacking machine is controlled to engage and disengage from the bottom surface of the end of the pallet on which the molded substrates are placed by a rotating means, and an arm that controls the elevation and descent of the pallet by a lifting means. The pallet is transferred by a chain conveyor above the cart carried into the stacking machine, and the chain conveyor is lowered to place the pallet on the cart, and then an arm is placed opposite the bottom surface of the end of the pallet. At the same time, the arm is raised to lift the pallet, and then the next pallet is transferred and placed on the trolley by the chain conveyor, and then the arm is lowered to place the previous pallet on the next pallet, and then The self-M pallet picker is characterized in that the arm is lowered to face the bottom surface of the end of the lower pallet, and then raised to lift the pallet on the cart, and the above operations are repeated to stack the pallets. Layering system.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12602382A JPS5917425A (en) | 1982-07-20 | 1982-07-20 | System for automatically separating and stacking pallets |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12602382A JPS5917425A (en) | 1982-07-20 | 1982-07-20 | System for automatically separating and stacking pallets |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5917425A true JPS5917425A (en) | 1984-01-28 |
Family
ID=14924788
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12602382A Pending JPS5917425A (en) | 1982-07-20 | 1982-07-20 | System for automatically separating and stacking pallets |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5917425A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5226391A (en) * | 1975-08-25 | 1977-02-26 | Mitsubishi Chem Ind Ltd | Catalyst used for production of carboxylic acid ester |
-
1982
- 1982-07-20 JP JP12602382A patent/JPS5917425A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5226391A (en) * | 1975-08-25 | 1977-02-26 | Mitsubishi Chem Ind Ltd | Catalyst used for production of carboxylic acid ester |
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